calibracion de la curva

ml(SO4=) NTU
0 1.76 curva de calibracion
5 16.2
25
10 36.9
15 71.3
20 f(x) = 0.1923536582x + 1.2609885991
20 101

15

10

0
0 20 40 60 80 100 12

a= 0.1924
b= 1.261
calculo de concentracion de sulfatos

N° NTU SO4=
1 1.36 0.51
2 4.34 16.00
3 4.82 18.50
4 1.8 2.80
5 2.93 8.67
6 1.42 0.83
7 3.89 13.66
8 187 965.38
9 2.9 8.52
10 5.2 20.47
11 6.52 27.33
12 10.4 47.50
13 5.02 19.54

fecha 04/10/19

calibracion e la curva
25

N° ml NTU
20 f(x) = 0.2300977091x + 0.7210797811
R² = 0.9886838366

15
 25

1 0 1.73 20 f(x) = 0.2300977091x + 0.7210797811

2 5 15.7 R² = 0.9886838366

3 10 36.5 15
4 15 61.4
5 20 86.3 10

0
0 10 20 30 40 50 60 70 8

Col umn C Li near (Col umn

a= 0.2301
b= 0.7211

N° NTU SO4=
1 114 492.30
107 461.88

tanda N° 1 tanda N°2

N° NTU SO4=(mg/L) N° NTU SO4=

1 38.9 165.9 1 66 283.7
2 41.1 175.5 2 32.6 138.5
3 62.6 268.9 3 40.5 172.9
4 87.7 378.0 4 49.1 210.3
5 32.8 139.4 5 64.9 278.9
6 8.6 34.2 6 44.6 190.7
7 45.6 195.0 7 24.2 102.0
8 136 587.9 8 58 248.9
9 6.22 23.9 9 56.6 242.8
10 3.02 10.0
11 76.7 330.2
12 109 470.6
13 8.01 31.7
cion

80 100 120

10797811
10797811

40 50 60 70 80 90 100

umn C Li near (Col umn C)

tanda N°3 10/17/2019

N° NTU SO4= N°
1 16.7 69.4 1
2 12.9 52.9 2
3 5.5 20.8 3
4 2.35 7.1 4
5 3.4 11.6 5
6 3.33 11.3 6
7 7.67 30.2 7
8 8.26 32.8 8
9 8.76 34.9
10 5.01 18.6
11 1.73 4.4
12 4.81 17.8
13 2.69 8.6
14 52.9 226.8
15 14.3 59.0
16 38.7 165.1
17 47.7 204.2
18 164 709.6
19 52.9 226.8
20 2.54 7.9
21 35.4 150.7
22 20.2 84.7
23 1.59 3.8
24 13.3 54.7
25 17.5 72.9
26 9.7 39.0
27 93 401.0
28 16.5 68.6
29 13.3 54.7
30 25.6 108.1
31 41.5 177.2
32 31.3 132.9
33 177 766.1
34 4.96 18.4
35 2.34 7.0
36 2.98 9.8
37 2.26 6.7
38 3.6 12.5
39 3.19 10.7
40 10 40.3
NTU SO4= N° NTU SO4=
15 62.1 1 24.2 102.0
41.3 176.4 2 33.1 140.7
45.7 195.5 3 35.7 152.0
22.5 94.6 4 9.55 38.4
46.3 198.1 5 11.1 45.1
40.3 172.0 6 200 866.1
33.2 141.2 7 10.5 42.5
37.6 160.3 8 669 2904.3
9 29.2 123.8
10 239 1035.5
11 242 1048.6
12 40.1 171.1
13 38.8 165.5
14 36.4 155.1
15 23.6 99.4
16 264 1144.2
17 27 114.2
18 9.4 37.7
19 46.3 198.1
20 23.8 100.3
21 60.3 258.9
22 44.3 189.4
23 2.89 9.4
24 11 44.7
25 985 4277.6
26 30.1 127.7
27 81.4 350.6
28 25.8 109.0
29 18.8 78.6
30 24.6 103.8
31 22.6 95.1
32 8.95 35.8
33 39.7 169.4
34 87.2 375.8
 Preparacion de lolucion valorada de EDTA de 0,01 M

a) preparacion de solución patron de carbonato de calcio(CaCO3)

�_𝐶𝑎𝐶𝑂3=0,3g 0.3 FORMULA

�_𝑠𝑜�= 250 mL =>0,25L 0.25 �_𝑪𝒂𝑪𝑶𝟑=𝒎/(𝑷�∗𝑽(𝑳))
100,09 g/mol
〖��〗 _𝐶𝑎𝐶𝑂3= 100.09

por tanto
�_����� = 0.012 mol/L

�_𝑶^𝑶
concentracion exacta de EDTA

DATOS:
FORMULA
�_𝐶𝑎𝐶𝑂3= 25 mL �_𝑬𝑫𝑻�= 〖 (�∗𝑽) 〗 _𝑪𝒂𝑪𝑶𝟑/𝑽_𝑬𝑫𝑻�
�_𝐶𝑎𝐶𝑂3= 0.012 mol/L
�_(𝐸𝐷𝑇𝐴(𝑔𝑎𝑠𝑡 𝑒𝑛 𝑡𝑖𝑡))= 16 mL

�_𝑬𝑫𝑻�= 0.019 0.01

calculos para la dureza total de agua

DATOS:
�_(𝑪𝒂𝑪𝑶𝟑/𝑯𝟐𝑶)= 〖 (�∗�) 〗 _𝑬𝑫𝑻�/𝑽_(𝑯𝟐𝑶(𝒎𝑳))
�_�� 0.019
��=
�_( 〖𝐸𝐷𝑇𝐴 /𝐻2𝑂 〗 _((�𝐿)) ) 6
100.09 �_(���� /�
/�� ���
� �� )= 0.00112 mol/L ==> 112.5
〖�𝑔〗 _(𝐶𝑎𝐶𝑂3
〖��〗 _����3=
〖��〗 _𝐶𝑎𝑂= 56.08
�_𝐻2𝑂= mL 100 para CaO se determina por estequiometria CaCO3 + Δ →CaO +CO2

�_(���� /���
/��
� � 63.0332701
�)=

�_( 〖𝐶𝑎𝐶𝑂 3〗 dureza total ∑▒█(𝐝𝐞 𝐥𝐚 @dureza 𝐭𝐨𝐭𝐚𝐥)

�_( 〖𝐸𝐷𝑇𝐴 /𝐻2𝑂 〗 _((�𝐿)) )
item _((�𝑜�/𝐿) ) 〖�𝑔〗 _(𝐶𝑎𝐶𝑂3/𝐿)
〖�𝑔〗 _(𝐶𝑎𝑂/𝐿)
1 4.5 112.5 180.162 100.944 281.1 3
2 0.8 32.0288 17.9456 50.0 6
3 1.7 68.0612 38.1344 106.2 9
4 3.9 156.1404 87.4848 243.6 12
5 1.1 44.0396 24.6752 68.7 15
6 7.6 304.2736 170.4832 474.8 18
7 1.1 44.0396 24.6752 68.7 21
 8 8.6 344.3096 192.9152 537.2 24
9 4.7 188.1692 105.4304 293.6 27
10 4.3 172.1548 96.4576 268.6 30
11 4.1 164.1476 91.9712 256.1 33
12 4.2 168.1512 94.2144 262.4 36
13 5.6 224.2016 125.6192 349.8 39
14 5.2 208.1872 116.6464 324.8 42
15 4.1 164.1476 91.9712 256.1 45
16 4 160.144 89.728 249.9 48
17 1.7 68.0612 38.1344 106.2 51
18 2.1 84.0756 47.1072 131.2 54
19 1.7 68.0612 38.1344 106.2 57
20 1.8 72.0648 40.3776 112.4 60
21 4.1 164.1476 91.9712 256.1 63
22 3.9 156.1404 87.4848 243.6 66
23 2.5 100.09 56.08 156.2 69
24 1.1 44.0396 24.6752 68.7 72
25 12.9 516.4644 289.3728 805.8 75
26 1.5 60.054 33.648 93.7 78
27 1 40.036 22.432 62.5 81
28 3.3 132.1188 74.0256 206.1 84
29 0.9 36.0324 20.1888 56.2 87
30 1 40.036 22.432 62.5 90
31 3.4 136.1224 76.2688 212.4 93
32 2 80.072 44.864 124.9 96
33 4.7 188.1692 105.4304 293.6 99
34 1.5 60.054 33.648 93.7 102
 〖�𝑔〗 _(𝐶𝑎𝐶𝑂3/𝐿)

aCO3 + Δ →CaO +CO2

�_( 〖𝐸𝐷𝑇𝐴 /�2� 〗 _((��)) ) suma

1.9 76.0684 42.6208 118.7
2 80.072 44.864 124.9
2.1 84.0756 47.1072 131.2
1.2 48.0432 26.9184 75.0
1.4 56.0504 31.4048 87.5
1.7 68.0612 38.1344 106.2
3 120.108 67.296 187.4
2.6 104.0936 58.3232 162.4