Acetone

Version 2.1

Effective Date: 28.05.2012

Material Safety Data Sheet

1. IDENTIFICATION OF THE SUBSTANCE/ PREPARATION AND COMPANY/ UNDERTAKING

Material Name : Acetone

Uses : Industrial solvent.
Product Code : S1212, U8903, S1260

Supplier : Chemisol Inc.

3/F Johnson Bldg. #5 D. Muñoz St.
Tandang Sora, Quezon City
Philippines

Telephone : (632) 9385388

Fax : (632) 9383818

Emergency : (632) 9385388

Number

2. HAZARDS IDENTIFICATION

GHS Classification : Flammable Liquids: Category no. 2

Serious Eye Damage/Eye Irritation: Category 2A
Specific Target Organ Toxicity (single exposure): Category no. 3
Narcotic effects.
Aspiration Hazard: Category no. 2
GHS Label Elements
Symbol(s) :

Signal Words : Warning

GHS Hazards Statements : PHYSICAL HAZARDS:
H225: Highly flammable liquid and vapor.
HEALTH HAZARDS:
H320: Causes eye irritation.
H336: May cause drowsiness or dizziness.
H305: May be harmful if swallowed and enters airways.
ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard under GHS criteria.
GHS Precautionary statements
Prevention : P210: Keep away from heat/sparks/open flames/hot surfaces. -
No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting
equipment.
P242: Use only non-sparking tools.
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P243: Take precautionary measures against static discharge.

P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear protective gloves/protective clothing/eye
protection/face protection.
P235: Keep cool.
Response : P301+P310: IF SWALLOWED: Immediately call a POISON
CENTER or doctor/physician.
P331: Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/take off
immediately all contaminated clothing. Rinse skin with
water/shower.
P304+P340: IF INHALED: Remove to fresh air and keep at rest
in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical
advice/attention.
P370+P378: In case of fire: Use for extinction.
P370+P379: In case of fire: Use foam, water spray or fog for
extinction.
P312: Call a POISON CENTER or doctor/physician if you feel
unwell.
Storage : P403+P233: Store in a well-ventilated place. Keep container
tightly closed.
P235: Keep cool.
P405: Store locked up.

Disposal : P501: Dispose of contents and container to appropriate waste

site or reclaimer in accordance with local and national
regulations.

Other Hazards which do

not result in classification : Exposure may enhance the toxicity of other materials.
Repeated exposure may cause skin dryness or cracking.
Slightly irritating to respiratory system.

Aggravated Medical
Condition : Pre-existing medical conditions of the following organ(s) or organ
system(s) may be aggravated by exposure to this material : Eyes.
Respiratory. Skin.

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Material Formal Name : Propan-2-one

Synonyms : Dimethyl Ketone
CAS No. : 67-64-1
INDEX No. : 606-001-00-8
EINECS No. : 200-662-2
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Classification of Components according to GHS

Chemical Name Synonyms CAS No. Hazard Class Category Hazard Statements Conc.
Flam. Liq., 2; Eye Irrit., 2; H225;H319;
Acetone 67-64-1 100.00%
STOT SE, 3; H336;

Additional Information : Refer to Chapter 16 for full text of EC R-phrases.

4. FIRST AID MEASURES

Inhalation : Remove to fresh air. If rapid recovery does not occur, transport to the nearest
medical facility for additional treatment.
Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by
washing with soap if available.
Eye Contact : Immediately flush eyes with large amounts of water for 15 minutes while
holding the eyelids open. Transport to the nearest medical facility for
additional treatment.
Ingestion : If swallowed, do not induce vomiting: transport to the nearest medical facility
for additional treatment. If vomiting occurs spontaneously, keep head below
hips to prevent aspiration.
Advice to Physician : Potential for chemical pneumonitis. Consider: gastric lavage with protected
airway, administration of activated charcoal.

5. FIRE FIGHTING MEASURES

Clear fire area of all non-emergency personnel.

Specific Hazards : Containers exposed to intense heat from fires should be cooled with large
quantity of water. The vapour is heavier than air, spreads along the ground and
distant ignition is possible.
Extinguishing Media : Alcohol- resistant foam, water spray or fog. Dry chemical powder, carbon
dioxide, sand or earth may be used for small fires only.
Protective Equipment for : Wear full protective clothing and self contained
Firefighters breathing apparatus. Proper protective equipment including breathing apparatus
must be worn when approaching a fire in a confined space.
Additional Advice : All storage areas should be provided with adequate fire fighting facilities. Keep
adjacent containers cool by spraying with water.

6. ACCIDENTAL RELEASE MEASURES

Avoid contact with spilled or released material. Immediately remove all contaminated clothing. For guidance on
selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. For guidance on
disposal of spilled material see Chapter 13of this Material Safety Data Sheet. Observe all relevant local and
international regulations.

Protective Measures : Avoid contact with spilled or released material. Immediately remove all
contaminated clothing. For guidance on selection of personal protective
equipment see Chapter 8 of this Material Safety Data Sheet. For guidance on
disposal of spilled material see Chapter 13 of this Material Safety Data Sheet.
Shut off leaks, if possible without personal risks. Remove all possible sources
of ignition in the surrounding area, use appropriate containment (of product and
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fire fighting water) to avoid environmental contamination. Prevent from

spreading or entering drains, ditches or rivers by using sand, earth, or other
appropriate barriers. Attempt to disperse the vapour or to direct its flow to a
safe location for example by using fog spray. Take precautionary measures
against static discharge. Ensure electrical continuity by bonding and grounding
(earthing) all equipment. Monitor area with combustible gas indicator.
Clean Up Methods : For large liquid spills (> 1 drum), transfer by mechanical means such as
vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away
residues with water. Retain as contaminated waste. Allow residues to evaporate
or soak up with an appropriate absorbent material and dispose of safely.
Remove contaminated soil and dispose of safely. For small liquid spills (<1
drum), transfer by mechanical means to a labeled, sealable container for
product recovery or safe disposal. Allow residues to evaporate or soak up with
an appropriate absorbent material and dispose of safely. Remove contaminated
soil and dispose of safely.

Additional Advice : See Chapter 13 for information on disposal. Notify authorities if any exposure
to the general public or the environment occurs or is likely to occur

7. HANDLING STORAGE

General Precautions : Avoid breathing of or contact with material. Only use in well ventilated areas.
Wash thoroughly after handling. For guidance on selection of personal
protective equipment see Chapter 8 of this Material Safety Data Sheet. Use the
information in this data sheet as input to a risk assessment of local
circumstances to help determine appropriate controls for safe handling, storage
and disposal of this material.
Handling : Avoid inhaling vapour and/or mists. Avoid contact with skin, eyes and
clothing. Electrostatic charges may be generated during pumping. Electrostatic
discharge may cause fire. Ensure electrical continuity by bonding and
grounding (earthing) all equipment. Restrict line velocity during pumping in
order to avoid generation of electrostatic discharge (<= 10 m/sec). Avoid
splash filling. Do NOT use compressed air for filling, discharge, or handling
operations. Handling Temperature: Ambient.
Storage : Keep container tightly closed. Must be stored in a diked (bunded) well-
ventilated area, away from sunlight, ignition sources and other sources of heat.
Must be kept inhibited during storage and shipment as material can polymerise.
Vapours from tanks should not be released to atmosphere. Breathing losses
during storage should be controlled by a suitable vapour treatment system,
storage Temperature: Ambient.
Product Transfer : Keep containers closed when not in use. Do not use compressed air for filling,
discharging or handling.
Recommended Materials : For containers, or container linings use mild steel, stainless steel.
Unsuitable Materials : Aluminum. Most plastics. Natural, butyl, neoprene or nitrile rubbers.
Container Advice : Containers, even those that have been emptied, can contain explosive vapours.
Do not cut, drill, grind, weld or perform similar operations on or near
containers.
Additional Information : Use the information in this data sheet as input to risk assessment of local
circumstances to help determine appropriate controls for safe handling, storage
and disposal of this material. Ensure that all local regulations regarding
handling and storage facilities are followed.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

Material Source Type Ppm mg/m3 Notation

Acetone ACGIH TWA 500 ppm

ACGIH STEL 750 ppm

Material Sources Hazard Designation

Acetone ACGIH Not classified as a human
carcinogen.

Exposure Controls
Personal Protective Equipment : Personal protective equipment (PPE) should meet recommended national
Respiratory Protection
Hand Protection
Eye Protection
Protective Clothing
Monitoring Methods
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: The level of protection and types of controls necessary will vary depending
upon potential exposure conditions. Select controls based on a risk assessment
of local circumstances. Appropriate measures include: Provide adequate
ventilation in storage areas. Use sealed systems as far as possible. Adequate
explosion-proof ventilation to control airborne concentrations below the
exposure guidelines/limits. Local exhaust ventilation is recommended. Eye
washes and showers for emergency use.
standards. Check with PPE suppliers.
: If engineering controls do not maintain airborne concentrations to a level
which is adequate to protect worker health, select respiratory protection
equipment suitable for the specific conditions of use and meeting relevant
legislation. Check with the respiratory protective equipment suppliers. Where
air-filtering respirators are suitable, select an appropriate combination of mask
and filter. Select a filter suitable for organic gases and vapours [boiling point
<65 ºC (149 ºF)] meeting EN371. Where air-filtering respirators are unsuitable
(e.g., airborne concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing apparatus.
: Where hand contact with the product may occur the use of gloves approved to
relevant standards (e.g Europe: EN374, may provide suitable chemical
protection: Longer term protection: Nitrile rubber gloves Incidental
contact/Splash protection: PVC or neoprene rubber gloves. Personal hygiene is
a key element of effective hand care. Gloves must be only worn on clean
hands. After using gloves, hands should be washed and dried thoroughly.
Application of a non-perfumed moisturizer is recommended.
: Monogoggles(EN166)
: Chemical resistant gloves/gauntlets, boots, and apron. Skin protection not
ordinarily required beyond standard issue work clothes.
: Monitoring of the concentration of the substances in the breathing zone of
workers or in the general workplace may be required to confirm compliance
with an OEL and adequacy of exposure control. For some substances biological
monitoring may also be appropriate. Examples of sources of recommended air
monitoring methods are given below or contact supplier. Further National
methods may be available. National Institute of Occupational Safety and
Health (NIOSH), USA: Manual of Analytical Methods, http://www.cdc.gov/
niosh/nmam/nmammenu.html.
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Occupational Safety and Health Administration (OSHA), USA: Sampling and

Analytical Methods, http://www.osha-slc.gov/dts/sltc/methods/toc.html. health
and Safety Executive (HSE), UK: Methods for the determination of hazardous
Substances, http://www.hsl.gov.uk/search.htm.
Berufsgenossenschaftliches Institut fűr Arbeitssicherheit (BIA), Germany
http:/www.hvbg.de/d/bia/index.html. L’Institut National de Recherche et de
Securité, (INRS), Francehttp://www.inrs.fr/securite/hygiene_securite_travail.
html.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Clear Liquid

Odour : Characteristic
pH : Not applicable
Boiling point : 56 ºC / 133 ºF
Flash point : -18 ºC/ 0 ºF (IP 170)
Explosion/ Flammability : ca. 2.1- 13 % (V)
Limits in air
Auto-ignition temperature : 540 ºC/1,004 ºF (ASTM D-2155)
Vapour pressure : 24.7 kPa at 20 ºC/ 68ºF
Density : 790-792 kg/m3 at 20 ºC/ 68 ºF (ASTM D-4052)
Water solubility : at 20ºC/ 68ºF completely miscible.
n-octanol/water partition : 0.2
coefficient (log Pow)
Dynamic viscosity : 0.33 mPa.s at 20 ºC/ 68 ºF
Vapour density (air=1) : 2 at 20 ºC/ 68 ºF
Coefficient of expansion : 0.0014 ºC
Dielectric constant : 21.4 at 20 ºC/ 68 ºF
Heat of vapourisation : 525 kJ/kg ºC
Refractive index : 1.359 at ºC/ 68 ºF (ASTM D-1218)
Specific heat : 2.14 kJ/kg ºC at 20 ºC/ 68 ºF
Saturated vapour : 590 g/m3 at 20 ºC/ 68 ºF [estimated value(s)]
Concentration (in air)
Thermal conductivity : 0.16 W/m ºC at 20 ºC/ 68 ºF
Evaporation rate (nBuAc=1) : 5.6 (ASTM D 3539, nBuAc=1)
2 (DIN 53170, di-ethyl ether=1)
Surface tension : 22.8 mN/m at 20 ºC/ 68 ºF
Molecular weight : 58.08 g/mol

10. STABILITY AND REACTIVITY

Stability : Stable under normal conditions of use.

Conditions to Avoid : Avoid heat, sparks, open flames and other ignition sources.
Materials to Avoid : Strong oxidizing agents.
Hazardous Decomposition : None expected under normal use conditions.
Products

11. TOXICOLOGICAL INFORMATION

Basis for Assessment : Information given is based on product testing.

Acute Oral Toxicity : Low toxicity: LD50 >2000 mg/kg, Rat
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Acute Dermal Toxicity
Acute Inhalation Toxicity
Skin Irritation
Eye Irritation
Respiratory Irritation
Sensitization
Repeated Dose Toxicity
Mutagenicity
Carcinogenicity
Reproductive and
Developmental Toxicity
Additional Information
12. ECOLOGICAL INFORMATION
Acute Toxicity
Fish
Aquatic Invertebrates
Algae
Microorganisms
Mobility
Persistence/degradability
Bioaccumulation
13. DISPOSAL CONSIDERATIONS
Material Disposal
Container Disposal
Local Legislation
14. TRANSPORT INFORMATION
Land transport ADR/RID
Class 3 Classification code
Packaging group ll
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Acetone
Version 2.1
Effective Date: 28.05.2012
Aspiration into the lungs when swallowed or vomited may cause chemical
pneumonitis which can be fatal.
: Low toxicity: LD50 >2000 mg/kg, Rabbit
: Low toxicity: LC50 >2-20mg/l/ 4 hours, Rat
High concentrations may cause central nervous system depression resulting in
headache, dizziness and nausea; continued inhalation may result in
unconsciousness and/or death.
: Not irritating to skin.
Prolonged/ repeated contact may cause defatting of the skin which can lead to
dermatitis.
: Irritating to eyes.
: Inhalation of vapours or mists may cause irritation to the respiratory system.
: Not a skin sensitizer.
: Low systemic toxicity on repeated exposure.
: Not mutagenic.
: Not expected to be carcinogenic.
: Not expected to impair fertility.
: Causes slight foetotoxicity. Effects where seen at high doses only.
: Exposure may enhance the toxicity of other materials. May potentiate the
peripheral neurotoxicity of n-hexane, and the liver and kidney toxicity of some
chlorinated hydrocarbons such as carbon tetrachloride.
: Low toxicity: LC/EC/IC50 > 1000 mg/l
: Low toxicity: LC/EC/IC50 > 1000 mg/l
: Low toxicity: LC/EC/IC50 > 1000 mg/l
: Low toxicity: LC/EC/IC50 > 1000 mg/l
: If product enters soil, it will be mobile and may contaminate groundwater.
Dissolves in water.
: Readily biodegradable.
: Not expected to bioaccumulate significantly.
: Recover or recycle if possible. It is the responsibility of the waste generator to
determine the toxicity and physical properties of the material generated to
determine the proper waste classification and disposal methods in compliance
with applicable regulations.
: Drain container thoroughly. After draining, vent in a safe place away from
sparks and fire. Residues may cause an explosion hazard. Do not puncture, cut
or weld uncleaned drums. Send to drum recoverer or metal reclaimer.
: Local regulations may be more stringent than regional or national requirements
and must be complied with.
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Hazard id no. 339

Label 3
UN number 1301
Technical name Vinyl acetate, stabilized
Marine transport IMDG
Class 3
Packaging group ll
UN number 1301
Proper shipping name Vinyl acetate, stabilized
EmS F-E, S-D
MARPOL -
Label 3
Air transport ICAO/IATA
Class 3
Packaging group ll
UN number 1301
Proper shipping name Vinyl acetate, stabilized
Label 3

15. REGULATORY INFORMATION

The regulatory information is not intended to be comprehensive. Other regulations may apply to this material.

EC Label Name : ACETONE

EC Label/ EC Number : 200-662-2
EC Classification : Highly flammable. Irritant.
EC Annex I Number : 606-001-00-8
EC Symbols : F Highly flammable
Xi Irritant
EC Risk Phrases : R11 Highly flammable.
R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
EC Safety Phrase : S9 Keep container in a well-ventilated place.
S16 Keep away from sources of ignition- No smoking.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.

AICS : Listed.
DSL : Listed.
INV (CN) : Listed.
ENCS (JP) : Listed. (2)-542
TSCA : Listed.
EINECS : Listed. 200-662-2
KECI (KR) : Listed. KE-29367
PICCS (PH) : Listed.

Hazardous Substance Act. BE2535

16. OTHER INFORMATION

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R-phrase(s)

R11 Highly flammable.

R36 Irritating to eyes.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

MSDS Version Number : 2.1

MSDS Effective Date : 28.05.2012

MSDS Revisions : A vertical bar (‫ )׀‬in the left margin indicates an amendment from the previous
version.

MSDS Regulation : The content and format of this safety data sheet is in accordance with
Commission Directive 2001/58/EC of 27 July 2001, amending for the second
time Commission Directive 91/155/EEC.

Uses and Restrictions : Industrial Solvent.

Restricted to professional users.

MSDS Distribution : The information in this document should be made available to all who may
handle the product.

Disclaimer : This information is based on our current knowledge and is intended to describe
the product for the purposes of health, safety and environmental requirements
only. It should not therefore be construed as guaranteeing any specific property
of the product.

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