NEW VISION JUNIOR CBSE COLLEGE, AMBAJOGAI
th DATE : 00-00-2019
SUB: CHEMISTRY
TOPIC:
Part-1 (Examples)
1) Classify the following as open, closed or isolated
systems:
i) A beaker containing boiling water
ii) A chemical reaction taking place in an enclosed
flask
iii) A cup of tea placed on a table
iv) Hot water placed in perfectly insulated closed
container
v) A thermos flask containing hot coffee
2) Express the change in internal energy of a system
when
i) No heat is absorbed by the system from the
surroundings, but work (w) is done on the
system. What type of wall does the system
have?
ii) No work is done on the system, but q amount
of heat is taken out from the system and
given to the surroundings. What type of
wall does the system have?
iii) W amount of work is done by the system and q
amount of heat is supplied to the system.
What type of system would it be?
3) Calculate the internal energy change for each of the
following processes:
i) A system absorbs 428 J of heat and does work
equivalent to 286 J on its surrounding
ii) 62 J of work is done on the system and 128 J of
heat is transferred to the surroundings.
4) 2L of an ideal gas at a pressure of 10 atm expands
isothermally into a vacuum until its total volume is
10L.
i) How much heat is absorbed and how much work
is done in the expansion?
ii) How much heat is absorbed if this system
expands against a constant external pressure
of 1 atm?
iii) How much heat is absorbed if the expansion is
conducted reversibly at 298 K
5) A gas absorbs 120 J of heat and expans against the
external pressure of 1.10 atm from a volume of 0.5
L to 2.0 L. What is the change in internal energy? (1
L atm = 101.3 J)
6) Calculate U, q and w when 2.0 mol of an ideal gas
at 25C are compressed isothermally and reversibly
from 1.0 bar to 10.0 bar.
7) Three moles of hydrogen gas are compressed
isothermally and reversibly from 60 L to 20 L and
8.50 kJ of work is done on it. Assuming ideal
behavior, calculate the temperature of the gas.
PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com
(1)
CLASS: Std
TIME : 45Min
MAX. MARKS : 180
8) Calculate w and U for the conversion of 1 mol of
water at 100C to steam at 1 atm pressure. Heat of
vaporization of water at 100C is 40.670 kJ mol-1.
Assume ideal gas behavior.
9) A 6-litre cylinder contained 280 g of N2 gas at 27C.
Due to sudden leakage through the hole, all the gas
escaped into atmosphere and the cylinder became
empty. If the atmospheric pressure is 1.0
atmosphere, calculate the work done by the gas.
10) The heat of combustion of gaseous methane (CH4)
at constant volume is measured in a bomb
calorimeter at 298 K and is found to be -885.4 kJ
mol-1. Find the value of enthalpy change.
11) The enthalpy change (H) for the reaction:
N2 (g) + 3H2 (g)  2NH3 (g)
Is -92.38 kJ at 298 K. What is U at 298 K?
12) Enthalpy of combustion of carbon to CO2 (g) is -393
kJ mol-1. Calculate the heat released upon the
formation of 35.2 g of CO2 from carbon and
dioxygen gas.
13) If water vapour is assumed to be a perfect gas,
molar enthalpy change for vapourisation of 1 mol of
water at 1 bar and 100C is 41 kJ mol-1. Calculate
the internal energy change, when
i) 1 mol of water is vaporized at 1 bar pressure and
100C.
ii) 1 mol of water is converted into ice.
14) The heat liberated on complete combustion of 7.8 g
of benzene at constant volume at 25C has been
found to be 326.39 kJ. Calculate the heat of
combustion of benzene at constant pressure.
15) A swimming pool contains 1  105 L of water. How
much energy in joules is required to raise the
temperature of water from 20C to 25C? The
specific heat capacity of water is 4.184 J/C g.
16) a) Calculate the heat that must be supplied to raise
the temperature of 2 kg of water from 25C to its
boiling point at atmospheric pressure. The average
specific heat of water in the range 25-100C is
4.284 J K-1 g-1.
b) How long will a 2 kW heater take to supply this
energy?
17) a) Calculate the energy needed to raise the
temperature of 10.0 g of iron from 25C to 250C if
specific heat capacity of iron is 0.45 J C-1 g-1.
b) What mass of copper (specific heat capacity =
0.385 J C-1 g-1) can be heated through the same
temperature difference when supplied with the same
amount of energy as above.
Cell: 8050063005
 18) A chemist while studying the properties of gaseous
C2 Cl2F2, a chlorofurocarbon refeigerant cooled a
1.25 g sample at constant atmospheric pressure of
1.0 atm from 320 to 293 K. During cooling, the
sample volume decreased from 274 to 248 mL.
Calculate H and U for the chloroflurocarbon for
this process. For C2 Cl2F2, Cp = 80.7 J/mol K>
19) Calculate the number of kJ necessary to raise the
temperature of 60.0 g of aluminium from 35 to
55C. Molar heat capacity of Al is 24 J mol-1 K-1.
20) 0.562 g of graphite kept in a bomb calorimeter in
excess of oxygen at 298 K and 1 atmospheric
pressure was burnt according to the reaction:
C (graphite) + O2 (g)  CO2 (g)
During the reaction the temperature rises from 298
K to 298.80 K. If the heat capacity of the magnitude
calorimeter and its contents is 20.7 kJ/K, what is the
enthalpy change for the above reaction at 298 K and
1 atm?
21) The reaction of cyanamide [NH2CN (s)] with
dioxygen was carried out in a bomb calorimeter and
U was found be -742.7 kJ mol-1 at 298 K.
Calculate enthalpy change for the reaction at 298 K:
3 iii) C2H6(g) + 2 O2 (g)  2 CO2 (g) + 3 H2O (l);
NH2CN (s) + 2 O2 (g)  N2 (g) + CO2 (g) + H2O (l).
22) Red phosphorus reacts with liquid bromine as:
2P (s) + 3Br2 (l) 2pBr3 (g) rH = -243 kJ
Calculate the enthalpy change when 10.32 g of
phosphorus reacts with an excess of bromine.
23) The enthalpy for the reaction,
N2 (g) + 3H2 (g)  2NH3 (g)
Is -92.2 kJ. Calculate the enthalpy of formation of
ammonia.
24) Calculate the enthalpy change in the reaction:
4NH3 (g) + 3O2 (g)  2N2 (g) + 6H2O (l)
At 298 K given that the enthalpy of formation at
298 K for NH3 (g) and H2O (l) are -46.0 and -286.0
kJ mol-1 respectively.
25) Calculate the enthalpy change for the reaction
CH4 (g) + 2O2 (g)  CO2 (g) + 2H2O (l)
The enthalpy of formation of CH4 (g), CO2 (g) and
H2O (l) are -74.8 kJ mol-1, -393.5 8 kJ mol-1 and -
285.8 8 kJ mol-1 respectively.
26) The combustion of one mole of benzne takes place
at 298 K and 1 bar pressure. After combustion, CO2
(g) and H2O (l) are produced and 3267.0 kJ of heat
is liberated. Calculate the standard enthalpy of
formation, fH of benzene. Given that standard
enthalpy of formation of CO2 (g) and H2O (l) are
393.5 and -285.83 kJ mol-1 respectively.
27) Enthalpies of formation of Co (g), CO2 (g), N2O (g)
and N2O4 (g) are -110, -393, 81 and 9.7 kJ mol-1
respectively. Calculate rH fpr the reaction:
N2O4 (g) + 3 Co (g)  N2O (g) + 3 CO2 (g)
28) The enthalpies of combustion of CH4 and C2H6 are -
890.3 and -1559.7 kJ mol-1 respectively. Which of
the two has greater efficiency of fuel per gram?
29) In a gobar gas plant, gobar gas is obtained by
bacterial fermentation of animal refuse. It is found
PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com
(2)
to contain mainly methane and its heat of
combustion given by the equation:
CH4 (g) + 2O2 (g)  CO2 (g) + 2 H2O (g)
Is 809 kJ mol-1. How much gobar gas would have to
be produced per day for a small village community
of 100 families, if we assume that each family has to
be supplied 20,000 kJ of energy per day to meet all
its needs. The methane content in gobar gas is 80%
by weight.
30) a) A cylinder of gas supplied by a company is
assumed to contain 14 kg of butane. If a normal
family requires 20, 000 kJ of energy per day for
cooking, how long will the cylinder last?
b) If the air supplied to the burner is insufficient, a
portion of gas escaps without combustion.
Assuming that 25% of the gas is wasted due to this
inefficiency, how long will the cylinder last? (Heat
of combustion of butane = 2658 kJ/mol)
31) Calculate the enthalpy of formation of ethane from
the following data:
i) C (s) + O2 (g)  CO2 (g); rH = -393.5 kJ
1
ii) H2 (g) + 2 O2 (g)  H2O (l); rH = -285.8 kJ
7
rH = -1560.0 kJ.
32) Calculate the standard enthalpy of formation of
CH3OH (l) from the following data:
7
CH3OH (l) + O2 (g)  CO2 (g) + 2H2O (l); rH =
2
-726 kJ mol-1
C (s) + + O2 (g)  CO2 (g); rH = -393 kJ mol-1
1
H2 (g) + 2 O2 (g)  H2O (l); rH = -286.0 kJ mol-1
33) Calculate the enthalpy of formation of benzene
represented by the following reaction:
6C (s) + 3H2 (g)  C6H6 (l)
The standard enthalpy of combustion of benzene is -
3266.0 kJ and standard enthalpies of formation of
CO2 (g) and H2O (l) are -393.1 and -286.0 kJ
respectively.
34) Calculate the rH at 298 K for the reaction:
C (graphite) + 2H2 (G)  CH4 (g)
From the following data:
C (graphite) + O2 (g)  CO2 (g); rH = -393.5 kJ
mol-1
1
H2 (g) + 2 O2 (g)  H2O (l); rH = -285.8 kJ mol-1
CO2 (g) + 2H2O (l)  CH4 (g) + 2O2 (g); rH =
+890.3 kJ mol-1.
35) The enthalpies of solution of anhydrous CuSO4 and
hydrated CuSO4. 5H2O are -66.5 and 11.7 kJ mol-1
respectively. Calculate the enthalpy of hydration of
CuSO4 to CuSO4. 5H2O.
36) Calculate the enthalpy of formation of anhydrous
aluminium chloride, Al2Cl6 from the following data:
i) 2Al (s) + 6HCl (aq)  Al2Cl6 (aq) + 3H2 (g);
rH = -1004.0 kJ
ii) H2 (g) + Cl2 (aq)  2HCl (g); rH = -183.9 kJ
iii) HCL (g) + aq  HCL (aq); rH = -73.2 kJ
iv) Al2Cl6 (s) + aq  Al2Cl6 (aq); rH = -643.0 kJ.
Cell: 8050063005
 37) The standard enthalpies of formation of SO2 (g) and
SO3 (g) are -296.6 kJ and -395.6 kJ respectively.
Calculate H for the reaction:
1 are 414 kJ mol-1 and 330 kJ mol-1 respectively.
SO2 (g) 2 O2 (g)  SO3 (g)
38) Calculate the standard enthalpy of formation of
carbon disulphide (l). Given that the standard
enthalpies of carbon (s), sulphur (s) and carbon
disulphide (l) are -393.3, -293.72 and -1108.76 kJ
mol-1 respectively.
39) Calculate fH for chloride ion from the following
data:
1 1
2
H2 (g) + 2 Cl2 (g)  HCl (g); fH = -92.8 kJ mol-
1
HCl (g) + H2O  H3O+ (aq) + Cl- (aq)
dissH = -75.2 kJ mol-1.
40) Calculate H for the process at 25C of dissolving
1.0 mol of KCl in a large excess of water. Does this
process represent ionization reaction?
Explain.
fH [K+ (aq)] = -251.2 kJ mol-1
fH [Cl- (aq)] = -167.08 kJ mol-1
fH [KCl] = -437.6 kJ mol-1
41) Whenever an acid is neutralized by a base, the net
reaction is:
H+ (aq) + OH- (aq)  H2O (l) + 57.1 kJ
Calculate the heat evolved for the following
experiments:
i) 0.25 mol of HCl solution is neutralized by 0.25
mol of NaOH solution
ii) 0.60 mol of HCl solution is mixed with 0.30
mol of KOH solution
iii) 100 cm3 of 0.2 M HCl is mixed with 200 cm3 of
0.3 M NaOH
iv) 400 cm3 of 0.2 M H2SO4 is mixed with 600 cm3 of
0.1 M NaOH solution
42) When 1 g of liquid naphthalene (C10H8) solidifies,
149 J of heat is evolved. Calculate the heat of fusion
of naphthalene.
43) Calculate the enthalpy change when 2.38 g of
carbon monoxide (CO) vaporize at its normal
boiling point. Enthalpy of vapourization of CO is
6.04 kJ mol-1.
44) A boy after swimming comes out from a pool
covered with a film of water weighin 18 g. How
much heat must be supplied to evaporate this water
at 298 K? Calculate the internal energy of
vaporization at 100C. Hvap for water at 373 K =
40.66 kJ mol-1.
45) 18.0 g of water completely vapourises at 100C and
1 bar pressure and the enthalpy change for the
process is 40.79 kJ mol-1.
i) What will be the enthalpy change for vapourising
2 moles of water under the same
conditions?
ii) What is the standard enthalpy of vapourisation
for water?
46) Calculate rH for the reaction:
H 55) The oxidation of iron occurs as:
PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com
(3)
H – C – Cl (g)  C (g) + 2H (g) + 2Cl(g)
Cl
Average bond enthalpies of C – H and C – Cl bonds
47) Calculate rH for the reaction:
H H
C = C + 3O  2O = C = O + 2H-O-H
H H
The average bond enthalpies of various bbonds are:
Bond C-H O=O C=O O-H C=C
Bond enthalpy 414 499 724 460 619
(kJ mol-1)
48) Calculate C-C bond enthalpy from the following
data:
2C (graphite) + 3H2 (g);  C2H6 (g) rH = -84.67
kJ
C (graphite);  C (g) rH = 716.7 kJ
H2 (g);  2H (g) rH = = 435.9 kJ
Assume 416 kJ as the C-H bond enthalpy.
49) Propane has the structure H3C – CH2 – CH3.
Calculate the enthalpy change, rH for the
reaction:
C3H8 (g) + 5O2(g)  2CO2 (g) + 4H2O (g)
The average bond enthalpies of various bonds are
Bonds C-C C-H O=O C=O O-H
(kJ mol-1) 347 414 498 741 464
50) Calculate the enthalpy change for the process:
CCl4 (g)  C(g) + 4Cl (g)
And calculate bond enthalpy of C-Cl bond in CCl4
(g)
vapH (CCl4) = 30.5 kJ mol-1
rH (CCl4) = -135.5 kJ mol-1
aH (C) = 715.0 kJ mol-1
aH (Cl2) = 242 kJ mol-1
51) Calculate the bond enthalpy of C – H bond given
that the enthalpy of formation of CH4, enthalpy of
sublimation of carbon and bond dissociation
enthalpy of H2 are -74.8, +719.6 and 435.4 kJ mol-1
respectively.
52) Calculate the entropy change in surroundings when
1.00 mol of H2O (l) is formed under standard
conditions.
rH = -286 kJ mol-1.
53) Predict in which of the following entropy
increases/decreases”
a) H2(g)  2H (g)
b) 2 NaHCO3 (s)  Na2CO3(s) + CO2(g) + H2O(g)
c) A liquid crystallizes into a solid
d) Temperature of a crystalline solid is raised from
0 K to 115 K.
54) Consider the reaction for the dissolution of
ammonium nitrate:
NH4NO3(s)  NH4+ (aq) + NO3- (aq)
H = +28.1 kJ mol-1, S = 108.7 J K-1 mol-1.
Calculate the change in the entropy of the
surroundings and predict whether the reaction is
spontaneous or not at 25C?
Cell: 8050063005
 4Fe (s) + 3O2 (g)  2Fe2O3 (s)
The enthalpy of formation of Fe2O3 (s) is -824.2 kJ
mol-1 and entropy change for the reaction is -549
JK-1 mol-1 at 298 K. Inspite of negative entropy
change of this reaction, why is the reaction
spontaneous at 298 K?
56) The standard enthalpy change for the transition of
liquid water to steam is 40.8 kJ mol-1 at 373 K.
Calculate the entropy of vapourisation of water?
57) Calculate the enthalpy of vaporization per mole for
ethanol. Given S = 109.8 JK-1 mol-1 and boiling
point of ethanol = 78.5C.
58) The enthalpy of vaporization of liquid diethyl ether
(C2H5)2 is 26.0 kJ mol-1 at its boiling point (35.0C).
Calculate S for the conversion of
a) Liquid to vapour and
b) Vapour to liquid at 35C.
59) For the melting of ice at 25C:
H2O (s)  H2O (l)
The enthalpy of fusion is 6.97 kJ mol-1 and entropy
of fusion is 25.4 J mol-1 K-1. Calculate the free
energy change and predict whether melting of ice is
spontaneous or not at this temperature.
60) Enthalpy and entropy change of a reaction are 40.63
kJ mol-1 and 108.8 J K-1 mol-1 respectively. Predict
the feasibility of the reaction at 27C.
61) H and S for the reaction:
1 The standard Gibs energy for the reaction at 1000 K
Ag2O(s)  2Ag(s) + O2(g)
2 is -8.1 kJ mol-1. Calculate its equilibrium constant.
Are 30.56 k J mol-1 and 66.0 J K-1 mol-1
respectively. Calculate the temperature at which the
Gibbs energy change for the reaction will be zero.
What will be the direction of the reaction at this
temperature and at temperature below this
temperature and why?
62) Predict whether it is possible or not to reduce
magnesium oxide using carbon at 298 K according
to the reaction:
MgO(s) + C(s)  Mg(S) + CO(g)
rH = +491.18 kJ mol-1 and
rS = 197.67 JK-1 mol-1
If not at what temperature, the reaction becomes
spontaneous.
63) Calculate the standard Gibbs free energy change
from the free energies of formation data for the
following reaction:
15
C6H6(l) + 2 O2(g)  6CO2(g) + 3H2O(g)
Given that: fG [C6H6(l)] = 172.8 kJ mol-1
fG [CO2(g)] = -394.4 kJ mol-1
fG [H2O(g)] = -228.6 kJ mol-1
64) Consider the reaction:
4NH3 (g) + 5O2 (g)  4NO(g) + 6H2O(l); G = -
1010.5 kJ
Calculate fG [NO(g)] if fG [NH3(g)] = -16.6 kJ
mol-1 and fG [H2O(l)] = -237.2 kJ mol-1.
65) Calculate rGfor the following reactions using
fG values and predict which reactions are
spontaneous.
PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com
(4)
a) Ca (s) + Cl2 (g)  CaCl2 (s)
1
b) H2O (s)  Hg (l) + O2(g)
2
c) NH3(g) + 2O2 (g) HNO3 (l) + H2O (l)
fG values (kJ mol-1) are:
CaCl2 (s) = -748.1, HgO(s) = -58.84
NH3 (g) = -16.45, HNO3 (l) = -80.71,
H2O (l) = -237.13.
66) Silane (SiH4) burns in air as:
SiH4(g) + 2O2(g)  SiO2(s) + 2H2O(l)
The standard Gibbs energies of formation of
SiH4(g), SiO2 (s) and H2O (l) are +52.3, -805.0 and -
228.6 kJ mol-1 respectively. Calculate Gibbs energy
change for the reaction and predict whether the
reaction is spontaneous or not.
67) In a fuel cell methanol is oxidized with oxygen as:
3
CH3OH (l) + 2 O2(g)  CO2(g) + 2H2O (l)
Calculate the standard Gibbs energy change for the
reaction that can be converted into electrical work.
If standard enthalpy of combustion for methanol is -
726 kJ mol-1, calculate the efficiency of conversion
of Gibbs energy into useful work. The standard
Gibbs energies of formation, fG (kJ mol-1) are:
CO2 (g) = -394.4, H2O (l) = -237.2, CH3OH (l) = -
166.2.
68) For the water gas reaction
C(s) + H2O(g)  CO (g) + H2(g)
69) Calculate rG for conversion of oxygen to ozone:
3
O2(g)  O3(g) at 298 K.
2
Kp for this conversion is 2.47  10-29.
70) Calculate equilibrium constant for the reaction at
400 K.
2NOCl(g)  2NO(g) + Cl2(g)
H = 77.2 kJ mol-1 and
S = 122 JK-1 mol-1 at 400 K.
71) The standard Gibbs energy (fG) for the formation
of SO2 (g) and SO3 (g) are -300.0 and -371.0 kJ mol-
1
at 300 K respectively. Calculate G and
equilibrium constant for the following reaction at
300 K:
2SO2 (g) + O2 (g)  2SO3 (g)
72) AT 60C, dinitrogen tetroxide is 50% dissociated.
Calculate the standard free energy change at this
temperature and at one atmosphere.
73) Find out the value of equilibrium constant for the
following reaction at 298 K
2NH3(g) + CO2(g)  NH2CONH2 (aq) + H2O (l)
Standard Gibbs energy change, fG at this
temperature is -13.6 kJ mol-1.
74) It is planned to carry out the reaction:
CaCO3 (s)  CaO (s) + CO2 (g)
At 1273 K and 1 bar pressure.
rH = 176 kJ mol-1 and rS = 157.2 kJ mol-1
a) Is the reaction spontaneous at this temperature
and pressure?
Cell: 8050063005
 b) Calculate the value of Kp at 1273 K for the
reaction.
75) For the reaction at 28 K
2A (g) + B (g)  2D (g)
U = -10.5 kJ and S = -44.1 JK -1
Calculate the G for the reaction and predict
whether the reaction may occur spontaneous or not.
76) Using the following data, calculate the value of
equilibrium constant for the following reaction at
298 K.
3HC  CH  C6H6 (g)
Acetylene Benzene
Assuming ideal behaviour
fG (HC  CH) = 2.09  10 J mol5 -1
fG (C6H6) = 1.24  105 J mol-1
R = 8.314 JK-1 mol-1
Can the reaction be recommended for the synthesis
of benzene?
77) Calculate rSm for the reaction:
4Fe (s) +3O2 (g)  2Fe2O3 (s)
-1 -1
Given that: Sm (Fe) = 27.3 JK mol , Sm (O2) =
-1 -1
205.0 JK mol and Sm (Fe2O3) = 87.4 JK mol . -1 -1
78) Calculate the entropy changes for the following
reactions:
i) 2CO (g) + O2 (g)  2CO2 (g)
ii) 2H2 (g) + O2 (g)  2H2O (l)
Entropies of different compounds are:
CO(g) = 197.6 JK-1 mol-1, O2(g) = 205.03 JK-1 mol-1
-1 -1
CO2(g) = 213.6 JK mol , H2(g) = 130.6 JK mol -1 -1
H2O (l) = 69.96 JK-1 mol-1
79) Calculate the standard molar entropy change for the
formation of gaseous propane (C3H8) at 298 K.
3C (graphite) + 4H2 (g)  C3H8 (g)
-1
Standard molar entropies Sm (JK mol ) are: -1
C (graphite) = 5.7, H2 (g) = 130.7, C3H8 (g) = 270.2.
80) Calculate the free energy change at 298 K for the
reaction:
Br2 (l) + Cl2 (g)  2BrCl (g)
H = 29.3 kJ at 298 K. The entropies of Br2 (l), Cl2 reactions:
(g) and BrCl (g) at the above temperature are 152.3,
-1 -1
223.0 and 239.7 J mol K respectively.
81) Calculate the standard Gibbs energy change for the
combustion of -D glucose at 298 K:
C6H12O6 (s) + 6O2  6CO2 (g) + 6H2O (l)
Given that standard enthalpies of formation (kJ mol
1
) of U for the decomposition of 200 g of N2O under
C6H12O6 = -1274.5, CO2 = -393.5, H2O = -285.8.
Entropies (J K mol-1)
C6H12O6 = 212.1, O2 = 205.0, CO2 = 213.6, H2O =
69.9.
82) Calculate the standard free energy change for the
formation of methane at 298 K:
C (graphite) + 2H2 (g)  CH4 (g)
The following data are given:
fH (kJ mol-1): CH4 (g) = -74.81
-1
Sm (kJ mol ): C (graphite) = 5.70, H2 (g) = 130.7
CH4 (G) = 186.3.
83) Calculate the standard Gibbs energy change for the
formation of propane at 298 K:
PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com
(5)
3C (graphite) + 4H2 (g)  C3H8 (g)
fH for propane, C3H8 (g) = -103.8 kJ mol-1.
Given: Sm [C3H8 (g)] = 270.2 JK-1 mol-1
Sm [graphite] = 5.70 JK-1 mol-1
And Sm [H2 (g)] = 130.7 JK-1 mol-1
Part-2 (Problems)
1) Which of the following are open, close or nearly
isolated systems?
i) Human being
ii) The earth
iii) Can of tomato soup
iv) Ice cube tray filled with water
v) Helium filled in balloon
2) Which of the following are state functions?
i) Height of a hill
ii) Distance travelled in climbing the hill
iii) Energy change in climbing the hill
3) A system gives out 30 J of heat and does 75 J of
work. What is the internal energy change?
4) During a process, a system absorbs 710 J of heat
and does work. The change in internal energy for
the process is 460 J. What is the work done by the
system?
5) Four moles of an ideal gas at 2.5 atm and 27C are
compressed isothermally to half of its volume by an
external pressure of 3 atm. Calculate w, q and U.
6) A gas expands isothermally from 10 dm3 to 20 dm3
at 27C and work obtained is 4.620 kJ. Calculate the
number of moles of the gas.
7) The enthalpy changes for the following reactions at
298 K and 1 atm are given below:
i) CH3COOH(l) + 2O2(g)  2CO2(g) + 2H2O(l);
H = -874 kJ
ii) CH3CH2OH(l) + 3O2(g) 2CO2(g) + 3H2O(l);
H = -1363 kJ
Calculate the internal energy changes for these
8) The enthalpy of combustion of benzoic acid
(C6H5COOH) at 298 k and 1 atm pressure is -2546.0
kJ mol-1. What is Ufor the reaction?
9) Gaseous N2O decomposes at 298 K and forms N2 (g)
and O2 (g). The H for the reaction at 1 atm
- pressure and 298 K is -163.15 kJ. What is the value
the same conditions?
10) A 1.250 g sample of octane (C8H18) is burned in
excess of oxygen in a bomb calorimeter. The
temperature of calorimeter rises from 294.05 K to
300.78 K. If heat capacity of calorimeter and its
contents is 8.93 kJ/K, calculate the heat transferred
to calorimeter.
11) 20 g of ammonium nitrate (NH4NO3) is dissolved in
125 g of water in a coeffee-cup calorimeter, the
temperature of which falls from 296.5 K to 286.4 K.
Find the value of q for the calorimeter (Treat heat
capacity of water as the heat capacity of the
calorimeter and its contents).
Cell: 8050063005
 12) 1 g of graphite is burnt in a bomb calorimeter in
excess of oxygen at 298 k and 1 atmospheric
pressure according to the equation:
C (graphite) + O2(g)  CO2 (g)
During the reaction, temperature rises from 298 K to
299 K. If the heat capacity of the bomb calorimeter
is 20.7 kJ K-1, what is the enthalpy change for the
above reaction at 298 K and 1 atm?
13) The enthalpy of formation of Fe2O3 (s) is -824.2 kJ
mol-1. Calculate the enthalpy change for the
reaction:
4Fe (s) + 3O2  2Fe2O3 (s)
14) The rH for the reaction,
4S (s) + 6O2 (g)  4SO3 (g)
Is -1583.2 kJ. Calculate Hf of sulphur trioxide.
15) Calculate fH for the reaction,
CO2 (g) + H2 2CO (g) + H2O (g)
Given that fH for CO2 (g), 2CO (g) and H2O (g)
are -393.5, -111.3 and -241.8 kJ mol-1 respectively.
16) The enthalpy of formation of C2H5OH (l), CO2 (g)
and H2O (l) are -277.0, -393.5 and -285.8 kJ/mol
respectively. Calculate the enthalpy change for the
reaction:
C2H5OH (l) + 3O2 (g)  2CO2 (g) + 3H2O (l)
17) Calculate the standard enthalpy of formation of
ethylene, C2H4 (g) from the following
thermochemical equation:
C2H4 (g) + 3O2 (g)  2CO2 (g) + 2H2O (l); rH = -
1323 kJ
Given the standard enthalpy of formation of CO2 (g)
and H2O (g) are -393.5 and -249 kJ mol-1
respectively.
18) The standard molar enthalpy of formation of
ethane, carbon dioxide and liquid water are -21.1, -
94.1 and -68.3 kcal respectively. Calculate the
standard enthalpy change of the following reaction:
2C2H6 (g) + 7O2 (g)  4CO2 (g) + 6H2O (l)
19) Calculate rH for the reaction:
2H2S (g) + 3O2 (g)  2H2O (g) + 2SO2 (g)
Given fH values: H2S (g) = -20.60; H2O (l) = -
285.83; SO2 (g) = -296.83 kJ mol-1
20) The enthalpy of formation of CH4, C2H6 and C4H10
are -74.8, -84.7 and -126.1 kJ mol-1 respectively.
Arrange them in the order of their efficiency as fuel
per gram (enthalpy of formation of CO2 (g) and H2O
(l) are -393.5 and -285.8 kJ mol-1 respectively).
21) Sucrose undergoes combustion as:
C12H22O11 (s) + 12O2 (g)  12CO2 (g) + 11H2O (l);
+5645 kJ mol-1
i) How much energy will be liberated when 51.3 g of
sucrose in burnt?
ii) What is the energy required for the production of
5.472 g of sucrose.
22) A cylinder of indane gas contains 11.2 kg of butane.
A normal family requires 25000 kJ energy per day
for cooking. How long will the cylinder of gas last if
the efficiency of combustion is 80%. (Heat of
combustion of butane is 2658 kJ mol-1).
PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com
(6)
23) An intimate mixture of Fe2O3 and Al is used in a
solid fuel rocket. Calculate the fuel per gram and
fuel value per cc of mixture. Heats of formation and
densities are as follows:
rH (Al2O3) = 399 kcal/mole, rH (Fe2O3) = 199
kcal/mole
(Density of Fe2O3 = 5.2 g/cc. Density of Al = 2.7
g/cc)
24) Calculate the enthalpy of formation of acetic acid
(CH3COOH) if its enthalpy of combustion is -867
kJ mol-1. The enthalpies of formation of CO2 (g) and
H2O (l) are -393.5 and -285.9 kJ mol-1 respectively.
25) Calculate the standard enthalpy of formation of
propane (C3H8) if its enthalpy of combustion is -
220.2 kJ mol-1. The enthalpies of formation of CO2
(g) H2O (l) are -393.5 and -285.8 kJ mol-1
respectively.
26) Calculate the enthalpy of formation of ethyl alcohol
from the following data:
C2H5OH (l) + 3O2 (g)  2CO2 (g) + 3H2O (l);
rH = -1368.0 kJ
C (s) + O2 (g)  CO2 (g); rH = -393.5 kJ
1
H2 (g) + 2 O2 (g)  H2O (l); rH = -286.0 kJ
27) Calculate the enthalpy of formation of methane
from the following data:
C (s) + O2 (g)  CO2 (g); rH = -393.5 kJ
H2 (g) + 2O2 (g)  2H2O (l); rH = -571.8 kJ
CH4 (g) + 2O2 (g)  CO2 (g) + 2H2O (l);
rH = -890.3 kJ
28) Calculate the enthalpy of allotropic transformation
from monoclinic to rhombic sulphur from the
following data:
S (rhombic) + O2 (g)  SO2 (g); rH = -294.1 kJ
S (monoclinic) + O2 (g)  SO2 (g); rH = -295.4
kJ
29) Enthalpies of solution of BaCl2.2H2O and BaCl2 are
8.8 and -20.6 5 kJ mol-1 respectively. Calculate the
heat of hydration of BaCl2 to BaCl2.2H2O.
30) The enthalpies of combustion of C2H4 (g), C2H6 (g)
and H2 are -1409.5 kJ, -1558.3 kJ and -285.6 kJ,
respectively. Calculate the enthalpy of
hydrogenation of ethylene.
31) Calculate the enthalpy of formation of KOH (s)
from the following data:
1
K (s) + H2O (l) + (aq)  KOH (aq) + 2 H2 (g); rH
= -200.8 kJ
1
H2 (g) + O2 (g)  H2O (l); rH = -286.3 kJ
2
KOH (s) + (aq)  KOH (aq); rH = -58.6 kJ
32) The combustion of butane (C4H10) is exothermic by
2878.7 kJ mol-1. Calculate the standard enthalpy of
formation of butane given that the standard
enthalpies of formation of CO2 (g) and H2O (l) are -
393.5 kJ mol-1 and -285.8 5 kJ mol-1 respectively.
33) Calculate the enthalpy of combustion of nitric oxide
(NO) from the following data:
1 1
N2 (g) + O2 (g)  NO (g); rH = 90.7 kJ
2
1
2
2
N2 (g) + O2 (g)  NO2 (g); rH = 34.0 kJ
Cell: 8050063005
 34) The molar enthalpies of combustion of C2H2 (g), C
(graphite) and H2 (g) are -310.62 kcal, -94.05 kcal
and -68.32 kcal respectively. Calculate the standard
enthalpy of formation of C2H2 (g).
35) Calculate rH for the reaction,
1
H2 (g) + 2 O2 (g)  H2O (l)
Given that bond enthalpies of H-H bond, O=O bond
and O-H bond are 433 kJ mol-1, 492 kJ mol-1 and
464 kJ mol-1
36) Calculate the enthalpy of hydrogenation:
C2H4 (g) H2 (g)  C2H6 (g)
Given that the bond enthalpies of H –H, C = C, C –
C and C – H bonds are 433, 615, 347 and 413 kJ
mol-1 respectively.
37) Calculate the bond enthalpy of H – Cl given that the
bond enthalpies of H2 and Cl2 are 435.4 and 242.8
kJ mol-1 respectively and enthalpy of formation of
HCl (g) is -92.2 kJ mol.
38) The enthalpy change for the reaction:
C3H8 (g) + 5O2 (g)  3CO2 (g) + 4H2O (g);
rH = -1662 kJ mol-1
The bond enthalpies of different bonds (in kJ mol-1)
are:
C –C C – H C = O O – H
347 414 741 464
Calculate bond enthalpy of O = O bond in O2
molecules.
39) Calculate the entropy change involved in the
vaporization of water at 373 K to vapours at the
same temperature (Latent hat of vaporization =
2.275 kJ/g).
40) 30.4 kJ of heat is required to melt 1 mol of sodium
chloride. The entropy during melting is 28.4 J mol-
1 -1
K . Calculate the melting point of sodium chloride.
41) Calculate entropy of fusion and vaporization for
chlorine from the following data:
fusH = 6.40 kJ mol-1 m.p. = 102C
vapH = 20.4 kJ mol-1 b.p. = -34C
42) vapS of acetone is 93.0 JK mol-1. If boiling point
-1
of acetone is 56C, calculate the heat required for
the vaporization of 1 g of acetone.
43) The enthalpy of vaporization of benzene (C6H6) is
30.8 kJ mol-1 at its boiling point (80.1C). Calculate
the entropy change in going from:
i) Liquid to vapour, and
ii) Vapour to liquid at 80.1C.
44) vapH for water is 40.73 kJ mol-1 and vapS is 109
JK-1 mol-1. Calculate the temperature at which liquid
water will be in equilibrium with water vapour.
45) Calculate the entropy change of n-hexane when 1
mole of it evaporates at 314.7 K (vapH = 29.0 kJ
mol-1).
46) Calculate the Gibbs energy change on dissolving
one mole of sodium chloride at 25C.
Lattice energy = +777.8 kJ mol-1
Hydration of NaCl = -774.1 kJ mol-1
S at 25C = 43 JK-1 mol-1
47) The values of H and S for two reactions are
given below:
PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com
(7)
Reaction A: H = -10.5  103 J mol-1
S = +31 J K-1 mol-1
Reaction B: H = -11.7  103 J mol-1
S = -105 J K-1 mol-1
Decide whether these reactions are spontaneous or
not at 298 K.
48) At what temperature does the reduction of lead
oxide to lead by carbon becomes spontaneous?
PbO + C  Pb (s) + CO (g)
For the reaction, H and S at 25C are 108.4 kJ
mol-1 and 190 JK-1 mol-1 respectively.
49) For the reaction at 298 K
2A + B  C
H = 40 kJ mol-1 and S = 0.2 kJ K-1 mol-1
At what temperature will the reaction becomes
spontaneous considering H and S to be constant
over the temperature range.
50) Consider the reaction:
2NO (g) + O2 (g)  2NO2 (g)
Calculate the standard Gibbs energy change at 298
K and predict whether the reaction is spontaneous or
not. fG (NO) = 86.69 kJ mol-1, . fG (NO2) =
51.84 kJ mol-1.
51) Calculate rG for the reaction:
C6H12O6 (s) + 6O2 (g)  6 CO2 (g) + 6H2O (l)
fG values (kJ mol-1) are:
C6H12O6 (s) = -910.2, CO2 (g) = -394.4, H2O (l) = -
237.2
52) Calculate G for the reaction
1 1
NO (g)  N2 (g) + O2 (g)
2 2
If K = 1.55  1015 at 298 K.
53) The equilibrium constant for the reaction:
CO2 (g) + H2 (g)  CO (g) + H2O (g)
Is 73 at 25C. Calculate standard free energy
change.
54) Calculate the equilibrium constant for the following
reaction at 298 K:
2H2O (l)  2H2 (g) + O2 (g)
fG (H2O) = -237.2 kJ mol-1, R = 8.314 J mol-1 K-1.
55) The equilibrium constant for the reaction:
CH3COOH (l) + C2H5OH (l)  CH3COO C2H5 (l) +
H2O (l)
Has been found to be equal to 4 at 25C. Calculate
the free energy change for the reaction.
56) Calculate the entropy change for a reaction:
X Y
Given that H = 28.40 kJ mol-1 and equilibrium
constant is 1.8  10-7 at 298 K.
57) Calculate the equilibrium constant for the following
reaction at 298 K and 1 atmospheric pressure:
C (graphite) + H2O (l)  CO (g) + H2 (g)
Given fH at 298 K for H2O (l) = -286.0 kJ mol-1
For CO (g) = -110.5 kJ mol-1
S at 298 K for the reaction = 252.6 JK-1 mol-1
58) For the equilibrium reaction:
2H2 (g) + O2 (g)  2H2O (l) at 298 K,
G = -474.78 kJ mol-1. Calculate log K for it. (R =
8.314 J K-1 mol-1).
Cell: 8050063005
 59) Calculate the equilibrium constant for the reaction: c) U = H+pV d) U = pV
1
NO (g) + 2 O2 (g)  NO2 (g) 3) The volume of gas is reduced to half from its
original volume. The specific heat will be
Given fH at 298 K: NO (g) = 90.4 kJ mol-1, NO2
a) Reduce to half
(g) = 33.8 kJ mol-1 and S at 298 K = -70.8 JK-1
b) Be doubled
mol-1.
c) Remain constant
60) H and Sfor the reaction: d) Increase four times
Br2 (l) + Cl2 (g)  2BrCl (g) 4) The heat evolved in the combustion of benzene is
At 298 K are 29.3 kJ mol-1 and 104.1 JK-1 mol-1 given by the equation:
respectively. Calculate equilibrium constant for the 𝟏𝟓
reaction. C6H6 (g) + 𝟐 O2 (g)  6CO2 (g) + 3H2O (l), H =
61) Calculate the standard free energy change for the -3264.6 kJ mol-1
reaction: The heat energy change when 39 g of C6H6 are
H2 (g) + I2 (g)  2HI (g) H = 51.9 kJ mol-1 burnt in an open container will be:
Given: S (H2) = 130.6 JK-1 mol-1, a) +816.15 kJ mol-1 b) +1632.3 kJ mol-1
S (I2) = 116.7 JK-1 mol-1 and S (HI) = 206.3 JK-1 c) -1632.2 kJ mol-1 d) -2448.45 kJ mol-1
mol-1. 5) Which of the following equations represents
62) Calculate r G for the reaction:
enthalpy of formation of H2O?
1 a) 2H2 (g) + O2 (g)  2H2O (l); H = -ve
CO (g) + 2 O2 (g)  CO2 (g) H = -282.8 kJ
b) 2H2O2 (g)  2H2O (l) + O2 (g); H = +ve
Standard entropies: CO2 (g) = 213.6, CO (g) = 197.6 c) H2 (g) + 1/2 O2 (g)  2H2O (l); H = +ve
and O2 (g) = 205.0 (all in J mol-1). Predict whether d) 2H2O2 (g)  2H2 (g) + O2 (g); H = +ve
the reaction is spontaneous or not at standard state. 6) The enthalpy of neutralization of NaOH with
63) Calculate the change of entropy, rS at 298 K for HCl is 57.1 kJ with CH3COOH, it is -55 kJ. This
the reaction in which urea is formed from NH3 and happens because
CO2 a) Acetic acid is an organic acid
2NH3 (g) + CO2 (g)  NH2CONH2 (aq) + H2O (l) b) Acetic acid is little soluble in water
The standard entropies (JK-1 mol-1) are: c) Acetic acid is a weak acid and requires lesser
NH2CONH2 (aq) = 174.0, H2O (l) = 69.9, NH3 (g) = sodium hydroxide for neutralisation
192.3, CO2 (g) = 213.7. d) Some heat is required to ionize acetic acid
64) Calculate the standard molar entropy change for the completely
following reactions at 298 K: 7) Which of the following thermodynamic relation
a) 4Fe (s) + 3O2 (g)  2Fe2O3 (s) is correct?
[S (Fe2O3) = 87.4, S (Fe) = 27.3, S (O2) = 205.1 (all in a) dG = VdP – Sd/T
JK-1 mol-1) b) dU = PdV + TdS
b) Ca (s) + 2H2O (l)  Ca(OH)2 (aq) + H2 (g) c) dH = -VdP + TdS
[S Ca(OH)2 = -74.5, S (Ca) = 41.42, S (H2) = 130.7, d) dG = VdP + SdT
S (H2O) = 69.91 (all in JK-1 mol-1) 8) Enthalpy of a reaction is given as:
c) Na2CO3 (s) + 2HCl (aq)  2NaCl (aq) + H2O a) H = U + pV b) H = U - pV
(l) + CO2 (g) c) H = U + pV d) H = U - pV
[S Na2CO3 = 136.0, S (HCl) = 56.5, S (NaCl) = 9) In an adiabatic process, no transfer of heat takes
115.13, S (H2O) = 69.9, S (CO2) = 213.74 (all in place between system and surroundings. Choose
JK-1 mol-1). the correct option for free expansion of an ideal
65) Using fH and Sm calculate the standard molar gas under adiabatic condition from the following.
Gibbs energy of formation, fG for each of the a) q = 0, T  0, w = o
following: b) q  0, T = 0, w = o
a) CS2 (l) b) N2H2 (l) c) q = 0, T = 0, w = o
fH (CS2) = 89.70 kJ mol-1, fS (CS2) = 151.34 d) q = 0, T < 0, w  o
JK-1 mol-1 10) fU of formation of CH4 (g) at certain
fH (N2H4) = 50.63 kJ mol-1, fS (N2H2) = 121.21 temperature is -393 kJ mol-1. The value of fH is
JK-1 mol-1. a) Zero b) < fU
Part-3 (MCQ-A) c) > fU d) Equal tpo fU
1) For reaction, N2 (g) + 3H2 (g)  2NH3 (g) which 11) The heat change for the reaction:
of the following is valid? C (s) + 2S (s)  CS2 (l) is 102.4 kJ. It represents
a) H = U b) H > U a) Heat of formation
c) H < U d) none of the above b) Heat of combustion
2) Which of the following represents the first law of c) Heat of solution
thermodynamics? d) Heat of fusion
a) q = U - w b) H = q+w

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(8) Cell: 8050063005
 12) The equations representing the combustion of 21) The enthalpy change in freezing 1 g of water (fus
carbon and carbon monoxide are: H = 6.0 kJ mol-1) will be
C (s) + O2 (g)  CO2 (g) H = -284.5 kJ/mol the a) -6000.0 J b) -333 J
heat of formation of 1 mol of CO (g) is: c) 333.33 J d) 60.0 J
a) -109.5 kJ/mol b) +109.5 kJ/mol 22) For which of the following reactions, S is not
c) +180.0 kJ/mol d) +100 kJ/mol positive:
13) H for the combustion of a compound is: a) I2 (s)  I2 (g)
a) Positive b) CuO (s) + H2 (g)  Cu (s) + H2O (l)
b) Zero c) 2O3 (g)  3O2 (g)
c) Negative d) CH4 (g) + 2O2 (g)  CO2 (g) + 2 H2O (g)
d) May be positive or negative 23) In which of the following cases, reaction is
14) Molar heat capacity of ethanol is 110.4 J K. Its spontaneous at all temperatures?
specific heat capacity is a) H > 0; S > 0
a) 2.4 b) 55.2 b) H < 0; S > 0
c) 5.078 kJ d) 110.4
c) H < 0; S < 0
15) Enthalpy of formation of ammonia is -46.0 kJ
d) H < 0; S = 0
mol-1. The enthalpy change for the reaction:
24) On the basis of thermochemical equations (i), (ii)
2NH3 (g)  N2 (g) + 3H2 (g)
and (iii), which of the algebraic relationship is
a) 46.0 kJ mol-1 b) -23.0 kJ mol-1
-1 correct.
c) 92.0 kJ mol d) -92.0 kJ mol-1
i) C (graphite) + O2  CO2 (g); r H = x kJ mol-1
16) For an ideal gas, Cp and Cv are related as 𝟏
𝐶𝑝 ii) C (graphite) + 𝟐 O2  CO (g); r H = y kJ
a) Cp – Cv = R b) 𝐶 = R
𝑣 mol-1
c) Cp + Cv = R d) Cv – Cp = R 𝟏
iii) CO (g) + O2  CO2 (g); r H = z kJ mol-1
17) The fH for CO2 (g), CO (g) and H2O (g) are - 𝟐
393.5, -110.5 and -241.8 kJ mol-1 respectively. a) z = x + y b) x = y - z
The standard enthalpy change (in kJ) for the c) x = y + z d) y = 2z-x
reaction: 25) The relation G = H - TS was given by:
CO2 (g) + H2 (g)  CO (g) + H2O (g) is a) Boltzman b) Faraday
a) 524.1 b) 41.2 c) Gibbs Helmholtz d) Thomson
c) -262.5 d) -41.2 26) If equilibrium constant for a reaction is K, then
18) Equal volumes of one molar HCl and H2SO4 are standard free energy change is:
neutralized (separately) by dilute NaOH solution a) G = -RT log K
and x kcal and y kcal of heats are liberated. b) G = RT ln K
𝐺
Which of the following is true? c) 𝑅𝑇 = -log K
a) x = y b) x = 0.5 y 𝐺
1 d) 𝑅𝑇 = -2.303 log K
c) x = d) none
2𝑦 27) For a reversible process at equilibrium, the
19) The entropy change can be calculated by using change in entropy may be expressed as:
𝒒
expression S = 𝒓𝒆𝒗 . When water freezes in a ∆𝐻
𝑻 a) S = T qrev b) S = 𝑇
glass beaker, choose the correct statement 𝑞
amongst the following: c) S = 𝑒𝑟𝑣
𝑇
d) S = TH
a) S (system) decreases but S (surroundings) 28) Free energy, G may be defined as:
remains the same a) G = U - TS b) G = U -+TS
b) S (system) increases but S (surroundings) c) G = H - TS d) G = U + H - TS
decreases 29) Free energy change is related to enthalpy and
c) S (system) decreases but S (surroundings) entropy changes as:
increases a) G = H - TS
d) S (system) decreases but S (surroundings) b) G = TS - H
∆𝐻− ∆𝑆
also decreases c) G =
𝑇
20) Standard molar enthalpy of formation of CO2 is d) G = H + TS
equal to 30) For a spontaneous reaction, G should be:
a) Zero a) Positive
b) Standard molar enthalpy of combustion b) Negative
c) The sum of standard molar enthalpies of c) Equal to zero
formation of CO and O2 d) May be positive or negative
d) The standard molar enthalpy of combustion of
carbon (graphite)

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(9) Cell: 8050063005
 31) Which of the following conditions is not c) w (reversible) > w (irreversible)
favourable for the feasibility of a reaction? d) w (reversible) = w (irreversible) + Pex.V
a) H = +ve, TS = =ve and TS > S 41) Which of the following statements is correct?
b) H = -ve, TS = +ve a) The presence of reacting species in a covered
c) H = -ve, TS = -ve and TS < H beaker is an example of open system
d) H = +ve, TS = +ve and TS < H b) There is an exchange of energy as well as matter
32) In an isothermal expansion of an ideal gas between the system and the surroundings in a closed
against vacuum, the work involved is: system
a) Zero b) Maximum c) The presence of reactants in a closed vessel made
c) Minimum d) none of these up of copper is an example of a closed system
33) Out of ice, water and vapors, the most random d) The presence of reactants in a thermos flask or
state is: any other closed insulated vessel is an example of a
a) Ice b) Vapours closed system
c) Water d) Both ice & water 42) During complete combustion of one mole of
34) In a spontaneous change, a system undergoes: butane, 2658 kJ of heat is released. The
a) Lowering of free energy thermochemical reaction for above change is
b) Lowering of entropy a) 2C4H10 (g) + 13O2 (g)  8CO2 + 10H2O (l);
c) Increases in internal energy cH = -2658.0 kJ mol-1
13
d) No energy change b) C4H10 (g) + 2 O2 (g)  4CO2 + 5H2O (g);
35) Which of the following expression is true?
1 cH = -1329.0 kJ mol-1
a) fH (CO, g) = 2 fH (CO, g) 13
c) C4H10 (g) + 2 O2 (g)  4CO2 + 5H2O (l);
1
b) fH (CO, g) = fH (C, graphite) + 2 fH cH = -2658.0 kJ mol-1
(O2, g) 13
1
C4H10 (g) + O2 (g)  4CO2 + 5H2O (l);
2
c) fH (CO, g) = fH (CO, g) - fH cH = +1658.0 kJ mol-1
2
(O2, g) 43) The enthalpy of vaporization of liquid water
d) fH (CO, g) = cH (C, graphite) - cH using data
(CO, g) 𝟏
H2 (g) + O2 (g)  H2O (l) H = -285.77 kJ
36) If G is zero for a reaction, then 𝟐
𝟏
a) H = 0 H2 (g) + 𝟐 O2 (g)  H2O (g) H = -241.84 kJ is
b) S = 0 a) +43.93 kJ mol-1 b) -43.93 kJ mol-1
c) K (equilibrium constant) = zero b) +527.61 kJ mol d) -527.61 kJ mol-1
-1

d) K (equilibrium constant) = 1 44) Given that

37) The standard free energy changeG is related C + O2  CO2 H = -x kJ
to equilibrium constant Kp as 2CO +  2CO2 H = -y kJ
a) Kp = e-G / RT The enthalpy of formation of CO will be
−𝐺 2𝑥−𝑦
b) Kp = 𝑅𝑇 a) y – 2x b) 2
𝑦−2𝑥
c) Kp = RT ln G c) d) 2x - y
2
d) G = e-kp / RT 45) Which of the following is true for a reaction:
38) If f G for NH3 (g) is -16.4 kJ mol-1, then G H2O (l)  H2O (g) at 100C, 1 atm pressure
for the reaction: N2 (g) + 3H2 (g)  2NH3 (g) is a) H = U b) U = 0
a) 32.8 kJ mol-1 b) 16.4 kJ mol-1 c) H = 0 d) H = TS
-1
c) -16.4 kJ mol d) -32.8 kJ mol-1 46) Given:
39) Which of the following is not correct? C + 2S  CS2; H = 117 kJ
a) G is zero for a reversible reaction C + O2  CO2; H = -393 kJ
b) G is positive for a spontaneous reaction S + O2  SO2; H = -297 kJ
c) G is negative for a spontaneous reaction The heat of combustion of CS2 and CO2 and SO2
d) G is positive for a non-spontaneous reaction is
40) The pressure-volume work for an ideal gas can a) -1104 kJ mol-1 b) 1104 kJ mol-1
be calculated by using the expression w = - c) +807 kJ mol -1
d) -807 kJ mol-1
𝑽
∫𝑽 𝑻 𝑷𝒆𝒙 𝒅𝑽. The work can also be calculated from 47) When 5 g of sulphur is burnt to SO2, 46 kJ of
𝒕
the pV-plot by using the area under the curve heat is liberated. What is the enthalpy of
within the specified limits. When an ideal gas is formation of sulphur dioxide?
compressed (a) reversibly or (b) irreversibly a) -147.2 kJ b) +147.2 kJ
from volumes Vi to Vf choose the correct option. c) +294.4 kJ d) -294.4 kJ
a) w (reversible) = w (irreversible) 48) The enthalpy of formation of two compounds A
b) w (reversible) < w (irreversible) and B are -84 kJ and -156 kJ respectively. Which

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(10) Cell: 8050063005
 one of the following statements is correct? d) Isobaric, isothermal, isochoric
a) A and B are endothermic compounds 7) A reaction occurs spontaneously if
b) A is more stable than B a) TS < H and both H and S are +ve
c) A is less stable than B b) TS > H and H is +ve and S is -ve
d) Both are unstable c) TS > H and both H and S are +ve
49) Which of the following statement is false? d) TS = H and both H and S are +ve
a) Work is a state function 8) The enthalpy of hydrogenation of cyclohexene is
b) Temperature is a state function -119.5 kJ mol-1. If resonance energy of benzene is
c) Change in the state is completely defined when -150.4 kJ mol-1, its enthalpy of hydrogenation
the initial and final states are specified would be:
d) Work appears at the boundary of the system a) -208.1 kJ mol-1 b) -269.9 kJ mol-1
50) In a closed insulator container, a liquid is stirred c) -358.5 kJ mol -1
d) -508.9 kJ mol-1
with a paddle to increases the temperature. 9) The enthalpy and entropy change for the
Which of the following is true? reaction:
a) U = w  0, q = 0 Br2 (l) + Cl2 (g)  2BrCl (g)
b) U = w = q  0 30 kJ mol-1 and 105 J K-1 mol-1 respectively. The
c) U = 0, w = q  0 temperature at which the reaction will be in
d) w = 0, U = q  0 equilibrium is:
Part-4 (MCQ-B) a) 273 K b) 450 K
1) For which one of the following equations is rH c) 300 K d) 285.7 K
is equal to fH for the product? 10) Consider the following reactions:
a) N2 (g) + O2 (g)  N2O3 (g) i) H+ (aq) + OH- (aq)  H2O (l);
b) CH4 (g) + 2Cl2 (g)  CH2Cl (g) + 2HCl (g) H = -x1 kJ mol-1
c) Xe (g) + 2F2 (g)  XeF4 (g) 𝟏
ii) H2 (g) + O2 (g)  H2O (l);
𝟐
d) 2CO (g) + O2 (g)  2CO2 (g) H = -x2 kJ mol-1
2) For the reaction:
iii) CO2 (g) + H2 (g)  CO (g) + H2O (l);
C3H8 (g) + 5O2 (g)  3CO2 (g) + 4H2O (l) at H = -x3 kJ mol-1
constant temperature, H - U is 𝟓
a) +RT b) -3RT iv) C2H2 (g) + O2 (g)  2CO2 (g) + H2O (l);
𝟐
c) +3RT d) -RT H = +x4 kJ mol-1
3) If the bond energies of H –H, Br- Br and H – Br Enthalpy of formation of H2O (l) is
are 433, 192 and 364 kJ mol-1 respectively, the a) +x1 kJ mol-1 b) –x2 kJ mol-1
H for c) +x3 kJ mol -1
d) –x4 kJ mol-1
H2 (g) + Br2 (g)  2HBr (g) is 11) Given that the bond energies of H – H and Cl –
a) +103 kJ b) -261 kJ Cl are 430 kJ mol-1 and 240 kJ mol-1 respectively
c) -103 kJ d) -261 kJ and fH for HCl is -90 kJ mol-1, bond enthalpy of
4) Considering entropy (S) as a thermodynamic HCl is
parameter, the criterion for the spontaneity of a) 245 kJ mol-1 b) 290 kJ mol-1
-1
any process is c) 380 kJ mol d) 425 kJ mol-1
a) Ssystem - Ssurroundings > 0 12) The average molar heat capacities of ice and
b) Ssystem > 0 water are respectively 37.8 J/mol and 75.6 J/mol
c) Ssurroundings > 0 and the enthalpy of fusion of ice is 6.012 kJ/mol.
d) Ssystem + Ssurroundings > 0 The amount of heat required to change 10 g of
5) A cylinder of gas supplied by Bharat Petroleum ice at -10C to water at 10C would be
is assumed to contain 14 kg of butane. If a a) 2376 J b) 4752 J
normal family requires 20,000 kJ energy per day c) 3970 J d) 1128 J
for cooking, butane gas in the cylinder last e) 1985 J
for………days (HC of C4H10 = -2658 kJ per 13) Which of the following are not state functions?
mole) i) q + w ii) q iii) w iv) H - TS
a) 15 days b) 20 days a) (i) & (iv) b) (ii), (iii) and (iv)
c) 50 days d) 40 days c) (i), (ii) and (iii) d) (ii) and (iii)
d) 32 days 14) The reactions which have standard free energy
6) Five moles of a gas is put through a series of change less than zero, always have equilibrium
changes as shown graphically in a cyclic process. constant to be
The processes a) Unity b) Greater than unity
c) Less than unity d) Zero
A  B, B  C and C  A respectively are:
a) Isochoric, isobaric, isothermal 15) Entropy changes for the process
b) Isobaric, isochoric, isothermal H2O (l)  H2O (g)
c) isochoric, isothermal, isobaric

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(11) Cell: 8050063005
 At normal pressure and at 274 K are given b) Cl2 (g)  2Cl (g)
below: c) 2SO2 (g) + O2 (g)  2SO3 (g)
S system = -22.13, S surroundings = +22.05 d) 2KClO3 (s)  2KCl (s) + 3O2 (g)
The process is non-spontaneous because e) H2O (l)  H2O (g)
a) S system is -ive 24) Standard enthalpy of vaporization vapH for
b) S surroundings is +ive water at 100C is 40.66 kJ mol-1. The internal
c) S universe is -ive energy of vaporization of water at 100C (in kJ
d) S system  S surroundings mol-1) is
16) The heats of atomization of PH3 (g) and P2H4 (g) a) +37.56 b) -43.76
are 954 kJ mol-1 and 1485 kJ mol-1 respectively. c) +43.76 d) +40.66
The P – P bond energy in kJ mol-1 is (Assume water vapour to behave like an ideal
a) 213 b) 426 gas)
c) 318 d) 1272 25) In which of the following reactions, standard
e) 107 reaction entropy change (S) is positive and
17) The values of H and S for the reaction, standard Gibb’s energy change (G) decreases
C (graphite) + CO2 (g)  2CO (g) sharply with increasing temperature?
Are 170 kJ and 170 J/K respectively. This 1
a) C (graphite) + 2 O2 (g)  CO (g)
reaction will be spontaneous at 1
a) 910 K b) 1110 K b) CO (g) + 2 O2 (g)  CO2 (s)
c) 510 K d) 710 K 1
c) Mg (s) + 2
O2 (g)  MgO (s)
18) From the following bond energies: 1 1 1
H – H bond energy: 431.37 kJ mol-1 d) C (graphite) + 2 O2 (g) 2 CO2 (g)
2
C = C bond energy: 606.10 kJ mol-1 26) The enthalpy of fusion of water is 1.435 kcal/mol.
C – C bond energy: 336.49 kJ mol-1 The molar entropy change for the melting of ice
C – H bond energy: 410.50 kJ mol-1 at 0C is
Calculate the bond enthalpy of the following a) 10.52 cal/ (mol K)
reaction: b) 21.04 cal/ (mol K)
c) 5.260 cal/ (mol K)
a) -243.6 kJ/mol b) -120.0 kJ/mol d) 0.526 cal/ (mol K)
c) 553.0 kJ/mol d) 1523.6 kJ/mol 27) In the following reaction:
19) Standard entropies of X2, Y2 and XY3 are 60, 40 4NO2 (g) + O2 (g)  2N2O5 (g); H = -110 kJ;
and 50 kJ mol-1 respectively. For the reaction: If N2O5 (s) is formed instead of N2O5 (g) in the
𝟏 𝟑
𝟐
X2 + 𝟐 Y2  XY3; H = -30 kJ reaction, the enthalpy change (in kJ) would be
To be at equilibrium, the temperature should be (enthalpy of sublimation of N2O5 (s) is +53 kJ
a) 500 K b) 750 K mol-1)
c) 1000 K d) 1250 K a) -216 b) -162
20) Four grams of graphite is burnt in a bomb c) +108 d) +216
calorimeter of heat capacity of 30 kJ K-1 in excess e) +162
of oxygen at 1 atmospheric pressure. The 28) For the reaction, X2O4 (l)  2XO2 (g)
temperature rises from 300 to 304 K. What is the U = 2.1 kcal, S = 20 cal K-1 at 300 K
enthalpy of combustion of graphite (in kJ mol-1)? Hence, G is
a) 360 b) 1440 a) 2.7 kcal b) -2.7 kcal
c) -360 d) -1440 c) 9.3 kcal d) -9.3 kcal
e) -520 29) The enthalpies of solution for copper sulphate
21) Enthalpy change for the reaction, pentahydrate and anhydrous copper sulphate are
4H (g)  2H2 (g) is -869.6 kJ. respectively 11.7 and -65.5 kJ mol-1. The
The dissociation energy of H – H bond is hydration enthalpy of anhydrous copper
a) -434.8 kJ b) -869.6 kJ sulphate is
d) +434.8 kJ d) +217.4 kJ a) 53.8 kJ mol-1 b) -9.8 kJ mol-1
-1
22) Which of the following is correct option for free c) -77.2 kJ mol d) -53.8 kJ mol-1
-1
expansion of an ideal gas under adiabatic e) 77.2 kJ mol
condition? 30) The standard enthalpy of formation of NH3 (g) is
a) q = 0, T  0, w = 0 -91.8 kJ mol-1. The amount of heat required to
b) q  0, T = 0, w = 0 decompose 34 g of NH3 (g) into its elements is
c) q = 0, T = 0, w = 0 a) 183.6 kJ b) 91.8 kJ
c) 45.9 kJ d) 137.7 kJ
d) q = 0, T < 0, w  0
e) 275.4 kJ
23) Choose the reaction with negative S value.
31) Calculate the work done by 16 g of oxygen gas
a) 2NaHCO3 (s)  Na2CO3 + CO2 (g) + H2O (g) (assume ideal behavior) of molar mass 32 g mol-1

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(12) Cell: 8050063005
 undergoing isothermal reversible expansion at 41) If the bond dissociation energies of XY, X2 and
300 K from an initial volume of 2.5 L to the final Y2 (all diatomic molecules are in the ratio of
volume of 25 L in litre atm. (R = 8.2  10-2 L atm 1:1:0.5 and DfH for the formation of XY is -200
K-1 mol-1) kJ mol-1, the bond dissociation energy of X2 will
a) -56.64 b) 28.32 be
c) 113.28 d) 56.64 a) 100 kJ mol-1 b) 200 kJ mol-1
-1
e) -113.28 c) 800 kJ mol d) 400 kJ mol-1
32) The heat of combustion of carbon to CO2 is - 42) An ideal gas is allowed to expand both reversibly
393.5 kJ/mol. The heat released for the formation and irreversibly in an isolated system. If Ti is the
of 35.2 g of CO2 from carbon and oxygen gas is: initial temperature and Tf is the final
a) -630 kJ b) -3.26 kJ temperature which of the following is correct?
c) -315 kJ d) +315 kJ a) Tf > Ti for reversible process but Tf = Ti for
33) Which of the following statements is correct for a irreversible process
reversible process in a state of equilibrium? b) (Tf)rev = (Tf)irrev
a) G = -2.30 RT log K c) Tf = Ti for both reversible and irreversible
b) G = 2.30 RT log K processes
c) G = -2.30 RT log K d) (Tf)irrev = (Tf)rev
d) G = 2.30 RT log K 43) The standard enthalpy of formation, fH at 298
34) The enthalpy changes for a reaction does not K for methane, CH4 (g) is -74.8 kJ mol-1. The
depend upon additional information required to determine the
a) Use of different reactants for the same product average energy for C – H bond formation would
b) The nature of intermediate reaction steps be
c) The differences in the initial and final a) Latent heat of vaporization of methane
temperature of the involved substances b) The first four ionization energies of carbon and
d) The physical state of the reactants and products electron gain enthalpy of hydrogen
35) The bond energies of C – C, C = C, H – H and C c) The dissociation energy of hydrogen molecules,
– H linkages are 350, 600, 400 and 410 kJ per H2
mol respectively. The heat of hydrogenation of d) The dissociation energy of H2 and enthalpy of
ethylene is sublimation of carbon
a) -170 kJ mol-1 b) -260 kJ mol-1 44) The enthalpy change for the following processes
c) -400 kJ mol-1 d) -40 kJ mol-1 are listed below:
36) To neutralize completely 20 mL of 0.1 M aqueous Cl2 (g) = 2Cl (g) : 242.3 kJ mol-1
solution of phosphorous acid (H3PO3), the I2 (s) = 2I (g) : 151.0 kJ mol-1
volume of 0.1 M aqueous KOH required is ICi (g) = I (g) + Cl (g) : 211.3 kJ mol-1
a) 10 mL b) 20 mL I2 (s) = I2 (g) : 62.76 kJ mol-1
c) 40 mL d) 60 mL Given that the standard states for iodine and
37) The enthalpies of combustion of carbon and chlorine are I2 (s) and Cl2 (g), the standard
carbon monoxide are -393.5 and -283 kJ mol-1 enthalpy of formation for ICl (g) is
respectively. The enthalpy of formation of a) -16.8 kJ mol-1 b) +16.8 kJ mol-1
-1
carbon monoxide is c) +244.8 kJ mol d) -14.6 kJ mol-1
a) 110.5 kJ mol-1 b) 676.5 kJ mol-1 45) (H - U ) for the formation of carbon monoxide
c) -676.5 kJ mol -1
d) -110.5 kJ mol-1 (CO) from its elements at 298 k is (R = 8.314 JK-1
38) An ideal gas expands in volume from 1  10-3 m3 mol-1)
to 1  10-2 m3 at 300 K against a constant a) 1238.78 J mol-1 b) -2477.57 J mol-1
-1
pressure of 1  105 Nm-2. The work done is c) 2477.57 J mol d) -1238.78 J mol-1
a) -900 J b) -900 kJ 46) Assuming the water vapour is an ideal gas, the
c) 270 kJ d) 900 kJ internal energy change (U) when 1 mole of
39) What would be the heat released when an water is vapourised at 1 bar pressure and 100C
aqueous solution containing 0.5 mol of HNO3 is (given molar enthalpy of vapourisation of water
mixed with 0.3 mol of OH- (enthalpy of at 1 bar and 373 K = 41kJ mol-1 and R = 8.3 J
neutralization is -57.1 kJ). mol-1 K-1) will be
a) 28.5 kJ b) 17.1 kJ a) 3.7904 kJ mol-1 b) 37.904 kJ mol-1
-1
c) 45.7 kJ d) 1.7 kJ c) 41.00 kJ mol d) 4.100 kJ mol-1
e) 2.85 kJ 47) Identify the correct statement regarding a
40) For a spontaneous reaction, the DG, equilibrium spontaneous process:
constant (K) and Ecell will be respectively, a) Endothermic processes are never spontaneous
a) - ve, > 1, + ve b) + ve, > 1, - ve b) Exothermic processes are always spontaneous
c) - ve, < 1, - ve d) - ve, > 1, - ve c) Lowering of energy in the reaction process is the
only criterion for spontaneity

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(13) Cell: 8050063005
 d) for a spontaneous process in an isolated system, 54) For a particular reversible reaction at
the change in entropy is positive temperature T, H and S were found to be both
48) In conversion of limestone to lime, + ve. If Te is the temperature at equilibrium, the
CaCO3 (s)  CaO (s) + CO2 (g) reaction would be spontaneous when
The values of H and S are +179.1 kJ mol-1 a) Te is 5 times T b) T = Te
and 160.2 J/K respectively at 298 K and 1 bar. c) Te > T d) T > Te
Assuming that H and S do not change with 55) The amount of heat released when 20 mL 0.5 M
temperature, the temperature above which NaOH is mixed with 100 mL 0.1 M HCl is x kJ.
conversion of limestone to lime will be The heat of neutralization is
spontaneous is: a) -100 x kJ/mol b) -50 x kJ/mol
a) 1200 K b) 845 K c) +100 x kJ/mol d) + 50 x kJ/mol
c) 1118 K d) 1008 K 56) One molar of an ideal gas expands at a constant
49) Using the following thermochemical equations temperature of 300 K from an initial volume of
i) S (Rh) + 3/2 O2 (g)  SO3 (g); H = -2x kJ/mol 10 litre to a final volume of 20 litre. The work
ii) SO2 (g) + 1/2 O2 (g)  SO3 (g); H = -2y done in expanding the gas is
kJ/mol a) 750 Joule b) 1728 Joule
Find out the heat of formation of SO2 (g) in c) 1500 Joule d) 3456 Joule
kJ/mol 57) Molar heat capacity of aluminium is 25 JK-1 mol-
1
a) (2x + y) b) (x + y) . The heat necessary to raise the temperature of
c) (2x/y) d) (y – 2x) 54 g of aluminium (Atomic mass 27 g mol-1) from
e) (2x – y) 30C to 50C is
50) Oxidising power of chlorine in aqueous solution a) 1.5 kJ b) 0.5 kJ
can be determined by parameters indicated c) 1.0 kJ d) 2.5 kJ
below: e) 2.0 kJ
𝟏 𝟏/𝟐∆𝒅𝒊𝒔𝒔𝑯 ∆𝒆𝒈 𝑯 ∆𝒉𝒚𝒅 𝑯 58) The entropy of change involved in the isothermal
Cl2 (g) → Cl (g) → Cl- (g) → Cl- reversible expansion of 2 moles of an ideal gas
𝟐
(aq) from a volume of 10 dm3 to a volume of 100 dm3
The energy involved in the conversion of 1/2Cl2 at 27C is
(g) to Cl- (aq) (using data, dissHCl2 = 240 kJ mol-1, a) 38.3 J mol-1 K-1 b) 35.8 J mol-1 K-1
egHCl = -349 kJ mol-1, hydHCl- = -381 kJ mol-1) c) 32.3 J mol K-1 -1
d) 42.3 J mol-1 K-1
will be 59) The value of enthalpy change (H) for the
a) +120 kJ mol-1 b) +152 kJ mol-1 reaction:
-1
c) -610 kJ mol d) -850 kJ mol-1 C2H5OH (l) + 3O2 (g)  2CO2 (g) + 3H2O (l)
51) In a fuel cell methanol is used as fuel and oxygen At 27C is -1366.5 kJ mol-1.The value of internal
is used as an oxidizer. The reaction is: energy change for the above reaction at this
𝟑
CH3OH (l) + O2 (g)  CO2 (g) +2 H2O (l) temperature will be
𝟐
At 298 K, standard Gibb’s energies of formation a) -1369.0 kJ b) -1364.0 kJ
for CH3OH (l), H2O (l) and CO2 (g) are -166.2, - c) -1361 kJ d) -1371.5 kJ
237.2 and -394.4 kJ/mol respectively. If standard 60) Identify the correct statement from the following
enthalpy of combustion of methanol is -726 in a chemical reaction.
kJ/mol, efficiency of the fuel cell will be: a) The entropy always increases
a) 80% b) 87% b) The change in entropy along with suitable change
c) 90% d) 97% in enthalpy decides the fate of a reaction
52) On the basis of the following thermochemical c) The enthalpy always decreases
data (fG H+ (aq) = 0) d) Both the enthalpy and the entropy remains
H2O (l)  H+ (aq) + OH- (aq), H = 57.32 kJ constant
𝟏 61) Choose the reaction in which H is not equal to
H2 (g) + 𝟐 O2 (g)  H2O (l), H = -286.2 kJ
U?
The value of enthalpy of formation of OH- at a) C (gr) + O2 (g)  CO2 (g)
25C is b) C2H4 (g) + H2 (g)  C2H6 (g)
a) -22.88 kJ b) -228.88 kJ c) 2C (gr) + H2 (g)  C2H62 (g)
c) +228.88 kJ d) -343.52 kJ
d) H2 (g) + I2 (g)  2HI (g)
53) The standard enthalpy of formation of NH3 is -
e) N2 (g) + O2 (g)  2NO (g)
46.0 kJ mol-1. If the enthalpy of formation of H2
62) The standard enthalpies of combustion of C6H6
from its atoms is -436 kJ mol-1 and that of N2 is -
(l), C (graphite) and H2 (g) are respectively -3270
712 kJ mol-1, the average bond enthalpy of N – H
kJ mol-1, -394 kJ mol-1 and -286 kJ mol-1. What is
bond NH3 is
the standard enthalpy of formation of C6H6 (l) in
a) +1056 kJ mol-1 b) -1102 kJ mol-1
-1 kJ mol-1 ?
c) -964 kJ mol d) +352 kJ mol-1
a) -48 b) +48

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(14) Cell: 8050063005
 c) -480 d) +480 71) The enthalpy of vaporization of a certain liquid
e) -72 at its boiling point of 35C is 24.64 kJ mol-1. The
63) The incorrect expression among the following is value of change in entropy for the process is
𝑉𝑓
a) In isothermal process, Wreversible = -nRT ln 𝑉 a) 704 J K1 mol-1 b) 80 J K1 mol-1
∆𝐻°−𝑇 ∆ 𝑆°
𝑖 c) 24.64 J K1 mol-1 d) 7.04 J K1 mol-1
b) ln K =
𝑅𝑇 72) The value of H for cooling 2 mol of an ideal
c) K = e-G/RT monoatomic gas from 225C to 125C at constant
∆𝐺𝑠𝑦𝑠𝑡𝑒𝑚 𝟓
d) = -T pressure will be [given Cp = 𝟐 R]
∆𝑆𝑡𝑜𝑡𝑎𝑙
64) The standard Gibbs free energy change (G) at a) 250 R b) -500 R
25C for the dissociation of N2O4 (g) to NO2 (g) is c) 500 R d) -250 R
(given, equilibrium constant = 0.15, R = 8.314 73) Given that
JK/mol) C + O2  CO2; H = -x kJ
a) 1.1 kJ b) 4.7 kJ 2CO + O2  2CO2; H = -y kJ
c) 8.1 kJ d) 38.2 kJ The heat of formation of carbon monoxide will
65) For isothermal expansion of an ideal gas, the be
𝑦−2𝑥
correct combination of thermodynamic a) b) y + 2x
2
parameters will be 2𝑥−𝑦
c) 2x - y d)
a) U = 0, q = 0, w  0, and H  0 2
b) U  0, q  0, w  0, and H = 0 74) The entropy of vaporization of a liquid is 58 J K-1
mol-1. If 100 g of its vapour condenses at its
c) U = 0, q  0, w = 0, and H  0
boiling point of 123C, the value of entropy
d) U = 0, q  0, w  0, and H = 0
change for the process is (molar mass of the
66) A certain reaction has a H of 12 kJ and a S of
liquid = 58 mol-1).
40 JK-1. The temperature above which the
a) -100 J K-1 b) 100 J K-1
reaction becomes spontaneous is -1
c) -123 J K d) 123 J K-1
a) 27C b) 27 K e) 1230 J K-1
c) 300C d) 30C 75) The ratio of heat liberated at 298 K from the
e) 30 K combustion of one kg of coke and by burning
67) If H and S are positive for a reaction, the water gas obtained from kg of coke is (assume
reaction will be spontaneous only when coke to be 100% carbon, enthalpies of
a) TS = H b) TS > H combustion of C, CO and H2 as 393.5 kJ, 285 kJ,
c) TS < H d) TS is negative 285 kJ respectively all at 298 K).
68) Calculate the enthalpy change for the reaction: a) 0.79:1 b) 0.69:1
C2H4 (g) + H2 (g)  C2H6 (g) c) 0.86:1 d) 0.96:1
Using the data given below: 76) At 25C, the combustion of 1 mol of liquid
C2H4 (g) + 3O2 (g)  2CO2 (g) + 2H2O (l) benzene, the heat of reaction at constant pressure
H = -1415 kJ is given by
𝟕 𝟕
C2H6 (g) + 𝟐 O2 (g)  2CO2 (g) + 3H2O (l) C6H6 (l) + 𝟐 O2 (g)  6CO2 (g) + 3H2O (l)
H = -1566 kJ H = -780.980 cal
𝟏
H2 (g) + O2 (g)  H2O (l) H = -286 kJ
𝟐
Calculate the heat of reaction at constant volume
a) 780.086 kcal b) -782.470 kcal
a) -437 kJ b) +35 kJ
c) -390.043 kcal d) 390.043 kcal
c) -135 kJ d) none of these
77) For complete combustion of ethanol, C2H5OH (l)
69) A piston filled with 0.04 mol of an ideal gas
expands reversibly from 50.0 mL to 375 mL at a + 3O2 (g)  2CO2 (g) + 3H2O (l), the amount of
heat produced as measured in bomb calorimeter,
constant temperature of 37.0C. As it does so, it
absorbs 208 J of heat. The values of q and w for is 1364.47 kJ mol-1 at 25C. Assuming ideality the
the process will be )R = 8.314 J/mol K) (ln 7.5 = enthalpy of combustion, CH, for the reaction
2.01) will be (R = 8.314 J mol-1)
a) q = +208 J, w = +208 J a) -1350.50 kJ mol-1 b) -1366.95 kJ mol-1
-1
b) q = +208 J, w = -208 J c) -1361.95 kJ mol d) -1460.50 kJ mol-1
c) q = -208 J, w = -208 J 78) For the reaction X2Y4 (l)  2XY2 (g) at 300 K the
d) q = -208 J, w = +208 J values of U and S are 2.2 kcal and 20 cal K-1
70) The values of H and S of a certain reaction are respectively. The value of G for the reaction is
-400 kJ mol-1 and -20 kJ mol-1 K-1 respectively. a) -3400 cal b) 3400 cal
The temperature below which the reaction is c) -2800 cal d) 2000 cal
spontaneous is 79) Given R = 8.314 JK mol-1, the work done during
-1

a) 100 K b) 20C combustion of 0.90 kg of ethane (molar mass =

c) 20 K d) 120C

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(15) Cell: 8050063005
 30) at 300 K is 88) The species which by definition has zero
a) -18.7 kJ b) 18.7 kJ standard molar enthalpy of formation at 298 K is
c) 6.234 kJ d) -6.234 kJ a) Br2 (g) b) Cl2 (g)
80) Which among the following is a feature of c) H2O (g) d) CH4 (g)
adiabatic expansion? 89) Using the data provided, calculate the multiple
a) V < 0 b) U < 0 bond energy (kJ mol-1) of a C  C bond in c2H2.
c) U > 0 d) T = 0 That energy is (take the bond energy of a C – H
81) What is the amount of work done when two bond as 350 kJ mol-1):
moles of an ideal gas is compressed from a 2C (s) + H2 (g)  C2H2 (g); H = 225 kJ mol-1
volume of 1 m3 to 10 dm3 at 300 K against a 2C (s)  2C (g) ; H = 1410 kJ mol-1
pressure of 100 k Pa? H2 (g)  2H (g); H = 330 kJ mol-1
a) 99 kJ b) -99 kJ a) 1165 b) 837
c) 114.9 kJ d) -114.9 kJ c) 865 d) 815
82) In thermodynamics, a process is called reversible 90) The standard enthalpies of formation of CO2 (g),
when H2O (l) and glucose (s) at 25C are -400 kJ/mol, -
a) Surroundings and system change into each other 300 kJ/mol and -1300 kJ/mol respectively. The
b) There is no boundary between system and standard enthalpy of combustion per gram of
surroundings glucose at 25C is
c) The surroundings are always in equilibrium with a) +2900 kJ b) -2900 kJ
the system c) -16.11 kJ d) +16.11 kJ
d) The system changes into surroundings 91) For the process H2O (l)  H2O (g) at T = 100C
spontaneously and 1 atmosphere pressure, the correct choice is
83) One mole of a non-ideal gas undergoes a change a) S system > 0 and S surroundings > 0
of state (2.0 atm. 3.0L, 95K)  (4.0 atm, 5.0L, b) S system > 0 and S surroundings < 0
245 K) with a change in internal energy, U = c) S system < 0 and S surroundings > 0
30.0 L atm. The change in enthalpy (H) of the d) S system < 0 and S surroundings < 0
process in L atm is
a) 40.0 b) 42.3
c) 44.0
d) Not defined because pressure is not constant
84) The enthalpy of vaporization of a liquid is 30 kJ
mol-1 and entropy of vaporization is 75 Jmol-1.
The boiling point of the liquid at 1 atm is
a) 250 K b) 400 K
c) 450 K d) 600 K
85) Two moles of an ideal gas is expanded
isothermally and reversibly from 1 L to 10 L at
300 K. The enthalpy change (in kJ) for the
process is
a) 11.4 kJ b) -11.4 kJ
c) 0 kJ d) 4.8 kJ
86) The reaction A to B is not feasible but on
changing entropy through a series of steps:
ACDB
S (A  C) = 50 ev,
S (C  D) = 30 ev,
S (B  D) = 20 ev.
The entropy change A  B would be
a) 100 ev b) 60 ev
c) -60 ev d) -100 ev
87) For the process:
H2O (l) (1 bar, 373 K)  H2O (g) (1 bar, 373 K),
the correct set of thermodynamic parameters is:
a) G = 0, S = + ve
b) G = 0, S = - ve
c) G = + ve, S = 0
d) G = - ve, S = + ve

PARAMESHWAR SWAMY E-mail: prswamy3005@gmail.com

(16) Cell: 8050063005