Ujian Tengah Semester

MA Termodinamika – Program Studi Teknik Kimia, Fakultas Teknik Universitas Indonesia

Selasa, 1 April 2014, Pk. 08.00-10.00
Pengajar: Kamarza Mulia, Ph.D.

Soal pertama (15)

Berikan penjelasan bagaimana CO2 phase equilibrium cell dapat digunakan untuk menentukan titik triple and titik kritis
CO2? Jelaskan menggunakan hukum pertama termodinamika dan diagram P-T untuk CO2 berikut ini.

Soal kedua (20)

An evacuated tank with 1 m3 capacity is initially empty with no fluid inside. Water in the amount of 2 L and at 25C is
transferred into the tank. At midday, thermal equilibrium is assumed to be attained and fluid temperature of 60C is
uniform throughout the tank. At this condition do we find water in the tank as a mixture of liquid and vapor or only as
water vapor?

Soal ketiga (20)

A 20 L portable compressed propane tank is being refilled where some propane gas was initially present at 1 bar and
30.8C. This portable tank was then connected to a large propane storage tank as a source of high pressure propane
gas at 20 bar and 70C. Calculate the mass of propane added into the tank at the end of the filling process if: (a).
Filling was done slowly such that temperature was always constant at 30.8C and the process stopped at the point
where the propane vapor became a saturated vapor; (b). Filling was done up to the point where the propane vapor
became a saturated vapor and the pressure is equal to the pressure in the large storage tank. Use the propane
property table in the attachment. Could you explain why the calculated results are different?

Soal keempat (15)

Steam enters a nozzle at a low velocity so that it can be ignored. The inlet pressure is 23.2x10 3 torr and the inlet
temperature is 371C while the exit pressure is 5.2x10 3 torr and the exit velocity is 488 m/sec. Mass flow rate of the
steam is 181 kg/h. Calculate the exit temperature of the steam in C and the cross sectional area of the nozzle at the
exit in m2.

Soal kelima (10)

Perhatikan diagram z=z(T,p) utk hidrogen berikut ini.
a) Gunakan diagram diatas untuk menjelaskan pada kondisi bagaimana suatu gas dapat diasumsikan bersifat sebagai
gas ideal.
b) Apabila gas memiliki nilai z sama dengan satu pada T dan P tertentu, apakah kita dapat langsung menyimpulkan
bahwa gas tersebut bersifat ideal?
Soal keenam (20)
1 mole of CO is reacted with 25%-excess pure oxygen. If the reactor feed gas temperature is 25C, the conversion is
100%, and the reactor is operated adiabatically, calculate the temperature of the gas coming out of the reactor.
Assume the the ideal gas heat capacities (cp/R) to be constant, 5 for CO2 and 4 for O2.