EJERCICIO 1

C2 H 4( g ) + H 2O( l ) � C2 H 5OH ( l ) ( 600K )

Especie
C2H4 H2O C2H5OH Unidades
ni -1 -1 1
DH0f,i 52510 -241818 -234950
DG0f,i 68440 -228572 -167850

ol
J/m
DH 0
rxn -45642
DG 0
rxn -7718

CORRECCIÓN
C2H4 H2O C2H5OH
A 1.424 8.712 33.866 DA 23.73
B 1.44E-02 1.25E-03 -1.73E-01 DB -0.188244
C -4.39E-06 -1.80E-07 3.49E-04 DC 0.00035374

DHrxn -12468.402
DGrxn -28154.912 DH T = DH 298.16
0
+ DCP0hm ( T - 298.15)
T2=Trxn 600
T1=T0 DH 298.15
� 0
298.15
( DG / RT ) = ( DG / RT ) - �
K

0 0
Tma 449.075 T2 T1 = 25�
C

R 8.314 Jmol-1 K-1

CPma 109.900938

DCP0hm DC DD
R
= DA + ( DB ) Tma +
3
( 4Tma2 - T1T2 ) +
T1T2
- 298.15)

DH 298.15
� 0
+ DC phm ( T2 - T1 ) �
��1 - 1 �
= ( DG / RT )
0
- �
� �
T1 = 25�
C R �T2 T1 �
EJERCICIO 2
CO2( g ) + 3H 2( g ) � CH 3OH ( g ) + H 2O( g ) ( 900 K )

Especie
CO2 H2 CH3OH H2O Unidades
ni -1 -3 1 1
DH 0
f,i -393510 0 -200940 -241818
DG 0
f,i -394370 0 -162320 -228572

ol
J/m
DH0rxn -49248
DG0rxn 3478

CORRECCIÓN
CO2 H2 CH3OH H2O
A 5.457 3.249 2.211 3.47 DA -9.523
B 1.05E-03 4.22E-04 1.22E-02 1.45E-03 DB 1.14E-02
C 0 0 -3.45E-06 0.00E+00 DC -3.45E-06
D -1.16E-05 8.30E-07 0 1.21E-06 DD 1.03E-05

DHrxn -69577.441
DGrxn -129951.31 DH T = DH 298.16
0
+ DCP0hm ( T - 298.15 )
T2=Trxn 900
T1=T0 DH 298.15
� 0
+
298.15
( DG 0
/ RT ) = ( DG / RT )
0
- �
K

Tma 599.075 T2 T1 = 25�

C

R 8.314 Jmol-1 K-1

CPma -33.778253

DCP0hm DC DD
R
= DA + ( DB ) Tma +
3
( 4Tma2 - T1T2 ) +
T1T2
- 298.15 )

DH 298.15
� 0
+ DC phm ( T2 - T1 ) �
��1 - 1 �
= ( DG / RT )
0
- �
� �
T1 = 25�
C R �T2 T1 �
EJERCICIO 3 C2 H 5OH ( l ) + O2( g ) � CH 3COOH ( l ) + H 2O( l ) ( 345K )

Especie
C2H5OH O2 CH3COOH H2O Unidades
ni -1 -1 1 1
DH0f,i -234950 0 -432800 -241818
DG0f,i -167850 0 -374600 -228572

ol
J/m
DH 0
rxn -439668
DG 0
rxn -435322

CORRECCIÓN valores En tabla C1 capacidad calorifica

C2H5OH O2 CH3COOH H2O
A 33.866 3.639 27.281933 8.712 DA -1.511067
B -1.73E-01 5.06E-04 -1.06E-01 1.25E-03 DB 6.73E-02
C 3.49E-04 0 1.61E-04 -1.80E-07 DC -1.88E-04
D 0 -2.27E-06 0.00 0 DD 2.27E-06

DHrxn -439420.2
DGrxn -572775.2 DHT = DH 298.16
0
+ DCP0hm ( T - 298.15 )
T2=Trxn 345
T1=T0 DH 298.15
� 0
+
298.15
( DG 0
/ RT ) = ( DG / RT )
0
- �
K

Tma 321.575 T2 T1 = 25�

C

R 8.314 Jmol-1 K-1

CPma 5.28915821

DCP0hm DC DD
R
= DA + ( DB ) Tma +
3
( 2
4Tma - T1T2 ) +
T1T2
ad calorifica

- 298.15 )

DH 298.15
� 0
+ DC phm ( T2 - T1 ) �
��1 - 1 �
= ( DG / RT )
0
- �
� �
T1 = 25�
C R �T2 T1 �