#8943

Cp
During an adiabatic process, the pressure of a gas is found to be proportional to the cube of its absolute temperature. The ratio for the gas is :
Cv

3
A
2

4
B
3

2
C
1

5
D
3

#18590

A 20.0 cc mixture of C O, C H and H e gases is exploded by an electric discharge at room temperature with excess of oxygen. The volume contraction is found to be 13.0 cc. A
4

further contraction of 14.0 cc occurs when the residual gas is treated with K OH solution. The composition of the gaseous mixture in terms of volume percentage will be :

A C O : 40% , C H4 : 20% , H e : 40%

B C O : 40% , C H4 : 30% , H e : 20%

C C O : 50% , C H4 : 20% , H e : 30%

D C O : 50% , C H4 : 10% , H e : 40%

#28775
The maximum number of isomers (including stereoisomers) that are possible on mono-chlorination of the following compound, is:

A 8

B 9

C 10

D 11

#29690

Which of the following compounds would undergo Cannizzaro reaction?

A) H C H O

B) C 6 H5 C H O

C) C l 3C − CHO

D) (C H 3 )3 C − CHO

A A and B only
 B B and C only

C C and D only

D A, B, C and D

#31957

Match the chemical conversions in List-I with appropriate reagents given in List-II.

List 1 List 2

1 (i)H g(OAc)2 ; (ii)N aBH4

A 2 N aOEt

3 Et − Br

4 (i)BH3 ; (ii)H2 O2 /N aOH

D
#74327

Calculate the potential of an indicator electrode versus the standard hydrogen electrode, which originally contained 0.1M M nO and 1.72M H , and was treated with F e
−
4
+ 2+
,

necessary to reduce 90% of K M nO to M n

4
2+
. [E 0

M nO4 −/M n
2
= 1.51V ]

A 1.4V

B 1.5V

C 1.6V

D 1.3V

#74514

100 ml of 0.1 M solution of a weak acid H A has molar conductivity 5 Scm 2

mol
−1
. The osmotic pressure of the resulting solution obtained after dilution of original solution upto 1

litre at 500 K, assuming ideal solution is: 

∞
(Given : λm (H
+ 2
) = 450 Scm mol
−1 ∞
,  λm (A
− 2
) = 50 Scm mol
−1
, R = 0.08 L atm mole −1
K
−1
, √−−
10 = 3.2)

A 0.3128 atm

B 0.4128 atm

C 0.5128 atm

D 0.6128 atm

#76036

Which is/are the correct IUPAC name(s) of the corresponding structures?

 A

3-(N-Ethylamino)-2-methylcyclohexan-1-ol

3- (2-Aminoethyl)-2-methylcyclohexan-1-ol

Methyl 4-chlorocarbonyl-3-cyanobutanoate

Cyclohexanal

#262519

Tritium, T (an isotope of H ) combines with fluorine to form weak acid T F , which ionizes to give T . Tritium is radioactive and is a β− emitter. A freshly prepared aqueous
+

solution of T F has pT (equivalent of pH ) of 1.5 and freezes at −0.372 ∘

C . If 600 mL of freshly prepared solution were allotted to stand for 24.8 years.

If ionization constant of T F is Ka = 7.3 × 10

−x
, value of x is :

(Given K for water =

f 1.86 kg mol K
−1
, t 1/2 for tritium = ).
12.4 years
#482271

Identify the conjugate acids and bases in the following equation:

           N H 3 + H2 O ⇌ N H
+

4
+ OH
−

A (H2 O, OH
−
) and (N H +

2
, N H3 )

B (H2 O, OH
−
) and (N H +

4
, NH
2−
2
)

C (H2 O, OH ) and (N H 3, N H4 )

D (H2 O, OH
−
) and (N H +

4
, N H3 )