Name: _______________________

11 Chemistry Roll #:
Time: 30Min; Marks:17
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Q1) Choose the most appropriate option. Cutting / overwriting is not allowed: 17 Marks
i) The mass of two moles of electrons is:
A) 1.10 mg B) 1.008 mg C) 0.184 mg D)1.673 mg
ii) Quantum number value for 2p orbitals are:
A) n = 2, l=1 B) n = 1, l = 2 C) n-1, l = 0 D)n = 2, l = 0
iii) When 6 d orbital is complete, the entering electron goes to:
A) 7 f B) 7 s C) 7p D)7 d
iv) Splitting of spectral lines of the hydrogen atom under the influence of magnetic field is called:
A) Stark effect B) Zeeman effect C) Compton effect D)Photoelectric effect
v) The nature of positive rays depends on
A) the nature of B) the nature of C) the nature of residual D)the temperature
electrode discharge tube gas
vi) The maximum number of electrons in a sub-shell is given by:
A) 2e + 1 B) 2e - 1 C) 2(2e + 1) D)2(2e - 1)
vii) Maximum no. of electrons in an orbital is:
A) 6 B) 10 C) 14 D)2
viii) The number of bonds in nitrogen molecule is:
A) One sigma and one pi B) One sigma and two pi C) Three sigma only D)Two sigma and one pi
ix) Which of the following species has unpaired electrons in anti-bonding molecular orbitals:
A) O2 2+ B) N2 2− C) B2 D)f2
x) Which of the following has highest bond energy:
A) HI B) HBr C) HCl D)HF
xi) Formation of chemical bond takes place when.
A) Energy is absorbed B) Forces of repulsion C) Forces of attraction D)Forces of attraction
overcome forces of are equal to forces of overcome forces of
attraction. repulsion. repulsion.
xii) Total number of bonds in C2 H4 molecule are:
A) Six B) Four C) Five D)Eight
xiii) The number of bonds in oxygen molecule is:
A) One sigma and one pi B) One sigma and two pi C) Three sigma only D)Two sigma only
xiv) The hybridization of carbon in C2 H4 is:
A) SP 3 B) SP2 C) SP D) dSP3
xv) For the reaction NaOH + HCl → NaCl+ H2 O, the change in enthalpy is called:
A) Heat of reaction B) Heat of formation C) Heat of neutralization D)Heat of combustion
xvi) qp = qv
qv
A) qp < qv B) qp > qv C) qp = D)none of these
2

xvii)If an endothermic reaction is allowed to take place very rapidly -in the air, the temperature of the
surrounding air:
A) Remain constant B) Increases C) Decreases D)Remain unchanged

 
11 Chemistry Name: _______________________

Roll #:
Time: 2:30Hr; Marks:68
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Q2) Write short answers of ANY EIGHT (08) of the following: 16 Marks
i) Energy of an electron is inversely proportional to 'n2' but energies of higher orbits are always greater
than those of the lower orbits. Justify it.
ii) Write two defects of Rutherford's atomic model.
iii) Calculate mass of an electron when e = 1.758 × 1011 C. kg −1
m

iv) Calculate the mass of electron when its e/m value is 1.7588 x 1011 C Kg −1 .
v) Define Zeeman's effect and Stark effect.
vi) Define co-ordinate covalent bond and give an example.
vii) The bond angles of Fl2 O and NH3 are not 109.5∘ like that of CH4 . Although O-atom and N-atom are
3
SP hybridized like C-in CH4 , give reason.
viii)Helium is diamagnetic in nature, justify.
ix) What is octet rule? Give two examples of compounds which deviate from it.
x) State the geometry of NH3 molecule on the basis of VSEPR theory.
xi) Is it true that AH and AF have the same values for the reaction taking place in the solution state?
Explain.
Q3) Write short answers of ANY EIGHT (08) of the following: 16 Marks
e
i) Why value for the cathode rays is just equal to that of electron?
m

ii) Define Zeeman's effect and Stark effect.

iii) Write down the electronic configuration of Fe (26) and Br (35).
iv) Transition temperature is the term used for elements as well as compounds. Explain.
v) How neutrons were discovered by Chadwick? Give the equation of nuclear reaction involved.
vi) Why the melting points, boiling points, heat of sublimation and heat of vaporization of electrovalent
compounds are higher as compared with those of covalent compounds?
vii) Define bond order. Calculate bond order of hydrogen molecule.
viii)Define co-ordinate covalent bond and give an example.
ix) Why the abnormality of bond length and bond strength in HI is less prominent than that of HCl?
x) Why ionic crystals do not conduct electricity in the solid state?
xi) What is a thermochemical equation? What information does it convey? Explain with an example.
xii) The melting points, boiling points, heat of vaporizations and heat of sublimations of electrovalent
compounds are higher than covalent compounds. Explain.
Q4) Write short answers of ANY SIX (06) of the following: 12 Marks
i) Calculate mass of an electron when e
= 1.758 × 10
11
C. kg
−1
m

ii) How the K-series, L-series and M-series of x-rays spectrum are produced?
iii) MOT is superior to VBT, explain.
iv) Why the energy of antibonding molecular orbital is higher than corresponding bonding molecular
orbitals?
v) The dipole moments of CO2 and CS2 are zero but that of SO2 is 1.61D.
vi) What is octet rule? Give two examples of compounds which deviate from it.
vii) Define ionization energy. Give two factors on which it depends.
viii)Differentiate between exothermic reaction and endothermic reaction.
ix) What is internal energy of a system?

Give explanatory answers of (both parts of) ANY THREE of the following: 24 Marks
5A) Describe Millikan's Oil Drop Method for the measurement of charge on electron
5B) Explain important points of molecular, orbital theory and draw structure of nitrogen (N2 ) molecule
according to this theory
6A) Define the following with example: (i) System (ii) Non-spontaneous reactions (iii) Surrounding (iv)
Endothermic reactions.
6B) Define quantum numbers. Discuss briefly Azimuthal quantum number.
7A) Describe the bonding in O2 according to molecular orbital theory and explain its paramagnetic
property.
7B) State and explain Hess's law of constant heat summation with an example.
8A) Discuss magnetic and spin quantum numbers.
8B) Define hybridization-process and explain the structure of ethyne (C2 H2 ) molecule on its basis.
9A) State and explain Hess's law of constant heat summation with an example.
9B) Define quantum numbers. Discuss briefly Azimuthal quantum number.
10A) How will you describe the paramagnetic character of O2 molecule on the basis of M.O.T?