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B.Sc - III Semester - V

2018-04

B.Sc - III Sem - V : April 2018 : Question

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Shivaji University, Kolhapur

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No.
B.Sc. (Part-III) (Semester-V) Examination, April - 2018
CHEMISTRY
Inorganic Chemistry (Paper-X)
Sub. Code : 65824
Day and Date : Wednesday, 18-04-2018 Total Marks : 40
Time : 3.00 p.m. to 5.00 p.m.

Instructions : 1) All questions are compulsory.

2) Figures to the right indicate full marks.
3) Draw the neat labeled diagrams wherever necessary.

Q1) Select the most correct alternative among those given below and rewrite the
sentences. [8]

a) Temperature at which substance becomes superconductor is called___

temperature.
i) super ii) higher
iii) critical iv) optimum
b) For dimer the degree of polymerization is____
i) 4 ii) 3
iii) 2 iv) 1
c) In octahedral complex co-ordination number (CN) of central metal atom
is___.
i) 4 ii) 6
iii) 5 iv) 7
d) According to HSAB concept___is soft acid.
i) Na+ ii) Ni2+
iii) Hg2+ iv) Mg2+

P.T.O.
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e) In p-type semiconductor electrical conductivity is due to migration of___
i) protons ii) holes
iii) electrons iv) atoms
f) The term ‘organometallic compounds’ was introduced by___.
i) Lewis ii) Faraday
iii) Frankland E.C. iv) Werner
g) Polymer containing same types of atoms in their backbone are called
as___polymers.
i) heteroatomic ii) monoatomic
iii) mixed iv) synthetic
h) Cis-trans isomers are possible in____complexes.
i) trigonal ii) tetrahedral
iii) square planer iv) both trigonal and tetrahedral

Q2) Attempt any two of the following. [20]

a) Classify the solids as insulator, semiconductor and conductor on the
basis of band theory.
b) On the basis of VBT explain the structures of Ni(CO) 4 and
Cr(CO)6carbonyls.
c) Draw the MO diagrams of [Co(NH3)6]3+ and [Ti(H2O)6 ]3+ ions. Explain
their magnetic properties.

Q3) Attempt any three of the following. [12]

a) Explain acid base strength and hardness & softness.
b) Explain nature of bonding in simple metal carbonyls.
c) Explain geometrical isomerism in metal complexes with CN=4.
d) Mention any four properties of metallic solids.
e) What are silicones? Give their applications.

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