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DISSERTATION REPORT
ON
MASTERS OF TECHNOLOGY
IN
ENVIRONMENTAL ENGINEERING
By
SHIVANI MAHAR
2017PCE5258
SHIVANI MAHAR
2017PCE5258
My sincere gratitude to Dr. Mahesh Kumar Jat, H.O.D., Civil Engineering Department,
MNIT Jaipur, for giving me the opportunity to complete this dissertation.
I would like to extend my gratitude to the PhD Scholar Miss. Kanika Saxena of Civil
Engineering Department, MNIT Jaipur and Mr. Sadique Ansari Yasin (Lab Technician,
PHE Lab) for their cordial nature and guidance during the course of my work.
Lastly, I would like to express my gratitude to my friends and family for their all-time
availability and useful suggestions during the course of this work.
Shivani Mahar
Environmental Engineering
2017PCE5258
CONTENTS
CHAPTER 1 ........................................................................................................................................ 8
INTRODUCTION ............................................................................................................................... 8
1.1 NEED FOR THE STUDY ....................................................................................................... 8
1.2 NEED FOR THE CONSTRUCTED WETLAND SYSTEM .................................................. 8
1.3 AIM OF THE STUDY............................................................................................................. 9
1.4 OBJECTIVES OF THE STUDY ............................................................................................. 9
CHAPTER 2 ...................................................................................................................................... 10
LITERTURE REVIEW ..................................................................................................................... 10
2.1 GENERAL ............................................................................................................................. 10
2.2 HISTORY OF WETLAND ................................................................................................... 11
2.3 CLASSIFICATION OF CONSTRUCTED WETLANDS .................................................... 12
2.4 CONSTRUCTED WETLANDS WITH SURFACE FLOW ................................................. 13
2.5 CONSTRUCTED WETLANDS WITH SUBSURFACE FLOW ......................................... 14
2.5.1 HORIZONTAL SUBSURFACE FLOW CONSTRUCTED WETLANDS-................. 14
2.5.2 VERTICAL FLOW CONSTRUCTED WETLANDS- ................................................. 16
2.5.3 HYBRID CONSTRUCTED WETLANDS ................................................................... 17
2.6 REMOVAL MECHANISM OF VARIOUS WASTE WATER PARAMETER................... 19
2.6.1 BOD ............................................................................................................................... 20
2.6.2 NITROGEN ................................................................................................................... 21
2.6.3 AMMONIFICATION .................................................................................................... 22
2.6.4 NITRIFICATION .......................................................................................................... 22
2.6.5 PHOSPHORUS.............................................................................................................. 22
3.1 GENERAL ............................................................................................................................. 24
3.2 STUDY SITE ......................................................................................................................... 24
3.3 LOCATION AND TIMING .................................................................................................. 26
3.4 LABORATORY ANALYSIS ............................................................................................... 26
3.4.1 BIOCHEMICAL OXYGEN DEMAND........................................................................ 26
3.4.2 CHEMICAL OXYGEN DEMAND .............................................................................. 26
3.4.3 AMMONIACAL NITROGEN: ..................................................................................... 26
3.4.4 PHOSPHORUS: ............................................................................................................ 26
3.4.5 pH................................................................................................................................... 26
3.4.6 NITRATE ...................................................................................................................... 26
3.5 INSTRUMENTS USED ........................................................................................................ 26
Intellical™ ISENO3181 Nitrate......................................................................................................... 27
Khera Instruments pvt. ltd.................................................................................................................. 27
CHAPTER 4 ...................................................................................................................................... 31
RESULTS AND DISCUSSION ........................................................................................................ 31
4.1 GENERAL ............................................................................................................................. 31
4.2 PHOSPHATES ...................................................................................................................... 31
4.3 AMMONIACAL NITROGEN .............................................................................................. 32
4.4 NITRATES ............................................................................................................................ 34
4.5 pH........................................................................................................................................... 35
4.6 COD ....................................................................................................................................... 35
LIST OF FIGURES
Figure 1 Classification of constructed wetlands (Vymazal and Kröpfelová, 2008) .......................... 13
Figure 2 Schematic diagram of the experiment setup ........................................................................ 24
Figure 3 Microwave ........................................................................................................................... 28
Figure 4 Cod Digester Unit ................................................................................................................ 29
Figure 5 Nitrate Electrode .................................................................................................................. 30
Figure 6 Phosphate Concentration In Raw ,Inlet And Outet ............................................................. 32
Figure 7 Reduction In Phosphate ....................................................................................................... 32
Figure 8 Ammoniacal Nitrogen Concentration .................................................................................. 33
Figure 9 % Reduction In Ammoniacal Nitrogen ............................................................................... 33
Figure 10 pH ...................................................................................................................................... 35
LIST OF TABLE
Table 1 Instruments used in the laboratory ........................................................................................ 27
CHAPTER 1
INTRODUCTION
1.1 NEED FOR THE STUDY
Rapidly urbanizing centers around the world face multiple challenges in their water and
wastewater management. In many developing country cities, water supply has not been able
to keep up with a rapidly increasing demand principally because a majority of the readily
available sources have already been exploited (Padowski and Gorelick, 2014, McDonald et
al., 2014). Further, many also lack adequate wastewater treatment infrastructure and
consequently discharge a large portion of their wastewater directly into surface water-
bodies impacting the health of downstream users and the environment (Ujang and Buckley,
2002; Corcoran, 2010). Water use continues to grow in a city as population increases,
thereby increasing the generation of wastewater. Partially treated as well as untreated
wastewater is picked up by the nearby rivers and lakes from the surrounding areas. A
substantial amount of this water is used downstream for agriculture, domestic purposes and
industries. The use of polluted river water for irrigation not only increases the health risks
for farmers and consumers of food crops, but also for the environment. Increasing water
shortages and wastewater discharge have exacerbated the problem, as has water pollution
caused by rapid urbanization, leading to further shortages of accessible drinking water
(Shao et al. 2006).In this context, waste water treatment and its reuse within the city is an
attractive solution that can simultaneously address both the above problems (Garcia and
Pargament, 2014; Jamwal et al., 2014).
Constructed wetlands are treatment systems that use natural processes involving wetland
vegetation, soils, and their associated microbial assemblages to improve water quality.
Constructed wetlands are comparatively less costly to construct and operate with ease of
maintenance as well as more effective in treatment of waste water. Wetlands are found to be
easygoing for different loading rates.
Wetland was firstly introduced in 1950’s by Seidel who named it “hydro-botanical system”.
This system was used for the removal of pollutants from wastewater. It was further
improved by following the hybrid system of vertical and horizontal filtration beds (Seidel,
1992).
The ecosystem of wetland systems has the specific characteristics which makes them
suitable for wastewater purification:
(1) The semi-aquatic system with partial oxic and partial anoxic environment.
(2) Provides basis to support the tall and highly productive plantation for taking up the
nutrients.
(3) And enhance the growth of the microbial film supported on media
(Verhoeven,Meuleman, 1999).
Wetland receives, hold and recycle nutrients and support vegetation at microscopic as well
as macroscopic level (Crites and Techobanoglous 1998; Hammer 1989).
The constructed wetlands are also known as reed beds which describe sub-surface flow
constructed wetland. In 1970s and 1980s, these systems were introduced as a result of
concern for treatment of municipal or domestic wastewater. Since 1990s, it has been used
for almost all types of wastewater such as landfill leachate, runoff, food processing,
industrial, agriculture farms, main drainage or sludge dewatering (Farooqi et al., 2008).
Kadlec and Knight (1996) define that the constructed wetland systems are designed to
utilize natural process for wastewater quality improvement. The constructed wetland
systems are engineered systems to facilitate the purification process by removing
contaminants in wastewater via a combination of physical (filtration, sedimentation)
chemical (precipitation, adsorption) and biological (microbial activity, vegetation
accumulation, plant uptake) processes for different type of wastewater.
Constructed wetlands are found to be promising for removal of TS, TDS, TSS, COD, BOD,
TKN and total phosphorus as well as microbial contaminants (Gersberg et al.,1994;
Green,1994; Kadlec, 1989; Knight, 1987).
2.2HISTORY OF WETLAND
Wetlands occur in a wide range of landscapes and may support permanent shallow
(generally <2 m) or temporary standing water. They have soils, substrates, and biota
adapted to flooding and/or water logging and associated conditions of restricted aeration.
Wetlands are far more important in the biosphere than their 5-8% of the landscape suggests
(Mitsch, Gosselink, Anderson, & Zhang, 2009) Wetlands are extremely diverse not only for
their physical characteristics and geographical distribution but also within particular
landscape units such as floodplains, mires, or marshes (Maltby, E., Ed. Functional
Assessment of Wetlands, 2009)
Wetlands provide many important ecological services to human society. Ecosystem services
represent the benefits that living organisms obtain directly or indirectly from the ecosystem
(Costanza, et al., 1997) Natural wetlands have been used for wastewater treatment for
centuries as convenient wastewater discharge sites for as long as sewage has been collected,
i.e., at least 100 years in some locations. In many cases, however, the reasoning behind this
use was disposal, rather than treatment, and the wetland simply served as a convenient
recipient that was closer than the nearest river waterway. (Wentz, W. A,1987).Uncontrolled
discharge of wastewater, though, led in many cases to an irreversible degradation of many
wetland areas.
Cooper & Boon, 1987, pointed out that the use of natural wetlands for treatment of
wastewater has been practiced in the United Kingdom for more than a century. Examples of
old wetland sites used to treat wastewater in North America include the Great Meadows
natural wetland near the Concord River in Lexington, Massachusetts beginning in 1912, the
Cootes Paradise natural wetland near Hamilton, Ontario(1919), the Brillion Marsh in
Wisconsin (1923), and a natural cypress swamp near the city of Waldo, Florida (1939).
(Kadlec, R. H.; Knight, R. L,1996 )
The growing knowledge about wetland functions and values have caused a radical change
of attitude toward wetlands since the 1950s and the use of natural wetlands for wastewater
disposal decreased in some parts of the world. Unfortunately, in some parts of the world the
deterioration of wetlands with wastewater still occurs. Natural wetlands are still used for
wastewater treatment under controlled conditions (Mander & Jenssen, 2002)(Kadlec, 2009)
Emergent plants
Surface flow Submerged plants Sub-surface flow
Free floating plants
Floating-leaved plants Horizontal Vertical
Downflow
Upflow
TIdal
Hybrid system
Removal of nitrogen is variable and the magnitude of reduction depends on many factors
including inflow concentration, chemical form of nitrogen, water temperature, season,
organic carbon availability, and dissolved oxygen concentration. Ammonia is most
effectively removed through nitrification in aerobic zones of the water column followed by
denitrification of nitrate in anaerobic zones in the litter layer at the bottom
FWS CWs provide sustainable removal of phosphorus but at relatively slow rates.
Phosphorus removal occurs from adsorption and precipitation but in the FWS system it is
limited by little contact between water column and the soil (Vymazal 2011).
Design methods are based on either volume or area. Volume-based methods use hydraulic
retention time to optimize pollutant removal whereas area-based methods assess pollutant
reduction using the overall wetland area(Economopoulou & Tshrintzis, 2004)
The most common application for FWS wetlands is for tertiary treatment of municipal
wastewater and also for stormwater runoff and mine drainage waters.
They provide greater storm/surge capacity and thus, less chance for hydraulic failureFWS
wetlands are suitable in all climates, including the far north. However, ice formation can
reduce the rates of some removal processes, especially nitrogen conversion and removal
(Vymazal 2011).
Suspended solids
Sedimentation, filtration
2.6.1 BOD
Organic compounds are degraded in constructed wetlands with horizontal sub-surface flow
(HSF CWs) both aerobically and anaerobically and it is difficult to quantify the ratio
between aerobic and anaerobic degradation. Ottova et al. (1997) found that the numbers of
aerobic heterotrophic bacteria in wastewater entering vegetated beds of HSF CWs are
higher than anaerobic ones but anaerobic bacteria prevail in the out flowing water. This
indicates that aerobic bacteria naturally die-off as a result of unfavorable anerobic or anoxic
conditions during the passage through the filtration medium of vegetated beds.
Aerobic degradation of soluble organic matter is governed by the aerobic heterotrophic
bacteria according to the following reaction:
(CH2 O) + O2 → CO2 + H2 O
Cooper et al. (1996) pointed out that both groups consume organics but the faster metabolic rate of
the heterotrophs means that they are mainly responsible for the reduction in the BODs of the system.
Insufficient supply of oxygen to this group will greatly reduce the performance of aerobic biological
oxidation, however, if the oxygen supply is not limited, aerobic degradation will be governed by the
amount of active organic matter available to the organisms. In most systems designed for the
treatment of domestic or municipal sewage the supply of dissolved organic matter is sufficient and
aerobic degradation is limited by dissolved oxygen concentration.
Anaerobic degradation is a multi-step process that occurs within constructed wetlands in the absence
of dissolved oxygen (Cooper et aI., 1996). The process can be carried out by either facultative or
obligate anaerobic heterotrophic bacteria. In the first step the primary end-products of fermentation
are fatty acids such as acetic (Eq. 2), butyric, and lactic (Eq, 3) acids, alcohols (Eq. 4) and the gases
C02 and H2 (Vymazal 1995, Vymazal et al., 1998):
Monomers
(e.g., monosachharides, amino acids)
Primary fermentation
2nd Fermentation
Acetogenesis acetogenesis
Acetate
CH4+CO2
CH4
2.6.2 NITROGEN
Nitrogen exists in many forms and various interrelated processes convert it from one form
to another in a complex system called the nitrogen cycle. Nitrogen enters most primary and
secondary treatment wetlands as organic N and ammonium (NH4-N), with tertiary systems
receiving a mixture of nitrogen species including nitrate. In most wetlands, some level of
nitrogen transformation is expected and/or mandated before discharge of the final effluent
to a water body. In many cases the expectation is conversion to nitrate, a less toxic form of
nitrogen, but increasingly more jurisdictions expect total nitrogen (TN) removal from
wastewater. Virtually all pathways of the nitrogen cycle are active in treatment wetlands,
including mineralization (ammonification), ammonia volatilization, nitrification,
denitrification, plant and microbial uptake, nitrogen fixation, nitrate reduction, anaerobic
ammonia oxidation, adsorption, desorption, burial, and leaching (Vymazal, 2007).
However, it is believed that only some of these pathways
2.6.3 AMMONIFICATION
Ammonification consists of the conversion of organic N to ammonium through extracellular
activity from enzymes excreted by microorganisms (Vymazal, 2007). Ammonification is
considered a necessary first step to nitrogen conversion to nitrate and/or removal, but is
seldom a limiting step for subsequent TN removal.
2.6.4 NITRIFICATION
Nitrification is the oxidation of ammonium to nitrate facilitated by a consortium of
autotrophic microbes with nitrite as a major intermediate product. For the process to take
place, the microorganisms, oxygen, alkalinity and micronutrients must be present in the
wastewater. Autotrophic nitrifiers are typically slower growing microorganisms than
aerobic heterotrophs and can thus be outcompeted in the presence of readily biodegradable
organic matter. A major advantage of VF wetlands is their high oxygenation capacity and
thus their ability to nitrify. Some nitrification can occur in HF systems, especially when
lightly loaded with organic matter, but nitrification is often a limiting step to nitrogen
removal in HF systems. Nitrification alone is a conversion process and does not result in
nitrogen removal, unless it is adequately coupled to denitrification.
2.6.5 PHOSPHORUS
Phosphorus enters most treatment wetlands primarily as organic phosphorus and
orthophosphate, but most organic phosphorus is converted to orthophosphate as part of
organic matter degradation. Mechanisms that play a part in phosphorus removal in
treatment wetlands include chemical precipitation, sedimentation, sorption and plant and
microbial uptake. Unfortunately, most of these processes are slow or not active unless
special media are used to enhance abiotic processes. As with nitrogen, plants incorporate
phosphorus into their biomass but this can be a removal mechanism only if plants are
harvested and is thus subject to the same limitations as nitrogen plant uptake as a removal
mechanism. The effectiveness of treatment wetlands for phosphorous removal is determined
by the applied loading rate. In very lightly loaded FWS systems, such as for effluent
polishing, phosphorus removal can be excellent and due primarily to soil accretion
(sedimentation and co-precipitation with other minerals). For treatment of typical secondary
wastewater using VF and HF systems, removal is generally quite modest once the sorptive
capacity of the media is saturated. Considerable research has been conducted to find media
with high phosphorus sorptive capacities with some success. These filter media are referred
to as reactive media (see Section 6.2). As all media, reactive media have a finite capacity,
however, it is possible to delay saturation to a period of years, which may be suitable in
certain situations. Another option is to use an additional unplanted filter bed in which the
reactive media can be periodically replaced without losing the removal capacity for other
constituents in upstream cells. This sacrificial filter is generally left unplanted to facilitate
removal of the material once it reaches its sorption capacity. A common approach is to dose
chemical salts (iron or aluminium based) to react with phosphorus upstream of the treatment
wetland and use the system to retain any residual precipitated solids (Brixand Arias, 2005;
Lauschmann et al., 2013; Dotro et al., 2015).
CHAPTER 3
METHODOLOGY
3.1GENERAL
This chapter discusses the description of setup involving type of constructed wetland, its
dimensions, vegetation and media type and configuration, site description, sample
collection, operation and laboratory analysis of the raw, inlet and treated water.
3.2STUDY SITE
Experimental setup is prestablished at orient residency ,muhana mundi road , Jaipur ,
Rajasthan, India. Where constructed wetland was used to improve the quality of
domestic wastewater. The domestic waste water is fed into the constructed wetland
after primary sedimentation. The waste water from orient residency which houses
250 people has the average daily rate of flow of 0.27 liter per seconds. Domestic
waste water is the water which is disposed from houses, It comes from kitchen,
toilets, sinks, showers, washing machines. The strength and composition of
the domestic waste water changes on hourly, daily and seasonal basis, with the
average strength dependent on per capita water usage, habits, diet, living standard
and life style. From houses the domestic waste comes directly to the primary
sedimentation tank, which is consisted of two large underground tanks of sizes 10 ×
10 × 12 feet. First tank is a primary sedimentation tank and second is a storage tank.
A pump is connected to the second tank so that the water from that tank can fed into
the inlet of the wetland.
Pump
Primary
Domestic Storage
sedimentation
waste water tank
tank
3.4LABORATORY ANALYSIS
The waste water from sedimentation tank , inlet water to wetland and outlet water from
wetland was analyzed for BOD ,COD, ammonical nitrogen, phosphorous, nitrates and pH .
3.4.4 PHOSPHORUS:
Stannous Chloride Method was used as per (APHA, Standard Methods for the Examination
of Water and Wastewater 1999) (4500-P D. Stannous Chloride Method)
3.4.5 pH
pH of the treated wastewater sample was measured using pH meter available in the PHE
laboratory, MNIT, Jaipur.
3.4.6 NITRATE
The nitrates were determined using electrode method
1. Burette
3. Microwave Samsung
Intellical™ ISENO3181
8. Nitrate electrode Nitrate
Photos of the instruments presented in the table number --- is given below.
Figure 3 Microwave
Figure 4 COD DIGESTER UNIT
Figure 5 NITRATE ELECTRODE
CHAPTER 4
RESULTS AND DISCUSSION
4.1GENERAL
This chapter discusses with all the results and discussion related to efficiency of wetland.
These results are on the basis of experiments which were conducted in the MNIT PHE lab,
Jaipur.
The BOD, COD, phosphates, pH, ammonical nitrogen and nitrates showed compatibility
with the data reported in the literature. The pH of the raw water, inlet water and outlet water
was slight alkaline ranging from 7.27 to 7.95. The maximum pH was reported to be 7.95.
The raw pH was already in the limits prescribed for reuse.. The major contributors of
phosphates are detergents where the phosphate containing detergents are still being used. A
low concentration of phosphates indicates high per capita use of water. Concentrations
between 6 and 23 mg Tot-P/l can be found in traditional wastewaters in areas where
phosphorus detergents are used. However, in regions were non-phosphorus detergents are
used the concentrations range between 4 and 14 mg/l. In bathroom grey wastewater the total
phosphorus and phosphate concentrations were 0.1–57 and 0.1–2 mg/l, respectively (Eva
Eriksson, 2002). The (Washington state department of health, 2009) reported mean of total
P to be 2.8 mg/l in the greywater including kitchen waste water and laundry waste water.
The total P concentrations of 1.37 mg/l in greywater were reported (B. Jefferson, 2004).
Although the mean concentration of nitrates was 8.11 mg/l which is just below
4.2 PHOSPHATES
The concentration of phosphates was found to be already very low, maximum being 1.982
mg/l as P4 O−
3 in raw waste-water and 0.794 mg/l in inlet of the wetland. and 0.295 mg/l at
The figure no. 8 shows the concentration of phosphates in raw, inlet and outlet water. The
concentration of phosphates in raw water was reported maximum to be 1.982 mg/l which is
is ranging from 1.657 mg/l to 1.982 mg/l. In inlet it is ranging from 0.637mg/l to 0.794 mg/l
and in outlet it is ranging from 0.143 mg/l to 0.315 mg/l.
2.5
1.5
RAW
1 INLET
OUTLET
0.5
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
90.00
80.00
70.00
60.00
50.00
40.00
30.00
20.00
10.00
0.00
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
0.8
0.7
AMMONIACAL NITROGEN (mg\l)
0.6
0.5
RAW
0.4
INLET
0.3 OUTLET
0.2
0.1
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
80.00
% REDUCTION IN AMMONIACAL NITROGEN
70.00
60.00
50.00
40.00
30.00
20.00
10.00
0.00
0 2 4 6 8 10 12 14 16 18
RAW
3
INLET
OUTLET
2
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
60
50
40
30
20
10
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
8.2
7.8
7.6
7.4 Series1
7.2 Series2
7 Series3
6.8
6.6
6.4
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
4.6 COD
The figure no. 8 shows the COD of raw, inlet and outlet water. The COD in raw water was
reported maximum to be 840 mg/l and it is ranging from 735 mg/l to 840 mg/l . In inlet
it is ranging from mg/l to mg/l and in outlet it is ranging from 1.26 mg/l to 2.68 mg/l.
900
800
700
600
500 RAW
400 INLET
OUTLET
300
200
100
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
40
35
30
25
20
15
10
0
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
4.7 BOD
The figure no. 8 shows the BOD of raw, inlet and outlet water. The BOD in raw water was
reported maximum to be 540.5 mg/l and it is ranging from 301.30 mg/l to 540.5 mg/l. In
inlet itis ranging from 130 mg/l to 185.64 mg/l and in outlet it is ranging from 105 mg/l to
150 mg/l.
600.00
500.00
400.00
RAW
300.00
INLET
200.00 OUTLET
100.00
0.00
1 2 3 4 5 6 7 8 9 10 11
25.00
20.00
15.00
10.00
5.00
0.00
1 2 3 4 5 6 7 8 9 10 11