1.

The correct electron-dot formulation for hydrogen

The valence electrons of representative elements cyanide shows:
are (a) 2 double bonds and two lone pairs of electrons
(a) in s orbitals only. on the N atom.
(b) located in the outermost occupied major energy (b) 1 C-H bond, 1 C=N bond, 1 lone pair of electrons
level. on the C atom and 1 lone pair of electrons on the N
(c) located closest to the nucleus. atom.
(d) located in d orbitals. (c) 1 C-H bond, 1 C-N bond, 2 lone pairs of electrons
(e) located in the innermost occupied shell. on the C atom and 3 lone pairs of electrons on the N
2. atom.
Which of the following pairs of elements and valence (d) 1 triple bond between C and N, 1 N-H bond and 2
electrons is incorrect? lone pairs of electrons on the C atom.
(a) Al - 3 (e) 1 triple bond between C and N, 1 C-H bond and 1
(b) Br - 7 lone pair of electrons on the N atom.
(c) S - 4 9.
(d) Sr - 2 The correct dot formulation for nitrogen trichloride
(e) Tl - 3 has:
3. (a) 3 N-Cl bonds and 10 lone pairs of electrons.
With regard to the species 16O2-, 19F- and 20Ne, which (b) 3 N=Cl bonds and 6 lone pairs of electrons.
of the following statements is correct? (c) 1 N-Cl bond, 2 N=Cl bonds and 7 lone pairs of
(a) All three species contain 10 electrons. electrons.
(b)The sum of the neutrons in all three species is 27. (d) 2 N-Cl bonds, 1 N=Cl bond and 8 lone pairs of
(c) The sum of the protons in all three species is 28. electrons.
(d) Both 19F- and 20Ne contain 20 neutrons. (e) 3 N-Cl bonds and 9 lone pairs of electrons.
(e) none of the above 10.
4. What is the total number of electrons in the correct
Which of the following does not have a noble gas Lewis dot formula of the sulfite ion?
electron configuration? (or Which of the following is (a) 8
not isoelectronic with a noble gas?) (b) 24
(a) S2- (c) 26
(b) Ba+ (d) 30
(c) Al3+ (e) 32
(d) Sb3- 11.
(e) Sc3+ In the Lewis structure for the OF2 molecule, the
5. number of lone pairs of electrons around the central
Which one of the formulas for ionic compounds oxygen atom is
below is incorrect? (a) 0
(a) SrCl2 (b) 1
(b) Cs2S (c) 2
(c) AlCl3 (d) 3
(d) Al3P2 (e) 4
(e) CaSe 12.
6. The electronic structure of the SO2 molecule is best
Which is classified as nonpolar covalent? represented as a resonance hybrid of ____
(a) the H-I bond in HI equivalent structures.
(b) the H-S bond in H2S (a) 2
(c) the P-Cl bond in PCl3 (b) 3
(d) the N-Cl bond in NCl3 (c) 4
(e) the N-H bond in NH3 (d) 5
7. (e) This molecule does not exhibit resonance.
Which one of the compounds below is most likely to 13.
be ionic? Consider the bicarbonate ion (also called the
(a) GaAs hydrogen carbonate ion). After drawing the correct
(b) ScCl3 Lewis dot structure(s), you would see:
(c) NO2 (a) two double bonds around the central carbon
(d) CCl4 atom.
(e) ClO2 (b) three single bonds around the central carbon
8. atom.
 (c) four single bonds around the central carbon atom. 21.
(d) two equivalent resonance forms. Which of the following species is planar?
(e) three equivalent resonance forms. (a) NH3
14. (b) H3O+
Draw one of the resonance structures of SO 3. The (c) SO32-
formal charge of S is (d) PF3
(a) +2 (e) NO3-
(b) +1 22.
(c) 0 What kind of hybrid orbitals are utilized by the
(d) -1 carbon atom in CF4 molecules?
(e) -2 (a) sp
15. (b) sp2
Which one of the following violates the octet rule? (c) sp3
(a) PCl3 (d) sp3d
(b) CBr4 (e) sp3d2
(c) NF3 23.
(d) OF2 A neutral molecule having the general formula
(e) AsF5 AB3 has two unshared pair of electrons on A. What is
16. the hybridization of A?
Choose the molecule that is incorrectly matched (a) sp
with the electronic geometry about the central atom. (b) sp2
(a) CF4 - tetrahedral (c) sp3
(b) BeBr2 - linear (d) sp3d
(c) H2O - tetrahedral (e) sp3d2
(d) NH3 - tetrahedral 24.
(e) PF3 - pyramidal What hybridization is predicted for sulfur in the
17. HSO3- ion?
Choose the species that is incorrectly matched with (a) sp
the electronic geometry about the central atom. (b) sp2
(a) NO2- - trigonal planar (c) sp3
(b) ClO4- - tetrahedral (d) sp3d
(c) SO32- - pyramidal (e) sp3d2
(d) ClO3- - tetrahedral 25.
(e) BrO4- - tetrahedral Which of the following four molecules are polar:
18. PH3 OF2 HF SO3?
Which of the following pairs of molecules and their (a) all except SO3
molecular geometries is WRONG? (b) only HF
(a) NF3 - trigonal planar (c) only HF and OF2
(b) H2O - bent (d) none of these
(c) BF3 - trigonal planar (e) all of these
(d) AsF5 - trigonal bipyramidal 26.
(e) SeF6 - octahedral Which molecule is nonpolar?
19. (a) H2Se
Which molecule has a linear arrangement of all (b) BeH2
component atoms? (c) PF3
(a) CH4 (d) CHCl3
(b) H2O (e) SO2
(c) CO2 27.
(d) NH3 The F-S-F bond angles in SF6 are ______.
(e) BF3 (a) 109o28'
20. (b) 120o only
Which polyatomic ion is incorrectly matched with its (c) 90o and 120o
ionic geometry? (d) 45o and 90o
(a) SiCl62- - trigonal bipyramidal (e) 90o and 180o
(b) PH4+ - tetrahedral 28.
(c) ClO2- - angular Which response contains all of the characteristics
(d) NH4+ - tetrahedral listed that should apply to phosphorus trichloride,
(e) SO42- - tetrahedral PCl3, and no other characteristics?
 (1) trigonal planar (c) 1
(2) one unshared pair of electrons on P (d) 5/2
(3) sp2 hybridized at P (e) 2
(4) polar molecule 35.
(5) polar bonds Which of the following is the correct electron
(a) 1, 4, 5 configuration for C2?
(b) 2, 3, 4 (a) 1s2 2s2 2py2 *1s2 *2s2 *2py2
(c) 1, 2, 4 (b) 1s2 *1s2 2s2 *2s2 2py2 *2pz1 2p1
(d) 2, 4, 5 (c) 1s2 *1s2 2s2 *2s2 2py2 2pz2
(e) another combination (d) 1s2 *1s2 2s2 *2s2 2py1 2pz1
29. (e) 1s2 *1s2 2s2 *2s2 2py1 *2py1 2pz1 *2pz1
A (pi) bond is the result of the 36.
(a) overlap of two s orbitals. What is the correct electron configuration for the
(b) overlap of an s and a p orbital. molecular ion, B2+?
(c) overlap of two p orbitals along their axes. (a) 1s2 *1s2 2s2 *2s2 2p2
(d) sidewise overlap of two parallel p orbitals. (b) 1s2 *1s2 2s2 *2s2 2py2
(e) sidewise overlap of two s orbitals. (c) 1s2 *1s2 2s2 *2s2 2py2 2pz1
30. (d) 1s2 *1s2 2s2 *2s2 2p1 2py1
A triple bond contains ___ sigma bond(s) and ___ pi (e) none of the above.
bond(s). 37.
(a) 0, 3 Draw the molecular orbital diagram for the
(b) 3, 0 molecular ion, N2+. The number of electrons in the
(c) 2, 1 2p molecular orbital is:
(d) 1, 2 (a) 0
(e) 3, 2 (b) 1
31. (c) 2
The perchloric acid molecule contains: (d) 3
(a) 13 lone pairs, 1 bond, and 4 bonds. (e) 4
(b) 9 lone pairs, no bonds, and 6 bonds. 38.
(c) 8 lone pairs, 2 bonds, and 7 bonds. What is the bond order in O2+?
(d) 2 lone pairs, 3 bonds, and 4 bonds. (a) 3.5
(e) 11 lone pairs, no bonds, and 5 bonds. (b) 2.0
32. (c) 1.5
Draw a complete line-bond or electron-dot formula (d) 2.5
for acetic acid and then decide which statement (e) 0
is incorrect. 39.
(a) One carbon is described by sp2 hybridization. Draw the molecular orbital diagram for B2. The
(b) The molecule contains only one bond. number of unpaired electrons in the B2 molecule is
(c) The molecule contains four lone pairs of valence _____.
electrons. (a) zero
(d) One carbon is described by sp3 hybridization. (b) 1
(e) Both oxygens are described by sp3 hybridization. (c) 2
33. (d) 3
Which statement is false? A sigma molecular orbital (e) 4
(a) may result from overlap of p atomic orbitals 40.
perpendicular to the molecular axis (side-on). Which one of the following statements is false?
(b) may result from overlap of p atomic orbitals (a) Valence bond theory and molecular orbital
along the molecular axis (head-on). theory can be described as two different views of
(c) may result from overlap of two s atomic orbitals. the same thing.
(d) may result from overlap of one s and one p (b) When one considers the molecular orbitals
atomic orbitals. resulting from the overlap of any two specific atomic
(e) may be either bonding or antibonding. orbitals, the bonding orbitals are always lower in
34. energy than the antibonding orbitals.
Carbon monoxide has ten bonding electrons and (c) Molecular orbitals are generally described as
four antibonding electrons. Therefore it has a bond being more delocalized than hybridized atomic
order of orbitals.
(a) 3
(b) 7
 (d) One of the shortcomings of molecular orbital (c) OBr- and OH-
theory is its inability to account for a triple bond in (d) OBr- and HOBr
the nitrogen molecule, N2. (e) H2O and HOBr
(e) One of the shortcomings of valence bond theory 47.
is its inability to account for the paramagnetism of Which is the strongest acid?
the oxygen molecule, O2. (a) HClO4
41. (b) HClO3
Antibonding molecular orbitals are produced by (c) HClO2
(a) constructive interaction of atomic orbitals. (d) HClO
(b) destructive interaction of atomic orbitals. (e) HF
(c) the overlap of the atomic orbitals of two negative 48.
ions Which of these species is probably
(d) all of these the weakest acid?
(e) none of these (a) HCl
42. (b) H3PO4
Which statement regarding (c) H2PO4-
stable heteronuclear diatomic molecules is false? (d) HPO42-
(a) All have bond orders greater than zero. (e) HNO3
(b) The antibonding molecular orbitals have more of 49.
the character of the more electropositive element Consider the neutralization reactions between the
than of the more electronegative element. following acid-base pairs in dilute aqueous solutions:
(c) Their molecular orbital diagrams are more (1) CH3COOH + NaOH
symmetrical than those of homonuclear diatomic (2) HNO3 + Mg(OH)2
molecules. (3) H3PO4 + Ba(OH)2
(d) The bonding molecular orbitals have more of the (4) HCl + KOH
character of the more electronegative element than (5) H2CO3 + LiOH
of the less electronegative element.
(e) The greater is the difference in energy between For which of the reactions is the net ionic equation:
two overlapping atomic orbitals, the more polar the H+ + OH- H2O ?
resulting bond is, due to electrons occupying the
resulting bonding molecular orbital. (a) 1, 3
43.
(b) 1, 4, 5
Arrhenius defined an acid as:
(c) 2, 3
(a) a species that can donate a proton. (d) 4
(b) a species that can accept a proton. (e) 1
(c) a source of OH- ions in water.
50.
(d) a sourse of H+ ions in water. Which one of the following represents the net
(e) a species that can accept a pair of electrons. ionic equation for the reaction of nitric acid with
44. aluminum hydroxide?
In the Bronsted-Lowry system, a base is defined as:
(a) 3H+ + Al(OH)3 Al3+ + 3H2O
(a) a proton donor.
(b) 3HNO3 + Al(OH)3 Al(NO3)3 + 3H2O
(b) a hydroxide donor.
(c) HNO3 + OH- NO3- + H2O
(c) an electron-pair acceptor.
(d) H+ + OH- H2O
(d) a water-former.
(e) 3NO3- + Al3+ Al(NO3)3
(e) a proton acceptor.
51.
45.
+ - Which one of the following is an amphoteric metal
In the equation: HF + H2O H3 O + F
hydroxide?
(a) H2O is a base and HF is its conjugate acid.
(a) KOH
(b) H2O is an acid and HF is the conjugate base.
(b) Ba(OH)2
(c) HF is an acid and F- is its conjugate base.
(c) Pb(OH)2
(d) HF is a base and H3O+ is its conjugate acid.
(d) LiOH
(e) HF is a base and F- is its conjugate acid.
(e) Mg(OH)2
46.
52.
For the system shown here: HOBr + OH- H2O + According to the Lewis theory, a base _____ .
OBr- (a) is a proton acceptor.
Bronsted would classify the base species as: (b) is a proton donor.
(a) OH- and HOBr (c) makes available a share in a pair of electrons.
(b) H2O and OH- (d) produces OH- ions in aqueous solution.
 (e) accepts a share in a pair of electrons. the (COOH)2 is to be completely neutralized in an
53. acid-base reaction.)
How many grams of Ca(OH)2 are contained in 1500 (a) 0.033 N
mL of 0.0250 M Ca(OH)2 solution? (b) 0.045 N
(a) 3.17 g (c) 0.066 N
(b) 2.78 g (d) 0.090 N
(c) 1.85 g (e) 0.12 N
(d) 2.34 g 60.
(e) 4.25 g What volume of 0.100 N HNO3 is required to
54. neutralize 50.0 mL of a 0.150 N solution of Ba(OH)2?
What volume of 12.6 M HCl must be added to (a) 50.0 mL
enough water to prepare 5.00 liters of 3.00 M HCl? (b) 75.0 mL
(a) 1.19 L (c) 100. mL
(b) 21.0 L (d) 125 mL
(c) 0.840 L (e) 150. mL
(d) 7.56 L 61.
(e) 2.14 L How many grams of NaOH would be required to
55. neutralize all the acid in 75.0 mL of 0.0900 N H2SO4?
What is the molarity of the salt produced in the (a) 0.540 g
reaction of 200 mL of 0.100 M HCl with 100 mL of (b) 0.270 g
0.500 M KOH? (c) 1.32 g
(a) 0.0325 M (d) 0.660 g
(b) 0.0472 M (e) 0.859 g
(c) 0.0667 M 62.
(d) 0.0864 M What is the oxidation number for carbon in CaC2O4?
(e) 0.0935 M (a) 0
56. (b) +2
What volume of 0.50 M KOH would be required to (c) +3
neutralize completely 500 mL of 0.25 M (d) +4
H3PO4 solution? (e) +6
(a) 2.5 x 102 mL 63.
(b) 1.4 x 103 mL Balance the molecular equation for the following
(c) 83 mL redox reaction. What is the sum of the coefficients?
(d) 7.5 x 102 mL Don't forget coefficients of one. Use the smallest
(e) 5.2 x 102 mL whole number coefficients possible.
57. H2SO4(aq) + HI(aq) I2(s) + SO2(g)
A 0.6745 gram sample of KHP reacts with 41.75 mL (a) 7
of KOH solution for complete neutralization. What is (b) 9
the molarity of the KOH solution? (Molecular weight (c) 11
of KHP = 204 g/mol. KHP has one acidic hydrogen.) (d) 13
(a) 0.158 M (e) 5
(b) 0.099 M 64.
(c) 0.139 M For the reaction between permanganate ion and
(d) 0.079 M sufite ion in basic solution, the unbalanced equation
(e) 0.061 M is:
58. MnO4- + SO32- MnO2 + SO42-
How many equivalents of phosphoric acid are
contained in 300 mL of 4.00 M phosphoric acid? When this equation is balanced using the smallest
(Assume the acid is to be completely neutralized by whole number coefficients possible, the number of
a base.) OH- ions is
(a) 0.600 eq (a) two on the right.
(b) 1.20 eq (b) two on the left.
(c) 2.40 eq (c) three on the right.
(d) 3.60 eq (d) four on the right.
(e) 4.80 eq (e) four on the left.
59. 65.
Calculate the normality of a solution that contains Balance the following redox equation in acidic
4.5 g of (COOH)2 in 3000 mL of solution? (Assume solution with the smallest whole number coefficients
 possible. What is the sum of all the coefficients? (Do (a) 46.9 g/eq
not forget coefficients of one.) (b) 93.8 g/eq
Cu + SO42- Cu2+ + SO2 (in acidic solution) (c) 187.6 g/eq
(a) 9 (d) 375.2 g/eq
(b) 10 (e) 562.8 g/eq
(c) 11 71.
(d) 12 What is the normality of a K2Cr2O7 solution prepared
(e) 13 by dissolving 5.00 g of K2Cr2O7 in 200 mL of solution,
66. which will be used in the
When the following equation is balanced with the following unbalanced reaction?
smallest possible set of integers, what is the sum of Cr2O72- + SO32- Cr3+ + SO42- (in acidic solution)
all the coefficients? (Do not forget coefficients of (a) 0.733 N
one.) (b) 0.226 N
Cr2O72- + H2S Cr3+ + S (in acidic solution) (c) 0.510 N
(a) 13 (d) 0.441 N
(b) 24 (e) 0.810 N
(c) 19 72.
(d) 7 What mass of KMnO4 must be dissolved to prepare
(e) 29 1.25 L of 0.110 N KMnO4 solution? It is used in the
67. reaction in which MnO4- ions oxidize Fe2+ into
When the following equation is balanced with the Fe3+ ions and are reduced to Mn2+ ions under acidic
smallest possible set of integers, what is the sum of conditions?
all the coefficients? (Do not forget coefficients of (a) 4.34 g
one.) (b) 23.8 g
MnO4- + Se2- MnO2 + Se (in basic solution) (c) 115 g
(a) 20 (d) 19.1 g
(b) 22 (e) 70.6 g
(c) 24 73.
(d) 26 A 0.250 M solution of Na2C2O4 is to be used in a
(e) 28 reaction in which the C2O42- will be oxidized to CO2.
68. What is the normality of this Na2C2O4 solution?
Consider the following unbalanced equation in acidic (a) 0.250 N
solution: (b) 1.00 N
NaClO3 + H2O + I2 HIO3 + NaCl (c) 0.125 N
A 25.0 mL sample of 0.0833 M NaClO3 reacted with (d) 0.0625 N
30.0 mL of an aqueous solution of I2. How many (e) 0.500 N
grams of I2 were contained in the I2 solution? 74.
(a) 0.264 g What volume of a 0.150 N KI solution is required to
(b) 0.397 g react in basic solution with 34.1 mL of a 0.216 N
(c) 0.236 g solution of KMnO4? The products in the reaction
(d) 0.159 g include MnO2 and IO3-.
(e) 0.317 g (a) 25.4 mL
69. (b) 37.9 mL
Consider the following unbalanced net ionic (c) 12.6 mL
equation: (d) 98.2 mL
NO2- + MnO4- NO3- + Mn2+ (in acidic solution) (e) 49.1 mL
What is the molarity of a sodium nitrite, NaNO2, 75.
solution if 30.0 mL of it just reacts with 0.238 grams Calculate the normality of a NaClO solution if 35.00
of KMnO4? mL of the solution is required to react with 0.615 g
(a) 0.410 M of Zn according to the following unbalanced
(b) 0.126 M equation:
(c) 0.0502 M Zn + ClO- Zn(OH)2 + Cl- (in basic solution)
(d) 0.251 M (a) 0.537 N
(e) 0.0316 M (b) 0.275 N
70. (c) 0.108 N
What is the equivalent weight (in grams) of (d) 0.366 N
copper(II) nitrate for use in a reaction involving the (e) 0.791 N
conversion of copper(II) to copper metal?
76. I. P1V1 = P2V2
A solution of nitrous acid was standardized in a II. PV = constant
reaction where HNO2 NO3- and its III. P1/P2 = V2/V1
concentration was determined to be 0.100 N nitrous (a) I only
acid. What volume of this 0.100 N nitrous acid (b) II only
solution would be required to oxidation of 0.200 g of (c) III only
CoCl2 to CoCl3 according to the following net ionic (d) I, II, and III
equation? (e) another combination
Co2+ + HNO2 Co3+ + NO (in acidic solution) 82.
(a) 33.9 mL The volume of a sample of nitrogen is 6.00 liters at
(b) 15.4 mL 35oC and 740 torr. What volume will it occupy at
(c) 7.70 mL STP?
(d) 67.8 mL (a) 6.59 L
(e) 30.8 mL (b) 5.46 L
77. (c) 6.95 L
What is the sum of all coefficients when the (d) 5.67 L
following net ionic equation is balanced using the (e) 5.18 L
smallest whole number coefficients possible? Do not 83.
forget coefficients of one. The density of chlorine gas at STP, in grams per liter,
MnO4- + Mn2+ MnO2 (in basic solution) is approximately:
(a) 19 (a) 6.2
(b) 16 (b) 3.2
(c) 13 (c) 3.9
(d) 11 (d) 4.5
(e) 7 (e) 1.3
78. 84.
Which statement is false? What pressure (in atm) would be exerted by 76 g of
(a) The density of a gas is constant as long as its fluorine gas in a 1.50 liter vessel at -37oC?
temperature remains constant. (a) 26 atm
(b) Gases can be expanded without limit. (b) 4.1 atm
(c) Gases diffuse into each other and mix almost (c) 19,600 atm
immediately when put into the same container. (d) 84
(d) The molecular weight of a gaseous compound is a (e) 8.2 atm
non-variable quantity. 85.
(e) Pressure must be exerted on a sample of a gas in What is the density of ammonia gas at 2.00 atm
order to confine it. pressure and a temperature of 25.0 oC?
79. (a) 0.720 g/L
A sample of oxygen occupies 47.2 liters under a (b) 0.980 g/L
pressure of 1240 torr at 25oC. What volume would it (c) 1.39 g/L
occupy at 25oC if the pressure were decreased to (d) 16.6 g/L
730 torr? (e) 0.695 g/L
(a) 27.8 L 86.
(b) 29.3 L A container with volume 71.9 mL contains water
(c) 32.3 L vapor at a pressure of 10.4 atm and a temperature
(d) 47.8 L of 465oC. How many grams of the gas are in the
(e) 80.2 L container?
80. (a) 0.421 g
A sample of nitrogen occupies 5.50 liters under a (b) 0.183 g
pressure of 900 torr at 25oC. At what temperature (c) 0.129 g
will it occupy 10.0 liters at the same pressure? (d) 0.363 g
(a) 32oC (e) 0.222 g
(b) -109oC 87.
(c) 154oC What is the molecular weight of a pure gaseous
(d) 269oC compound having a density of 4.95 g/L at -35 oC and
(e) 370oC 1020 torr?
81. (a) 24
Under conditions of fixed temperature and amount (b) 11
of gas, Boyle's law requires that (c) 72
 (d) 120 (e) The theory explains most of the observed
(e) 44 behavior of gases at ordinary temperatures and
88. pressures.
A 0.580 g sample of a compound containing only 93.
carbon and hydrogen contains 0.480 g of carbon and A mixture of 0.50 mol H2(g) and 0.50 mol N2(g) is
0.100 g of hydrogen. At STP, 33.6 mL of the gas has a introduced into a 15.0 liter container having a
mass of 0.087 g. What is the molecular (true) pinhole leak at 30oC. After a period of time, which of
formula for the compound? the following is true?
(a) CH3 (a) The partial pressure of H2 exceeds that of N2 in
(b) C2H6 the container.
(c) C2H5 (b) The partial pressure of N2 exceeds that of H2 in
(d) C4H10 the container.
(e) C4H12 (c) The partial pressures of the two gases remain
89. equal.
A mixture of 90.0 grams of CH4 and 10.0 grams of (d) The partial pressures of both gases increase
argon has a pressure of 250 torr under conditions of above their initial values.
constant temperature and volume. The partial (e) The partial pressure of H2 in the container
pressure of CH4 in torr is: increases above the initial value.
(a) 143 94.
(b) 100 If helium effuses through a porous barrier at a rate
(c) 10.7 of 4.0 moles per minute, at what rate (in moles per
(d) 239 minute) would oxygen gas diffuse?
(e) 26.6 (a) 0.20
90. (b) 0.50
What pressure (in atm) would be exerted by a (c) 2.0
mixture of 1.4 g of nitrogen gas and 4.8 g of oxygen (d) 8.0
gas in a 200 mL container at 57oC? (e) 1.41
(a) 4.7 95.
(b) 34 A real gas most closely approaches the behavior of
(c) 47 an ideal gas under conditions of:
(d) 27 (a) high P and low T
(e) 0.030 (b) low P and high T
91. (c) low P and T
A sample of hydrogen gas collected by displacement (d) high P and T
of water occupied 30.0 mL at 24oC on a day when (e) STP
the barometric pressure was 736 torr. What volume 96.
would the hydrogen occupy if it were dry and at Which one of the following statements about the
STP? The vapor pressure of water at 24.0oC is 22.4 following reaction is false?
torr. CH4(g) + 2O2(g) CO2(g) + 2H2O(g)
(a) 32.4 mL (a) Every methane molecule that reacts produces
(b) 21.6 mL two water molecules.
(c) 36.8 mL (b) If 32.0 g of oxygen reacts with excess methane,
(d) 25.9 mL the maximum amount of carbon dioxide produced
(e) 27.6 mL will be 22.0 g.
92. (c) If 11.2 liters of methane react with an excess of
Which one of the following statements is not oxygen, the volume of carbon dioxide produced at
consistent with the kinetic-molecular theory of STP is (44/16)(11.2) liters.
gases? (d) If 16.0 g of methane react with 64.0 g of oxygen,
(a) Individual gas molecules are relatively far apart. the combined masses of the products will be 80.0 g.
(b) The actual volume of the gas molecules (e) If 22.4 liters of methane at STP react with 64.0 g
themselves is very small compared to the volume of oxygen, 22.4 liters of carbon dioxide at STP can be
occupied by the gas at ordinary temperatures and produced.
pressures. 97.
(c) The average kinetic energies of different gases What total gas volume (in liters) at 520oC and 880
are different at the same temperature. torr would result from the decomposition of 33 g of
(d) There is no net gain or loss of the total kinetic potassium bicarbonate according to the equation:
(translational) energy in collisions between gas 2KHCO3(s) K2CO3(s) + CO2(g) + H2O(g)
molecules. (a) 56 L
 (b) 37 L
(c) 10 L
(d) 19 L
(e) 12 L
98.
Calculate the weight of KClO3 that would be required
to produce 29.5 L of oxygen measured at 127oC and
760 torr.
2KClO3(s) 2KCl(s) + 3O2(g)
(a) 7.82 g
(b) 12.2 g
(c) 14.6 g
(d) 24.4 g
(e) 73.5 g
99.
Which of the following statements is false?
(a) The properties of N2(g) will deviate more from
ideality at -100oC than at 100oC.
(b) Van der Waal's equation corrects for the non-
ideality of real gases.
(c) Molecules of CH4(g) at high pressures and low
temperatures have no attractive forces between
each other.
(d) Molecules of an ideal gas are assumed to have no
significant volume.
(e) Real gases do not always obey the ideal gas laws.
100.
The ideal gas law predicts that the molar volume
(volume of one mole) of gas equals:
(a) gRT/PV
(b) (MW)P/RT
(c) 1/2ms-2
(d) RT/P
(e) 22.4 L at any temperature and pressure
101.
Three 1.0 liter flasks are filled with H2, O2 and Ne,
respectively, at STP.
Which of the following statements is true?
(a) Each flask has the same number of gas molecules.
(b) The velocity of the gas molecules is the same in
each flask.
(c) The density of each gas is the same.
(d) There are twice as many O2 and H2 molecules as
Ne atoms.
(e) None of the above is true.
102.
For a gas, which pair of variables are inversely
proportional to each other (if all other conditions
remain constant)?
(a) P, T
(b) P, V
(c) V, T
(d) n, V
(e) n, P
ANSWER KEY 57. D
58. D
1. B 59. A
2. C 60. B
3. A 61. B
4. B 62. C
5. D 63. A
6. D 64. A
7. B 65. B
8. E 66. B
9. A 67. B
10. C 68. E
11. C 69. B
12. A 70. B
13. D 71. C
14. A 72. A
15. E 73. E
16. E 74. E
17. C 75. A
18. A 76. E
19. C 77. B
20. A 78. A
21. E 79. E
22. C 80. D
23. D 81. D
24. C 82. E
25. A 83. B
26. B 84. A
27. E 85. C
28. D 86. E
29. D 87. C
30. D 88. D
31. E 89. D
32. E 90. D
33. A 91. D
34. A 92. C
35. C 93. B
36. E 94. E
37. B 95. B
38. D 96. C
39. C 97. D
40. D 98. E
41. B 99. C
42. C 100. D
43. D 101. A
44. E 102. B
45. C
46. C
47. A
48. D
49. D
50. A
51. C
52. C
53. B
54. A
55. C
56. D