Académique Documents
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L. C. Kaley, P.E.
Trinity Bridge, LLC
Savannah, Georgia USA
1.0 ABSTRACT
The Joint Industry Project for Risk-Based Inspection (RBI JIP) was initiated and
managed by API within the refining and petrochemical industry in 1992. The
work from the JIP resulted in two publications, API 580 Risk-Based Inspection
released in 2002 and API 581 Base Resource Document – Risk-Based Inspection
originally released in 1996. The concept behind these publications was for API
580 to introduce the principles and present minimum general guidelines for RBI
while API 581 was to provide quantitative RBI methods. The API RBI JIP has
made major advances in the technology since the original publication of these
documents and released the 1st addendum to the third edition of API RP 581
Risk-Based Inspection Methodology in December 2017. API RP 581 is a is a
three-part document, Part 1 – Inspection Planning Methodology, Part 2 –
Probability of Failure Methodology, and Part 3 – Consequence of Failure
Methodology. This paper provides a step-by-step worked example that
demonstrates the technology documented in API 581, Third Edition, 1st
Addendum to be released by API in 2018.
This document is intended solely for the internal use of Trinity Bridge, LLC and may not be reproduced or
transmitted by any means without the express written consent of Trinity Bridge, LLC.
All rights reserved.
97.625
165
tmin 2 0.6950 inch
13, 750 0.85 0.6 165
4.) Determine the Art parameter using Equation (2.13) based on age and trdi
from Step 1 and tmin from Step 6 using Equation (2.13).
C agetk agerc
Art max r ,bm ,0
trdi
FS Thin
YS TS E 1.1
2
FS Thin
30 60 0.85 1.1
2
FS 42.075
Thin
p1 p1 p1
I1Thin 0.35
2 Co p 2 Co Co Co
Thin
N BThin NCThin Thin
ND
I 2Thin PrpThin ThinA A ThinB ThinC ThinD
p2 p2 p2
I 2Thin 0.06
3 Co p 3 Co Co Co
N Thin N BThin NCThin Thin
ND
I 3Thin PrpThin ThinA A ThinB ThinC ThinD
p3 p3 p3
I 3Thin 0.02
Thin Thin
10.) Calculate the Posterior Probabilities, Pop1 , Pop 2 and PoThin
p3
I1Thin
Po Thin
Thin
I1 I 2Thin I 3Thin
p1
0.35
p1
PoThin
0.35 0.06 0.02
PoThin
p1 0.8140
I 2Thin
Po Thin
Thin
I1 I 2Thin I 3Thin
p2
0.06
p2
PoThin
0.35 0.06 0.02
PoThin
p2 0.1395
I 3Thin
p3
PoThin
I1Thin I 2Thin I 3Thin
0.02
p3
PoThin
0.35 0.06 0.02
PoThin
p3 0.0465
11.) Calculate the parameters, 1Thin , 2Thin , 3Thin
Where :
COVt 0.20
COVS f 0.20
COVP 0.05
1 2
DS1 2 Art 2 COVt 2 1 DS1 Art COVS f 2 ( SRThin
p ) 2 COVP 2
1 1 0.053 0.2574
1Thin
12 0.0532 0.202 1 1 0.053 0.202 (0.2574) 2 0.052
2
1Thin 3.6263
2 2
DS2 2 Art 2 COVt 2 1 DS2 Art COVS f 2 ( SRThin
p ) 2 COVP 2
1 2 0.053 0.2574
2Thin
22 0.0532 0.202 1 2 0.053 0.202 (0.2574) 2 0.052
2
2Thin 3.5252
2
DS3 2 Art 2 COVt 2 1 DS3 Art COVS f 2 ( SRThin
p ) 2 COVP 2
1 4 0.053 0.2574
3Thin
4 0.053 0.20 1 4 0.053 0.202 (0.2574) 2 0.052
2 2 2 2
3Thin 3.2366
Calculate the thinning base DF at the RBI Date and Plan Date
D Thin
PoThin
p1 1
Thin
PoThin
p2
2Thin Po
Thin
p3
3Thin
fb
1.56 E 04
0.8140 NORMSDIST 3.6263
0.1395 NORMSDIST 3.5252
DThin
0.0465 NORMSDIST 3. 2366
1.56 E 04
fb
fb @ RBI Date 1.1196
DThin
D Thin
PoThin
p1 1
Thin
PoThin
p2
2Thin Po
Thin
p3
3Thin
fb
1.56 E 04
0.8140 NORMSDIST 3.6263
0.1395 NORMSDIST 3.5252
DThin
0.0465 NORMSDIST 3. 2366
1.56 E 04
fb
fb @ Plan Date 159.71
DThin
12.) Calculate the final thinning DF at the RBI Date and Plan Date
DThin
fb FIP FDL
D Thin
max ,1
f
FCM
0.49 1 1
DThin
f max ,1
1
fb @ RBI Date 1.1196
DThin
DThin
fb FIP FDL
D Thin
max ,1
f
FCM
126.65 1 1
DThin
f max ,1
1
D fb @ Plan Date 159.71
Thin
4.2 Calculation of Stress Corrosion Cracking Damage Factor
The following example demonstrates the steps required for calculating the
HIC/SOHIC-H2S damage factor:
1.) Determine the number of historical inspections and historical inspection
effectiveness category: A 1C cracking inspection was been performed on
10/8/1999 this vessel
2.) Determine time in-service, age, from the last A, B, C or D inspection
performed to the RBI and Plan Dates.
age @ RBI Date = 25.5 years
age @ Plan Date = 35.5 years
3.) Determine the environmental severity for cracking based on the H2S content
of the water, PWHT and pH: Low
4.) Based on susceptibility in Step 3, determine the severity index, SVI, from
Table 10.5: SVI = 1
5.) Determine the base damage factor for HIC/SOHIC-H2S cracking,
/ SOHIC H2 S
DHIC
fB using Table 6.4 based on the number of and highest inspection
effectiveness determined in Step 1, and the severity index, SVI, from Step
4:
/ SOHIC H 2 S
DHIC
fB 1
6.) Calculate the escalation in the DF at the RBI Date and Plan Date
D HIC / SOHIC H 2 S
Max[age,1.0]
1.1
HIC / SOHIC H 2 S
Min ,5000
fB
D f
FOM
HIC / SOHIC H 2 S
1 Max[25.5,1.0]1.1
D Min ,5000
f
1
DfHIC / SOHIC H 2 S
@ RBI Date Min 35.25,5000 35.25
D HIC / SOHIC H 2 S
Max[age,1.0]
1.1
HIC / SOHIC H 2 S
Min ,5000
fB
D f
FOM
HIC / SOHIC H 2 S
1 Max[35.5,1.0]1.1
D Min ,5000
f
1
D HIC
f
/ SOHIC H 2 S
@ Plan Date Min 50.73,5000 50.73
4.3 Calculation of Damage Factor Combination for Multiple Damage
Mechanisms
If more than one damage mechanism is present, the total damage factor, D f total
is given by Equation (2.2).
D f total Dthin
f gov D f gov D f gov D f
extd scc htha
Dbrit
f gov D f
mfat
D f total Dthin
f gov D f gov D f gov D f
extd scc htha
Dbrit
f gov D f
mfat
1.) Calculate the release hole size area, An , using Equation (3.8)
A3,hole d2 42 12.57 inch 2
4 4
2.) Select the appropriate release rate calculation using the stored fluid phase
determined.
3.) Determine the viscosity correction factor, K v , n : for non-viscous fluids, the
viscosity correction factor is set equal to 1.
4.) Calculate the release rate, Wn , for the release area An determined in Step 2
using Equation (3.3).
An 2 g c Ps Patm
Wn Cd K v ,n l
C1 l
12.57 2 32.2 101 0
Wn 0.61 1 33.61
12 33.61
Wn 298.6733 lb / sec
Since the total massavail , n 36,607.99 kg (80,454.78 lbs) is greater than 4,536 kg
(10,000 lb), the release is instantaneous.
2.) Determine the Flammable Equipment Damage Area constants a and b from
Tables 5.8 and 5.9 for the release phase determined in Step 3 and using
Equation (3.17).
Instantaneous
b 1 factmit
AINL INST
CAcmd ,n a massn
eneff n
1 0
AINL INST
27.96 80, 454.78 lb
0.72
CAcmd ,3
4.6222
AINL INST
CAcmd ,3 = 95,177.55 ft 2
Continuous
b 1 factmit
AINL INST
CAcmd ,n a massn
eneff n
1 1 0
AINL INST
CAcmd ,3 49.48 298.6733 lb/sec
4.6222
AINL INST
CAcmd ,3 = 1, 644.35 ft 2
Final Results
Instananeous Continuous
,1 11,357.52 ,1 6.42
AIL AIL
CAcmd CAcmd
,2 46,840.70 ,2 102.77
AIL AIL
CAcmd CAcmd
,3 95,177.55 ,3 1, 644.35
AIL AIL
CAcmd CAcmd
,4 210,158.01 ,4 26,309.54
AIL AIL
CAcmd CAcmd
Instananeous Continuous
CA AINL
cmd ,1 100, 247.08 ,1 40.71
AINL
CAcmd
,2 346,333.16 ,2 651.36
AINL AINL
CAcmd CAcmd
Continuous
1 factmit
a massn
INST b
CAinjAINL
,n
eneff n
1 1 0
CAinjAINL
,3
INST
125.2 298.6733 lb
4.6222
INST
CAinjAINL
,3 = 4,160.72 ft 2
Instananeous Continuous
CA AINL
inj ,1 11,357.52 ,1 6.42
CAinjAINL
,2 46,840.70
CAinjAINL ,2 102.77
CAinjAINL
,3 95,177.55
CAinjAINL ,3 1, 644.35
CAinjAINL
,4 210,158.01
CAinjAINL ,4 26,309.54
CAinjAINL
Instananeous Continuous
CAinjAIL,1 30,114.14 CAinjAIL,1 16.25
CAinjAIL,2 131, 749.65 CAinjAIL,2 260.04
CAinjAIL,3 275, 733.93 CAinjAIL,3 4,160.72
CAinjAIL,4 629, 267.74 CAinjAIL,4 66,571.44
4.) Calculate Instantaneous/Continuous Blending factor
rate4
factnIC min , 1.0
C5
where : C5 55.6
33.23
fact3IC min , 1.0
55.6
fact3 min 0.5977, 1.0
IC
fact3IC 0.5977
AINL
CAcmd AINL INST
,n CAcmd ,n
AINL CONT
factnIC CAcmd ,n 1 factnIC
,3 57,549.86 ft
AINL 2
CAcmd
,1 32.93
AINL
CAcmd
,2 1,848.75
AINL
CAcmd
,3 57,549.86
AINL
CAcmd
,4 210,158.01
AINL
CAcmd
AIL
CAcmd AIL INST
,n CAcmd ,n
AIL CONT
factnIC CAcmd ,n 1 factnIC
,3 389,143.33 ft
AIL 2
CAcmd
,1 274.67
AIL
CAcmd
,2 13,564.90
AIL
CAcmd
,3 389,143.33
AIL
CAcmd
,4 1, 288, 031.03
AIL
CAcmd
6.) Calculate the AIT Blending factor
fact AIT
Ts AIT C6 for Ts C6 AIT Ts C6
2 C6
fact AIT 1 for Ts C6 AIT
AIT 696.0
Ts 101F
C6 100
Ts C6 101 100 201F 696.0
fact AIT 0
,1 32.93
AINL
CAcmd
,2 1,848.75
AINL
CAcmd
,3 57,549.86
AINL
CAcmd
,4 210,158.01
AINL
CAcmd
, n = CAinj , n fact
CAinjflam , n 1- fact
AIL AIT
+CAinjAINL AIT
,1 86.53
AINL
CAcmd
,2 5,172.07
AINL
CAcmd
,3 166, 482.12
AINL
CAcmd
,4 629, 267.74
AINL
CAcmd
8.) Final Weighted Flammable Consequence Area for Equipment Damage:
4 flam
gff n CAcmd ,n
flam
CAcmd n 1
gff total
8.00E -06
32.93 2.00E -05 1,848.75
CA flam
2.00E -06
57,549.86 6.00E -07 210,158.01
cmd
3.060E -05
flam
CAcmd 9, 099.11 ft 2
4 flam
gff n CAinj ,n
CAinjflam n 1
gff total
8.00E -06
86.53 2.00E -05 5,172.07
CA flam
2.00E -06
166, 482.12 6.00E -07 629, 267.74
inj
3.060E -05
CAinjflam 26, 622.82 ft 2
The final consequence area for the equipment damage and personnel injury is
the maximum of the areas calculated. For this worked example, the maximum
damage area is the flammable consequence for personnel injury or 2,473.34 m2
(26,622.82 ft2).
A similar procedure is used for determining the consequences associated with
releases of toxic chemicals such as H 2S, ammonia or chlorine. Toxic impact
areas are based on probit equations and can be assessed whether the stream is
pure or a percentage of a hydrocarbon stream. For simplicity, the toxic
calculation is not included in this worked example.
A limitation of Level 1 consequence analysis is that it can only be performed for
the cases where the component fluid is best represented by one of the reference
fluids. The Level 1 consequence analysis has been used by the refining industry
for over 10 years with success. However, as international interest has grown in
API RBI in the refining and petrochemical industries, as well as in the chemical
industries, the limited fluids available were insufficient and the cost to develop
additional fluids was high. The Level 2 analysis was developed to address the
limitations of Level 1 and to provide a wider industry audience with
consequences a more rigorous approach.
5.8 Determining Financial Consequence
Failure (loss of containment) not only has safety consequences, represented by
flammable and toxic consequence areas but there are costs associated the
release of hazardous materials that does not result in damage to equipment or
serious injury to personnel. Since the costs include more than business
interruption, analysis for financial consequence is determined by the sum of the
following individual costs, shown in Equation (3.97):
Where:
FC is the final financial consequence, € ($)
FCaffa is the financial consequence of damage to surrounding equipment on the
unit, € ($)
FCenviron is the financial consequence of environmental clean-up, € ($)
And:
Population Density, personnel/ft2 = 0.00005
Production, $/day = 50,000
Injury Cost, $/fatality = $5,000,000
Environmental Cost, $/event = 0
Equipment Cost, $/ft2 = 1,200
5.9 Component Damage Cost, FCcmd
The Damage cost uses a cost required for repair of the damaged component,
independent of other damage caused by the event. The cost of repair,
holecost , for different release hole sizes can be found in Table 5.15 and are
provided below.
Damage Costs, holecost
¼” hole cost - $5,000
1” hole cost - $12,000
4” hole cost - $20,000
Rupture cost - $40,000
The values in Table 5.15 are based on carbon steel prices. For other materials a
material cost factor, matcost , is used to adjust the cost of alloy materials. The
drum in this worked example is constructed of carbon steel so a matcost of 1 will
be used.
Finally, the cost to repair or replace the component is a probability weighted
average of the individual repair costs determined for each release hole size and
calculated using Equation (3.98).
4
gff n holecostn
FCcmd n 1 matcost
gfftotal
holecost1 5, 000 8.00 E 0.0400
-06
4
gff n Outagen
Outagecmd n 1 Outagemult
gff total
Other Outage Days, Outageaffa – If a component fails and that failure results in
an affected area, the cost of downtime for replacement or repair of surrounding
equipment in the area is considered using Equation (3.101).
6
1.242 0.585log10 FCaffa 10
Outageaffa 10
(3.101)
6
1.242 0.585log10 10,918,936.9710
10
70.69 days
(3.102)
2.88 70.69 days 50, 000 $/day
$3, 678,107.97
5.12 Potential Injury Cost, FCinj
When injuries as a result of an event are possible and costs of potential injuries
are determined, appropriate resources can be managed and allocated to prevent
injuries from occurring. A population density, popdens , is determined and
reflects the proximity of personnel to the equipment location such as control
rooms, walkways, roads, etc. In addition to the population density, the cost per
individual, injcost , potentially affected by the failure is considered to reflect
typical costs to businesses of an injury up to and including fatal injuries. When
assigning this value, consideration should be given to the following:
Any existing company standards for such calculations,
Local medical/compensation costs associated with long-term disability,
Legal/settlement costs,
Indirect costs such as increased regulatory scrutiny, loss of reputation, etc.
The costs associated with personnel injury are computed using Equation
(3.103). The popdens is 0.0005/m2 and injcost €5,000,000/serious injury.
FCinj CAinj popdens injcost
(3.103)
26, 622.82 5.00 E -04 5, 000, 000 $6, 655, 706.05
R(t ) Pf (t ) C (t ) (1.5)
So for the area risk calculation for our worked example, the Risk at the RBI Date
using the maximum area calculated in the consequence of failure section is:
R(t ) Pf (t ) CA
1.) Calculate the Art at the Plan Date with the planned inspection
(0.010 0) 14
Art 1 0.1867
0.75
2.) Calculate the inspection effectiveness factors, I1Thin , I 2Thin , I 3Thin , using
Equation (2.17) and values from Tables 4.5 and 4.6
1 Co p1 Co Co Co
N Thin N BThin NCThin Thin
ND
I1Thin PrpThin ThinA A ThinB ThinC ThinD
p1 p1 p1
I1Thin 0.245
p2 p2 p2
I 2Thin 0.012
p3 p3 p3
I 3Thin 0.002
Thin Thin
3.) Calculate the Posterior Probabilities, Pop1 , Pop 2 and PoThin
p3
I1Thin
p1
PoThin
I1Thin I 2Thin I 3Thin
0.245
p1
PoThin
0.245 0.012 0.002
PoThin
p1 0.9459
I 2Thin
p2
PoThin
I1Thin I 2Thin I 3Thin
0.012
p2
PoThin
0.245 0.012 0.002
PoThin
p2 0.0463
I 3Thin
p3
PoThin
I1Thin I 2Thin I 3Thin
0.002
p3
PoThin
0.245 0.012 0.002
PoThin
p3 0.0077
1 2
DS1 2 Art 2 COVt 2 1 DS1 Art COVS f 2 ( SRThin
p ) 2 COVP 2
1 1 0.187 0.2574
1Thin
1 0.187 0.20 1 1 0.187 0.202 (0.2574) 2 0.052
2 2 2 2
1Thin 3.3211
2
DS2 2 Art 2 COVt 2 1 DS2 Art COVS f 2 ( SRThin
p ) 2 COVP 2
1 2 0.187 0.2574
2Thin
2 0.187 0.20 1 2 0.187 0.202 (0.2574) 2 0.052
2 2 2 2
2Thin 2.5213
2
DS3 2 Art 2 COVt 2 1 DS3 Art COVS f 2 ( SRThin
p ) 2 COVP 2
1 4 0.187 0.2574
3Thin
4 0.187 0.20 1 4 0.187 0.202 (0.2574) 2 0.052
2 2 2 2
3Thin 0.0258
5.) Calculate the thinning base DF at the RBI Date and Plan Date
D Thin
PoThin
p1 1
Thin
Po
Thin
p2
2Thin Po
Thin
p3
3Thin
fb
1.56 E 04
0.8140 NORMSDIST 3.3211
0.1395 NORMSDIST 2.5213
DThin
0.0465 NORMSDIST ( 0.0258)
1.56 E 04
fb
D fb @ Plan Date with inspection 29.71
Thin
6.) Calculate the final thinning DF at the RBI Date and Plan Date
DThin
fb FIP FDL
D Thin
@ Plan Date with inspection max ,1
f
FCM
29.71 1 1
DThin
f @ Plan Date with inspection max ,1
1
DThin
f @ Plan Date with inspection 29.71
Calculate Future POF, COF and Risk at the Plan Date with recommended
inspection, the POF at the Plan Date with the recommended inspection is:
POFPlan = 3.06E -05 35.59 1 1.09E -03 failures / year
The COF at the Plan Date with the recommended inspection is still 1,590 m 2,
because COF is invariant with time. And the future Risk at the Plan Date with
the recommended inspection is:
Riskplan = 1.09E -03 failures / yr ×26,622.83 ft 2 = 28.99 ft 2 / year
Since the risk at the Plan Date after inspection is 28.99 ft2/year, the Risk at the
Plan Date with the recommended inspection is below our established Risk Target
of 40 ft2/year.
The following Table summarizes the results of the worked example
demonstrated in this paper.
API, API RP 581 API RBI Technology, Third Edition 1st Addendum, January 2018,
American Petroleum Institute, Washington, D.C.
11.0 TABLES
Part 1, Table 3.1 – Steps in Consequence Analysis
Section in this Part
Level 1
Level 2
Conseq
Step Description Consequ
uence
ence
Analysi
Analysis
s
Determine the released fluid and its properties, including the
1 4.1 5.1
release phase.
Select a set of release hole sizes to determine the possible
2 4.2
range of consequence in the risk calculation.
3 Calculate the theoretical release rate. 4.3 5.3
4 Estimate the total amount of fluid available for release. 4.4
Determine the type of release, continuous or instantaneous, to
5 determine the method used for modeling the 4.5
dispersion and consequence.
Estimate the impact of detection and isolation systems on
6 4.6
release magnitude.
Determine the release rate and mass for the consequence
7 4.7 5.7
analysis.
8 Calculate flammable/explosive consequence. 4.8 5.8
9 Calculate toxic consequences. 4.9 5.9
10 Calculate non-flammable, non-toxic consequence. 4.10 5.10
Determine the final probability weighted component damage
11 4.11 5.11
and personnel injury consequence areas.
12 Calculate financial consequence. 4.12
Part 2, Table 3.1 – Suggested Component Generic Failure Frequencies
PIPE-8,
PIPE-10,
Pipe 8.00E-06 2.00E-05 2.00E-06 6.00E-07 3.06E-05
PIPE-12,
PIPE-16,
PIPEGT16
PUMP2S,
Pump 8.00E-06 2.00E-05 2.00E-06 6.00E-07 3.06E-05
PUMPR,
PUMP1S
Tank650 TANKBOTTOM 7.20E-04 0 0 2.00E-06 7.22E-04
Tank650 COURSE-1-10 7.00E-05 2.50E-05 5.00E-06 1.00E-07 1.00E-04
KODRUM,
COLBTM,
FINFAN,
Vessel/FinFan FILTER, 8.00E-06 2.00E-05 2.00E-06 6.00E-07 3.06E-05
DRUM,
REACTOR,
COLTOP,
COLMID
Note:
See references [1] through [8] for discussion of failure frequencies for equipment
Table 4.2 – Properties of the Representative Fluids Used in Level 1 Consequence Analysis
Cp Auto-
Liquid Ideal Gas
NBP Ambient Ignition
Fluid MW Density Specific
(F) State Temp.
(lb/ft3) Heat Eq. Ideal Gas Ideal Gas Ideal Gas Ideal Gas Ideal Gas
Constant Constant Constant Constant Constant (F)
A B C D E
C1-C2 23 15.639 -193 Gas Note 1 12.3 1.150E-01 -2.87E-05 -1.30E-09 N/A 1,036
C3-C4 51 33.61 -6.3 Gas Note 1 2.632 0.3188 -1.347E-04 1.466E-08 N/A 696
C5 72 39.03 97 Liquid Note 1 -3.626 0.4873 -2.6E-04 5.3E-08 N/A 544
C6-C8 100 42.702 210 Liquid Note 1 -5.146 6.762E-01 -3.65E-04 7.658E-08 N/A 433
C9-C12 149 45.823 364 Liquid Note 1 -8.5 1.01E+00 -5.56E-04 1.180E-07 N/A 406
C13-C16 205 47.728 502 Liquid Note 1 -11.7 1.39E+00 -7.72E-04 1.670E-07 N/A 396
C17-C25 280 48.383 651 Liquid Note 1 -22.4 1.94E+00 -1.12E-03 -2.53E-07 N/A 396
C25+ 422 56.187 981 Liquid Note 1 -22.4 1.94E+00 -1.12E-03 -2.53E-07 N/A 396
Pyrophoric 149 45.823 364 Liquid Note 1 -8.5 1.01E+00 -5.56E-04 1.180E-07 N/A Note 4
Aromatic 104 42.7 293 Liquid Note 2 8.93E+04 2.15E+05 7.72E+02 9.99E+04 2.44E+03 914
Styrene 104 42.7 293 Liquid Note 2 8.93E+04 2.15E+05 7.72E+02 9.99E+04 2.44E+03 914
Water 18 62.3 212 Liquid Note 3 2.76E+05 -2.09E+03 8.125 -1.41E-02 9.37E-06 N/A
Steam 18 62.3 212 Gas Note 3 3.34E+04 2.68E+04 2.61e+03 8.90E+03 1.17E+03 N/A
Acid/Caustic 18 62.3 212 Liquid Note 3 2.76E+05 -2.09E+03 8.125 -1.41E-02 9.37E-06 N/A
Methanol 32 50 149 Liquid Note 2 3.93E+04 8.79E+04 1.92E+03 5.37E+04 8.97E+02 867
Ammonia 17.03 38.55 -28.2 Gas --- --- --- --- --- --- N/A
H2 2 4.433 -423 Gas Note 1 27.1 9.270E-03 -1.38E-05 7.650E-09 N/A 752
H2S 34 61.993 -75 Gas Note 1 31.9 1.440E-03 2.430E-05 -1.18E-08 N/A 500
HF 20 60.37 68 Gas Note 1 29.1 6.610E-04 -2.03E-06 2.500E-09 N/A 32000
HCl 36 74 -121 Gas --- --- --- --- --- --- N/A
CO 28 50 -312 Gas Note 2 2.91E+04 8.77E+03 3.09E+03 8.46E+03 1.54E+03 1128
DEE 74 45 95 Liquid Note 2 8.62E+04 2.55E+05 1.54E+03 1.44E+05 -6.89E+02 320
Nitric Acid 63 95 250 Liquid --- --- --- --- --- --- N/A
AlCl3 133.5 152 382 Powder Note 1 4.34E+04 3.97E+04 4.17E+02 2.40E+04 N/A 1036
NO2 90 58 275 Liquid --- --- --- --- --- --- N/A
Phosgene 99 86 181 Liquid --- --- --- --- --- --- N/A
TDI 174 76 484 Liquid --- --- --- --- --- --- 1148
PO 58 52 93 Liquid Note 2 4.95E+04 1.74E+05 1.56E+03 1.15E+05 7.02E+02 840
EEA 132 61 313 Liquid Note 2 1.06E+05 2.40E+05 6.59E+02 1.50E+05 1.97E+03 715
EE 90 58 275 Liquid Note 2 3.25E+04 3.00E+05 1.17E+03 2.08E+05 4.73E+02 455
EG 62 69 387 Liquid Note 2 6.30E+04 1.46E+05 1.67E+03 9.73E+04 7.74E+02 745
EO 44 55 51 Gas Note 2 3.35E+04 1.21E+05 1.61E+03 8.24E+04 7.37E+02 804
Table 4.8 – Component Damage Flammable Consequence Equation Constants
Fluid Fluid Type Continuous Releases Constants Instantaneous Releases Constants
Auto-Ignition Not Likely Auto-Ignition Likely Auto-Ignition Not Likely Auto-Ignition Likely
(AINL-CONT) (AIL-CONT) (AINL-INST) (AIL-INST)
Gas Liquid Gas Liquid Gas Liquid Gas Liquid
a b a b a b a b a b a b a b a b
C1-C2 TYPE 0 43.0 0.98 280.0 0.95 41.0 0.67 1079 0.62
C3-C4 TYPE 0 49.48 1.00 313.6 1.00 27.96 0.72 522.9 0.63
C5 TYPE 0 25.17 0.99 536.0 0.89 304.7 1.00 13.38 0.73 1.49 0.85 275.0 0.61
C6-C8 TYPE 0 29.0 0.98 182.0 0.89 312.4 1.00 525.0 0.95 13.98 0.66 4.35 0.78 275.7 0.61 57.0 0.55
C9-C12 TYPE 0 12.0 0.98 130.0 0.90 391.0 0.95 560.0 0.95 7.1 0.66 3.3 0.76 281.0 0.61 6.0 0.53
C13-C16 TYPE 0 64.0 0.90 1023 0.92 0.46 0.88 9.2 0.88
C17-C25 TYPE 0 20.0 0.90 861.0 0.92 0.11 0.91 5.6 0.91
C25 + TYPE 0 11.0 0.91 544.0 0.90 0.03 0.99 1.4 0.99
Pyrophoric TYPE 1 12.0 0.98 130.0 0.90 391.0 0.95 560.0 0.95 7.1 0.66 3.3 0.76 281.0 0.61 6.0 0.53
Aromatics TYPE 1 17.87 1.097 103.0 0 374.5 1.055 11.46 0.667 70.12 0 512.6 0.713 701.2 0
Styrene TYPE 1 17.87 1.097 103.0 0 374.5 1.055 11.46 0.667 70.12 0 512.6 0.713 701.2 0
Water TYPE 0
Steam TYPE 0
Acid/Caustic TYPE 0
Methanol TYPE 1 0.026 0.909 1751 0.934 28.11 0.667 1.919 0.900
H2S TYPE 0 32.0 1.00 203.0 0.89 148.0 0.63 357.0 0.61
HF TYPE 0
DEE TYPE 1 39.84 1.134 737.4 1.106 320.7 1.033 6289 0.649 155.7 0.667 5.105 0.919 5.672 0.919
C3-C4 TYPE 0 125.2 1.00 836.7 1.00 57.72 0.75 1769 0.63
C5 TYPE 0 62.05 1.00 1545 0.89 811.0 1.00 28.45 0.76 4.34 0.85 959.6 0.63
C6-C8 TYPE 0 68.0 0.96 516.0 0.89 828.7 1.00 1315 0.92 26.72 0.67 12.7 0.78 962.8 0.63 224.0 0.54
C9-C12 TYPE 0 29.0 0.96 373.0 0.89 981.0 0.92 1401 0.92 13.0 0.66 9.5 0.76 988.0 0.63 20.0 0.54
C13-C16 TYPE 0 183.0 0.89 2850 0.90 1.3 0.88 26.0 0.88
C17-C25 TYPE 0 57.0 0.89 2420 0.90 0.32 0.91 16.0 0.91
C25 + TYPE 0 33.0 0.89 1604 0.90 0.081 0.99 4.1 0.99
Pyrophoric TYPE 1 29.0 0.96 373.0 0.89 981.0 0.92 1401 0.92 13.0 0.66 9.5 0.76 988.0 0.63 20.0 0.54
Aromatics TYPE 1 64.14 0.963 353.5 0.883 1344 0.937 487.7 0.268 18.08 0.686 0.14 0.935 512.6 0.713 1.404 0.935
Styrene TYPE 1 64.14 0.963 353.5 0.883 1344 0.937 487.7 0.268 18.08 0.686 0.14 0.935 512.6 0.713 1.404 0.935
Water TYPE 0
Steam TYPE 0
Acid/Caustic TYPE 0
Methanol TYPE 1 0.016 1.008 4484 0.902 37.71 0.688 6.255 0.871
HF TYPE 0
DEE TYPE 1 128.1 1.025 971.9 1.219 1182 0.997 2658 0.864 199.1 0.682 47.13 0.814 821.7 0.657 52.36 0.814
EEA TYPE 1 0.017 0.946 443.1 0.835 11.41 0.687 0.153 0.924
1 1 1 1 1 1 1 1 1 1 1 1 1 1
10 10 8 3 1 1 6 2 1 1 4 1 1 1
50 50 40 17 5 3 30 10 2 1 20 5 1 1
100 100 80 33 10 5 60 20 4 1 40 10 2 1
500 500 400 170 50 25 300 100 20 5 200 50 8 1
1000 1000 800 330 100 50 600 200 40 10 400 100 16 2
5000 5000 4000 1670 500 250 3000 1000 250 50 2000 500 80 10
Inspection Effectiveness
SVI 4 Inspections 5 Inspections 6 Inspections
E
D C B A D C B A D C B A
1 1 1 1 1 1 1 1 1 1 1 1 1 1
10 10 2 1 1 1 1 1 1 1 1 1 1 1
50 50 10 2 1 1 5 1 1 1 1 1 1 1
100 100 20 5 1 1 10 2 1 1 5 1 1 1
500 500 100 25 2 1 50 10 1 1 25 5 1 1
1000 1000 200 50 5 1 100 25 2 1 50 10 1 1
5000 5000 1000 250 25 2 500 125 5 1 250 50 2 1
Notes: SI is the Maximum Severity Index determined for each specific SCC Cracking
Mechanism