~t~~O~~

~obc3vJ0w--
rite the half-cell reaction for the following cells:
~. .: ~'YrtcJtOYt??
(a)~Ti3+ , Ti 4+
II Fe3+, Fe2+ §
(b) Pb(s) I PbS04(s) I so ~- II Zn2+ n(s)

(Cl@ Hg(~, Hg2C12 I cr H+ I H2, Pt(s)

(d) Pt(s) I QH2, Q, H+ CI-I AgCI(s) ~~ ts ~

QH~d oquinone and Q =Quinone

0) A~ It' '3.-t ~h4t-t}C

-/
eo....--- •

k.2--t
t,~ ~1i -+ le~ ~
--'­
~

b) .!-~' ~a~- -t rb
-- -1 C~}

C: rL.2-f
VI
f2e-~ ~ m

(~)

(01-)

C) ~ J,H} -r~ Cr ~ ~vt{

C.},~
__, : J \1 t t ~e -;;;;:! ~2--
-- CD..f-J (~)

A e. C~ l-12-~~~it~ .q H' "t~~~

L .~

 @ Wr'e the electrochemical notations forthe following reactions:

2
(a) H2(g) + Cu + -7 2H~ + Cu(s)

(b) C1 2(g) + 2Fe 2+ -7 2Fe 3+ + 2Cr

(e) Zo(s) + 2AgCI(s) -7 2Ag(s) + ZnCI 2

(d) [Fe(CNli- + ~H 2(gl -7 [Fe(CNll- + H+

d)
 L()Cr-f'LcJJ'v.> ~Do.-~
)

1
.
fj)
·3 ii).. Answer whether the following reactions will occur spontaneously or not,under standard condition. k:'V .... 1./­

() '11 d 3+ 2+?
a WI Fe re uces Fe to Fe.
EO( Fe2+/Fe) = -0.44 V an d E O( Fe3-1: 2+).\
/Fe =O.77v . \j !tnn
r'Y/V}JOq I r !:"I V
.{b) Wil4lefiildilgallate iOIl libel ate 02(g) tram water irl acidic medium? EO (Oz, HzO/H+) ';"1.22 V {Ef'(I)Yl 0'I'""
J')J Yl t :t
(c) will O2 (g) oxidizes gold to Au(CN); in presence of CN-(aq) and OH- (aq) ? ~
6~et
EO [Au(CN); /Au, CN-l = -0.60 V and EO (OJOW, H20) =0.40 V. 'hz
~~~M)
(d) would you use silver spoon to stir a solution of Cu (N0 3h?

EO (Ag+/ Ag) =0.80 V and EO (Cu2+ I Cu) =0.34 V

(e) reaction of Pb with AgN0 3. EO (Ag+/Ag) =0.80 V and EO (Pb2+/Pb) = -0.126V

3+ 2+?
(f) will Sn reduce Fe to Fe EO (Fe3+/Fe2+) = 0.77 V and E"(Sn2+/Sn) = 0.15 V

k Z:t
k'"2--1 -t x.e. - -sz:
C­
--- E-~~/Fe2T ~12~l-Yk-
O,Ti- - ( -u'tr~) ,= + r .2 IV
~. t'W;lt ~~) :'1: LSPqylNvrJ~ J
L-\
-t ]12-0 '-/ tv\n -r­ 02­
"'-'-~'"
o
Ece-H r-.
- Eo ,-1J-l>­
..,...... 1~2-:2

~
~)
A-u~
~

+­ 0).- -:' ErY\~

+L~~1iJ
10 'a e
f?JOU -.::-­ .~ b- H f_ ~ _ I~~
\
'.

~) v .'
E~y~
s: n" ~ ~ 0" 1 0 f -6 2- \J.

~ +ve- t57.··~e~)
. v/ ~/
E3' For the cell reaction 2C. 4+ + Co ~ 2C.3+ + eo 2+

EOce" is1.89 V. If Pco2',co .IS - 0 .28 V, what .IS the value of EO ?

ee4 +/Ce3 + •

Co ~ c;--++ Le­
e»

o
-- £ {e41Ct-1T ­

to

F ee4 ~ o» t .: /. bI v
-------
@ Determine the standard reduction potential for the half reaction'

CI2 + 2el§}7 2C\­

Given pt2+ + 2CI- ~ Pt + C1 2• EO = - 0.15 V

EO = 1.20 V

o
'£Ut/()~
o
-0, Is;- f .. 2- 0 -' f cJ:L/ U ,­

- !·3~ vL
@ Wrae cell reactionfor the following cell and determinestandard state emf of the cell

EO (Ag+/Ag) =0.80 V e •

EO (Sn 2+/Sn) = -0.14 V I

tSt,·1

.r'

\
'i1
V
Given the standard reduction potentials TI+ +

Examine the sponaneity of the reaction, 3TI+

«: ~ TI, EO =-0.34 V and T13+ + 2e- ~ TI+, EO =1.2SV.
~ 2TI + TI3+. Also find EO for this disproportionation.

e
E U1-/ T) ~ - 0 t 34 \I

"""""-1 0 ?:,.t
1\ --t -.--!'
2~ ~
T,.q -t­
o 1·2.S-V
El»/Tf+ ­

3-rQ-+ ~ ~T,e. +1~5t

\1+ +I~- ~ T). ~:
£{) : : - .SRfc --< R(A­

::=- ~o·~4 -l J.. J-d

=r-I.S-j v-I
-\I1I Dr1 Sf(Jl'l~ 1
(3)
.~ Calculate the equilibrium constnant for the reactin Fe + cuso4

(Fe/Fe 2+) = 0.44 V, EO(Cu/Cu 2+) =-0.336 V.

<=> FeSO4 + Cu at 25°C. Given EO

--
-- o
be e1)::c. £~P c. ~ SRfp,
z: o. 33-' -CO' 44)
~~.O·i-¥
~~r'

~_Ce..-v,-
II _,J'
- I/(...e-\;\
__0
'. -
,o~J . [~r9.
_ - • - a-1

M- ~"'-) t G-cU.:o-- 0 /~. ~

C)' ()~. ~r~ k

'1 ~ ~::::- .z, 0 , 1-1 0-U J

~
. ~ . Mg(s) I Mg
or a cell
operating the cell. E
2+(aq) II Ag+(aq) I A
/M ) _
.
the
g. Find .
maximum work that can be obtain d b

O(Mg 2+ g _ -2.37V, EO(Ag+/Ag) = 0.8 V. e y

?.-i
A: ~ M- --f 2-C
-- ~~ (~.) Q
,~ -2 ~) i-~
L '~~1 c~)

~ ~~-\ + l-~~
~-

~ ~" -i f\I\([ r'

l ~.) Q)
D .~

l~+I'O -E1~Yo'
O: q - C- '2-"31) :::?" l';l'V

o
\J~ '=- ~ 'Y\ F E:(~l

: -f 6 , 1/ g, I 0
 ~e
U n st;ndard reduction potential at 'S'C for the red uction
. of water

2H 0 + 2e-
20
~+ H2 + 20H- .IS -0.8277 volt. Calculate !1GO & the equilib nurn
. constant far the reaction

2 ~ H30 + OH- at 25°C.

p
E I -= -0 .'6 211­
()), :=: L.

N~LU ~ ~ ~ 1<J Md-d. ~ ~ ~'"fd> ~

~ ~' -i». 4'\ CD I /.g.UcPL 1l~ ~

p.-etclLol /-0 ~,( cD I' Y t~ Let{

'vvL

~
,tj ;) H)..- 0 -+- ffl1 -- CD ~~
J( -,~l~~-~'\ -t. --
y"" ,
MiA ~-{o'-~ ~
c::.

qj2 H L
-
~
" ~Hrf -f'2-C £2­
Crt to

;;}' ~H3D+-tU E2-~O

(9 H~ -\- 1~2- 0

\-", ~ 2-,
, ~

~ ~

6~ l rf ()
Q!L­ 'Q
'0
, -- b~3
~~I~E)_
,6~~~ =- ~ 2- '{~bTh\)) (-b~~F!)
~1)

- - L1 Ct"':: -~~?'uRT ,Q"if K..

JS-92~6<) :::: -::;>-3 0>1 (t;i.?,J'!J (2 n ) ~J k.

k ::: [O-t­

., K ~ ~ e.rv-'
2- M2P ~ l'it t (Y!I\'­ ~'lSl L 21 t>r-titJ
Q At 25°C the value of K for the equilibrium Fe3+ + Ag ¢:> Fe2+ + Ag+ is 0.531 mol/litre. The standard

V electrode potential for Ag+ + e ¢:> Ag is 0.799V. What is the standard potential for Fe3+ + e ¢:> Fe2+?

Af

l()

~~

O~~,

------~-------~
 -d-"~
\I'-.. ~==-v.~~ '1--1\\/1 J
~R- tA (j ,L.J"1 ,
I~~~ -

()')~,o 1L , ,
~-------.J bi / f 7./)
en -~_-o~ 1-b c~ c'-""
4;; w Lf/ill .: 0 .. > Y
6?
-Q. '1.- -h normal potential of Zn referred ~ SHE is O.76V and that of Cu is -0.34V at 25°C. When e'ce~s ofZn is
d to CuS 4' Zn displaces Cu2+ till equilibrium is reached. What is the ratio of Zn2+ to

equilibrium?
Cu2+ ions at
)

--­-
C9> :::-­ ( ~?-~J
L~~j
~ cO
- ~eu:LY6..- ~ 'ZY'/'2n \4'
:= + 0- 1Y - l ~ D fr:rG) ~ ~

z: ~dl ~ ~ 'o~
2­
I, ~

E~tl »: ~ ~ ;:LK
o
. .
[~~-~1
- 2­

D ,OS!
2­
--,--~-

, nll' d ,~~-::;- 1
 CkecJ<: ~~
'r'~
~aM- c -= .~

W.ConSlder the followlng sequence of re ctlons :urrlng inthe acid medium. AU emf [standard) ---.. d
~~l Cand expressed in volt unit: are measure at

MnO-4 0.564) ~ I. 02-

1V1n 2.26 .
Mn0 0.95 ) Mn3+ 1.51 ) Mn2+ -1.18 > Mn
4 ) 2

for: MnO ~ -7 Mn
2
(a) Determine EO +

2­
MnO 4 when the

c
tV M~{)I ~ + ,e--
.
MV\0(
I " '....
E, :::O·s-r,Y/l)"')
@
'J..; N.Y\02- Ek -=: o? \'2 /, 1 1J.v ~ 2­
.0

MV\ O~ -+ ~e- 1}

- Nr?i E~ ~ I(). 15') 113:::: 1

0J N Y\ D2- -t' e. o
E~ ::, rC'S' I I I) 'i ::::. J
Q)
@)
(2;-= - J. Jg f Yl,,"".2..

o)~ f\'IV\Di +
© CD + Q) T ® -rev
~
_ /. ( \ -f 6U",>-- 4~GlOy.,_ ~~t)~
~.. 6G 6

i~\; FF-~ z: f'{\/~" t Yl2-ft-.: t !)?'f~3o t~;t,,"

E{,O-:: I(O'sb'i) -!-'2--('1' )..{,) -+1(O'l'fS-) +1( IS))

E;
 6)~ f\Iv~"DIV--+- /.-
-re. ~ 1Y1n2C/l4?IY)::O~
1 0

..:. i £::t ~ 2l 2· 2 b) tiC D ' 'l-'>j i- \ cr'('i)

f=!- =:- 2- C2-.2- c.) -\- L 't~) --\ L,~ ~0
0 -

4
~
l
--::-tI~---~
G:t;::- \'1q~\l J
~
1---­
-r-- • • r'!> 0'-- b ef;I-vL. 0 r: A·
8 calculatethe EMF of following cells at 2S C.

(i) Fe I FeS04{a = 0.1)

0

II CuS04(a = 0.01) I Cu E {Fe2+IF e)

O
=-0.44 V

(ii) Fe I Fe2+ (a 0.3)= II Sn 2+ (a =0.1) I Sn EO(CU

=
2+ICu) +0.34 V

(iii) Pt, H2{2atm) I HCI I H2{10 atm), Pt. EO(Sn 2+ISn) =-0.14 V

,) A2 k ~ te2-+t-'2.~
- (SJ (c; .1)

-
C- ." l.-u2-t f U -~
~
c.:
(~)
C)I 0
,.1-'
.,

L ell ~

R- ~ .~-ft~~

\~) (Or?)

eVA
 rt ~ ~}{++2-~~

L 2-) ( C-J
~)-I-' -+ 1L~ -;;; }fII-
( ~J
o
U )

( , .

E == -0·02.-° V­ r:
,_---------<L--l".

\
\
~~ What is the electrode potential of Mg2+ I Mg electrode at 25°C, in which the concentration Of Mg2+ is
l __::> 0.01 M. EO(Mg 2+ I Mg} = -2.36 V.

~..
£5 • o~ q -(m1-----'(J
-­ O'DC'1_ j\)j lluJ
~ \J

~7~&
~ c~l:= --'- lid V
 j

0
j
IeUI
. ,. E' 'nd Efa, 'h. cell Sn I Sn 2• (1M) /I Pb2• (lO-3M)I Pb. j

EO(So2+ I So} =-0.14 V EO(Pb2+ I Pb) _ j

J ­ -0.13 V. Whatdo you infer from cell EMF?

A~ 5n -,
~2..-+ + Le-~
j
..:e:::::­
j
(t M)
L:+
L--: Ph +2-e-- .>
Pb
j

-
-==--. ~
j
Cro~ (<;;)
j
C'eL,1 rpb2-f -+ £" ~ ,r' i:.-n f­
>
j

l (t)1 M) CS)
'2-:/
fb
C'M.)
('3)
j

~e-\Jl -- SR.Pc - ~ RPA- j

~\)'I3.+G'I~ '=-h-b1 =:E:eMl

j

- j

j
I' ~ --- * I _ -::: (b~
l 0'- ..1 j

~- Q-on -~(J (lO'? j

j
L
j
- O· 01 - () 'Og gr- j

I E =--O.01-SSS-"l, j

j
_ ~ r L eJ l
tyJot srp~'Y)~
c-(V\ l6
~ VhRI~', r- tk-P~) 1-tt.z ~
j

~ C- cJJ ~-"J_-,,~
'. I 0-(""1 j

j
e At what concentrationof Cu 2+ In a solution of CuSO. wfll the electrode potential be zeroat 25'C?Can the

oxidation potential become positive? EO (Cu I Cu 2+) = -O.34V.

~~:L \ i L~ -:2 ~ t:::::- ~

COl"J (SJ [ Q'l-'J
12'\) -:::: O· ~ ~ V /' 'Yl -::- 2­

tJ ~ O·>LJ ~ O'O~_ ~r [~~~

./
 ~

.. ~. . .

@ A zrnc electrode Is placed in a 0.1 M solution at 25·C. Assuming that the salt Is 20% dissociated at this
dilution calculate the electrode potential. EO(Zn 2+ I Zn) =-0.76 V.

[711'21)= 0-2-1'0"

:::;;z-~
(~)

- _ o.. :},(, - O~ O-rJ_

~
~ Calculate the EMF of a Daniel cell when the concentration of ZnS04 and CuS04 are 0.001 M and 0.1 M
C.7 respectively. The standard potential of the cell is 1.1 V. •

c. \ (42-1 ~ ilL ~ CM '

P\ ~ ~~ t-A'L4 ~L

~~

t:ce1\
~ Calculate the pH of following solutions.

=
(i) Pt, H2 1 HC!, E 0.25 V (ii) Pt, H2 I H2S0 4, E =0.30 V

-iJ
_tJbY\b~ ~
'0 .~:::- 0 ~.
l:­
I

,i'W-i 4": _
a,·3D -==- t) - ? '/- ~ [1<1'°
- ~J [~j ~ [s-' 0 ~ := r~ ]
G The EMFof the cell M I M"+(O.02 M) II H+(lM) I H2(g)(1 atm), Pt at 2S'C is O.81V. Calculate the valency
~etal if the standard oxidation of the metal is O.76V.

-
:L \--t ~
--L: If\ fv\)
-+

~t~'A-
 @) EMF of the cell Zn I ZnSO41a • O.Z} II ZnSO41aZ} I Zn " -0.0088V at ZS·c. calculate the value of aZ·

. ~ ~'L-\ + 2-~-
--
-=::::::-­
l C\ ~--') J3
t

f 1~;;;:;; bl
( "»

----------------'"

~'L1 -r:en --::. bn?-i

CCA-z) 0) (JA~\) 2.) f

~=. 0-1­
4­
, 10
- , ~ ce..t\ ::::-. 0 7

Nt..{'1\0.t- =+"" ' \ >

EC-eA)
,)
O'DO~g

o'2-q &~ , (-~rj

ern. \rlfdJ

 ~ Equinormal solutions of two weak acids, HA(pKa =3) and HB(pKa = 5) are each placed in contact with
l7 standard hydrogen electrode at 25°C. When a cell is constructed by interconnecting them through a salt
bridge, find the emf of the cell.

...-----­
/.~. L ·
. . r\- -- .>
s: H t l-~ ~

~C\)

J2 't-\'i + \12.­
19)
E~l ::-0 /
v\ ;...-1­

~ccl \ -==- D- or os)

/-
Ece\\ --D' O~ l!

I ......- r
 @ In two vessels ea<h containing 500ml water, 0.5 m mol of aniline (Kb =10-9) and 25mmol of Hel a are
added separately. Two hydrogen electrodes are constructed using these solutions. Calculate the emf of
cell madeby connecting them appropriately.
t-tAcUs ~ C~~

~;·t(VLL

~,(" "" \0 "3 - c... ~ I t):\

D'~

-
~

~ H.t -+ Irt-V- ~
< - l c-,)

~~C=~J
-i:
-
)

o o~oS}
........

r, ~ r-, t--q ]04_ (~ X

/'

~ The emf of the cell Ag I Agi I KI(O.OSM) II AgN03(O.022 M) I Ag is 0.769 V. Calculate the solubility
C/ product of Agl.

--

~~
H
.,. -t- '~fr
"
CJ- t: Q. 0 2--2­
.

<;; ~ 4 "-AJ
\~) ~)

-.
t (i~r~) .
CD' o~ Y,CO~Q2-2)

[9,2 k~_
C!~ o~'I-. [}, 02-2)

-
~ Considerthe cell Ag I AgBr(s) I Br-II AgCI(s)lcn Ag at 25°C. The solubility product constants of
C/ AgBr and AgCI are respectively 5 x 10-13 and 1 x 10- 1 °.For what ratio of the concentrations of
Br- and CI- ions would the emf of the cell be zero?

--

Lel.t "

E 0-051

11

o t
.­

~
~
~

... ~

,.
... , K).f ~f1-r
~Sf "a CJ
[ PoIJ LCLj )
r ~or)
-- !Yf~ ~·"'1 0 13
-
'I""""'">
c-
) "'---

CC--r ~J hp~J 1 Y-lcr-'O

--....
p
(§ calculate the emf ofthe cell

Pt, H2(1.0 atm) I CH3COOH(O.lM) II NH3(aq.O.01M) I H2(1.0 atm), Pt

~kif ,~~
:t.
l~)

(A{.3~~ +1
-r

'y ~ ~~'lf1Q,--f<2~~

..L.

cJ \A ~ --\- /Le,­
.k
((7-)
~
to ~ d\'I --di' ~ k ,\"'"\ "t ­
----
J~-I-,J)~ 1
.... Clr'\t J ~ Cz-:=- Rw ~ _K\.D~
T\< b ~ 0- ~ ,'" J '~16 -M()::C')(O'
I

, ­

\--j 2- + ~ l--t t ~ J \--1 rt -t '-4-,

(1~~) (el-) eel) lta.~)
, L
& '='- (C I _)
 , /' g r- I 0~( ~ 0 -, )

Kw
. r ~ 1--- 10 .--i­
I o.-J4

)g t -q-J
- ,?-i~
-
e The cell Pt, H2(latm) I H+(pH = x) II Normalcalomel Electrode has an EMF of O.67V at 25°C. Calculate the
pH of the solution. The oxidation potential of the calomel electrode on hydrogen scale is -O.28V.

\{~~+ t ~ \-l ~ H.-\ t2J"if­

~ Cla~) ~l

'L­

~ :2-. [H 7J
,

~R--fL - s~
~1 ()
()~ ?-g v-­

NUYlJ-+- 4
() ", b '1 ::=-. o 2- g
 C9\-lc<-M~:
~~.
(. ~~;)

B Voltage of the cell Pt, H,(l atm) I HOCN (10- 3M)

HOCN. Neglect [H+j b . .
ecause of oxidation of H2(g).
II A + (0
g .8M) I Ag(s) is 1.0006 V. Calculate the K
a
for

Ag+ + e -7 Ag(s) =0.8 V.

.....

-
-..

('

E
l' ~ c« z.
~

(- tZ

: - f /155;( IDVl
.... 1"_

10---3_ 3'JgS-xlo~~

Z- 1·~t:68 XILJ--Lj
&Iculate the voltage,E, of the cellat 25'C

. Mn(s) I Mn(OH!l(s) I MFl 2

+ 111M), OH-(l.OO x 10-4 M) II Cu 2+(O.19 M) I Cu(s)

given that Ksp =1.9 x 10-13 for Mn(OH)2(s)

EO (Mn 2+/Mn) = -1.18 V
o .
£: (U..A"1( u.;) z; e \.H
fV) 'Y)!l.--f + :::< €- ­
~
y=- ~ fvlY)\Q}1) L
[ (JYl- J'1-./
CLe­
(S)

E
~ The overall formation constant for the reaction of 6 mol of CN- with cobalt(ll) is 1 x 1019. Th~ standard
L7 reduction potential for the reaction

[CO(CN)613- + «: -7 Co(CN)64- is -0.83 V.

Calculate the formation constant of [CO(CN)613­

Given C03+ + e- -7 C02+; EO = 1.82 V

~- 'i...­
~ ~)(,1 + Ie:- ~ ~~f'J)'1
E~-= 0 ,ot:;;4
I
k,a S­
Ir):::.
2­
Co ?---t .-1- t e. ~ -7 Co 1---\­

b'" ;:: 0 '0 ~ _ 1-0-( K3

k j.. -==- '1 r
Qj "'1--
lJO
to '
® The voltage of the cell

Zn(s) I Zn(CN)/-(0.450M), CW(2.65 x 10-3M) II Zn2+(3.84 x 10-4 M) I Zn(s)

=
is E + 0.099 V. Calculate the constant Kffor Zn2+ + 4CN-1il Zn(CN)42-, the only Zn2+ + CN

complexation of importance.

~L • :> VI~-t +2-e-

c.r-> ""?""" ( e, )

t'l.--t -\- 2L
Cf~
3 '<6\.\ 7- \ 6 ~
L-­
~l~~)'1)

~
kf [~(C- t-O ~J
C,LNr-J '1 y: Cl
-, .
t'r, S AI c) ~4 ~ kf~

Dl ~ w1- t ~
x--
~_L1
"/A 1 -t- ~
L.....
1)
 $

I £.f:dl ~o
, ,.,
LrTYlt. ~ L~1

C l -::. I· 6&fz x lO-7­

1<1- = ~ [Zh C'CiI/);j

[Zn J [crvj'it
2

L 5 3 C[
J )( ~ D/6
 @,volt. of theg• "II --- --

Pt' H {g, 608torr) I HCIO (4.34 x lO-3M) \ I S.C.E. is E =+ O.s32V. Calculae the dissociation constant
2
for HCIO. Given, E{SCE) = 0.242.

......
A:. 0 ...0
~
~H't +2e­
--- 2-

(-~~~) ~
:,r' e
EA- -- E .,-- o--.-------..
-c s-1
~ 2---.
'0

0' .S;:"3 I- -- '=.Cct= ~ EPr

~ ~

O~ ~~ 2­
~ (yc-. .,. ~ '1 V~I~
E-A-- -­ 0. 0 51

3
r U~f)
kt\
......,.

-
..-­ ~,2L~ Ylu
-
O.1-q -:- - o~
2..­

 u.,»: JJ ~C} , r­
Clllculaleenlropy and enthal h . .
py c ange In their standard state.
2-/ (J

d~:: vel p- .$01 T

$::- -~~)
'J -)p
~ ,6(,

6 Q ==-- _ Y\ ~ l \~ ~() = --2-'f.'f-S\4"~~·G

'2-£
= -i5{b2-/"{ROT
~ 6-~::o-- 6 H ~ 3, [L~s,)
C~~
6)1 :: -- d ~ 2- ~._g tJ t 300 (-~'tr<1~\
J

r L:, \-\ ~ -?, ~ "I' g oS- k.~

@HoW longa current of 2Ahasto be passed throuh a solutionof A,ND, to coat a metal surface of 80 .
3.
cm 2 with sum thick layer? Density of silver = 10.8g/cm

~7)e:- -rlT
~~ t Ay .~}e-~ ~
-
~
Q A current was passed thorough an aqueous solution of an unknown salt of pd for 160 min 50 sec.
~~32 gmof Pd+n was deposited at cathode. Find n. (Atomic wt. of pd = 106.4)

fet rn-t t Y1e: ~ Pet

~~ I ~\- L/AW'_
s- '.S2-- '::0 • t 0 (, '''1 t< (~ ')( ~ OJ b sro)
'Y) ~~q ~
~ metal Is known to form fluoride M',. When IDA of electricitv Is passed through a molten "It for
~30 sec" 1.95 g of metal isdeposited. Find the atomic weight of M. What will be the quantityof
electricity required to deposit the same mass of Cu from CuS04?

C~~) ({StF r 6)
I, qs ;;C (rnwt> y. 1,0 ~ 3.3b 2- X '1 ~rao

2''f4~ l e¥7S ~1 ,:s.~ at$lI.M:-hJ

fA ~ ~12J;, ~1­

UtrUtn~
 r;;:j;J
~actions
ml of 0.1 M (uSO. solution Is electrolyzed with a current of 0.965 A for a period of 200 sec. the
at electrodes are:

Cathode: Cu 2+ + 2e- rn Cu(s)

Assuming no change in volume during electrolysis, calculate the molarconcentration of Cu 2+, H+and
5°4 2- at the end of electrolysis.

fA.:) '\ U. '"()~JY\A.\,f")

)lor- ~ c..ko\

\f' _ '
~0-~1_~ __-----­
!j 'S"1YU ~ L.
:{ C.L~21 + :Le.- ---7 c: ~ 1 _: 'h-F- ""'.L 3
,-~ ')
(------~
-. S-0 '( 0' \
~ ID /
IO()D
..

, ()-oo

-,
(!Y\ 0 )
~ ryrA~J.

l '.: v» t-1 c, ::

LWJ
C ewt::. D' 0\.1 tvJ]
"--">
@ '0. fal,1y concentrated solution of CuSO4 is electrolyzed usln.O.o1 Fof electricltv. calculate:

(a) The weight of resulting solution (b) Equivalent of acid or alkali in the solution.

~M ~~-~f*~
t\
C)'O\

 Q An electric current is passed through electrolytic cells in series one containing Ag(N0 3)(aq). and other

V H2S04(aq). What volume of 02 measured at 27"C, 1 atm and 750 mm 3 Hg pressure would be liberated
from H2S04 if

(a) one mole of Ag+ is deposited from AgN03 solution

(b) 8 x 1022 ions of Ag+ are deposited from AON":! solution. gN. ~ 610") x

~J.t'.
~~:
~~ 0 ~ _0& +~ Ht~~~~
~~0--1~ I ~I-- tp.rvJ
~Ol-
1 t; CA
4y.. /j(,'=V
_

t;::'J~P>2-}»( 3~

- .

~)
- 2-2.­
rr'1if ~ g ~ID ~
...- ~
--
~"'Y--!t) 1-.1 1i 6.n-o ,J\j2~Y
~~ B66"'OD X 8
-,
0" ~ 11~

A
-6 Il\ 0/' o",r
~Cd amalgam is prepared by electrolysis of a solution of Cdel2 using a mercury cathode. How long should a
~ currecnt of SAbe passed in order to prepare 12% Cd-Hg amalgam on a cathode of 2gm Hg (Cd=112.4).

12-~' G\ -Her ~

t~ U -7 8~ ~ }!r
., ~ I~){~-? -~~~~
'l-t t{( 9

( 1: ~ '1 ,~\~ [A/.A;J ~~ ~)

2 'A 12- ::= 112,4!: (s: X b)

£~ 2---1 Q6StJO
 ~After electrolysis of NaCI solution with inert electrodes for a certanin period of time. 600 mL of the
V solution was left. Which was found to be IN in NaOH. During the same time, 31.75 g of Cu was
deposited in the copper voltammeter in series with the electrolytic cell. Calculate the percentage yield of
NaOH obtained.

--.~ Gx.~.~~
~
~-------
I~J-r+ oJ Le -7 Hi.,
N
~ ~rf2---0 1- l-e-- ~ >12-+ L~Hr-
eC\JCC~~
~~'r
1
,st
~i' 'N",~
~
Y) ~ ~:::- _&~~
2- «; ~ 6"ruv ~'~ I~r-~
~ (" .-.:r~ 2 -b '},S ;>( 6\....
2-'>< 9~D

I
~me qua~tily of el.ect'idty;s being used to liberate lodlne tat anode) and a metal' (at Ca;~ode). The
V;ass of x hb:rated IS 0.54g and the iodine is completely reduced by 50 cc of 0.1 M sodium thiosul hate.
Flnd the equivalent mass of x, P

~. c;-~ == ~~V\)
\J 1" &l:v:o (0A»t).12- 'f- 5)
'j.­ 1­ " 4' &~\)
{ -s ~}t0 ~ - ~ --Q
lrr*1 L­ ~-r- c; 6nJO ·

If<< M~ ~

l&-J ~ 0 ~oZr'fIJ} '1-10:

~
0' s:~ r-
l\1

1" /" \ ~~
 50··xO'}.Y)
-- -=--­
l()770
~The 3+IBi) and E 2+ I
L:Y
O(Bi O(Cu
standard reduction potential values, E CuI are 0.226 V and 0.344 V
respectively. A mixture of salts of bismuth and copper at unit concentration each is electro lysed at 25°C
to what value can [Cu2+] be brought down before bismuth starts to deposit, in electrolysis.

O':~ 7 [~1
£~ · ~ E:- ca- ~ cd{
-::€v
~
'U ~
J~ . 0
E. (st!dJf:,r'
c~ LluUJ J,. U .ucu p~~ (f?;Jf'~ftU~~

tA91Il~ --t ~ ~ d~'1-

:::- 0' ~ 4'i f Q 'O~ ~J t»: +j L

j [Cu1-~ z: ,(/, fVJ

 ~ A current of 2amps is used for 60 min. to electrolyze copper from a solution of Cu
2
+ at a potential of 0.337
L/VOltS. .

(a) How many coulombs are used

(b) How many moles Cuts) are plated out?

-(e) What weight Cuts) in grams is plated out?

(d) What power in watts was used?

Ck)
~ ~~..d"'Y 'j I j } ;' lttW ~

(W~(),t) ,~- ~~-~~~~y+vPO

. eJr
l Y1-t-~~

o ~~ 1- Gt0 ct~'\e ~ p'. liJ9

MJl~ <tN ~tMle1
~fV3:t rn~
f0-«J"Ul~::- V1- l;X C

~.
if' 2
you electrolyze a solution of Ni + (aq) to form Ni(s) for 2.00 h using a current of 2.50 amp, what mass of
~i(S) (AW =58.69 g/rnol] is produced at the cathode?

Nl'l-'f --r ~ ~ Nt'

(txfr) . lS)

r.f-ClA"'-~ I r />+ ~
--,

(Wt)N; ~~g. h"t ')( (~ 'Y-3(;0-0 )(L'~

L 1-- .~~

C;; e ~n zrrn I
,"
~ttery
~~er
wasused to supplya constantcurrent of what wasbelieved to be exactly0.45 A as readon a
in the external circuit. The cell was based on the electrolysis of a copper sulphate solution. During
the 30 min,that current was allowed to flow, a totalof 0.3 g of copper metal was deposited at the
cathode. Determine the extentto which the meterwas inaccurate

J ~>r- }c;tw
-=tr'~
6~'~ (i.! 601'- ( 0
)

1-~1~o

"

~~
~=(f.~ (, - Q' '1-9
Or ru"
 " CCJUk-7bz%u~
paf;J. (~10
1NJI/\ J ttl Y
.~;)

4 J1L

~
. .. ~J-- be ~'vf'
_/·"lIt0 -'lO.. A balloon is being filled with hydrogen produced by the electrolysis of an aqueous solution of an acid. How long
I

will it take to generate enough hydrogen to lift 1.5 kg by using a current of 8.5 A?

\t,OL ~[l,:{-(, gez

~ 4:t 0 ~yS
---
­
' <,

------------~------

.\
\,

1 >O\? z V Cp;[~ p?\ ~ -....

/Z-T
V)H 7.---. L lSOV
Ly

e>>«

-----=­
q£S7lD

.: ,,3S () L~. Ju;up \

~A current of 3.7 A is passed for 6 hrs. between Ni electrodes in O.5L of 2M solution of Ni(N03 )2' What is

V~he molarity of solution at the end of electrolysis?

t
/.

I
t
I

f
i
r

I
!,
!
i
I
1

!
!
I
i
" I
[
!

[ N~-J
@
e The reslstance of a conductivity cell filled with O.OIN solution of N,el is 210 ohm
at18°C.Calculate the e~.

conductivity cell is
ent conductivity of the solution. The cell constant of the

O.8~ C m---l

e lk-)
$( D·\63)

-
210 ohm CrY)

OlBB
, ,II. ~ ,_ ~, --l
- . ---r '-f" 1.9 X 10-- 0 nm em
~

~ 4-'$ )(\/((r
Ol'l1 J

rJ 419
 ... --- t
@ 1
i .'.") he molar conductivity of 0.1 M CH3COOH solution is 4 6 5 cm
conductivity and resistivity of the solution?
o
2
~
mol ~ Wh at lIS th e speerlflIC

~------

K-7 thFrt U>d,,-wmty

M -7 M.,{axl7-­ rJ--7'
1"'
"
~=- rY1

A~'~ A",
-( 'Yh~-) r-? ryz fcfn-f
Ui'b ~~ I V\ ~+. ~ 1

A¥J
-:7JlE -- =-
I
(JJ
4,1 r- l
---
L
<-S em ro.o
... k it e-o D ,---.
.;­

ro I
t
<

I
- 1/
he conductivity of pure water i onductivity cell with electrodes of cross sectional area 4
cm 2 and 2 cm apart is 8 x 10 rn 7 S cm lill , g'-f 1
10.- .5 ~m .... 1
Ii) What is resistance of conductivity cell ?

Iii) What current would flow through the cell under an applied potential difference of 1
volt?

(t~ ) R ­....., ~(~)

si.
ohm
b -....... g ')('0;+ .:
g ­ 6'~(
'--
..... (0
8
c~

h J, C ,,'
o rY\ m

J'D~
g

I::: L ~ G· '2 s « I b S-)

(,=- 1~6'X10-b A
....
l
----- <.
~ Resls tlvitv of O.1M KCI solution Is 213 ohm em In a conductIvity cell. Calculate the cell
~ constant if its resistance is 330 ohm. . ~ c>"
~ tell C_etJtV)1Nv'i
R= ~ t~)

S~D~ l:Ll3) (7;-)

~
. -'....:

&« ~ '. Resistance of a O.lM KCI solution in a conductance cell is 300 ohm and specific conductance of
O.lM KCI is 1.29 x 10- 2 ohm- 1 cm- 1. The resistance of O.lM NaCI solution in the same
cell is 380 ohm. Calculate the equivalent conductance of the O.lM NaCI solution.

~·K .LJ.­ ~U
,
)
.......,

qz\~ gr(~ R-L~ e, C-~)

"
(So-o XY
._­

f
-.1<2­

r
@~
'. •
" OhM
• For 0.01N KCI. the resistivity 709.22 Scm. Caicuiate the conductivity and eqUivalent
conductance.

,
\"
 .~ iW

[ A--)

fo;- 7oCf·t k ~rn. en']

2 7.- o 12.1- oIrm fYj

/1

It(.. J-~ O/Itt) ~~1 rYJ-I

E-
J .

ai c i ». 1

L DDV)(O~o)
 ( ,4hwr 8:P-.:2'?> 1- ·.5)
. A solution containing 2.08 g of anhydrous ba~chloride is 400 CC of water has a specific
conductivity 0.0058 ohm-1cm- 1. What are molar and equivalent conductivities of this
solution.

/Iv IV\. ";c k )< I {YUO z: 0' (lO> g "1- I Ct('J\:')

0' 01-~ O· D2'i

[AW\ : : 2- 3 L.33crhm~1 ~m rnc\~l 'L

ID"02-~ M '/.. ~
...\,.
()f ~f- ~

"
&9.
Equivalent conductance of 0.0' N Na,S04 solution is '12.4 ohm-' em' eq-l The equivalent

conductance at infinite dilution is 129.9 ohm- 1 cm 2. What is the degree of dissociation in

0.01 N Na2S04 solution?
\\ l-~LJ
~tJ~y~~~~
==- 0 r ~ bS'L
;0

~ f\M~0'1 ' \

f l-j·1
tf)(~.. Specific conductance
LY--' . of a saturated solution of AgBr is 8:486x10- 7 -1­
Speclflc conductance of
AgNO, and KNO
pure water at 2S·C .
3 are 137.4 I 133 I
7 6
ohm . em 1 at 25°C.
2
rs 0. S .,0- ohm- cm- . A"
131 ( S cm 2 -1
@ m For KBr I

solubility of AgBr in gm/litre. mol ) respectively. Calculate the

(<2 ~t- ~-1-1

:::- ~ . 4 g s "f...\ 0 - 1, <;; 1- I 0 /

o1rJ m" 1 em,-l
0'.1 g{;Alo1- o~ICm-J

-­-
---------~

r (

1· D:=J- 1-10-:7- YYll:>ll L

7~ I' '?,3> X LO'-~ (J/ L.

~atu"ted solution of AgCI at 2S'C has specific conductance of 1.12.,0- 6 ohm- 1 em-I
~~he A.: Ag" and A.:CI- are 54.3 and 65.5 ohm- 1 cm 2 / equi. respectively. Calculate the
solubility product of AgCI at 25'C.

M C'- #~. / ~
~ ~f' ~O!
..0
- ~ GL

.r'
. r~ i
l'
1
< k~<J. J'- I 0-0-0 ~ l

5 -A.». ~ Ai d.)'­ .s
2­

'dC?J £. 5
~~Yd'Of'Uorlc acid is weak acid. : t 25'C, the molar conductivity of O.002M HF is

\:7;76.2 ohm- 1 cm 2 mole- 1. If its Am = 405.2 ohm"",l cm 2 mole- 1, calculate its degree of
dissociation and equilibrium constant at the given concentration.

k l). :::- (L d-) C£oZ)_

o 0 .-- ICI~.1-)

Ld.'L
.... ~
k~
0:-

'"
[[r-c£)
­

r ~~~ {, .
, ~~IO
-~

1. ­
...
.~
@ ! The value of A% for HCI , NaCI an e- CH I&'
3COAIa

Calculate the value of A% for acetic acid If t h e '

at 250 C, calculate its degree of dlssodatl
are 426.1" 1265 and 91 S cm

. .
2 mo 1 respectively.
1- .

squlvelent conductivity of the given acetic acid is 48.15

Ion.

('2 vt

--
J:
~l~
r
10

hi- uJuJJt~ viC f

/~
'Il ()13 LDD11 ...,
I£)

vL ~1J(oD -J vl~ 1­ -(j)

pC) . -0

J\; \-{ ~ ­
r-(j)
0()
J\- Nt\cJ z:

1\'fJ A
oO
A~ f-S(
V'-' t
l1
,crAl 10"- -z: IV u'1;}ll\1 t ;vrJ.. ­
2
0) ~(j) -h)

-4.4' I ~ I ii-s -t:3J ~ !,!JO'£

0Wt2me/'""' 1
~alculate the specific conductance of a 0.1 M aqueous solution of NaCI at room
V':emperature, given that the mobilities of Na+ and CI- ions at this temperature are
4.26xlO- 8 a nd 6.80x10- 8 m 2 v- 1 s-l, respectively.

IL,tJo..
......
t .: ) ) N'fA 't
...
-S(;K'OQ

~ Y' I' 1- )'0 ~3 / .;ltr~ 6, ~bM O~ 3

bi r l Or-L- 0 h,~,-.l~ 1-f'(Y1DV"
s- J
~~~~~~I
,

\ ( :;. 1\r!~:X t(hJO X 0 . J

~ [.067 6~-1_h)Jr
~r the strong electrOy~es NaOH, Na~ and BaCI2 the molar ionic conductivities at infinite

~~Iutlon are 248.1x10 4, 126.5 x10 4 and 280.0 x10- 4 mho cm 2 mol- 1 respectively.
Calculate the molar conductivity of Ba(OH12 at infinite dilution.

($ rl

rIC f1:J..h ) 1-- ':0­

[) : :- cD + 2--CD - 2- (3)

- 2-&0 tZ'o~ + 2i-2-tr~,Jy.. tD~_2-0,H.rJ

--I I {Or-7

.: l2-g0 t ~ qj. • .2- - ~53.0 ) fled .

~ 15-~ 3 · 2- ,(I ~4 ] _ ~I
.- ~ Cftl-z-.~
@ At 25'C, ..: IH+I = 3.4982 xlO- 2 5 m 2 mol- 1 and ..: (OH-I=\8 x10- 2 5 m 2mol-1 .

Given: Sp. conductance = 5.1 x10- 6 S m- 1 for H20 , determine pH and Kw'

~ . )(l~l!"'g r. \00'0
(S;;S-9
Q:4''1 ' £ 2--)
g~2 t<IO (k0~~n[H2.[~~L_
g
If. qq 6L II( ~ 1/ -- L -=- S' I >I. l 0 ~ 6' )I ~-!--(­
l armfMj

It HE] c j<OL03)(lOf
I
-0) ,. .
..