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Egyptian Journal of Petroleum xxx (2017) xxx–xxx

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Fuel analyses and rank determination of the Egyptian Maghara main coal
seam, north central Sinai, Egypt
N.A.A. Edress a,⇑, A.R. Abdel-Fatah b
a
Geology Department, Faculty of Science, Helwan University, Helwan, Cairo, Egypt
b
El-Nasr-Co for Coke and Chemicals Industry, Helwan, Cairo, Egypt

a r t i c l e i n f o a b s t r a c t

Article history: Three geologic sections along the main coal seam (MCS) of the Middle Jurassic (Bathonian) Safa
Received 22 May 2017 Formation of Maghara mine are examined. Samples collected have been studied. The fuel analyses of coal
Revised 11 July 2017 samples were conducted to determine their Rank characteristic. Fuel analysis classified the studied
Accepted 30 July 2017
Maghara MCS as high grade coal, medium rank (D) of para-bituminous class based on its average values
Available online xxxx
of ash content 7.1% (dry-base; d.b), gross calorific value (29 Mj/kg; moist ash free) and random vitrinite
reflectance 0.43%. Synonym nomenclature of the studied Maghara coal based to ASTM classification is
Keywords:
high volatile (C) class of bituminous group with agglomerating character attributed to their values of
Coal
Maghara coal
gross calorific value 30 Mj/kg-(moist-mineral-matter-free; mmmf), fixed carbon 45% (dry-mineral-
Sinai matter-free; dmmf) and volatile matter 54.8% dmmf. Elemental ratio of H/C versus O/C indicate that
Egypt majority of the studied Maghara coal samples occupy the area of vitrinite genesis pathway on Van-
Fuel analyses Krevelen diagram, and within the area of per-hydrous in Seyler chart of dominated anoxic condition.
Rank determination Studied coal seam is a type III kerogen corresponding to humic characteristic, within the immature
and mature zones of coalification.
Ó 2017 Egyptian Petroleum Research Institute. Production and hosting by Elsevier B.V. This is an open
access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

1. Introduction fully synthesis by El Kady et al. [5] from carbon waste of Maghara
coal by using modified chemical and thermal process for wastew-
Coal has been the world’s fastest growing energy source in ater purifies utilization.
recent years, faster than gas, oil, nuclear, hydro and renewable. Varieties of the essential components of coal including carbon,
Coal is one of the world’s most important sources of energy, fuel- hydrogen, nitrogen, sulfur, and other substance play an important
ling almost 40% of electricity worldwide. role for combustion behavior of coal which extremely has no fixed
The Jurassic coal in Sinai Peninsula represents the only out- chemical formula [6]. It is formed from the compression and alter-
cropped coal seam of an economic value. It exposed and extended ation of partly decomposed peat. The transformation of vegetable
underground at the Maghara mine of north central Sinai of esti- material into peat and coal is commonly regarded as proceeding
mated total reserves of 22 million tons of which proved recover- in two steps, called the biochemical and physicochemical stage of
able reserves is 16 million ton [1–3]. coalification, respectively.
Coal has been produced from workings at El Maghara of 0.03 Coalification is always preceded by peatification and may be
million ton/year at the end of the year 2005. For further develop- followed by graphitization [7,8]. Such conditions exist in environ-
ment and determine the optimal uses of coal seam of Maghara, ments for peat accumulation in which transformed plants material
rank and fuel analyses must be well determined. to coal are called mires [9].
The concentration of natural radioactivity in El-Maghara coal The geochemical stage begins with the termination of microbial
mine was studied by Seddeek et al. [4] and they found that low degradation after covering of peat. The principal agents of the geo-
level of theses radioisotopes below quoted values and estimated chemical phase are temperature, pressure, volume and time. The
to be within safe limits. Recently, nano-activated carbon success- temperature is assigned as a crucial factor in coalificanion of coal
seams. The rise of temperature accelerates chemical reactions dur-
ing coalification [8,10,11].
Peer review under responsibility of Egyptian Petroleum Research Institute.
⇑ Corresponding author. The degree of coalification that has taken place determines the
E-mail address: nedress@outlook.com (N.A.A. Edress). rank of the coal. As the processes of coalification continue, there is

http://dx.doi.org/10.1016/j.ejpe.2017.07.012
1110-0621/Ó 2017 Egyptian Petroleum Research Institute. Production and hosting by Elsevier B.V.
This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012
2 N.A.A. Edress, A.R. Abdel-Fatah / Egyptian Journal of Petroleum xxx (2017) xxx–xxx

a progressive transformation of the deposit, the proportion of car- 1.1. Geological setting
bon relative to oxygen rises and volatile substances and water are
driven out. Continued compaction by overburden then converts Maghara region is located in the middle of Sinai Peninsula
lignite into bituminous (or soft) coal and finally into anthracite desert about 250 km northeast of Cairo and 50 km south of Sinai
(or hard) coal [12]. Mediterranean coast as shown in Fig. 1. It is located between lon-
0 0 0
gitude 33° 100 and 33° 40 East and latitude 30° 35 and 30o 50
North. Maghara region is considered a rectangular massive sedi-
mentary basin of about 54 km long and 30 km wide covering an
area of about 1300 km2 with longer axis trending NE-SW direction
[15].

1.2. Stratigraphy

Gebel Maghara coal bearing strata express at Mashaba and


Shusha formations of Lower Jurassic Age, Safa Formation of Middle
Jurassic and Masajid Formation of Upper Jurassic Age [16]. Only
five coal seams were recorded by the Sinai Coal Company in
1994 at Safa Formation, these five seams differ in thickness and
recognized as shown in Fig. 2. The lower part of Safa Formation
includes the economic coal seams of Gebel Maghara, the main
5th coal seams (MCS) of maximum thickness of 135 cm. The MCS
of Safa Formation underlies and overlies by thin black shale beds
ranging in thickness from 10 to 50 cm containing plant remains
in some parts.

1.3. Structure

The middle part of Maghara area is an asymmetric east-


northeast oriented doubly plunging anticline. The direction of anti-
cline is concordant with the Syrian arc structure trend through
NASinai, and its core is dome-like. The NW flank dips about 25°
while SE flank is very steep vertical where it is bounded by a major
Fig. 1. Location map of Maghara area [13,14]. reverse- thrust fault of Jurassic [14].

Fig. 2. A stratigraphic column of formations exposed at Gebel Maghara [17–19].

Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012
N.A.A. Edress, A.R. Abdel-Fatah / Egyptian Journal of Petroleum xxx (2017) xxx–xxx 3

2. Material and methods 3. Results and discussion

2.1. Sampling 3.1. Proximate analysis

Three geologic sections (M1, M2, and M3) were determined The proximate analysis of coal was developed as a convenient
Where M1 Section located at the deepest part of the main shaft and effective means for determining the distribution of products
of the mine with sedimentary cover reaching about 20 m whereas obtained by heating coal under a set of standard conditions to
the M2 and M3 sections are buried by 10 and 5 meters cover, determine the amount of moisture, volatile matter yield, ash yield,
respectively in Fig. 3. The average thickness of the coal seam is and fixed carbon from the coal sample. The variables are measured
1.35 m. Coal samples examined in theses sections were collected in weight percent (wt.%) and are calculated in several different
as channel sample from base to top. bases as shown in Tables 1 and 2.
The total moisture ranged between 0.41 and 4.41% with average
2.2. Analytical methods content (as-received; a.r)1.97% average 1.97%, If the moisture con-
tent in coal beds decreases with the depth of their burial [28]; then
All the coal samples were subjected to a complex of progressive this means(apart from other parameters and also accepting the
analytical methods. Proximate, ultimate and calorific values analy- validity of Hilt’s Law) that the depletion in moisture must simulta-
ses were performed only on selected samples. These were further neously indicate an increasing degree of coalification of the organic
pulverized to 250 mm (100 mesh) where determine according to matter. Average moisture of the three studied coal sections con-
ASTM [20] and ISO standards [21–27]. firms the Hilts law with slightly decrease with depth from 2.4 at
Random vitrinite reflectance was measured on collotelinite of section M3 to 1.5 at section M2. The amount of volatile matter
vitrinite maceral in each sample using a constant of 200 counted (dmmf) of studied coal indicate a broad range from 43.2 to 62%
points under incident monochromatic light, oil immersion objec- with average of 54.8% of medium rank coal, The measured coal
tive and calibration standards [25]. samples show an ash yield (d.b) between 2.09% and 37.8% with
Carbon, hydrogen, nitrogen and sulfur contents of separated average value of 7.1% which are typically of Mesotrophic mire sys-
maceral were determined using Vario Elementar Automatic Ana- tems mainly planar shape and The average mineral matter content
lyzer in Micro Analytical Center (MAC) at Cairo University. (Parr - formula) of 9.74%.

Fig. 3. Geologic map of the Maghara study area after [19].

Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012
4 N.A.A. Edress, A.R. Abdel-Fatah / Egyptian Journal of Petroleum xxx (2017) xxx–xxx

Table 1
The results of the proximate and ultimate analysis of samples of Maghara coal seams (As recived; a. r. and Dry base; d.b.).

section Sample No. As-received basis(a.r),% Dry basis (d.b),%


M Ash V.M F. C Ash V.M F.C C% H% N% Sulfur
Total pyritic Sulfate organic
M1 10 2.03 13.8 49.83 34.38 14.05 50.86 35.1 73.28 5.51 1.21 7.43 3.81 0.89 2.73
9 0.41 2.59 55.73 41.27 2.60 55.96 41.4 73.49 5.67 1.53 4.4 0.41 0.59 3.4
8 0.55 9.63 55.41 34.41 9.68 55.72 34.6 72.71 4.61 1.76 3.84 0.46 1.46 1.92
7 0.6 2.59 55.48 41.33 2.61 55.81 41.6 72.63 4.69 0.44 2.58 1.41 0.35 0.82
6 0.9 3.15 54.33 41.62 3.18 54.82 42.0 73.38 5.79 1.32 3.95 1.94 0.9 1.11
5 2.64 7.72 50.61 39.03 7.93 51.98 40.1 73.59 5.52 1.22 3.6 2.17 0.41 1.02
4 2.48 6.5 48.75 42.27 6.67 49.99 43.3 71.6 5.07 1.01 2.63 0.62 0.78 1.23
3 2.63 5.65 51.38 40.34 5.80 52.77 41.4 71.61 5.15 1.24 3.28 1.4 0.54 1.34
2 2.78 5.4 49.95 41.87 5.55 51.38 43.1 69.79 5.36 0.98 2.44 1.58 0.17 0.69
1 4.41 36.1 39.81 19.65 37.8 41.65 20.6 43.03 5.41 0.85 4.36 2.01 0.72 1.63
M2 8 1.61 7.77 52.68 37.94 7.90 53.54 38.6 70.36 6.36 0.94 6.55 3.36 0.78 2.41
7 2.15 6.65 49.99 41.21 6.80 51.09 42.1 70.21 6.14 1.26 3.93 0.37 0.53 3.03
6 1.24 2.46 54.16 42.14 2.49 54.84 42.7 73.34 6.22 1.12 3.47 0.41 1.32 1.74
5 1.43 2.99 53.03 42.55 3.03 53.8 43.2 68.1 5.74 1.18 3.1 1.69 0.43 0.98
4 2.06 4.48 53.56 39.9 4.57 54.69 40.7 67.31 5.85 0.97 3.62 1.78 0.82 1.02
3 0.92 2.07 51.76 45.25 2.09 52.24 45.7 67.72 5.89 1.04 3.3 1.99 0.38 0.93
2 1.19 6.42 52.26 40.13 6.50 52.89 40.6 67.73 6.06 0.98 2.78 0.66 0.82 1.3
1 1.23 7.29 53.83 37.65 7.38 54.50 38.1 40.11 4.87 1.0 3.72 1.59 0.61 1.52
M3 10 2.29 22 44.6 31.15 22.47 45.65 31.9 57.98 5.44 1.17 5.68 2.91 0.68 2.09
9 2.64 7.32 50.51 39.53 7.52 51.88 40.6 56.98 5.44 0.76 4.1 0.38 0.55 3.17
8 3.09 6.4 52.01 38.5 6.60 53.67 39.7 70.09 6.59 1.11 3.66 0.44 1.39 1.83
7 2.8 2.77 49.47 44.96 2.85 50.90 46.3 70.19 6.71 1.05 2.84 1.55 0.39 0.9
6 2.61 3.46 52.59 41.34 3.55 54.00 42.4 76.14 5.52 1.1 3.3 1.62 0.75 0.93
5 2.34 2.71 52.88 42.07 2.78 54.15 43.1 76.32 5.49 1.0 3.5 2.11 0.4 0.99
4 1.08 2.31 52.58 44.03 2.34 53.15 44.5 69.91 5.52 1.0 3.3 0.78 0.98 1.54
3 2.57 3.96 52.22 41.25 4.06 53.60 42.3 69.83 5.62 1.06 3.0 1.28 0.49 1.23
2 2.58 5.13 52.56 39.73 5.27 53.95 40.8 42.74 4.89 1.24 2.9 1.88 0.20 0.82
1 2.03 5.77 41.93 50.27 5.89 42.80 51.3 41.35 4.17 1.03 4.3 1.98 0.71 1.6
Average 1.97 6.97 51.21 39.85 7.14 52.22 40.6 66.13 5.55 1.09 3.77 1.55 0.67 1.55

Table 2
The results of the proximate and ultimate analysis of samples of Maghara coal seams (dry-ash-free; daf and dry-mineral-matter-free; dmmf basis; moist-mineral-matter-free;
mmmf basis).

Section Sample No. Dry ash free(daf),% Dry mineral matter free (dmmf),% GCV (mmmf)
C% H% N% S (org)% O2 % MM(ParrFormula) C% H% Atomic Ratio F.C% V.M%
H/C O/C C/N
M1 10 85.3 6.41 1.41 3.18 3.75 19.26 90.8 6.82 0.90 0.04 70.5 43.2 56.8 28.46
9 75.5 5.82 1.57 3.49 13.7 5.23 77.5 5.98 0.93 0.13 56.1 43.2 56.8 29.72
8 80.5 5.1 1.95 2.13 10.3 12.57 83.2 5.27 0.76 0.10 48.2 39.2 60.8 31.85
7 74.6 4.82 0.48 0.84 19.3 4.23 75.8 4.90 0.78 0.19 181 43.3 56.7 31.11
6 75.8 5.98 1.36 1.15 15.7 5.61 77.7 6.13 0.95 0.15 65 44.3 55.7 32.16
5 79.9 6.0 1.33 1.11 11.6 10.54 82.3 6.17 0.90 0.11 70.1 45.6 54.4 31.83
4 76.7 5.43 1.08 1.32 15.5 8.65 78.4 5.55 0.85 0.15 82.9 48.3 51.7 30.05
3 76 5.47 1.32 1.42 15.8 8.07 77.9 5.60 0.86 0.16 67.2 45.8 54.2 29.61
2 73.9 5.67 1.04 0.73 18.7 6.00 74.2 5.70 0.92 0.12 82.9 46.8 53.2 30.64
1 69.2 8.7 1.37 2.6 18.2 43.25 75.8 9.53 1.51 0.32 58.9 38.0 62.0 28.46
M2 8 76.3 6.9 1.02 2.61 13.8 12.13 80.1 7.24 1.09 0.14 87.3 43.6 56.4 26.53
7 75.2 6.58 1.35 3.25 13.6 9.5 77.6 6.78 1.05 0.14 65.0 47.0 53.0 30.75
6 75.2 6.38 1.15 1.78 15.5 4.6 76.9 6.52 1.02 0.15 76.3 44.8 55.2 31.34
5 70.2 5.92 1.22 1.01 21.7 4.99 71.7 6.04 1.01 0.23 67.1 45.6 54.4 30.61
4 70.5 6.12 1.02 1.07 21.3 6.93 72.3 6.29 1.04 0.23 80.6 44.2 55.8 31.45
3 69.2 6.01 1.06 0.95 22.8 4.08 70.6 6.14 1.04 0.24 76.1 47.6 52.4 30.98
2 72.4 6.48 1.05 1.39 18.7 8.55 74.1 6.63 1.07 0.19 80.4 44.5 55.5 28.9
1 43.3 5.25 1.08 1.46 48.8 10.02 44.6 5.41 1.46 0.91 46.7 42.3 57.7 30.76
M3 10 74.8 7.02 1.51 2.7 14.0 27.4 79.9 7.49 1.13 0.17 57.8 44.1 55.9 24.7
9 61.6 5.88 0.82 3.43 28.3 10.37 63.6 6.07 1.15 0.35 87.7 46.0 54.0 24.7
8 75.0 7.06 1.19 1.96 14.8 9.15 77.1 7.25 1.13 0.15 73.6 44.6 55.4 29.6
7 72.3 6.91 1.08 0.92 18.8 4.64 73.6 7.04 1.15 0.19 78.0 49.5 50.5 29.0
6 78.9 5.72 1.14 0.96 13.2 5.65 80.7 5.85 0.87 0.13 80.8 45.7 54.3 30.94
5 78.5 5.65 1.03 1.02 13.8 4.92 80.3 5.77 0.86 0.13 88.9 45.9 54.1 32.3
4 71.6 5.65 1.02 1.58 20.2 4.34 73.1 5.77 0.95 0.21 81.9 46.5 53.5 32.1
3 72.8 5.86 1.1 1.28 19.0 6.04 74.3 5.98 0.97 0.19 77.2 45.8 54.2 32.04
2 45.1 5.16 1.31 0.86 47.6 7.28 46.1 5.27 1.37 0.79 40.2 44.8 55.2 29.92
1 43.9 4.43 1.09 1.7 48.8 8.73 45.3 4.57 1.21 0.89 47.0 56.8 43.2 30.67
Average 71.2 6.00 1.18 1.71 19.9 9.74 73.4 6.21 1.033 0.25 74.13 45.2 54.8 30.04

Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012
N.A.A. Edress, A.R. Abdel-Fatah / Egyptian Journal of Petroleum xxx (2017) xxx–xxx 5

Fixed carbon values estimated on (dmmf) range between 38% to be favorable to allow high extraction yield of hydrocarbon dur-
and 56.8% with average value of 45% and fuel ratio with average ing liquefaction process [30].
of 0.7 which rank the study coal within the range of the bituminous In this work the measured nitrogen content of studied coal sam-
coal. ples ranged between 0.48 and 1.95%, daf with average of 1.18%. in
the oxygen content (daf) of the studied samples with average of
19.9%. These moderate values indicate that the studied coal is in
3.2. Ultimate analysis the range of primary stage of maturity.

Carbon and hydrogen occurs in combined form in the complex


3.3. Gross calorific value
organic compounds that make up coal. The measured carbon con-
tent of studied coal samples (dry-ash-free; daf) ranges from 43.3 to
Gross calorific value of the Maghara coal under investigation
85.3%, with average of 71.2%, while hydrogen content (daf) lies
ranges between 24.7 and 32.3 MJ/kg (10617.8–13884.9 Btu/lb)
between 4.43 and 8.7% with average of 6%. The average total sulfur
with average of 30 MJ/kg (12900.5 Btu/lb) on (moist-mineral-
(dry-base; d.b.) of the studied coal is 3.77 wt% with ranging from
matter-free; mmmf) basis considered for rank determination.
2.44 to 7.43 wt%. It is relatively high in comparison to fresh water
peat swamps.
Chou [29] suggested that the sulfur in low-sulfur coals (<1 wt,% 3.4. Rank
S) is mainly of organic origin being derived from the parent plant
debris. However, in medium (1–3 wt% S) and high sulfur coals Rank refers to the degree of coalification (low-grade metamor-
(>3 wt% S). In general, the low sulfur content of the Maghara coal phism) endured by the organic matter. It can be estimated by mea-
(3.77; Table 1) and presence of pyrite (average; 1.55) is believed suring parameters which vary with changes in coal rank such as

Fig. 4. Rank of the Maghara coal seams on the basis of the different rank parameters according to international classification of in-seam coals [32] (right side) and standard
classification of coal by rank [20] on the left side.

Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012
6 N.A.A. Edress, A.R. Abdel-Fatah / Egyptian Journal of Petroleum xxx (2017) xxx–xxx

moisture content, specific energy, vitrinite reflectance, or volatile Consequently, studied Maghara coal correspond to high grade
matter [8,31]. Vitrinite reflectance, gross calorific value, moisture, coal according to ash content (dry-base; d.b.), and medium rank
volatile matter and fixed carbon are used to determination of the coals (D) of para-bituminous class based on gross calorific value
studied coal rank, obtained values of these parameters are assigned (moist-ash-free; maf) and average of vitrinit reflectance
within international classification of in-seam coals [32] and stan- Ro = 0.43% as shown in Fig. 4.
dard classification of coals by rank [20] where the higher rank coals The same equivalent rank nomenclature according to gross
are classified according to fixed carbon on a dry basis, while the calorific value (moist-mineral-matter-free; mmmf), fixed carbon
lower rank coals are classified according to calorific value on moist and volatile matter (dry-mineral-matter-free; dmmf) of ASTM
basis and the agglomerating character is used to differentiate standard show a bituminous rank group of high volatile bitumi-
between certain adjacent [33]. nous (c) class and commonly agglomerating coal. The carbon

Fig. 5. Position of the studied 5th Maghara coal seam samples on the Van-Krevelen Diagram using H/C vs. O/C atomic ratios.

Fig. 6. Position of the studied 5th Maghara coal seam samples on the Kerogen types Diagram of Durand & Monin using H/C vs. O/C atomic ratios.

Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012
N.A.A. Edress, A.R. Abdel-Fatah / Egyptian Journal of Petroleum xxx (2017) xxx–xxx 7

Fig. 7. The studied Maghara coal samples locations on Seyler’s chart.

increases, hydrogen decreases with increasing rank, but not lin- 3.6. Redox potential
early. The main physical changes are those of porosity, density
and hardness [8]. A position in the perhydrous field above the bright coal band
indicates a higher than average H/C ratio, whereas a plot in the
3.5. Elemental ratios subhydrous area below the bright coal band relates to a lower than
average H/C ratio [39]. Plotting the percentages of hydrogen
3.5.1. H/C and O/C atomic ratio against carbon (dry-mineral-matter-free; dmmf) shows that 70%
Based on dmmf basis of the derived atomic ratios of H/C versus of the studied coal samples lies within the area of per-hydrous
O/C, two essential diagrams are used to determine genesis and where these coals containing more hydrogen than the normal per-
degree maturation and coalification of the studied coal seams. centage of intense anoxic condition. 20% only of samples are situ-
Van Krevelen diagram [31], focused on the genetic pathway and ated within the Seyler coal band and the rest of subhydrous type
precursor development of coal components in Fig. 5. H/C atomic coal as shown in Fig. 7.
ratio of studied Maghara coal samples with average of 1.03
whereas the O/C atomic ratio 0.25. Plotting the obtained results 4. Conclusion
show that the majority of the studied coal samples occupy the area
of vitrinite genesis pathway with some tendency to exinite genesis The Sinai coal of El Maghara is highly volatile bituminous (C)
pathway. rank by A.S.T.M. classification which synonym of high grade coal
Kerogen-type diagram established by Durand and Monin [34] of medium rank (D) para-bituminous having agglomerating char-
concentrates on the degree of maturation of kerogen as a precursor acter. It is show waxy and resinous micro constituents of relatively
of petroleum and gas in Fig. 6. Coal samples of Maghara mine lie considerable amounts of hydrogen. The precursor plant materials
within the type III kerogen (low H/C ratio < 1.0, high O/C ratio; forming the studied coal are mainly of vascular plant based on C/
0.2 or 0.3) corresponding to humic characteristic, this kerogen is N ratio. These plants preserved under prehydrous zone of intense
immature to marginally mature. Half of coal samples are localized reducing condition. The coalification pathway of these plants takes
within the immature zone of diagensis stage of maturation and on a vitrinite genesis mainly within immature and mature zones
the transitional area to catagensis zone of maturation. The other within diagenisis and catagensis stages of maturation.
fifty percentage of coal samples present in the mature zone of cata-
genesis, which it lays between temperatures between 50 and Acknowledgments
115 °C [8,35,36].
The authors wish a sincere appreciation to Prof. Dr Khaled
3.5.2. C/N atomic ratio Ahmed Khaled, Geology Department, Faculty of Sciences, Helwan
This ratio is commonly used to detect of the origin of organic University for providing all facilities to achieve this study.
carbon-rich deposits whether it is of algal or land plants origin.
Algal type has atomic C/N ratio lies between 4 and 10 whereas, vas- References
cular land plants has C/N ratio bigger than 20 and up to 160
[37,38]. [1] Global Energy Statistical Yearbook, 2016, https://yearbook.enerdata.net/.
In the present study the atomic ratio C/N of studied coal sam- [2] L. Thomas, Coal geology, 2nd Ed., John Wiley & Sons Ltd, England, 2013, pp. 53–
86 (Chapter 3).
ples ranges between 40 and 181 with average of 75 which clearly [3] World Energy Council, World Energy Resources 2013 Survey, Regency House
corresponds with assumed origin of coal from vascular plants. 14 Warwick Street London W1B 5LT United Kingdom, 2013, p. 34, (Chapter 1).

Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012
8 N.A.A. Edress, A.R. Abdel-Fatah / Egyptian Journal of Petroleum xxx (2017) xxx–xxx

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Please cite this article in press as: N.A.A. Edress, A.R. Abdel-Fatah, Fuel analyses and rank determination of the Egyptian Maghara main coal seam, north
central Sinai, Egypt, Egypt. J. Petrol. (2017), http://dx.doi.org/10.1016/j.ejpe.2017.07.012

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