Let CO2 moles in exhaust stream are x

CO2 already present =13.375

Let CO2 produced = y

CH4 consumed = 12.611

Then

According to given information

13.375  y  x
 x – y  13.375
x
12.611  y 
4
 4  12.611  4 y  x
x  4 y  4  12.611
x – y  13.375
 5 y  4  12.611  13.375
4  12.611  13.375
y
5