calibracion de la curva

ml(SO4=) NTU
0 1.76 curva de calibracion
5 16.2
25
10 36.9
15 71.3
20 f(x) = 0.1923536582x + 1.2609885991
20 101

15

10

0
0 20 40 60 80 100 120

a= 0.1924
b= 1.261
calculo de concentracion de sulfatos

N° NTU SO4=
1 1.36 0.51
2 4.34 16.00
3 4.82 18.50
4 1.8 2.80
5 2.93 8.67
6 1.42 0.83
7 3.89 13.66
8 187 965.38
9 2.9 8.52
10 5.2 20.47
11 6.52 27.33
12 10.4 47.50
13 5.02 19.54

fecha 04/10/19

calibracion e la curva
25

N° ml NTU
20 f(x) = 0.2300977091x + 0.7210797811
R² = 0.9886838366

15
 25

1 0 1.73 20 f(x) = 0.2300977091x + 0.7210797811

2 5 15.7 R² = 0.9886838366

3 10 36.5 15
4 15 61.4
5 20 86.3 10

0
0 10 20 30 40 50 60 70 80

Col umn C Li near (Col umn C)

a= 0.2301
b= 0.7211

N° NTU SO4=
1 114 492.30
107 461.88

tanda N° 1 tanda N°2

N° NTU SO4=(mg/L) N° NTU SO4=

1 38.9 165.9 1 66 283.7
2 41.1 175.5 2 32.6 138.5
3 62.6 268.9 3 40.5 172.9
4 87.7 378.0 4 49.1 210.3
5 32.8 139.4 5 64.9 278.9
6 8.6 34.2 6 44.6 190.7
7 45.6 195.0 7 24.2 102.0
8 136 587.9 8 58 248.9
9 6.22 23.9 9 56.6 242.8
10 3.02 10.0
11 76.7 330.2
12 109 470.6
13 8.01 31.7
acion

80 100 120

10797811
10797811

40 50 60 70 80 90 100

umn C Li near (Col umn C)

tanda N°3

N° NTU SO4=
1 16.7 69.4
2 12.9 52.9
3 5.5 20.8
4 2.35 7.1
5 3.4 11.6
6 3.33 11.3
7 7.67 30.2
8 8.26 32.8
9 8.76 34.9
10 5.01 18.6
11 1.73 4.4
12 4.81 17.8
13 2.69 8.6
14 52.9 226.8
15 14.3 59.0
16 38.7 165.1
17 47.7 204.2
18 164 709.6
19 52.9 226.8
20 2.54 7.9
21 35.4 150.7
22 20.2 84.7
23 1.59 3.8
24 13.3 54.7
25 17.5 72.9
26 9.7 39.0
27 93 401.0
28 16.5 68.6
29 13.3 54.7
30 25.6 108.1
31 41.5 177.2
32 31.3 132.9
33 177 766.1
34 4.96 18.4
35 2.34 7.0
36 2.98 9.8
37 2.26 6.7
38 3.6 12.5
39 3.19 10.7
40 10 40.3
 Preparacion de lolucion valorada de EDTA de 0,01 M

a) preparacion de solución patron de carbonato de calcio(CaCO3)

�_𝐶𝑎𝐶𝑂3=0,3g 0.3 FORMULA

�_𝑠𝑜�= 250 mL =>0,25L 0.25 �_𝑪𝒂𝑪𝑶𝟑=𝒎/(𝑷�∗𝑽(𝑳))
100,09 g/mol
〖��〗 _𝐶𝑎𝐶𝑂3= 100.09

por tanto
�_����� = 0.012 mol/L

�_𝑶^𝑶
concentracion exacta de EDTA

DATOS:
FORMULA
�_𝐶𝑎𝐶𝑂3= 25 mL �_𝑬𝑫𝑻�= 〖 (�∗𝑽) 〗 _𝑪𝒂𝑪𝑶𝟑/𝑽_𝑬𝑫𝑻�
�_𝐶𝑎𝐶𝑂3= 0.012 mol/L
�_(𝐸𝐷𝑇𝐴(𝑔𝑎𝑠𝑡 𝑒𝑛 𝑡𝑖𝑡))= 16 mL

�_𝑬𝑫𝑻�= 0.019

calculos para la dureza total de agua

DATOS:
�_(𝑪𝒂𝑪𝑶𝟑/𝑯𝟐𝑶)= 〖 (�∗�) 〗 _𝑬𝑫𝑻�/𝑽_(𝑯𝟐𝑶(𝒎𝑳))
�_�� 0.019
��=
�_( 〖𝐸𝐷𝑇𝐴 /𝐻2𝑂 〗 _((�𝐿)) ) 6
100.09 �_(���� /�
/�� ���
� �� )= 0.00112 mol/L ==> 112.5
〖�𝑔〗 _(𝐶𝑎𝐶𝑂3
〖��〗 _����3=
〖��〗 _𝐶𝑎𝑂= 56.08
�_𝐻2𝑂= mL 100 para CaO se determina por estequiometria CaCO3 + Δ →CaO +CO2

�_(���� /���
/��
� � 63.0332701
�)=

�_( 〖𝐶𝑎𝐶𝑂 3〗 dureza total∑▒█(𝐝𝐞 𝐥𝐚 @𝐝𝐮𝐫𝐞𝐳𝐚 𝐭𝐨𝐭𝐚𝐥)

�_( 〖𝐸𝐷𝑇𝐴 /𝐻2𝑂 〗 _((�𝐿)) )
item _((�𝑜�/𝐿) ) 〖�𝑔〗 _(𝐶𝑎𝐶𝑂3/𝐿)
〖�𝑔〗 _(𝐶𝑎𝑂/𝐿)
1
2
3
4
5
6
7
 8
9
10
11
12
13
 〖�𝑔〗 _(𝐶𝑎𝐶𝑂3/𝐿)

aCO3 + Δ →CaO +CO2