Vous êtes sur la page 1sur 9

1.

ETALOANE
Conc. Ac. Benzoic [mg/L] Vol. din sol. Stoc conc. Sol. Stoc [mg/L] Abs. etalon
0 0 200 0
8 1 vol. final [ml] 0.572
16 2 25 0.673
24 3 0.756
32 4 0.831
40 5 0.908
48 6 1.006
2.PROBE
Abs. proba 1 pepsi twist C x prb. 1 Abs. proba 2 pepsi light C x prb.2

ABSORBANTA
0.159 6.41 0.239 9.64
0.159 6.41 0.239 9.64
0.157 6.33 0.237 9.56
0.157 6.33 0.237 9.56
0.156 6.29 0.237 9.56

conc. Ac. Benzoic in prb. 1 conc. Ac. Benzoic in prb. 2


-1.665334
100.18 150.58
100.18 150.58
98.92 149.32
98.92 149.32
98.29 149.32
99.29 149.82 conc. Medie
0.29 0.19 s x
0.29 0.13 % RSD
2.78 2.78 t
2.24 2.24 (n)^1/2
0.35 0.24 C.I.
99.29±0.32 149.82±0.21 C
CURBA DE ETALONARE
1.2
f(x) = 0.0248434066x
R² = 0.9267366762
1

0.8
ABSORBANTA

0.6 curba de etalonare


Linear (curba de etalonare)
0.4

0.2

-1.66533453693773E-16
0 10 20 30 40 50

-0.2

CONCENTRATIA
1.ETALOANE
Conc. Sol. Azotit [μg/L] Vol. din sol. Stoc conc. Sol. Stoc [μg/L] Abs. etalon
0 0 4 0
0.08 1 vol. final [ml] 0.064
0.16 2 50 0.116
0.32 4 0.164
0.48 6 0.214
0.64 8 0.271
0.80 10 0.322
2. PROBE
Prb. 1- ABS Prb. 1- conc. In cuva Conc. In proba conc. Medie s x 0.011
0.081 0.188 18.788 t 2.780
0.081 0.188 18.788 % RSD 0.057
0.080 0.186 18.556 18.788 C.I. 0.012
0.082 0.190 19.020
R: 18.788±0.012
0.081 0.188 18.788
Prb. 2-ABS Prb. 2- conc. In cuva Conc. In proba conc. Medie s x 0.002
0.076 0.176 8.812 t 2.780
0.076 0.176 8.812 % RSD 0.018
0.075 0.174 8.696 8.765 C.I. 0.002
0.075 0.174 8.696
R: 8.765±0.002
0.076 0.176 8.812
CURBA DE ETALONARE
0.35
f(x) = 0.4312217195x
0.3 R² = 0.9836994982
0.25
ABSORBANTA

0.2 curba de etalonare


Linear (curba de
0.15 etalonare)
0.1
0.05
0
0 0.2 0.4 0.6 0.8 1
CONCENTRATIE
ANALIZA BERII
PROBE CULOARE ECHIVALENTA - METODA VIZUALA
Proba Proba analitica Volum solutie I2 0.1N Culoare (ECB)* RSD (%) 14.1799307958
1 0.56 9 C.I. 1.82
2 0.66 10.3 s x 1.64
Bere
BLONDA 3 0.88 12.9 ECB* mediu 11.56
4 0.94 14.1 Media±C.I. (ECB) 11.56±1.82
5 0.74 11.5

1 1.28 392 RSD (%) 27.04


2 1.32 404 C.I. 118.85
Bere
BRUNA 3 1.22 372 s x 106.88
4 1.28 392 ECB* mediu 395.20
5 1.36 416 Media±C.I. (ECB) 395.20±118.85
CULOARE ECHIVALENTA - METODA INSTRUMENTALA GRADUL DE AMAREALA
A 430nm Culoare (ECB) RSD (%) 0.0012 A 275nm Grad de amareala (BU)
0.257 6.425 C.I. 0.0000834 1.086 54.3
0.258 6.450 s x 0.000075 1.091 54.55
0.257 6.425 ECB mediu 6.435 1.089 54.45
0.257 6.425 Media±C.I. (ECB) 6.435±8.34E-5 1.093 54.65
0.258 6.450 1.090 54.5

0.285 142.5 RSD (%) 0.021 1.088 54.4


0.284 142 C.I. 0.033 1.079 53.95
0.285 142.5 s x 0.030 1.088 54.4
0.284 142 ECB mediu 142.3 1.080 54
0.285 142.5 Media±C.I. (ECB) 142.3±0.033 1.088 54.4
GRADUL DE AMAREALA
RSD (%) 0.012
C.I. 0.007
sx 0.007
BU mediu 54.490
Media ± C.I. (BU) 54.490±0.007

RSD (%) 0.040


C.I. 0.024
sx 0.022
BU mediu 54.230
Media ± C.I. (BU) 54.230±0.024
metoda LS-LR-FAAS masa proba 0.5015
C Zn C Zn det. [mg/kg] % RSD C Zn adevarata 198
1.14 227.318 114.8071 C mediu 235.69
1.14 227.318 114.8071 sx 17.53
1.21 241.276 121.8567 C.I. 21.8
1.21 241.276 121.8567
1.21 241.276 121.8567
C Cu C Cu det. [mg/kg] % RSD C Cu adevarata 167
1.06 211.366 126.5664 C mediu 211.37
1.06 211.366 126.5664 sx 0
1.06 211.366 126.5664 C.I. 0
1.06 211.366 126.5664
1.06 211.366 126.5664

metoda CS-HR-FAAS % RSD


C Zn 0.26 C Zn det. 260.8 C Zn adev. 198.00 131.73
C Cu 0.19 C Cu det. 188.3 C Cu adev. 167.00 112.78
C Cd 0.00 C Cd det. -2.5 C Cd adev. 1.44 -173.09
D
C Co 0.54 C Co det. 543.2 C Co adev. 17.50 3103.83 I
C Ni 0.07 C Ni det. 68.1 C Ni adev. 30.40 224.00 L
C Fe 21.70 C Fe det. 21635.1 C Fe adev. N.D. U
A
C Cr 0.17 C Cr det. 166.9 C Cr adev. 46.30 360.47 T
C Mn 0.74 C Mn det. 734.7 C Mn adev. 741.00 99.15 A

C Zn 1.22 C Zn det. 243.3 C Zn adev. 198.00 122.86


C Cu 0.95 C Cu det. 189.5 C Cu adev. 167.00 113.47
C Cd 0.01 C Cd det. 2.0 C Cd adev. 1.44 141.24
C Co 0.09 C Co det. 18.6 C Co adev. 17.50 106.42
C Ni 0.25 C Ni det. 49.8 C Ni adev. 30.40 163.65 C
C Fe 48.94 C Fe det. 9758.7 C Fe adev. N.D. O
N
C Cr 0.31 C Cr det. 61.5 C Cr adev. 46.30 132.91 C
C Mn 3.46 C Mn det. 689.3 C Mn adev. 741.00 93.03 .
metoda ICP-AES
Cx C det. C adev. % RSD
Na 2.05 1.22 N.D.
Mg 26.61 15.92 N.D.
Al 144.10 86.20 N.D.
K 53.20 31.82 N.D.
Ca 54.40 32.54 N.D.
Cr 0.41 0.25 46.30 0.53
Mn 4.18 2.50 741.00 0.34
Fe 153.00 91.53 N.D.
Co 0.42 0.25 17.50 1.44
Ni 0.16 0.09 30.40 0.31
Cu 1.37 0.82 167.00 0.49
Zn 1.26 0.75 198.00 0.38
Sr 0.94 0.56 N.D.
Cd 0.02 0.01 1.44 0.81
Ba 1.26 0.76 217.00 0.35
Pb 0.44 0.26 83.10 0.31
Ag 0.00 0.00 N.D.
In 2.54 1.52 N.D.
Tl 0.37 0.22 N.D.
Bi 76.20 45.58 N.D.