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RESEARCH METHODS PAPERS

PLOTTING EQUATION FOR GAUSSIAN PERCENTILES AND A SPREADSHEET PROGRAM FOR


GENERATING PROBABILITY PLOTS

JAMES H. BALSILLIE1, JOSEPH F. DONOGHUE 2, KENJI M. BUTLER 2, AND JENNIFER L. KOCH 2


1 Geological Investigations Section, The Florida Geological Survey, 903 W. Tennessee St., Tallahassee, Florida 32304-7700, U.S.A.
2 Department of Geosciences, The Florida State University, Tallahassee, Florida 32306, U.S.A.

e-mail: Jim.Balsillie@dep.state.fl.us

ABSTRACT: Two-dimensional plotting tools can be of invaluable assistance in tifiable data (e.g., sediment grain size) plotted against the cumulative percent oc-
analytical scientific pursuits, and have been widely used in the analysis and currence (or cumulative probability), which is a nonlinear axis. Typically, the arith-
interpretation of sedimentologic data. We consider, in this work, the use of metic axis is the horizontal axis representing grain size. The nonlinear (Gaussian)
arithmetic probability paper (APP). Most statistical computer applications do axis is the vertical axis and represents the cumulative percent weight from the sieve
not allow for the generation of APP plots, because of apparent intractable non- fractions. The cumulative probability distribution of the paper has commonly been
linearity of the percentile (or probability) axis of the plot. We have solved this termed the ‘‘normal’’ distribution. It should not be so designated, however, because
problem by identifying an equation(s) for determining plotting positions of ‘‘normal’’ is applied in too many applications. Johann Carl Friedrich Gauss (1777–
Gaussian percentiles (or probabilities), so that APP plots can easily be computer 1855) was its originator, and it should properly be referred to as the Gaussian
generated. An EXCEL example is presented, and a programmed, simple-to-use distribution or Gaussian probability density distribution (GPDD). APP, constructed
EXCEL application template is hereby made publicly available, whereby a com- so that the ogive (S-shaped curve on arithmetic paper) plots as a straight line, was
plete granulometric analysis including data listing, moment measure calcula- developed in 1913 by Hazen (1914), and is acknowledged as a milestone in statis-
tions, and frequency and cumulative APP plots, is automatically produced. tical graphic applications (http://www.math.yorku.ca/SCS/Gallery/milestone/
sec7.html). There are three fundamental properties of the GPPD that when plotted
on APP require understanding.
First, if the quantified data, in general, conform to the Gaussian distribution, any
INTRODUCTION one sample shall, if it is precisely Gaussian, plot as a straight line on APP. Second,
are the natural data of any one sample precisely equivalent to the GPDD? Most are
Sediment grain-size data are used in many geologic and engineering applications. The not, nor would we wish them so, for it is the deviation from the Gaussian that tells
grain-size distribution of a sediment sample provides information on the relative energy us something about the sample. This is especially true for sediment grain-size dis-
level present in the environment under which the sediment was transported and deposited. tributions. Third, natural data plotted on APP may, in many applications, be made
It also contributes practical information of engineering importance. For instance, in beach up of several straight-line segments. These segments are often attributable to some
restoration projects, the mean grain size and standard deviation using composite statistics identifiable natural cause or process. For instance, Tanner (1991) found, by analysis
(see Balsillie and Tanner 1999) of the grain-size distribution are used in calculations to of over 11,000 sediment samples from all types of environments, that the geometry
determine the suitability of local sand deposits as borrow material for nourishment, as of straight-line segments for sediment distributions can definitively identify whether
well as in predicting the maintenance renourishment needs of a project (e.g. Krumbein the latest transportation–depositional history of the sediment sample was due to
1957; James 1975; Hobson 1977; U. S. Army 1984). eolian, littoral, fluvial, settling processes, etc., or even combinations of processes
Standard methods of quantifying sediment textural data employ statistical mea- (Balsillie 1995). Balsillie (1999) found that they may be related to storm- and hur-
sures (mean, standard deviation, skewness, kurtosis), grain-size distribution dia- ricane-induced erosion.
grams, and frequency and cumulative frequency probability plots. Probability con- Arithmetic-arithmetic, logarithmic-logarithmic, arithmetic-logarithmic (semilogarith-
siderations are based on the underlying concept that sediments conform to the ‘‘Nor- mic), and other plotting media have been used to display analytical GPDD results. The
mal’’ or Gaussian density distribution function. The Gaussian distribution plays a above three properties will invariably not be evident except where APP is used.
central role in all of statistics. It is, perhaps, the most ubiquitous distribution utilized
in all the sciences. Results from statistical application of the Gaussian distribution PLOTTING EQUATION
are best plotted using arithmetic probability paper (APP). The usefulness of APP is,
among informed practitioners, of unequaled practical importance when compared to Statistical packages commonly provide the numerical values of standard textural
other plotting options. The graph paper has one arithmetic axis that represents quan- parameters, and can plot distribution diagrams, which typically have arithmetic co-

FIG. 1.—Gaussian percent plotting position on


APP versus Gaussian plotting position on an
arithmetic scale. Solid line represents measured
data, circles represent fitted data from Equation 1.

JOURNAL OF SEDIMENTARY RESEARCH, VOL. 72, NO. 6, NOVEMBER, 2002, P. 929–943


Copyright q 2002, SEPM (Society for Sedimentary Geology) 1527-1404/02/072-929/$03.00
930 J.H. BALSILLIE ET AL.

FIG. 2.—Arithmetic-arithmetic (right axis) and


arithmetic probability (left axis) plots, precise
Gaussian fit generated using EXCEL, and
segment analysis of a sediment sample.

ordinates. The probability plot is, however, with very few exceptions not available in which X is the Gaussian percentage (G P) when 0.01% , G P # 50%, and X 5
in standard statistical packages. Very few computer statistical applications allow for (100 2 G P) when 50% # G P , 99.99%. Alternatively, Y9 can be determined from
plotting on APP because the cumulative percent occurrence (or cumulative proba- a modification of a plotting equation given by Zelen and Severo (1965), given by
bility) axis is nonlinear and, ostensibly, intractable.
If one inspects APP, it becomes apparent that the cumulative percent axis is symmet-
rical about the 50th percentile (or 0.5 probability). This makes quantification somewhat
simpler, because only half requires quantification, which can then be applied to the other
half. A mathematical investigation was undertaken by one author (JHB) to discover a
Y9 5 49.99 2 13.41 t 2
[ 2.30753 1 2.27061t
1.0 1 0.9929t 1 0.04471t 2 ] (2a)

in which
sufficiently precise quantifying relationship. The best representation was found using a
fifth-order transcendental polynomial. The equation is given by

! ln (0.01X)
1
t5 (2b)
550 1 (50 2 Y9)
Y9 when 0.01% , G p # 50% 2
Y5 (1a)
when 50% # G p , 99.999% Either equation for determining Y9 will suffice for plotting purposes, although in
this work we use Equation 1.
in which Y is the linear plotting position of the Gaussian percentage on an arithmetic The goodness of fit of the plotting position equation (Equation 1) is illustrated in
scale, G P is the Gaussian percentage, and Y9 is given by Figure 1, which has a Pearson product–moment correlation coefficient exceeding
0.9999. On the average, the absolute difference between actual and predicted per-
Y9 5 exp{2.9315 1 0.2663 ln X 2 0.01462(ln X) 2 centiles is 0.049%, with a maximum difference of 0.179%. Actual plotting positions
1 0.003297(ln X) 3 2 0.001252(ln X) 4 were determined by physically measuring the probability axis on a piece of proba-
bility paper. Hence, there is to be expected some measurement error in the actual
1 0.00282(ln X) 5 } (1b) data. This does not compound the error, and the statistically fitted equation is sound.
GAUSSIAN PERCENTILE PLOTTING EQUATION 931

FIG. 3.—Example of worksheet DATA of the EXCEL application GRANPLOTS.xls.

In fact, the differences shown in Figure 1 lie well within the width of a fine pencil if the last arithmetic percent is 99.998, the Gaussian value will be 99.9896% using
line for an APP plot on letter-size paper. The predicted percentiles, therefore, suc- Equation 1. If the last arithmetic percent is less than 99.99%, which might occur
cessfully represent Gaussian percentiles for plotting purposes. because of sample truncation or filtering (Tanner 1964), then the result derived from
the equation is correct.
AN APPLIED EXAMPLE It was noted above that APP allows for straight-line segment analysis. A surface
sediment grab sample from Cedar Key, Florida (Fig. 2) illustrates the usefulness of
The method is demonstrated using a granulometric example. Figure 2 is an EX- APP. It is apparent from Figure 2 that the arithmetic-arithmetic plot (triangles) shows
CEL application where an APP plot has been constructed. There is, however, one a typical S-shaped curve (ogive) with no straight-line segments. For the APP plot
significant note. Equation 1 is applicable where the Gaussian percent, PG, is in the (circles), one can discern relative to the straight-line segment representing the central
range 0.01 , PG , 99.99, because these are the limits specified on standard APP. portion of the distribution, several straight-line segments. The segment from 0.325
The lower limit should not pose a problem. However, if the last arithmetic percent w to 1.75 w, because of the relative low angle of departure from the central segment,
is 99.99 and Equation 1 is applied it will result in a Gaussian value of 99.07%, identifies a transportation–depositional history possibly due to wave activity. The
which is incorrect. That is, 99.99% should also be the Gaussian value. Conversely, segment from 20.625 w to 0.325 w, because of its larger departure of angle from
932 J.H. BALSILLIE ET AL.

FIG. 4.—Example of chart ACUMPLOT of the


EXCEL application GRANPLOTS.xls providing
the arithmetic probability plot.

the central trend, identifies the coarse tail, which may be due to either a fluvial or constraints are specified, the first two columns of the left-hand table are automati-
a tidal transportation–depositional history (in this case it is undoubtedly tidal). There cally constructed by the program. The only other input required are the weights (i.e.,
is a third history of moderate settling represented by the fine tail, apparently under mass in grams) for each specified sieve interval in the third column. All output
still-water conditions. These histories are all consistent with known nearshore marine automatically appears upon data entry. This includes moment measures for the mean,
conditions at the sampling site on the low-energy Florida Gulf coast. For other standard deviation, skewness, kurtosis, relative dispersion, and the frequency plot.
signatures of transportation–depositional histories for other environments, the reader The arithmetic probability plot is also automatically generated in chart ACUMPLOT
is referred to the works of Tanner (1991; see also Balsillie 1995). (Fig. 4). Users should not attempt to change the vertical size of the chart within
EXCEL unless they are prepared to alter the position of ordinate values. Users can
GRANPLOT
and may need to change scale values for the abscissa. One can, however, export the
EXCEL plot to other applications and change its size without corrupting the plot.
Using Equation 1 we constructed an EXCEL spreadsheet application named Worksheet DATA currently allows for input of up to 41 data points to the table.
GRANPLOTS.xls for classified sieved data, and GRANPLOTT.xls for unclassified Note, however, that this application can be used for data other than granulometric
settling tube data. They are available at no charge from the Florida Geological purposes; auditing information, column headers for the table, and plot axes simply
Survey website at http://www.dep.state.fl.us/geology/. We describe here some char- would require respecification.
acteristics of the application for sieved data, bearing in mind that modifications
might be made. Detailed instructions are contained in the worksheet entitled READ- CONCLUSION
ME. The worksheet CALCULATIONS contains programming statements and data;
it should not be tampered with unless one is familiar with the EXCEL language. This paper has presented an equation for identifying plotting positions of Gaussian
Worksheet DATA and chart ACUMPLOT contain output results. In the upper right- percentiles (or probabilities). Using the equation, a programmed EXCEL application
hand corner of worksheet DATA (Fig. 3) are four items that require user input; (1) template has been made publicly available, whereby a complete granulometric anal-
start (finest) sieve size, (2) end (coarsest) sieve size, (3) pan size, and (4) sieve size ysis including data listing, moment measure calculations, and frequency and cu-
interval (the latter because this application is for grouped data). Once these initial mulative APP plots, is automatically produced. The EXCEL application includes
PROCESSING UNDISTURBED MARINE SAND SEDIMENTS AND RECONSTRUCTING FABRIC AND POROMETRY 933

two programmed spreadsheets, one for sieved data (GRANPLOTS) for classified HOBSON, R.D., 1977, Review of design elements for beach-fill evaluation: U.S. Army, Coastal
data, and the other for settling tube data (GRANPLOTT) for unclassified data. Engineering Research Center, Technical Paper 77–6, 51 p.
JAMES, W.R., 1975, Techniques in evaluating suitability of borrow material for beach nourish-
ment: U.S. Army, Coastal Engineering Research Center, Technical Memorandum 60, 81 p.
ACKNOWLEDGMENT KRUMBEIN, W.C., 1957, A method for specification of sand for beach fills: U.S. Army, Beach
Erosion Board, Technical Memorandum 102, 82 p.
We thank Walter Schmidt, State Geologist, Florida Geological Survey, for his TANNER, W.F., 1964, Modification of sediment size distributions: Journal of Sedimentary Pe-
valuable editorial comments on the manuscript. trology, v. 34, p. 156–164.
TANNER, W.F., 1991, Suite statistics: the hydrodynamic evolution of the sediment pool, in
REFERENCES Syvitski, J.P.M., ed., Principles, Methods and Application of Particle Size Analysis: Cam-
bridge, U.K., Cambridge University Press, p. 225–236.
BALSILLIE, J.H., 1995, William F. Tanner on environmental clastic granulometry: Florida Geo- U.S. ARMY, 1984, Shore Protection Manual: U.S. Army, Corps of Engineers, Coastal Engi-
logical Survey, Special Publication 40, 145 p. neering Research Center, Washington, D.C., 2 vols., 1272 p.
BALSILLIE, J.H., 1999, Volumetric beach and coast erosion due to storm and hurricane impact: ZELEN, M., AND SEVERO, N.C., 1965, Probability functions, in Abramowitz, M., and Stegun, I.,
Florida Geological Survey, Open File Report 78, 37 p. eds., Handbook of Mathematical Functions, with Formulas, Graphs, and Mathematical Ta-
BALSILLIE, J.H., AND TANNER, W.F., 1999, Suite versus composite statistics: Sedimentary Ge- bles: Washington, D.C., U.S. Department of Commerce, National Bureau of Standards, p.
ology, v. 125, p. 225–234. 925–995.
HAZEN, A., 1914, Storage to be provided in impounding reservoirs for municipal water supply:
American Society of Civil Engineers, Transactions, v. 77, p. 1529–1669. Received 18 September 2001; accepted 4 April 2002.

A TECHNIQUE FOR PROCESSING UNDISTURBED MARINE SAND SEDIMENTS AND RECONSTRUCTING


FABRIC AND POROMETRY

KENNETH J. CURRY1, MARITZA ABRIL1, JANA B. AVANT1, CONRAD CURRY 2, RICHARD H. BENNETT 2, AND MATTHEW H. HULBERT3
1 University of Southern Mississippi, Hattiesburg, Mississippi 39406, U.S.A.
2 SEAPROBE, Inc. Picayune, Mississippi 39466, U.S.A.
3 Research Dynamics, West Chester, Pennsylvania 19380, U.S.A.

e-mail: kenneth.curry@usm.edu

ABSTRACT: Study of marine sediment pore fluid pathways and porometry re- knife. Later, Jim (1985) reviewed similar techniques for embedding sediment sam-
quires careful analysis of the fabric of ‘‘undisturbed’’ sediment samples. A ples and Lavoie et al. (1996) described a mini-core technique for subsampling fine-
novel solution to the preservation of the interstitial organic material and the in grained sediment.
situ fabric or sedimentary structure is the application, with little modification, We solved the sampling-disturbance problem for noncohesive sediments (sand)
of well-established biological techniques employing agar infiltration. The solid- by gently impregnating the sand in the field with liquid agar (very low viscosity of
ified agar preserves fabric during subsequent epoxy impregnation. Once im- 1.002 centipoise at 208C comparable to that of water) using an infiltration pressure
pregnated, porosity of the samples can be measured using image analysis of of about 0.254 kPa (0.037 psi). Agar is a polysaccharide agarose in which the
polished surfaces of the microfabric and/or a gravimetric–volumetric technique. hydrogen bonds of the hydroxyl groups cross link as the solution cools to room
Porosity was about 10% higher with image analysis, apparently because of temperature, thus solidifying and stabilizing the sand particles. The particles were
problems in visualizing carbonates and edges of grains. Tortuosity was mea- then held together sufficiently for subsequent infiltration with a series of miscible
sured as a function of pathlength ratios taken in stacked planes of microfabric fluids and epoxy resin. Once the resin was cured, a series of polished sand surfaces
images. The technique allowed us to detect variability in directional tortuosity were successively precision ground from the surface of the epoxy embedded spec-
as a function of orthogonal pathlength ratios. Three-dimensional stacking of imens so that the two-dimensional microfabric of each surface could be imaged and
digitally acquired wireframe images of sequential planes through the microfa- studied. The purpose of this paper is to describe our procedure and techniques in
bric allows visualization of long continuous pores, some with 2.6 mm length. detail with examples of the data and observations.

MATERIALS AND METHODS


INTRODUCTION
Field Work.—Sand sediments saturated with seawater were carefully collected
The microfabric of sediment is defined by the three-dimensional particle arrange- (i.e., undisturbed) by divers during July 17–18 and October 23–24 (1999) offshore
ments and particle associations of the individual grains of a sedimentary deposit. Panama City and Fort Walton Beach, Florida, respectively, in thin-walled stainless
Study of the microfabric and porometry provides important information on funda- steel metal cores of 7.2 cm internal diameter by 15 and 30 cm in length and plastic
mental sediment properties including porosity, permeability, pore fluid pathways, cores of 9 cm internal diameter by 25 cm in length. The cores were processed on a
sediment bulk density, acoustic properties, and stress–strain behavior (Bennett et al. research vessel at sea near the collecting locations with minimal handling. The cores
1989; Bennett et al. 1996). The study of microfabric of undisturbed marine sand has were kept in a water bath for at least 45 minutes until they reached 558C. Three
been confounded by the degree of difficulty encountered in both collecting and subcores of 14 mm diameter by 9 cm in length were taken from each core using a
processing of sediment without altering its in situ configuration. Efforts to examine brass tube. The subcores were slowly infiltrated by pouring 2% liquid agar with the
the microfabric of marine sands and particle associations face the problems of pre- agar remaining in a liquid state at 558C (Fig. 1A). The large core was removed from
serving the three-dimensional configuration of the microenvironment and avoiding the water bath without removing the subcores and allowed to cool for 45 to 90
major disturbances of the microorganisms and extracellular materials intimately as- minutes while the agar in the subcores solidified. The sediment subcores were gently
sociated with the pore structure also present in fine-grained sediment (Bennett et al. removed from the brass tubes with a plunger that fit the inside diameter of the tubes.
1999). The subcores were cut into 1 cm length sections (Fig. 1B) and their orientation and
Perhaps the earliest work and techniques of embedding fine-grained marine sed- position (depth below the sediment–water interface) in the original core was noted.
iment samples with Spurr’s epoxy resin for microfabric study were developed by Solidified agar plugs are easy to handle for subsequent processing. India ink was
Bennett (1976) and Bennett et al. (1977). These techniques were later expanded for applied to one side of each plug to mark its orientation for subsequent stereology
the study of organo-clay microfabric studies (Baerwald et al. 1991; Bennett et al. and 3-D reconstruction.
1999). These samples were critical-point dried and impregnated under vacuum with Infiltration Techniques.—The agar-infiltrated sediment plugs were fixed to sta-
the low-viscosity Spurr’s epoxy resin for later ultra-thin sectioning with a diamond bilize organic material in the pores with 2% formaldehyde and 2.5% glutaraldehyde

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