Académique Documents
Professionnel Documents
Culture Documents
INTRODUCTION
Safe drinking water is a human’s birth right as much a birth right as clean air. However, much of
the world’s population will not have access to safe drinking water of the six billion people on
earth, more than one billion (one in six) lack access to safe drinking. Moreover about 2.5 billion
(more than one in three) do not have access to adequate sanitation services.
Together these short comings spawn water borne diseases that kill more than 6 million children
each year (RWAS 2002). The problem scarcity or insufficient portable drinking water is more
pronounced in developing or third world countries. In Nigeria for instance, government could
scarcely afford the cost of the infrastructural outlay needed to provide portable water for the
citizens; a teeming population of about 140 million people. The problem is further compounded
by limited technology, insufficient technical inputs poor maintenance culture (for existing water
Given that wells constitute a major source of water to majority of Nigerians, adequate attention
should be given to this important source of drinking water. While drinking water standards are
enforced for public water systems, private water supplies (well waters) are not subjected to these
standards. Worked on the water quality of shallow wells located close to dump sites in Akure
Nigeria.
Characteristics of drinking water in bendel state of Nigeria. While (Amstrong and Schneider,
1971) researched into the preliminary chemical characterization of water in experimental lake
areas.
1
Dealt with the water quality in Akure, Nigeria safe drinking water must be among the highest
priority for every nation on earth. Today contaminated water kills more people than cancer,
AIDS, wars and accidents. It is virtually important that the water which humans drink is free of
disease causing germs and toxic chemicals that pose a threat to public health (RWAS 2002)
Water is a basic human need and is next to no other in importance. An abundant natural resource,
it is critical for the sustenance of human life. In fact above two third of a human body is made up
Water is a key determinant of sustainable development that should be carefully managed to make
for suitable and sustainable human health as well as general well being. The basic purposes for
which water is domestically required include drinking, bathing, cooking and general sanitation
such as laundry, flushing of closet and other household chores (Ogunawo, 2004)
Thus an assured source of water both qualitatively and quantitatively for these purposes greatly
improves the social and economic activities of the people. (Faniran, 1977) and (Oyebande, 1986)
Portable water supply to communities in Elele (Madonna) is the responsibility of the government
of Rivers State, which in most cases has been characterized by low productivity, low coverage
These supplies by government are absent in many rural communities. Rural dwellers therefore
depend on various available water resources. The quality of these sources is generally not
guaranteed and cases abound where health problems have arisen as a result of consumer drinking
from such sources. Previous studies on physiochemical properties of water have reported
2
shortages of existing supplies which imposes heavy burden on the health of the people and
The Elele community in Rivers State Nigeria has government operated water scheme. The
scheme provided by the Niger Delta development Commission (NDDC) which is functional.
Thus to meet their daily water need and household requirement, the residents source water from
On our rapidly industrializing world were many inorganic and organic substances, sometimes in
high concentrations, are constantly been introduced into water bodies and the soil periodic
knowledge of the physical and chemical characteristics of drinking water has become very
measurements of water and waste water indicator. These measurement include electrical
conductivity dissolved oxygen, total dissolved solid (TDS), total suspended solid (TSS),
chemical oxygen demand (COD), biochemical oxygen demand (BOD), temperature and heavy
metals. With respect to these measurements, world health organization (W.H.O) sets an
international reference point as standard for drinking water safety.( W.H.O, 2006) (Obahiagbon
and okieimen et al, 2007) indicated in their recent report that the major contaminant in drinking
water especially from wells in our towns are heavy metals, these heavy metals find their way into
the soil and ground water through activities like intense agriculture, power generation, industrial
discharge seepage of municipal landfills, septic tank effluence, to mention a few. The deleterious
and the detrimental effects of these heavy metals to the existence of humans, his crops and
animals cannot be over emphasized (Sanjay Kumar et al, 1990). Heavy metals accordance in the
3
bodies of organisms when they ingest them. (Egereon and Dike, 2007). Some marine algae
containheavy metal of concentration up to 100 times more than that of the water in which they
are living.
Elele is a town in Rivers State of Nigeria, until the mid 1990’s, water well and borehole were
uncommon features in the town, because of these regular supply of portable water, borehole has
become common recently. This water borehole has become common because of the epileptic
nature of the water distribution caused by poor maintenance culture and poor planning. On the
quest for portable water source, some of the dwellers soil water from these boreholes before
consumption. But contrary to their believe, boiling has no effect on water contaminant such as
heavy metals, rather it concentrates the ion of these metal in the water. Few reports are available
(Njoku et al, 2007) on the concentration of heavy metals in ground water within Imo and
environs.
To examine some of these water quality parameters of well water as a major source of drinking
An assessment of heavy metals concentration in water wells in Elele with the densely populated
Madonna University as a starting point. This will go a long way determine the pollution status of
these well waters and the potential impact of these metal to the surrounding ecosystem as a result
of food chain.
4
1.5 Scope of the Study
Elele is a medium sized community in Local Government Area (LGA) of Rivers State
geographically; Elele is located within the western position of the LGA. It is located on latitude
5.50 and longitude 6.13. it shares a boundary within the west, in the north, in the south and in the
east. The research proposal will also seek to arise the physical and chemical parameters and
collected will be limited to the University community only. (Njoku et al, 2007)
The significance of this study is geared towards ensuring that safe drinking water must be among
the highest priority for every nation on earth. This is because contaminated water kills people
than Cancer, AIDS, Wars or even accidents. It is virtually important that the water which humans
drink be free of diseases causing germs and toxic chemicals that pose a threat to public health.
More importantly, the study will be of great benefit to the communities where government could
scarcely afford the cost of infrastructural outlay needed to provide portable water for her citizens.
The problem is further compounded by limited technology, insufficient technical inputs, poor
maintenance culture (for existing water facilities), requsite skills and present global financial
meltdown.
More so, this study will apart from arising awareness about the quality of water consumed by
people, it will equally create government’s attention through relevant ministries to pay attention
to part of the state which hitherto had not been receiving adequate attention. It is hoped that the
data generated from the study will help the government in accessing quality of water consumed
5
CHAPTER TWO
Chemical applied for plant protection the most common among them being pesticide, chlorinated
pesticide applied in plants protection, 45% are herbicides, 36% insecticides, 17% are fungicides
and about 1% rodenticides; at least 10% of this appears in water sources infection infections
caused by contaminated water amount worldwide to some five million cases yearly. In
industrially developed countries, there is in the environment an elevated level of metal ions.
Different inorganic substances and ions have various positive and negative infections, the
metabolisms or organisms for instance, magnesium ions are involved in many cellular functions
like glycolysis, respiration and stability of ribosomers, manganese ions are important for the
Heavy metals are harmful even in their lowest concentration. In a more complicated state,
mutation could be suspected as was proved by (Zelibor et al, 1987) that metal are not degradable;
consequently they accumulate in the biological system resulting in chronic damage. (Yermelor et
al, 1975) believes that even in the case of a complete ban on production in all mercury plants,
6
2.1 SOURCES OF WATER
Rain water
Surface water
Ground water
Rain water
Rain water is naturally the purest source of water but as it gets down it absorbs compounds from
the atmosphere. It’s main components are chloride, nitrate, sulphate, sodium, potassium and
ammonium. The concentration can vary from roofs and prepared water. Shades which could
assist in polluting and making it one of the unfit sources of water for drinking. It is naturally the
Surface water
It includes streams, ponds and lakes. Its main ionic compounds include chloride, nitrates,
sulfates, magnesium and calcium concentration in different surface water contain humic
substances. The concentration of components here are more than those in rain water and ground
water, sea water could be considered as surface water. The sort contents in it is so much that it
cannot be used as drinking water because it could take the body a lot of work to flush out excess
salt before usage for metabolism. It is also inadequate in machinery used as it’s nest machine, it
7
Ground water
Ground water may be defined as the water in the ground that will move or drain freely by
gravity. Water beneath the surface where all the voids in the rocks and soils are filled. Ground
They are said to emanate from the melting of meteoric water into the ground, they have served as
source of domestic water supply. It offers cheap, purer supply. The main ionic components are
nitrates, chloride, sulfate, potassium, magnesium, sodium and calcium. This includes the natural
spring, wells, and boreholes flows unsteady and non uniform. As it’s peculate into the earth, it is
subjected to some purifying actions by numerous chains and impervious rock strata/layers
because of the disintegrating and dissolving power of water, it dissolves some of the rock which
makes up the earth layer making it to have impurities like oxides, nitrates, sulfate, calcium, iron
and magnesium, some level purify, shaft, springs, boreholes. Spring water has very little
This uses of water can be over emphasized used in virtually every area of life. it is vital to the
General cleaning of household properties like windows, cars, walls, floors e.t.c.
8
Heating and air conditioning
Physical Test
Color
Odor/taste
Temperature
Turbidity
Chemical Test
Dissolved oxygen
Alkalinity
Total hardness
Chloride
9
Table 2.1
Colour 15 Colorimetric
Ph 6.5-8.5 Electrometric
11
CHAPTER THREE
3.1 Materials
Apparatus
Volumetric flask
Beaker
Measuring cylinder
Conical flask
APHA/AWWA 1985
Desiccators
Spatula
Pipette
Burette
Turbid meter
PH meter
Glass electrode
12
Reagent Used
Sodium acetate, arsenic, hydroxylamine hydro chloride, EDTA, HN03, Ammonia, Potassium
I collected 9 well water samples from different locations in Madonna University Elele, namely
borehole located along welding department, borehole along pilgrim center, borehole in the
Triumph factory. A 250 ml capacity borosilicate glass sample bottle for chemical analysis was
washed with detergent concentrated HNO3 and rinsed with distilled water severally. At each
sampling site, the sampling bottle was rinsed thrice before taking samples. Composite well water
samples as collected from three major areas from the University as said earlier and information
on data time, temperature about sample collected was recorded on labels. Spacing between
sample collections in a given area will be about 500meters. Well water sample was collected
with 2 liter plastic hydro bios water sampler and kept in the laboratory refrigerator at 40°𝑐 prior
to analysis. The treatment after sampling depends largely on the type of analysis for elemental
analysis such as alkaline earth and trace metal, conc. HNO3 of high purity was added to the
sample to obtain pH less than 2. This technique stabilizes the samples, maintained the oxidation
state of the elements, discouraging precipitation metal and prevented metal from adhering to the
containers.
13
3.3 Methods
I analyzed for odor, taste and color with a sensory organs. Total dissolved solid and total solid
will be estimated by gravimetric method, turbidity will be measured by nephelo metric method,
temperature will be measured using a mercury thermometer while pH was done using a Philip
model PW 9418 PH meter after the meter has been duly calibrated with standard buffer of pH
4.0, 7.0, and 9.0 (Ademoroli, 1996) conductivity measurement was done using conductivity
meter model NATOP-PBS while acidity, alkalinity and total hardness will be done by titrimetry.
Chloride will be done by Mohr’s method and dissolved oxygen will be determined by Winkler’s
iodometric method. Also biochemical oxygen demand will be determined by Winkler’s method
heavy metals such as (Fe, Pb, Zn, Cu,) will be analyzed by Perkins-Elmer, S 3110 Boston ASS.
All results obtained will be subjected and referred to a statistical analysis and presented in
tabular form and be matched/compared against W.H.O standard for drinking water. The
A Philip analog pH meter was used to determine the pH of all samples. While the electrical
conductivity was determined using a conductivity meter of the grochek type of HI 9813 model,
both PH and electrical conductivity were determined according to (Egereomu and Ibeh, 2003) .
This was accomplished by the evaporation method. Evaporation dish was weighed and later
100cm³ of the water sample was introduced into the weighed dish and dried in an oven
maintained at 103°𝑐 for 1 hour. After drying it was transferred to a desiccators and allowed to
14
cool. The dish was finally weighed with it’s contents. The difference in weight to obtain the
weight of the total dissolved solid. (Franson, 1975) and (IIPA, 1970)
3.3.3 Temperature
The temperature of the three water samples was determined using the mercury-in- glass
3.3.4 Alkalinity
50ml of the water was pipette into a 250ml conical flask and 3 drops of methyl orange alkalinity
added and swirled. The solution was titrated with standard H2SO4 solution to a colourless end
point. The titral value were recorded as total alkalinity sample and the alkalinity calculated from
Volume of sample
solochrome black T indicator was also added and the solution stirred. The mixture was titrated
with 0.01m EDTA solution until the colour changed from wine red to pure blue with no reddish
tinge remaining. The total hardness of the water sample was calculated by the expression
15
For the determination of calcium hardness, 100 ml of water sample was introduced into a beaker
and 1 ml of NaOH buffer added. 3 drops of mirazine indicator were added to the solution and
stirred. The mixture was again titrated with standard 0.01N MEDTA solution until a colour
change from light red to deep red as the end point. The calcium hardness of water was calculated
The difference between the total hardness of water and the calcium hardness of water was
Dissolved Oxygen was measured with DO meter. Jenwey Model 9071 according to
APHA/AWWA (1985)
PROCEDURE: 100ml of water was measured into the conical flask. PH of the water was
adjusted to 8.0 using sodium hydroxide solution.10ml of potassium chromate was added to the
solution. the mixture was then titrated with 0.014M AgNO3 solution until the colour changed
from colourless to pinkish yellow is the end point . A blank of 0.02cm3 pure water was used for
16
3.3.8 Metal ion Determination
PROCEDURE: Determination of metallic ion(i.e. Fe, Pb, Zn, Cu) was done using the Perkins
Spectrophotometer technique. Stock solution from which working standards were prepared by
serial dilution was prepared as reported by Hatch water Analysis (1983). Standard graphs for the
detection of the elements were prepared according to (Enegeronu and ibeo, 2003) and standard
PROCEDURE: This was determined by looking at each of the water samples closely by direct
PROCEDURE: Distilled water was put into one of the glass tubes and one of the water samples
was put into the other (glass tube), the reading was taken by placing the disc over the end of the
tube containing distilled water.3 drops of methyl orange indicator was also added and it was
titrated against 0.1N HCl, the colour at the end-point was pale pink and the volume of 0.1N HCl
PROCEDURE: A wide-mouth glass-stopped bottle was rinsed internally and externally using
4M HCl acid until it was completely odorless. Then, it was finally rinsed with distilled water.
The bottle was filled with the sample half-way, the stopper was inserted and was shaken-
17
vigorously for 2 or 3 seconds, after which the stopper was quickly removed and the odor of
sample was observed by bringing the bottle close to the nostrils. This procedure was applied for
For the taste determination, the beakers were rinsed as described for odour above, then each of
the samples were poured into the beakers as soon as it was collected and the taste was noted.
3.3.12 Turbidity
PROCEDURE: After all the apparatus had been washed dried, the water samples which have
earlier been put in the conical flask were taken to the turbid meter for analysis. The curette was
rinsed thoroughly with the corresponding water samples to be tested and it was filled with the
sample up to the mark. It was handled with clean cloth. The curette was thoroughly dried and
cleaned to make sure no water or dirt was on it and it was put into the turbid meter. The sample
has to be left in the measurement until the value appearing on the screen is stable and is then
recorded. This procedure was done for the remaining water samples
18
3.4. Results
A 0.42 26.00
B 0.45 27.45
C 0.50 31.00
Calculation:
19
Table 3.2
Calculation: 𝑥 − 𝑦 × 100
z 1
20
Table 3.3 Determination of Dissolved Oxygen
pH
21
Volume of Sample used
Normality = 0.1
Vol. Of sample = 50
22
Table 3.6 Determination of Lead present
23
Table 3.7 Determination of Manganese present
24
CHAPTER FOUR
4.1 Findings
Table 4.1
Overall results of the Physiochemical Analysis of the Samples Compared with Standards
25
4.2 Discussion
Results therefore indicate multiple pollution potententials for most produce water parameters.
Despite the existence of produced water treatment measures government need to improve in
order to minimize pollution danger due to elemental contamination of the inland water to which
they discharge produced water (verla et al, (2007) accessed the physiochemical characteristics of
the produced water during crude oil processing and highlighted the public health implications.
Result showed gross population of surface water when discharged into water bodies or land the
effect of petroleum produced water could abet the bioaccumulation of heavy metals, toxic effect,
staining of discharge sites to detrimental biolological effect on plants, aquatic life and man.
(Bailey et al, 2000) produce encrustation of land by water bodies to which it is discharged.
(Egereonu, 2005)
26
CHAPTER FIVE
5.1 Conclusion
From the result of the analysis tabulated from in the table II which is the comparison of the result
samples with WHO standard, the physical parameters-odor, taste, temperature, color and water
appearance of the whole sample A, B, and C where odorless, colourless, tasteless and clear at room
temperature.
The result on the chemical parameters determined on all the sample showed that lead was slightly
higher than the WHO standard for all the samples (A, B, C). The concentration of lead in sample A, B, C
is 0.30, 0.18, 0.18 respectively, while that of the W.H.O standard is 0.01. The difference though little,
should not be dismissed with a wave of the hand, as continuous intake of this quality will eventually pose
danger to the human body. The other parameters determined were seen to fall within the range
propagated by W.H.O. The lead (Pb) concentration and other concentration of other parameter
studied in sample A were seen to be higher when compared with the result of the other samples
Out of the analyzed samples, sample B and C gave better results because they were
27
5.2 Recommendation
- There should be a regular analysis of the water sources to monitor pollution rate at all
time.
- The people living in this area (Elele Madonna) should be enlightened on proper waste disposal
- In case of treatment of water when taking, they should use easiest method of treatment which
is boiling process (boiling the water above 100c). This will increase its portability and also saves
more lives.
- In case of borehole drilling. People in this area (Elele Madonna) should avoid constructing of
- Borehole should not be constructed with lead pipe to avoid dangers pose to human body.
28
REFERENCES
Amoo A.I and Amuho U.E (2005) Comparison of water quality in concrete ringed water wells
Franson, M. A. (Ed) (1975) Standards Method for the Examination of Water and Waste – water
14th Ed. APHA – AWA – WDCF NY. 150 – 162 and 235 – 252.
Garg, S. P. (1978) Ground Water and Tube well Oxford and IBH Pub. Co. New Delhi. India.
International Institute for Tropical Agriculture (1970) selected methods for soil and plants
Jaman S.N and Ahmed A.S (2000) Treatment of textile waste water using line and activated
Obaniagbon K.O and Okieimen C.O (2007) ‘Comparison of the level of some toxic heavy Third
world Academic of Sciences, TWAS (2002): ‘safe Drinking Water’ The need, the problem
solution and action plan. Third world Academic of sciences, Italy, Pp 8-12
Obodo, G. A. (2001). The Toxic metals in River Niger and its Tributaries Journal of Indian
solutions with thiolated maize (zea mays) cob meal, biological waste, 30, Pp 225-230
TEPA (1991) Guidelines and Standards for Environmental Pollution Control in Nigeria 39.
Vogel, A. I. (1984) A Textbook of Inorganic Analysis 3rd Ed. Longman London, 256.
Wills, J. (2000): A Survey of Offshore Oil Field drilling Wastes and Disposal Techniques to
Reduce the Ecological Impact of Sea dumping. Saklin Environment Watch (13) Pp 23 – 29
30