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High-Strength
Steels New Types
on the Block
The world’s steel companies
have worked with customers
to create new alloys with
mechanical properties and
performance characteristics ome 40 years ago, the steel industry embarked on intensive research and devel-

that just a decade or two ago


would have seemed
S opment that produced a controlled rolling process that, combined with micro-
alloying, resulted in major breakthroughs in steel properties. Steels with small
amounts of aluminum, niobium, vanadium or titanium rolled at 880 C rather than
the conventional 1050 C resulted in high-strength low-alloy (HSLA) steels with ten-
improbable, if not downright sile strengths in the 350- to 650-MPa range, combined with good toughness. Next
came development of a process called CalSil treatment, by which the addition of sil-
impossible to achieve. Here’s icon and calcium to steels reduced sulphur content, bringing improved formabil-
a roundup of some of those ity both along and across the direction of rolling.
The next major breakthrough in steelmaking came in the mid-’90s when steel sup-
alloys. pliers further refined thermalmechanical processing, built new equipment such as
continuous-annealing lines, and began producing today’s advanced high-strength
steels (AHSS), with tensile strengths in the range of 440 to 980, with some steels now
BY BRAD F. KUVIN, EDITOR
offering 1400-MPa tensile strength. Within the next few years, industry analysts pre-
dict that as much as half of the steels in automobiles will be AHSS.
As AHSS products have begun to make a strong presence in the market, the

28 METALFORMING / FEBRUARY 2008 www.metalformingmagazine.com


amount of information on them—their As with other DP steels, Docol DP a minimum bending radius (for press
characteristics and properties, and tips types offer good formability, and at forming) of 1.5 times sheet thickness.
for forming and fabricating them—also more extreme levels of forming SSAB SSAB stresses that these minimum
has increased. For example, the Inter- recommends forming in the direction bending radii are valid for bending
national Iron and Steel Institute now transverse to the rolling direction rather processes and that in well-designed roll-
offers a publication titled Advanced than in the longitudinal direction. Also, forming lines fabricators might achieve
High Strength Steel Application Guide- when shearing or punching Docol DP, much smaller radii.
lines, available on its website, cutting clearance is of primary con- The firm expects major break-
www.worldautosteel.org. The publica- cern, says SSAB. It recommends a cut- throughs in applications for Docol Roll
tion, updated in September 2006, is a ting clearance of 10 to 12 percent of in automotive body and safety compo-
must reference for any company work- sheet thickness for Docol DP steels. nents. www.ssab.com
ing with AHSS. It describes the different SSAB also recently introduced AHSS
types of AHSS—dual-phase (DP), types for rollformers: Docol Roll, a pair U.S. Steel Talks Stamping,
transformation-induced plasticity of cold-reduced high-strength steels Hydroforming
(TRIP), complex-phase (CP), marten- that SSAB claims represent the world’s U.S. Steel Corp., stressing that it
sitic (MS), ferrite-bainitic (FB), twin- first AHSS alloys developed specifically develops new steels in partnership with
ning-induced plasticity (TWIP), hot for rollforming. Their primary benefi- its automotive-industry customers, has
formed (HF) and post-formed heat- cial mechanical property: a high ratio of had its AHSS grades in production vehi-
treatable (PFHT). yield strength to tensile strength, which cles since 1999. It offers hot-rolled dual-
Also a must for your library is the means that stresses in highly formed phase steels under the brand name
new Surface Vehicle Recommended areas of a rollformed part are compa- Dual-Ten, with products available as
Practice SAE J2745 document (see the rable to the stresses in less-formed hot-dip galvanized (HDG Dual-Ten)
sidebar to this article, page 32) issued in regions. Small differences in residual and hot-dip galvannealed (HDGA
July 2007 that categorizes and provides stresses over the entire part cross-section Dual-Ten).
the properties of AHSS automotive reduce the tendency for bending and The Dual-Ten line, introduced in
sheet steels. The recommended practice twisting, resulting in dimensionally sta- 2001 with the development of Dual-
covers 13 cold-rolled AHSS types (six ble and flat profiles. Ten 590 (590-MPa tensile strength),
DP alloys, three TRIP steels and four MS Another bonus with these steels, now comprises four alloys, with tensile
steels) and seven more hot-rolled sheet according to SSAB, is their high level of strengths from 590 to 980 MPa, the lat-
steels. internal cleanliness—a minimal amount est to hit the market being Dual-Ten
We contacted several of the world’s of slag inclusions in the steel allow the 980. Their high tensile-to-yield strength
steelmakers (in cooperation with the rollforming of very tight radii. Docol ratio (1.7 to 1.8 typically) enables the
International Iron and Steel Institute, Roll 800 (800-MPa minimum tensile steels to undergo rapid strain hardening
www.worldautosteel.org) to find out strength and 600-MPa minimum yield at lower strain levels, says U.S. Steel.
what AHSS steels they have recently strength) has a minimum bending This high strain-hardening behavior
developed and made available to the radius (for press forming) of 0.9 times enhances strain distribution during
market. What follows are brief descrip- sheet thickness; Docol Roll 1000 (1000- stamping and, during hydroforming,
tions; additional information can be MPa minimum tensile strength and limits buckling during end feeding. In
found on each company’s website. 850-MPa minimum yield strength) has comparison tests of Dual-Ten 600/590

New Swedish Steels Strain versus n-Value for U.S. Steel’s Dual-Phase AHSS Alloys
Include Rollforming Alloys
Swedish steelmaker SSAB offers a 0.30
Instantaneous n-value

full lineup of dual-phase AHSS types


under its Docol brand name. Its six 0.20
Docol DP steels available for the U.S.
market have minimum tensile strength 0.10
to 145 ksi (1000 MPa). These cold-
rolled dual-phase steels find global auto- 0.00
motive applications in door beams, 0.00 0.05 0.10 0.15 0.20
bumper reinforcements and seat tracks. True Strain
SSAB offers the steels in sheet thick- HSLA 340 Dual-Ten 600/590 Dual-Ten 500 Dual-Ten 780
nesses of 0.5 to 2.0 mm in widths from Dual-phase steels such as the Dual-Ten family from U.S. Steel, illustrated here,
800 to 1500 mm, depending on steel exhibit superior initial strain-hardening behavior when compared to high-strength
grade and thickness. low-alloy (HSLA) steels.

www.metalformingmagazine.com METALFORMING / FEBRUARY 2008 29


Advanced High-Strength Steels

and HSLA 340, the dual-phase steel Phase 780, NuPhase 800 (offered in 1500 offers a tensile strength to 1500
exhibited nearly a 20-percent increase in thicknesses of 0.8 to 2.0 mm) has a MPA. The firm recommends Usibor
draw-depth capability (using a T-chan- slightly different microstructure, says a 1500 as a replacement for many auto-
nel test). www.uss.com Nucor official. It’s recommended for motive components currently formed of
applications where other AHSS of dual-phase steels, including front- and
Nucor Increasing its Capacity comparable strength would not pro- rear-end rail extensions, A-, B- and
to Supply Galvanized AHSS vide adequate formability. Its mechan- hinge pillars and B-pillar reinforce-
Nucor entered the AHSS arena in ical properties: 800 to 980 MPa tensile ments, and door and bumper beams. It’s
2006 with the introduction of DP 590— strength; 680 to 850 MPa yield offered cold- or hot-rolled, and joins the
hot- and cold-rolled, galvanized and strength; 10 percent elongation. firm’s long list of AHSS steels, including
galvannealed products (the firm does www.nucor.com multiphase alloys (ferrite plus bainite
not produce an uncoated cold-rolled plus pearlite, with maximum 0.15 C) to
dual-phase steel). ArcelorMittal Creates 1200-MPa tensile strength, dual-phase
Nucor’s Dual Phase 590 is produced New R & D Entity steels, and TRIP steels to 980 MPa. In
at its CSP (compact strip production) When Arcelor and Mittal merged fact, just entering the testing phase late
facility in Berkeley, SC, in hot-rolled several months ago, the company quick- in 2007 was the firm’s newest TRIP
form from 2.5 to 6.5 mm thick, and ly formed its Automotive Worldwide steel, TRIP-Dual 1200, an advanced
cold-rolled hot-dip galvanized or gal- Business Unit, marrying the firm’s two ultra-high-strength bainitic steel.
vannealed sheet from 0.8 to 2.0 mm research and development groups. The Also, last spring ArcelorMittal, at a
thick. Compared to other DP590 grades new unit, stocked with more than 400 pair of European automotive confer-
available, Nucor officials claim that its engineers and technicians devoted to ences, reported results of its MARS
process yields improved mechanical automotive-related R & D projects, aims (mass-saving approach to rear suspen-
properties—elongation, formability, to develop breakthrough steel products sion) project, led by its automotive-
impact toughness and weldability to with quick speed to market, in addition applications research center in France,
name a few. For example, its hot-rolled to offer technical support. to study the impact of ultra-high-
DP 590 offers an impact energy of 100 New from ArcelorMittal Automo- strength steels in multi-link rear-sus-
ft.-lb., reportedly more than twice that tive is the press-hardened boron steel pension systems. Replacing high-
of other DP 590 steels the company has Usibor 1500 (maximum 0.25 C, 0.35 Si, strength and very-high-strength steels
tested. Dual Phase 590 has a tensile 1.4 Mn, 0.30 Cr and 0.005o B. Similar to with the firm’s multiphase steels
strength of 620 MPa, yield strength of SSAB’s Docol Boron 2/Domex 024 B (MP800 and MP800 HY), as well as a
380 MPa, total elongation of 25 percent and Boron 04/Domex 044 B, Usibor dual-phase steel (DP 980 HY, 675 MPa
and an n-value of 0.168.
Building on its success with Dual
Phase 590, Nucor recently launched
Dual Phase 780 (780 MPa minimum
tensile strength), also available hot- or
cold-rolled, galvanized or galvannealed.
Although the company can only pro-
duce hot-rolled dual-phase steels down
to 2.5 mm thick, it’s pursuing continu-
ous improvement at its mills so that it
will soon be able to produce lighter-
gauge hot-rolled products. And, later
this year Nucor will commission a new
galvanizing line at its facility in Decatur,
AL, to increase production capacity for
galvanized and galvannealed Dual Phase
590 and 780 in a variety of gauges and
widths.
Lastly, in its effort to provide metal-
formers with dual-phase steels with
optimum formability, specifically for
stretch-flange applications, Nucor
recently introduced NuPhase 800 steels. This ArcelorMittal cold-rolling mill in Brazil reduces the thickness of flat steel
A multi-phase steel similar to Dual products by rolling at room temperature.

30 METALFORMING / FEBRUARY 2008 www.metalformingmagazine.com


Advanced High-Strength Steels

yield strength, 1010 MPa tensile Japanese-Made Alloy High hole-expanding ratio (HER)—
strength), sliced the weight of the axle by Offers Improved this DP steel combines elongation and
21 percent, with a negligible cost Stretch-Flange Formability stretch-flange formability and has a
increase. www.arcelormittal.com Japan’s JFE Steel Corp. has offered medium yield point, medium elonga-
dual-phase cold-rolled advanced-high- tion and medium HER, recommended
strength sheet steels in the 780 to 1470- for bumper reinforcements, seat frames
SAE Publishes MPa tensile-strength range for several and seat rails.
years, offering good press formability, Extra-high HER—this steel has a
AHSS Sheet Steel spot weldability and stable mechanical high yield point, low elongation and
Specification properties, to improve vehicle crashwor- high HER, offering stretch-flange
Surface Vehicle Recommended thiness and fuel efficiency. In 2004 the formability equal to that of the 590-
Practice, document SAE J2745, issued last firm introduced a type with 980-MPa MPa-tensile-strength material. JFE says
July, categorizes and provides mechanical
properties of advanced high-strength auto-
tensile strength, in three variations, that that the steel allows designers to reduce
motive sheet steels. It incorporates dual- reportedly offers improved elongation the weight of seat frames while also
phase, martensitic types and TRIP steels. and stretch-flange formability, due to reducing part-manufacturing costs by
better control of microscopic-crack eliminating the welding of multiple
AHSS Grades—Cold-Rolled propagation during forming. parts. www.jfe-steel.co.jp/en
Min. tensile Min. yield JFE manufactures AHSS steels using
strength, MPa strength, MPa its continuous annealing process with Germans Develop
Dual-phase water quenching (it refers to the process Air-Hardening Steels
440 250 as CAL-WQ). The steels, particularly Salzgitter, Germany, is home to
490 290 the 980 type, have found wide acceptance Salzgitter Flachstahl, the largest steel
590 340
690 550 in seat-frame parts, to allow designers of subsidiary in the Salzgitter Group. In
780 420 seat structures to use the seat itself to 2006, the plant’s 4500 employees pro-
980 550 support impact during collisions. duced some 4.6 million tons of steel.
TRIP steels The JFE line of AHSS steels features The mill works closely with the firm’s
590 380 five products, with tensile strengths of technical customer-support partner,
690 400
780 420 780, 980, 1180, 1370 and 1470 MPa, Salzgitter Mannesmann Forschung, to
Martensitic steels with yield strengths from 430 to 1200 develop target-oriented solutions for
900 700 MPa and a carbon equivalent from 0.09 product and process optimization in
1100 860 to 0.23. The three new 980 types: cooperation with users and customers.
1300 1030 Low yield ratio—a high-ductility This close cooperation, according to
1500 1200
DP steel for stretch-formed parts that company officials, yields customer-ori-
features a low yield point, high elonga- ented and application-related product
AHSS Grades—Hot-Rolled tion and low hole-expanding ratio, rec- development.
Min. tensile Min. yield
strength, MPa strength, MPa ommended for body-in-white struc- An example of this comes with
Dual-phase
tural components such as pillars. Salzgitter’s recent release of two new
590 300
780 380
TRIP steels
590 400
780 450
HHE grades (high hole-expansion—
excellent edge-stretching behavior)
440 310
590 440
780 600

Anyone forming advanced high-


strength steels should consider ordering
a copy of this new SAE specification. In
addition to yield and tensile strengths, it
also specifies total elongation and n-val-
ues (where applicable). To order, log on
to www.sae.org, or e-mail customerser-
vice@sae.org.

32 METALFORMING / FEBRUARY 2008 www.metalformingmagazine.com


High-Strength Steels

This tunnel is stamped from Salzgit-


ter’s HCT600XD+Z alloy, a continu-
ously hot-dipped dual-phase steel.

air-hardening cold-strip steels—LH800


and LH900. While dual-phase steels
have their final mechanical properties
already in the as-delivered state, with lit-
tle change from processing, air-hard-
ening steels are delivered to the metal-
former in a soft state with excellent
formability, according to Salzgitter.
While AH steels have been around
for some time available only as long
products such as bar and wire, due to
high carbon content (1 percent or so),
the new breed of AH steels now have
low carbon content and a low carbon
equivalent, allowing manufacturers to
offer them in sheet products with good
formability and weldability. They then
attain final high-strength values during
forming and subsequent processing.
This gives stampers the ability to com-
bine good forming (deep-draw) prop-
erties with high strength in the final
component.
Material datasheets released on
LH800 and LH900 in November 2006
describe the steels as having outstand-
ing forming capabilities, and finished
components having high strength and
crash properties. Tensile strength of the
steels is at least 800 or 900 MPa (116 to
130 ksi).
Air-hardening steels fall under the
product category of post-forming heat-
treatable (PFHT) steels. Metalformers
deep-draw or otherwise form the steels,
then the parts are heattreated and hard-
ened or tempered by natural cooling.
Hydroformers—the alloys are readily
available as tubes and are very formable
—need not employ intermediate anneal-
ing when forming LH800 and LH900.
Salzgitter recommends its new PFHT steels

34 METALFORMING / FEBRUARY 2008 www.metalformingmagazine.com


Salzgitter’s New Air-Hardening Steels
…as delivered
Type Yield strength (MPa) Tensile strength (MPa) Percent elongation
Hot strip
LH800 280-400 480-650 >23
LH900 310-430 500-670 >22
Cold strip
LH800 310-430 450-570 >28 (> 0.16 n value)
LH900 330-450 480-600 >26 (> 0.15 n value)

…and after air-hardening:


LH800 600-700 800-900 >15
LH900 700-800 900-1000 >13

for A- and B-pillars, frame components cooling in the press, and a coating on
and cross members. Stampers can use the steel sheet to avoid oxidation and
existing tooling, says Salzgitter, with scaling of the sheet.
only minimal modifications. One caveat As an application example of the
to using these materials: They cannot be ability of its new steels to be formed,
delivered in galvanized form, since the Salzgitter cites testing performed at a
zinc coating would be compromised Magna facility where center pillars were
during heattreating. Rather, parts must deep-drawn from 1.8-mm-thick LH900
be batch-galvanized after treatment. sheet. Yield strength of the steel averaged
In addition to its new PFHT steels, 400 MPa after forming, 700 MPa after
Salzgitter recently introduced press- hardening and 750 MPa after temper-
hardening (PH) steel 22MnB5, a boron- ing. Tensile strength averaged 550 MPa
alloyed tempered steel that can achieve after forming, 1000 MPa after harden-
tensile strengths to 1300 to 1800 MPa ing and 950 MPa after tempering.
(190 to 260 ksi) after hot forming with Coming down the pike from Salzgit-
controlled in-die quenching (press ter: high-strength and -ductility (HSD)
hardening). These steels also get noto- steels under development for the last
riety for their high yield strength, based few years through a partnership with
on manganese (1.2 to 1.4 weight per- Corus. HSD steels contain high levels of
cent) and boron (0.0020 to 0.0035 manganese, and offer strength levels of
weight percent) content. Also recom- 600-1400 MPa with elongations of 70 to
mended for A- and B-pillars, frame 20 percent, respectively. To produce these
components and cross members, steels, Salzgitter is erecting a new pro-
22MnB5 also would prove ideal for duction line that will include electric-
penetration protection—sills, bumpers arc-furnace steelmaking and strip casting
and bumper mounts, and roof frames. using its BeST (belt-strip casting) tech-
Boron-alloyed tempered steels such nology. www.salzgitter-ag.de/en
as 22MnB5 can be formed in one or two MF
steps, depending on the complexity of Seminar: Higher-Strength Steel—
the component. As-delivered, stampers Solving the Problems
can cold-form the sheet, offered by Learn all about the properties of AHSS and
the techniques used to form and fabricate them at
Salzgitter in thicknesses from 1 to 3 this PMA-sponsored seminar May 22 in Cleveland,
mm and in widths from 900 to 1500 OH. Seminar topics include stretchability and
mm, and then harden in a separate bendability, springback, punch and blankholder
loads, tool temperature and wear, press loads and
process. Or, as an added step, stampers energy requirements, blanking damage and case
can hot-form the previously cold- studies. For more information, please contact
formed parts, with subsequent press Michelle Underwood: munderwood@pma.org,
216/901-8800 ext. 163.
hardening in the die. This requires water

www.metalformingmagazine.com

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