Safety data sheet

Carbon dioxide, refrigerated liquid.

Creation date : 27.01.2005 Version : 2.0 DE / E SDS No. : 9451
Revision date : 20.12.2010 page 1 / 3

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND P403 Store in a well-ventilated place.

OF THE COMPANY
Product name Precautionary Statement Disposal
Carbon dioxide, refrigerated liquid.
Trade name
Carbon dioxide liquified 3 COMPOSITION/INFORMATION ON INGREDIENTS
EC No (from EINECS): 204-696-9 Substance/Preparation: Substance.
CAS No: 124-38-9 Components/Impurities
Index-Nr. - Carbon dioxide, refrigerated liquid.
Chemical formula CO2 CAS No: 124-38-9
REACH Registration number: Index-Nr.: -
Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH), EC No (from EINECS): 204-696-9
exempted from registration. REACH Registration number:
Known uses Listed in Annex IV/V of Regulation (EC) No 1907/2006 (REACH),
Not known. exempted from registration.
Company identification Contains no other components or impurities which will influence the
Linde AG, Linde Gas Division, Seitnerstraße 70, D-82049 Pullach classification of the product.
E-Mail Address Info@de.linde-gas.com
Emergency phone numbers (24h): 089-7446-0 4 FIRST AID MEASURES
Inhalation
2 HAZARDS IDENTIFICATION In high concentrations may cause asphyxiation. Symptoms may
Classification of the substance or mixture include loss of mobility/consciousness. Victim may not be aware of
asphyxiation. Low concentrations of CO2 cause increased
Classification acc. to Regulation (EC) No 1272/2008/EC respiration and headache. Remove victim to uncontaminated area
(CLP/GHS) wearing self contained breathing apparatus. Keep victim warm and
Press. Gas - Contains refrigerated gas; may cause cryogenic burns rested. Call a doctor. Apply artificial respiration if breathing stopped.
or injury. Skin/eye contact
Immediately flush eyes thoroughly with water for at least 15 minutes.
Classification acc. to Directive 67/548/EEC & 1999/45/EC In case of frostbite spray with water for at least 15 minutes. Apply a
Not classified as hazardous to health. sterile dressing. Obtain medical assistance.
Asphyxiant in high concentrations. Ingestion
Risk advice to man and the environment Ingestion is not considered a potential route of exposure.
Refrigerated liquefied gas. Contact with productmay cause cold
burns or frostbite. 5 FIRE FIGHTING MEASURES
Label Elements Specific hazards
Exposure to fire may cause containers to rupture/explode. Non
- Labelling Pictograms flammable.
Hazardous combustion products
None.
Suitable extinguishing media
All known extinguishants can be used.
Specific methods
If possible, stop flow of product. Move container away or cool with
- Signal word water from a protected position.
Warning Special protective equipment for fire fighters
In confined space use self-contained breathing apparatus.
- Hazard Statements
H281 Contains refrigerated gas; may cause 6 ACCIDENTAL RELEASE MEASURES
cryogenic burns or injury. Personal precautions
EIGA-As Asphyxiant in high concentrations. Evacuate area. Wear self-contained breathing apparatus when
entering area unless atmosphere is proved to be safe. Ensure
- Precautionary Statements adequate air ventilation.
Environmental precautions
Precautionary Statement Prevention Try to stop release. Prevent from entering sewers, basements and
P282 Wear cold insulating gloves/face workpits, or any place where its accumulation can be dangerous.
shield/eye protection. Clean up methods
Ventilate area.
Precautionary Statement Reaction
P336+P315 Thaw frosted parts with lukewarm water. 7 HANDLING AND STORAGE
Do no rub affected area. Get immediate
Handling
medical advice/attention.
Suck back of water into the container must be prevented. Do not
allow backfeed into the container. Use only properly specified
Precautionary Statement Storage

9451 / EDV / 21.11.2010

 Safety data sheet
Carbon dioxide, refrigerated liquid.
Creation date : 27.01.2005 Version : 2.0 DE / E SDS No. : 9451
Revision date : 20.12.2010 page 2 / 3

equipment which is suitable for this product, its supply pressure and 14 TRANSPORT INFORMATION
temperature. Contact your gas supplier if in doubt. Check regularly ADR/RID
tightness of the plant. Refer to supplier's handling instructions. Class 2 Classification Code 3A
Storage UN number and proper shipping name
Secure cylinders to prevent them falling. Keep container below 50°C UN 2187 Carbon dioxide, refrigerated, liquid
in a well ventilated place. Observe "Technische Regeln Druckgase UN 2187 Carbon dioxide, refrigerated, liquid
(TRG) 280 Ziffer 5" Labels 2.2 Hazard number 22
Packing Instruction P203
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure limit value IMDG
Value type value Note Class 2.2
Germany - AGW 5.000 ppm TRGS 900 UN number and proper shipping name
UN 2187 Carbon dioxide, refrigerated, liquid
Personal protection Labels 2.2
Ensure adequate ventilation. Packing Instruction P203
EmS FC; SV
9 PHYSICAL AND CHEMICAL PROPERTIES
General information IATA
Appearance/Colour: Colourless liquid. Class 2.2
UN number and proper shipping name
Important information on environment, health and safety UN 2187 Carbon dioxide, refrigerated, liquid
Molecular weight: 44 g/mol Labels 2.2
Melting point: -56,6 °C Packing Instruction P202
Sublimation point: -78,5 °C Other transport information
Critical temperature: 31 °C Ensure vehicle driver is aware of the potential hazards of the load
Autoignition temperature: Not applicable. and knows what to do in the event of an accident or an emergency.
Flammability range: Not applicable. Ensure adequate ventilation. Avoid transport on vehicles where the
Relative density, gas: 1,52 load space is not separated from the driver's compartment. Before
Relative density, liquid: 0,82 transporting product containers ensure that they are firmly secured.
Solubility mg/l water: 2000 mg/l Ensure compliance with applicable regulations.
Other data
Gas/vapour heavier than air. May accumulate in confined spaces, 15 REGULATORY INFORMATION
particularly at or below ground level.

10 STABILITY AND REACTIVITY Further national regulations

Pressure Vessel Regulation
Stability and reactivity Regulations for the prevention of industrial accidents
Stable under normal conditions. Water pollution class
Not polluting to waters according to VwVwS from 27.07.2005.
11 TOXICOLOGICAL INFORMATION TA-Luft
General Not classified according to TA-Luft.
No known toxicological effects from this product.
16 OTHER INFORMATION
Ensure all national/local regulations are observed. The hazard of
12 ECOLOGICAL INFORMATION asphyxiation is often overlooked and must be stressed during
General operator training. Before using this product in any new process or
When discharged in large quantities may contribute to the experiment, a thorough material compatibility and safety study
greenhouse effect. should be carried out.
Global Warming Potential GWP Advice
1 Whilst proper care has been taken in the preparation of this
document, no liability for injury or damage resulting from its use can
13 DISPOSAL CONSIDERATIONS be accepted. Details given in this document are believed to be
correct at the time of going to press.
General Further information
Do not discharge into any place where its accumulation could be Linde safety advice
dangerous. To atmosphere in a well ventilated place. Discharge to No. 1 Handling of refrigerated liquid gases
atmosphere in large quantities should be avoided. Contact supplier No. 3 Oxygen deficiency
if guidance is required. No. 11 Transport of gas receptacles in vehicles
EWC Nr. 16 05 05 No. 12 Handling of carbon dioxide CO2

End of document

9451 / EDV / 21.11.2010

 Safety data sheet
Carbon dioxide, refrigerated liquid.
Creation date : 27.01.2005 Version : 2.0 DE / E SDS No. : 9451
Revision date : 20.12.2010 page 3 / 3

9451 / EDV / 21.11.2010