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PII: S0920-4105(15)30133-9
DOI: http://dx.doi.org/10.1016/j.petrol.2015.10.005
Reference: PETROL3198
To appear in: Journal of Petroleum Science and Engineering
Received date: 9 August 2013
Revised date: 2 October 2015
Accepted date: 6 October 2015
Cite this article as: M.A. Fernø, Ø. Eide, M. Steinsbø, S.A.W. Langlo, A.
Christophersen, A. Skibenes, T. Ydstebø and A. Graue, Mobility control during
CO2 EOR in fractured Carbonates using foam: Laboratory Evaluation and
numerical simulations, Journal of Petroleum Science and Engineering,
http://dx.doi.org/10.1016/j.petrol.2015.10.005
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Mobility Control during CO2 EOR in Fractured Carbonates Using Foam:
Laboratory Evaluation and Numerical Simulations
Fernø, M. A., Eide, Ø., Steinsbø, M., Langlo, S.A.W., Christophersen, A., Skibenes, A., Ydstebø, T. and Graue, A.
Department of Physics and Technology, University of Bergen, NORWAY
Abstract
Laboratory miscible CO2 and CO2-foam injection tests were performed to study CO2 EOR in fractured
carbonate core plugs and to evaluate the feasibility of using foam for mobility control in fractured
systems. A significant oil recovery was observed during CO2 injections at miscible conditions ranging
between 75 and 92% OOIP in cores with irreducible initial water saturation. In fractured core plugs
viscous displacement was negligible and the recovery was mainly driven by diffusion. Injection of pre-
generated CO2-foam accelerated oil recovery compared to pure CO2 injection in fractured core plugs, by
adding a viscous displacement in addition to diffusion. A conceptual numerical model was built to study
the effect of reduced fracture conductivity on oil recovery efficiency and the impact of system size and
orientation on diffusion dominated oil recovery during CO2 injection in fractured systems.
1. Introduction
It is estimated that more than 60% of the world's oil reserves are stored in carbonate reservoirs,
characterized by large heterogeneities and natural fractures with mixed or oil-wet conditions (Roehl and
Choquette, 1985), thus a large percentage of remaining oil reserves may be found as residual oil in
carbonate reservoirs. Secondary oil recovery in fractured carbonate reservoirs is typically low due to
ineffective water injection (Hirasaki and Zhang, 2004). This makes carbonates good candidates for CO2
enhanced oil recovery (EOR), because CO2 can achieve miscibility with oil at pressures of only 100-300
bar (Skjæveland and Kleppe, 1992).
Injection of CO2 as a technique for EOR has been used for over 40 years (Enick et al., 2012). In the United
States, CO2 EOR currently contributes 280 000 barrels of oil per day, just over 5% of the total U.S. oil
production. CO2 injection for enhanced oil recovery can be an effective way to recover additional oil after
waterfloods or pressure depletion, while at the same time store large quantities of CO2 underground
(Malik and Islan, 2000). The microscopic sweep during CO2 injection is potentially very high as a result of
miscibility between oil and CO2, diffusion and oil swelling. The macroscopic sweep efficiency, however, is
generally low as a result of the high CO2 mobility and low density. This causes fingering, gravity
segregation, and early breakthrough in the production well, resulting in the need to recycle large
quantities of CO2. This is especially challenging in fractured reservoirs, defined here as dual porosity
systems with bulk oil located in low permeability matrix surrounded by a high permeable fracture
network, where the contribution from viscous forces is limited. Here, the main production mechanism is
gravity drainage, with the additional benefit of diffusion and volume expansion of oil, especially near or at
miscible conditions (van Golf-Racht, 1982). Laboratory experiments indicate that miscible
displacement/drainage aided by diffusion in fractured reservoirs can be an efficient production
mechanism (Firoozabadi, 1994), however, it requires close fracture spacing for the rate of diffusion to
significantly contribute to oil recovery (Firoozabadi, 1994; Thompson and Mungan, 1969; Trivedi and
Babadagli, 2008). In most fractured reservoirs gas-oil gravity drainage is a slow process, with early
breakthrough of injected gas and poor CO2 utilization (see e.g. (Grigg and Schechter, 1997; Jonas et al.,
1990)).
The poor macroscopic sweep efficiency associated with the large mobility of the injected CO2 may be
improved with CO2-foam to produce a more favorable mobility ratio to increase sweep, and thereby
improve oil recovery (Talebian et al., 2013). Foam effectively increases the viscosity of the gas phase by
mixing gas and surfactant solution, creating a discontinuous gas phase separated by thin water films
(lamella) stabilized by the surfactant. While there have been several successful foam pilots (see e.g.
(Blaker et al., 2002; Li et al., 2009; Mukherjee et al., 2014; Sanders et al., 2012; Yu et al., 2008), historically
very few foam pilots in fractured reservoirs have been performed, and those few have largely been
deemed unsuccessful (Enick et al., 2012; Smith, 1988). This has been attributed to the lack of foam
generation mechanisms in fractures, namely snap-off, film division and leave-behind. Recent research,
however, confirms in-situ foam generation in single fractures (Buchgraber et al., 2012; Kovscek et al.,
1995), leading to increased sweep (Yan et al., 2006) and flow diversion within a rough-walled carbonate
fracture network during co-injection of surfactant and gas (Fernø et al., 2014). Hence, the reported
unsuccessful foam pilots in fractured reservoirs may be related to operational issues or lack of optimized,
field-specific surfactants (Castanier and Hanssen, 1995; Prieditis and Paulett, 1992), rather than lack of
foam generation mechanisms in fractured reservoirs. With the development of better surfactants
(Buchanan, 1998; Cui et al., 2014; Elhag et al., 2014; Ryoo et al., 2003), the injection of foam in naturally
fractured reservoirs is increasingly recognized as a potential EOR technique in fractured reservoirs
(Farajzadeh et al., 2012; Haugen et al., 2012; Lopera Castro et al., 2009; Panahi, 2004; Pancharoen et al.,
2012; Zuta and Fjelde, 2010). A comprehensive literature review of CO2 mobility control, including foam,
may be found in (Enick et al., 2012).
This work presented in this paper is part of a larger, ongoing, experimental program on CO 2 injection for
EOR in different oil/brine/rock systems at reservoir conditions (see e.g. (Eide et al., 2015a; Fernø et al.,
2014; Steinsbø et al., 2015). Within the experimental program both fractured and whole core samples are
used and several parameters are varied and investigated such as i) different rock types (with a range of
different porosity, permeability and wettability conditions); ii) oil composition (pure mineral oils and
crude oils); iii) temperature and pressure conditions (CO2 is injected both in its liquid and in its
supercritical state and at both miscible and not miscible conditions with the oil phase); iv) different initial
water saturations (secondary and tertiary CO2 injections) and v) EOR efforts such as CO2-foam injection
for mobility control. The objective of the present work is to build on previous results and study CO2 EOR in
fractured limestones to evaluate CO2-foam acceleration on oil recovery efficiency. A conceptual numerical
model was used to reproduce the experimental results by adjusting the fracture hydraulic conductivity
and history match important parameters such as initial water saturation and wettability.
2.2 Fluids
The core plugs were initially saturated with laboratory made synthetic brine or n-Decane. Injected CO2
was in its liquid state and first contact miscible with n-Decane at the experimental conditions 20 °C and 90
bar (Ayirala et al., 2006). Minimum miscibility pressure (MMP) was estimated to 54 bar at 20 °C using
CMG Winprop. CO2 and n-Decane viscosity and density at experimental conditions were found in NIST
Chemistry WebBook (Linstrom and Mallard, 2013), or measured in the laboratory (brine). Fluid
properties and compositions are listed in Table 1.
2
Table 1. Fluid properties and compositions.
Fluid Composition Density [g/ml] Viscosity [cP]
4wt%NaCl,
Synthetic formation brine 3.4wt%CaCl2 1.05 @ 20°C, 1bar 1.09 @ 20°C, 1bar
0.5wt%MgCl
Surfactant solution 1wt% AOS14-16
n-Decane C10H22 0.737 @ 20°C, 90bar 1.01 @ 20°C, 90bar
Decahydronaphthalene C10H18
North Sea Crude oil 0.85 @ 80°C, 1bar 2.7@ 80°C, 1bar
Liquid CO2 >99.99% 0.843 @ 20°C, 90bar 0.0788 @ 20°C, 90bar
Eight core plugs were fractured longitudinally with a band saw and thereafter reassembled with a 1mm
wide polyoxymethylene (POM) spacer to maintain a high permeable, open fracture. The POM spacer
contained separate apertures connected by high conductive flow channels and has been used in several
previous experiments without affecting fluid flow (Eide et al., 2015). The procedure to prepare a fractured
core plug with a POM spacer is shown in Figure 1: (A) The core plug was fractured longitudinally. (B) A
POM spacer was placed in the fracture. (C-E) The fractured core plug was reassembled and wrapped in
aluminum foil. (F-H) Inlet and outlet end pieces were also wrapped in aluminum foil. Before CO 2 injection
tests all core plugs were wrapped in aluminum foil to reduce exposure of CO 2 towards the rubber sleeve
inside the core holder. The core plugs were placed in a core holder and net confinement pressure of
approximately 15bar was kept constant during all injections. The fractured core plugs were initially
flooded with oil to fill the vertical oriented fracture before system permeability after fracturing (KFRAC)
was measured during different constant oil flow rates at S wi. Basic core properties, permeabilities and
wetting conditions are listed in Table 2.
3
Figure 1. The preparatory procedure prior to CO2 injections in fractured core plugs.
4
3. Numerical Model
A single porosity model was used to match the experimental CO 2 injections in fractured, partially oil- and
brine-saturated cylindrical Edwards limestone core plugs. A single semicylinder (Cartesian grid
34x21x12) was used due to system symmetry and to reduce simulation time (see Fig 2). This approach
was previously verified to accurately reproduce the oil recovery process by CO 2-oil diffusion in similar
systems [Eide et al., 2015]. Injection and production wells were placed in transverse fractures at the inlet
and outlet end face, connected with a longitudinal fracture. Longitudinal fracture dimensions were equal
to the experimental core plug fracture properties (normally L = 70mm, H = 50mm, W = 1mm). The two
transverse fractures at the inlet and outlet had the same height and width. All fractures were modeled
explicitly with linear relative permeability and no capillary pressure. Experimentally measured porosity,
permeability and fluid saturations was used as input in all matrix cells. A no-flow boundary was placed at
the curved circumference of the semicylinder. In whole core plug simulations the longitudinal fracture
was changed to a no-flow boundary. Oil and CO2 was modeled as a single phase, because phases were first-
contact-miscible at experimental condition, with molecular diffusion within the oil phase active in the
simulations. Diffusion of CO2 into the water phase was negligible at experimental conditions, and set to
zero. During CO2 injections in fractured systems (see Fig 2), all fractures were initially CO2-filled, and the
matrix was filled with oil. The exchange of fluids from the CO2 in the fractures and oil in the matrix
occurred by diffusion to produce that majority of the oil. The presence of initial water saturation affected
CO2-oil diffusion through water-shielding effects, modeled by increasing the effective diffusion length i.e.
increasing the tortuosity. In the model tortuosity is the ratio of the true path length traveled by a molecule
flowing through the medium to the macroscopic distance traveled, and increasing initial water saturation
was reflected by increasing the tortuosity.
Figure 2. The numerical CMG GEM single porosity model with three CO2-filled fractures (blue) adjacent to
an oil-filled rock matrix (red) constituting a fractured, semicylinder core plug. Flow was predominantly
through a longitudinal fracture connecting the inlet and outlet, and oil was produced by diffusion. Over
time, the oil saturation decrease symmetrically.
Simulation of foam injection is an active research area and a comprehensive literature survey may be
found in (Ma et al., 2013). The injection of foam in a fractured system is not yet established as a viable EOR
method, although recent results are promising (Farajzadeh et al., 2012; Fernø et al., 2014). One of the
main benefits of injecting foam for EOR is the increased apparent viscosity of injected gas phase. We do
not attempt to model foam flow in fractured systems explicitly here, but rather conceptually represent
foam flow as reduced fracture hydraulic conductivity. While not a comprehensive foam simulation, this
approach describes mobility reduction in the fracture only, without affecting the flow properties of the
matrix. This is consistent with previous experimental observations, which indicated that foam was
destroyed in the matrix due to the high oil saturation (Haugen et al., 2012). When the numerical model
reproduced the experimental results with changes in studied parameters (presence of fractures, initial
water saturation and wettability conditions), the validated model was used to investigate the influence of
system size and orientation, parameters that could not be studied experimentally.
5
4. Results and Discussion
Fourteen experimental secondary CO2 injection tests were performed in Edwards limestone core plugs,
studying the effect fracture permeability, variations in initial water saturation, the wettability preference
and injection scheme. Initial state before CO2 injection and injection scheme for the core plugs are listed in
Table 3. Measured oil production versus time for selected core plugs may be found in Table A.1 in the
Appendices.
Six CO2 foam injection test were performed to evaluate foam injections in fractured systems to increase
and accelerated oil production rate. A more efficient oil recovery was observed during CO2-foam
compared to CO2 injections: after 1PV injected RF=45%OOIP and after 2PV injected RF= 69% OOIP, on
average. Final oil recovery varied slightly in core plugs with similar test conditions, but the rock material
was heterogeneous with large variation in pore size distribution and high permeable zones.. The core ID,
fracture state, initial water saturation and wetting condition are listed for each test and also the CO 2
injection scheme. Figure 3 shows the accelerated oil recovery rate during CO2 foam injections in
fractured core plugs (black)compared to pure CO2 injections in fractured core plugs (grey).
6
1.0
0.9
0.8
L17 Whole Swi=0 SWW
Recovery factor [fraction OOIP]
0.0
0 1 2 3 4 5 6 7 8
Pore Volume Injected
Figure 3. Development in oil recovery during CO2 injection versus PV injected in all experimental core
plugs.
7
1.0
0.9
0.8
Recovery factor [fraction OOIP]
0.7
0.6
0.3
0.2
0.1
0.0
0.0 0.5 1.0 1.5 2.0
Time [day]
Figure 4. Development in oil recovery during CO2 injection versus time for whole (core plug L17) and
fractured (core plug L22) limestone core plugs as well as numerical simulations. The presence of a
fracture reduced the oil recovery rate and the final oil recovery.
8
1.0
0.9
0.8
Recovery factor [fraction OOIP]
0.1
0.0
0.0 0.5 1.0 1.5 2.0
Time [day]
Figure 5. Development in oil recovery during CO2 injection in whole core plugs (core plugs L17 and L9)
and fractured core plugs (core plug L22 and L23). A consistent shift to lower oil recovery with the
presence of an irreducible water phase present in the pore space for fractured core plugs was observed.
9
L33 Whole Swi=0.29 SWW FOAM L14 Whole Swi=0.34 OW FOAM E33 Frac Swi=0.19 SWW FOAM
E6 Frac Swi=0.19 OW FOAM L9 Whole Swi=0.23 SWW L23 Frac Swi=0.23 SWW
L33 dP E33 dP E6 dP
1.0 500
0.9 450
0.8 400
Recovery factor [fraction OOIP]
0.6 300
0.5 250
0.4 200
0.3 150
0.2 100
0.1 50
0.0 0
0 1 2 3 4 5
Pore Volume Injected
Figure 6. Development in oil recovery during CO2-foam injection in whole and fractured water-wet and
oil-wet cores. Differential pressure during foam floods is included.
The beneficial oil production acceleration effect of foam in fractured samples was not affect by matrix
wettability (see Figure 6) and may be explained with a change in fracture surface wettability by the
injected surfactant in oil-wet systems towards more water-wet conditions (Sanchez and Hazlett, 1992).
Stable foam creates a viscous pressure drop that forces the CO2 into the matrix, displacing, swelling and
mobilizing the oil (Farajzadeh et al., 2010; Rossen, 1995). The small size of the fractured core plug
systems exaggerates the rate of diffusion compared to reservoir scale. In larger systems where diffusion is
less dominate, the added viscous forces during foam injections are expected to contribute more to oil
recovery and also at an earlier stage as oil saturation close to the fracture will decrease below the critical
oil saturationvalue relatively faster in a large matrix block compared to a small matrix block.
10
1.0
0.9
0.8
Sim 20 mD
Recovery factor [fraction OOIP]
Sim 50 mD
0.7
Sim 500 mD
Sim 10000 mD
0.6
Sim 25000 mD
L17 Whole Swi=0 SWW
0.5
L33 Whole Swi=0.29 SWW FOAM
0.0
0.0 0.5 1.0 1.5 2.0
Time [day]
Figure 7. A reduction of fracture conductivity increased the oil recovery rate by increasing the transport
of CO2 from the fracture to the matrix.
11
1.0
0.9
0.8
Recovery factor [fraction OOIP]
0.7
0.6
0.5
0.4
Whole, Horizontal
Whole, Horizontal, No diffusion
0.3
Fractured, Vertical
Fractured, Vertical, No diffusion
0.2
Fractured, Horizontal
Fractured, Horizontal, No diffusion
0.1
0.0
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0
Time [day]
Figure 8. Development in oil recovery during CO2 injection in a numerical model with experimental size.
In experimental size systems diffusion was the dominating recovery mechanism.
Figure 9 shows development in oil recovery versus time for a whole system (with and without diffusion)
and a fractured system (with and without diffusion and with vertical and horizontal orientation) in a
system, which was one order of magnitude larger (L = 1.0 m) compared with the experimental core plug
size (L = 0.1 m). In the larger size system final oil recovery was similar to final oil recovery in smaller size
systems, but the recovery efficiency was much slower in terms of time. In the experimental size systems
final oil recovery in whole systems was reached after 1 day and after 17 days (in one order of magnitude)
larger size systems. As for the experimental sized system, the effect of diffusion in whole systems was
small, but also the fractured systems was less affected by deactivating the diffusion compared with the
experimental size system. In the larger fractured systems, the gravity effects was much more prominent:
the gravity stable vertical injections was much more efficient compared to horizontal injections,
regardless if diffusion was activated or not. The same trends, in terms of oil recovery efficiency, was
observed in system size even one order of magnitude larger (L=10.0 m, not shown). The importance of
gravity and system orientation increased, while the importance of diffusion decreased, with increasing
matrix size.
12
1.0
0.9
0.8
Recovery factor [fraction OOIP]
0.7
0.6
0.5
0.4
Whole, Horizontal
Whole, Horizontal, No diffusion
0.3
Fractured, Vertical
Fractured, Vertical, No diffusion
0.2
Fractured, Horizontal
0.0
0 10 20 30 40 50 60 70 80
Time [day]
Figure 9. Development in oil recovery during CO2 injection in a numerical model with one order of
magnitude larger size compared to experimental size core plugs. The importance of diffusion decreased
and gravity and system orientation increased, with increasing system size.
5. Conclusion
Laboratory CO2 and CO2-foam injection tests were performed to study CO2 EOR in fractured carbonate
core plugs and to evaluate the feasibility of using foam for mobility control in fractured systems. A
conceptual numerical model was built to study the effect of reduced fracture conductivity on oil recovery
efficiency and the impact of system size and orientation on diffusion dominated oil recovery during CO 2
injection in fractured systems. With this approach we have the following key observations:
1. Fractures significantly reduced the rate of oil recovery during pure CO2 injection and the injected
CO2 mainly flowed in the fracture. Oil recovery during CO2-injection in fractured core plugs was
mainly driven by molecular diffusion, with negligible viscous displacement driving CO2 from the
fracture to the matrix. The relative effect of diffusion was exaggerated in small core plugs, and oil
production rate decreased with increasing system size or increased fracture permeability.
2. Foam significantly increased the oil recovery rate compared to pure CO2 injection by adding a
viscous component to the oil recovery process. The increased pressure gradients measured
experimentally was a result of the decreased CO2 mobility by increasing the apparent CO2
viscosity with foam. Six CO2 foam injection tests all showed an accelerated oil recovery rate
compared to pure CO2 injections, with increased differential pressure across the core due to
reduced fracture conductivity. Foam flow was mainly in the fracture and not affected by initial
matrix wettability. Foam was not stable in the matrix with high oil saturation, due to the
combined effect of lamella destruction by oil and surfactant adsorption.
13
Acknowledgement
The authors are indebted to the Norwegian Research Council for financial support under Petromaks
project 200538 “Integrated Enhanced Oil Recovery in Fractured and Heterogeneous Reservoirs”. Statoil, BP
and ConocoPhillips are also thanked for their financial contribution.
Appendices
Table A.1 Oil production versus time for selected core plugs.
Core L9 L14 L17 L22 L23 E6 E33
Time [h] Recovery factor [fraction OOIP]
1 0.169 0.088 0.022 0.006 0.020 - 0.052
2 0.316 0.195 0.137 0.071 0.068 0.059 0.091
4 0.502 0.387 0.306 0.160 0.144 0.164 0.170
6 0.634 0.557 0.444 0.232 0.208 0.269 0.250
8 0.742 0.727 0.574 0.300 0.260 0.373 0.329
10 0.808 0.812 0.684 0.366 0.308 0.447 0.448
12 0.839 0.898 0.772 0.421 0.348 0.504
14 0.866 0.919 0.835 0.460 0.381 0.557
16 0.882 0.919 0.874 0.496 0.417
18 0.890 - 0.902 0.529 0.606
20 0.893 0.962 0.923 0.558 0.469 0.656
22 0.897 - 0.944 0.575 0.699
24 0.897 0.962 0.970 0.601
26 0.901 - 0.988 0.630 0.549 0.793
28 0.901 0.996 0.653 0.814
30 0.905 0.962 0.996 0.670 0.835 0.725
31 0.905 0.996 0.676 0.845
32 0.905 0.996 0.686 0.629 0.745
33 0.905 0.996 0.696 0.866
34 0.905 0.983 0.996 0.706 0.765
35 0.905 0.996 0.715 0.877
40 0.905 0.996 0.761 0.775
42 0.905 0.996 0.774 0.669 0.908
44 0.996 0.787 0.784
47 0.810
48 0.908
50 0.830
51
52 0.840
59 0.710
62 0.784
65 0.730
70 0.898
75 0.750
76
82 0.921
14
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HIGHLIGHTS
Laboratory CO2 injections in fractured carbonate cores produced on average 90%OOIP.
CO2 foam effectively accelerated oil recovery in fractured systems.
Increased apparent CO2 viscosity with foam reduced fracture conductivity.
A conceptual numerical model was built to match experimental results.
The numerical model was used to investigate fracture conductivity.
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