Lesson 1 – Solid State Time – 61+14 min = 75 min

1. Why the glass is considered to be super cooled liquid ? (1) ……….1 min
2. Why is milkiness in the visibility of glass made of ancient civilization ? (1) ………1 min
3. Explain the anisotropy in crystalline solid by drawing the diagram. (1) ………. 2 min
4. Copper shows conductivity in both solid and fused state whereas copper chloride shows
conductivity only in aqueos solution . Why ? (1) ………2 min
5. What do you mean by parameter of unit cell ? Write the parameters of monoclinic, triclinic ,
rhombohedral unit cell. (4) ……………………4 min
6. Write the parmeters for unit cell of graphite . (1) …………1 min
7. Fill in the blanks . (6) …………4 min
Unit Cell Number of atoms Co-ordination Relation between Packing efficiency
per unit cell number axial length a and
radius r
Face centered
cubic (fcc)
Body centered
cubic(bcc)
Primitive cell /
simple cubic

8 . Write the difference between tetrahedral and octahedral voids. (2)……………4 min
8. Write the coordination number of hcp , ccp , square close packing, hexagonal close packing ,
tetrahedral and octahedral void (3) ………3 min
9. Write the diagram of following (8) …………….20 min
(1) Frnkel defect (2) Schottky defect (3) Impurity defect (4) Metal excess defect due to excess of
cation (5) Metal excess due to anion deficiency (6) n – type semiconductor (7) p –type
semiconductor (8) band theory of conductor , insulator and semiconductor.

10. Write the density formula for cubic unit cell .(1) ……………1 min
11. Which type of stoichiometric and Nonstoichiometric defect is shown by NaCl ?(1)……………1 min
12. Why does ZnO becomes yellow on heating ? (1)………………2 min
13. Why is the color of NaCl crystal yellow ? (1)………………..2 min
14. What is happened when ferromagnetic Fe3O4 is heated at 850 K ? (1)……………1 min
15. What is the effect on pyroelectricity on keeping the temperature of crystal constant? (1) 1 min
16. What is difference between pyroelectricity and thermoelectricity ? (1)………2 min
17. What is fool’s gold ? Give the reason for this .(1) ………….3 min
18. Ferromagnetic substances make permanent magnet .why ? (1) …………2 min
19. By which manner paramagnetism is different from ferromagnetism ? ? (1) …….2 min
20. Give the examples of group 13 – 15 and group 12 – 16 compouds .What is the characterstic
property of these compounds ? (1) ………2 min
 4 . Chemical Kinetics
1. Write 4 differences between molecularity and order of the reaction.(2)
2. Write the units of rate constant of Zero, First and second order reactions. (1.5)
3. What do you mean by pseudo first order reaction ? give example. (2)
4. By which way the second order reaction can be changed into first order reaction. (1)
5. The reactions having more than 3 molecularity are very rare why ?(1)
6. What do you mean by activation energy ? How is it affect the rate of reaction?c(2)
7. Write the required three conditions for effective collision. (1.5)
8. Derive the formula for rate constant and half life period of zero order reaction. (3)
9. Derive the formula for rate constant and half life period of zero order reaction. (3)
10. Explain the effect of catalyst on the rate of reaction by diagram . (2)
11. Explain the effect of temperature on the rate of reaction by Maxwell curve . (2)
12. Which is the best theory of collision theory and transition state theory and why?(2)
13. Write the effect of temperature on the rate of reaction . (2)
14. What is the complex reaction ? By which way the order of this reaction is measured ? (2)
15. How catalyst affect the activation energy of reaction ? (1)
16. Write the relation between half life time t1/2 and initial concentration [R]० for nth order
reaction. (1)
17. Diplay the threshold energy, activation energy and activated complex in the reaction curve . (3)
18 . Draw the following graphs. (5)
(अ ) Between lnK and 1/T for arhenius equation.
(ब) Between the concentration of reactant and time for zero order reaction.
(स) Between rate of reaction and time for zero order reaction.
(द ) Between log ( [R]0 /[R]) and t for first order reaction.
(य ) Between log [R] and t for first order reaction.
19 . Write the equation to determine activation energy if the rate constant is K 1 at temperature T1
and K 2 at T 2 . (1)
20. What is the effect of the catalyst on the rate constant of the reaction ?(1)
21. What order of reaction is the basic hydrolysis of ester and dissociation of N2O . (1)