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Date: 16th Dec 2018 Bakliwal Tutorials-IIT

Comprehensive 2020 B-Test 7 YOUR STRATEGIC MOVE

Total Time: - 3.00 hrs Sub: - Physics, Chemistry & Math Max. Marks: -360

SET-A
Rules & regulations for BTEST

1. Immediately fill in the particulars on this page of the Test Booklet with Ball Point Pen provided in the examination
hall.

2. The Answer Sheet (OMR) is provided separately. Please fill in the particulars carefully with Ball Point Pen or
HB pencil only.

3. The test is of 3 hours duration.

4. The Test Booklet consists of 90 questions. The maximum marks are 360.

5. There are three parts in the question paper consisting of Physics, Chemistry and Mathematics having 30 questions
in each part of equal weightage. Each question is allotted 4 (four) marks for correct response.

6. Candidates will be awarded marks as stated above in instruction No. 5 for correct response of each question. ¼
(one-fourth) marks of the total marks allotted to the question (i.e. 1 mark) will be deducted for indicating incorrect
response of each question. No deduction from the total score will be made if no response is indicated for an item in
the answer sheet.

7. There is only one correct response for each question. Filling up more than one response in any question will be
treated as wrong response and marks for wrong response will be deducted accordingly as per instruction 6 above.

8. No candidate is allowed to carry any textual material, printed or written, bits of papers, pager, mobile phone, any
electronic device, etc. except the Admit Card inside the examination room/hall.

9. Rough work is to be done on the additional sheets provided

11. On completion of the test, the candidate must immediately hand over the Answer Sheet to the Invigilator on duty
in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them.

12. The CODE for this Booklet is A. Make sure that the CODE is marked properly on the answer sheet.

13. Do not fold or make any stray mark on the Answer Sheet.

Name of student

Roll No

Exam Hall

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PHYSICS
SECTION - I
Single Correct Answer Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.

Q.1 One end of meter stick is pinned to a smooth table so that stick can rotate freely in a plane parallel to the table
surface. Two horizontal forces are applied to the stick such that the rod does not rotate at all. One force has a
magnitude of 2 N and is applied perpendicular to the stick at the free end. The other force has a magnitude of 8 N
and acts at 30 with respect to the length of the stick. At what distance from the pinned end is the 8 N force
applied?
(A) 50 cm (B) 60 cm (C) 70 cm (D) 80 cm

Solution : (A)

Q.2 Two identical rings each of mass m with their planes mutually perpendicular, radius R are welded at their point of
contact O. If the system is free to rotate about an axis passing through the point P perpendicular to the plane of the
upper ring, then moment of inertia of the system about this axis is equal to:

2 2
(A) 6.5mR (B) 12mR (C) 6 mR2 (D) 11.5 mR
2

Solution : (D)
I  I1  I 2
 mR 2 
 [2 mR 2 ]    m (3R) 2 
 2 

Q.3 Perpendicular axis theorem can’t be applied for:


(A) ring (B) cone (C) disc (D) rectangular plane
Solution : (B)
Perpendicular axes theorem can be applied only for 2 Dimensional bodies

Q.4 The S–shaped uniform wire shown in figure has a mass M and the radius of curvature of each half is R. The
moment of inertia about an axis through A and perpendicular to the plane of the paper is:

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3 3
(A) MR2 (B) M R 2 (C) MR2 (D) 2MR2
4 2
Solution : (D)

Q.5 If I represents the moment of inertia of a solid sphere about an axis parallel to the diameter of the solid sphere at a
distance x from it, then which of the following graphs represents the variation of I with x?

Solution : (C)

Q.6 A rigid body can be hinged about any point on the x–axis. When it is hinged such that the hinge is at x, the moment
of inertia is given by I  2 x 2  12 x  27 . The x–coordinate of centre of mass is
(A) x  2 (B) x  0 (C) x  1 (D) x  3
Solution : (D) M.O.I. about C.O.M. is minimum

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I  I C .M .  Mx02
I  2 x 2  12 x  27
dI
  4 x  12  0
dx
x 3

Q.7 A constant force acting at the centre of a uniform disc of radius r is always perpendicular to the plane of the disc.
The disc can rotate about a chord at a distance ‘x’ from the centre of the disc. For what value of ‘x’ will the angular
acceleration of the disc be maximum?
r r r r
(A) (B) (C) (D)
3 3 2 2
Solution : (C)
 axis Fx
  2
I axis  Mr 
  Mx 2 
 4 
d
For max imum  , 0
dx
r2
  x2  2x2  0
4
xr/2

Q.8 Two insects P and Q are firmly sitting at the ends of a massless semicircular wire of radius R and two more insects
A and B are firmly sitting at the bottom of the wire. The wire is given an angular velocity 0 about a vertical axis
through its Centre as shown in the figure. Mass of each insect is M. Now A and B crawl to the opposite ends to
meet P and Q. Final angular velocity attained by the wire is equal to:

0 0 0
(A) (B) (C) (D) 20
4 2
Solution: (B)
uur uur
Li  L f


(2 mR 2 ) 0  2mR 2  2mR 2  ' 
0
' 
2

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Q.9 A smooth tube of certain mass containing two identical balls is rotated as shown in gravity free space and released.
The two balls move towards ends of the tube. Which of the following quantity is not conserved.

(A) Angular momentum of the whole system about vertical axis as shown in figure
(B) Net linear momentum of the two balls
(C) Kinetic energy of the whole system
(D) Angular speed of the tube

Solution : (D)

Q.10 A smooth turn table with small smooth circular edge is rotating with angular velocity 0 about a vertical axis
passing through centre. A particle is projected horizontally on the table at angle 300 with radius as shown and
make elastic collision with edges, then the variation of angular velocity of table with time is :

Solution : (C)
Since table is frictionless and force of collision is passing through centre

Q.11 Two horizontal discs of different radii are free to rotate about their central vertical axes. One is given some
angular velocity, the other is stationary. Their rims are now brought is contact. There is friction between the rims.
Choose the correct option
(A) The angular Momentum of system is.conserved about point of contact of disc.
(B) The angular momentum of system is conserved about Centre of mass of any disc
(C) The rotational kinetic energy of the system will be conserved
(D) None of these
Solution : (D)
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Angular momentum is not conserved. Because we observed, due to friction there is a net force on the two
cylinders independently, but as the two are pivoted at centre, this pivots must apply an external force to keep the
two cylinders at rest. Thus about any point we observe, there must be some torque due to the forces by or on
pivots, thus in this case angular momentum is not conserved. Due to friction energy will not be conserved.

Q.12 A uniform ring is rolling without sliding on a horizontal plane with centre of mass moving with constant velocity
v. Number of points on the ring which has speed v at any instant, are :
(A) 1 (B) 2 (C) 3 (D) None of these
Solution : (B)

When angle between V and WR

1r 1200

Vnet  v2  v2  2v.v cos 120  V

There are two points

Q.13 As shown in figure, S is a point on a uniform disc rolling with uniform angular velocity on a fixed horizontal
surface. The only force acting on the disc are its weight and contact forces exerted by horizontal surface. Which
graph best represents the magnitude of the acceleration of point S as function of time?

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Solution : (C)

Q.14 A ring of radius R rolls without sliding with a constant velocity with respect to ground. The radius of curvature of
the path followed by any particle of the ring at the highest point of its path will be :
(A) R (B) 2R (C) 4R (D) none

Solution : (C)

Q.15 A spool is pulled horizontally on rough surface by two equal and opposite forces as shown in the figure. Which of
the following statements are correct?

(A) The centre of mass moves towards left


(B) The centre of mass moves towards right
(C) The centre of mass remains stationary
(D) The net torque about the centre of mass of the spool is zero
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Solution : (B)

Q.16 A thin uniform metallic triangular sheet of mass M has sides AB=BC=L. What is its moment of inertia about axis
AC lying in the plane of the sheet?

ML2 ML2 ML2 2ML2


(A) (B) (C) (D)
12 6 3 3
Solution : (A)

By symmetry

2 mL2 mL2
2I  I 
12 12

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Q.17 A circular disc of radius R is free to oscillate about an axis passing through a point on its rim and perpendicular to
its plane. The disc is turned through an angle of 600 with vertical and released. Its angular velocity when it reaches
the equilibrium position will be
g 2g 2g 2g
(A) (B) (C) (D) 2
3R 3R R R

Solution : (B)

PE at   60 0 is Mgh (1-cos θ) where h is the distance between the axis of rotation and the centre of mass of the disc. Gain
1
in KE when the disc reaches the equilibrium position  I  2 where
2

1 3
I  I C . M  Mx 2  MR 2  MR 2  MR 2 . Here x is the distance between the centre of mass and the axis of rotation, i.e.x
2 2
= R.

Now PE = KE gives

1 2 3
MgR(1– cos 600)  I   MR 2  2
2 4

Q h  R

2g
Which gives   , which is choice (b).
3R

Q.18 A disc of mass M and radius R is rolling with angular speed  on a horizontal plane as shown in Fig. The
magnitude of angular momentum of the disc about the origin O is

1 3
(A) MR 2 (B) M R 2  (C) MR 2 D) 2 M R 2 
2 2

Solution : (C)

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Refer to Fig let OC=RC and let vcbe the velocity of the centre of mass of the disc. The linear momentum of the
centre of mass is Pc=Mvc If Lc is angular momentum of the disc about C, then the angular momentum about origin O is
L0=Lc+Rc+Pc

∴ Magnitude L0  I C   RC  Mv c sin 

1
 MR 2  MRC vc sin 
2

 1 2 
Q I c  MR 
 2 

1
 MR 2  MR  R
2
Q Rc sin   R and vc  R 
3
 MR 2
2

Hence the correct choice is (c).

Q.19 A uniform rod AB of length l rotating with an angular velocity  while its centre moves with a linear velocity
l
v . If the end A of the rod is suddenly fixed, the angular velocity of the rod will be:
6

3   2
(A)  (B) (C) (D) 
4 3 2 3
Solution : (C)

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L ML2 ML2
Mv   , '
2 12 3

 L L ML2 ML2
M .  .  '
6 2 12 3


'
2

Q.20 A rigid cylinder rolls at constant speed without slipping on top of a fixed horizontal plane surface. The acceleration
of a point on the circumference of the cylinder at the moment when the point touches the plane is:
(A) directed forward (B) directed up (C) directed down (D) zero

Solution : (B)

Q.21 A hollow sphere and a solid sphere having equal mass and equal radii are rolled down without slipping on a rough
inclined plane.
(A) The two spheres reach the bottom simultaneously
(B) The hollow sphere reaches the bottom with lesser speed
(C) The solid sphere reaches the bottom with greater kinetic energy
(D) The two spheres will reach the bottom with same linear momentum
Solution: (B)

 
 g sin  
a 2 
1 k 
 
 R2 

k2 2
For solid sphere  
R2 5

2
For hollow sphere  mR 2  mk 2
3

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2
k 2
2

R 3
so k s  k H
then as  aH

(so speed of solid sphere is greater then hollow sphere)

Q.22 A thick walled hollow sphere has outer radius R. It rolls down an inclined plane without slipping and its speed at
the bottom is v. If the inclined plane is frictionless and the sphere slides down without rolling. Its speed at the
bottom is 5v/4. What is the radius of gyration of the sphere?
R R 3R 3R
(A) (B) (C) (D)
2 2 4 4
Solution : (C)

1 2 1 2 2
Case- 1 : mgh  mv  mk 
2 2

2
1  5v 
Case- 2 : mgh  m   
2 4

1 v2 1 1 25 v 2
mk 2 2  mv 2  m 
2 R 2 2 16

k2 25
1
R2 16

k2 9
2

R 16

3R
k
4

Q.23 In the figure shown, a solid small ball of mass ‘m’ can move without sliding in a fixed cylindrical track of radius
R in vertical plane. It is released from the top. The resultant force on the ball at the lowest point of the track is.

10mg 17mg 3m g
(A) (B) (C) (D) zero
7 7 7

Solution : (A)

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Q.24 A horizontal force F is applied at the top of an equilateral triangular block having mass m. The minimum
coefficient of friction required to topple the block before translation will be:

2 1 1 1
(A) (B) (C) (D)
3 3 3 2

Solution : (C)

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Q.25 A plank of mass M is placed over smooth inclined plane and a sphere is also placed over the plank. Friction is
sufficient between sphere and plank. If plank and sphere are released from rest, the frictional force on sphere is

(A) up the plane (B) down the plane


(C) horizontal (D) zero
Solution : (D)
Both the sphere and the plank will slide down with same acceleration g sin θ
   
Q.26 The angular velocity of a body is   2
i  3 j  4k and a torque T  i  2 j  3k acts on it. The rotational power
will be
(A) 20 watt (B) 15 watt (C) 17 watt (D) 14 watt

Solution : (A)
ur ur
P  T.  20 w

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Q.27 A T shaped object with dimensions shown in the figure is lying on a smooth floor. A force is applied at the point P
parallel to AB such that the object has only the translational motion without rotation. Find the location of P with
respect to C.

(A) (3/4)l (B) l (C) (4/3)l (D) (3/2)l

Solution : (C)
The force should pass through the centre of mass of the assembly

Q.28 An object of mass M and radius R is performing pure rolling motion on a smooth horizontal surface under the
action of a constant force F as shown in Fig. The object may be

(A) disk (B) ring (C) solid cylinder (D) hollow sphere

Solution : (B)

Q.29 A sphere is released on a smooth inclined plane from the top. When it moves down, its angular momentum is
(A) Conserved about every point
(B) Conserved about the point of contact only
(C) Conserved about the centre of the sphere only
(D) Conserved about any point on a line parallel to the inclined plane and passing through the centre of the ball
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Solution : (D)
As the inclined plane is smooth, the sphere can never roll, rather it will just slip down. Hence, the angular
momentum remains conserved about any point on a line parallel to the inclined plane and passes through the centre
of the ball

Q.30 In the pulley system shown, if radii of the bigger and smaller pulley are 2m and 1m, respectively. There is no
slipping between any pulley and string. If acceleration of block A is 5 ms-2 in the downward direction, then
acceleration of block B will be

(A) 0 ms2 (B) 5 ms2 (C) 10ms


2
(D)
5
ms 2
2
Solution (D)

CHEMISTRY
SECTION - I
Single Correct Answer Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.

Q1. 
For the reaction H2(g) + I2(g) 2HI(g), Kc = 66.9 at 350°C and Kc = 50.0 at 448°C. The reaction is

(A) exothermic (B) endothermic

(C) no change of enthalpy (D) sign of enthalpy cannot be predicted from given data

Solution: (A)

K is decreasing as T is increasing.

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Q2. 1.1 mol of A is mixed with 2.2 mol of B and the mixture is kept in a one litre flask till the equilibrium,
A  2B  2C  D is reached. At equilibrium 0.2 mol of C is formed. The equilibrium constant (Kc) of the
above reaction is

(A) 0.002 (B) 0.004 (C) 0.001 (D) 0.003

Solution: (C)

Q3. 
The pressure of an equilibrium mixture of three gases NO, Cl2 and NOCl (2NO(g) + Cl2(g) 2NOCl(g)) is

suddenly decreased by doubling the volume of the container at constant temperature. When the system returns to
equilibrium

(A) the concentration of NOCl will have increased

(B) the value of equilibrium constant will have increased.

(C) the number of moles of Cl2 will have increased.

(D) the number of moles NO will have decreased.

Solution: (C)

Reaction shifts to that side where number of moles increases. In this case, it will be the backward reaction; so more
NO and Cl2 will be produced.

Q4. 
For the reversible reaction 2NO(g) + O2(g) 2NO2 (g),

Rate constant for forward reaction = 2.6 X 103 . Rate constant of backward reaction = 4.1. If a reaction mixture
contains 0.01 mole each of NO and O2 and 0.1 mole of NO2, then the reaction [using knowledge of law of mass
action]

(A) shifts in forward direction (B) shifts in backward direction

(C) is at equilibrium (D) is stopped.

Solution: (B)

Rate constant of forward reaction = 2.6 X 103

Rate constant of backward reaction = 4.1

K = 2.6 X 103/4.1 = 6.34 X 102


Q = (0.1)2/ [(0.01)2 (0.01)] =104; Q > K, backward direction.

Q5. Which of the following cannot act as buffer solution?

(A) 30 mL 0.1 M CH3COOH + 10 mL 0.3 M NH4OH

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(B) 10 mL 0.2 M Na2CO3 + 20 mL 0.2 M H2CO3

(C) 30 mL 0.1 M HCl + 10 mL 0.1 M H3PO4

(D) 10 mL 0.1 M NH4Cl + 5 mL 0.1 M NaOH

Solution: (C)

As it is a mixture of strong acid and weak acid.

Q6. The compressibility factor of a real gas is given by

160 P
Z  1  0.25 P  . The Boyle temperature of the gas is
T

(A) 298 K (B) 640° C (C) 470 K (D) 367° C

Solution: (D)

At Boyle temp., the gas behaves as ideal gas. So, Z = 1.

0.25P = 160P/T; T = 160/0.25 = 640 K = 367° C

Q7. 0.5 moles of a real gas present in a 10L vessel at certain temperature exert a pressure of 0.96 atm. Under similar
conditions, an ideal gas exerts a pressure of 1.0 atm. If volume of the gas molecules is neglected, what is the value
of van-der-Waals constant ‘a’ of the real gas?

(A) 4 (B) 16 (C) 32 (D) 20

Solution: (B)

 
Pressure correction n2a/V2 = 0.04; a = (0.04 10 10)/ (0.5 0.5) 
Q8. Three heat engines absorb 760 kJ heat from a source at 380 K and reject ( )650 kJ

( )560 kJ ( ) 504 kJ of heat respectively to a sink at 280 K. Find the correct order which describes the three
engines.

(A) reversible, irreversible, impossible. (B) irreversible, reversible, impossible.

(C) impossible, irreversible, reversible. (D) impossible, reversible, irreversible.

Solution: (B)

Max. possible efficiency = 1-(280/380) = 0.26

Efficiency of first engine = 1 – (650/760) = 0.14 [irreversible]

Efficiency of 2nd engine = 1 – (560/760) = 0.26 [reversible]

Efficiency of 3rd engine = 1 – (504/760) = 0.34 [Impossible]

Q9. At 90° C, pure water has [H+] = 10-6. Based on this, find the incorrect statement.

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(A) increasing the temperature increases the degree of ionization of water.

(B) at 90° C, pH of pure water will be 7.

(C) at 90° C, pH of a 10-6 M HCl solution will be slightly less than 6.

(D) ionic product of water at 90° C is 10-12.

Solution: (B)

Q10. A solution is a mixture of 0.05M NaCl and 0.05 M NaI. The concentration of iodide ion in the solution when AgCl
just starts precipitating is equal to:

K sp AgCl  11010 M2 ;Ksp AgI  4 1016 M2 

(A) 4  1 0  6 M (B) 2  10 8 M (C) 2  1 0  7 M (D) 8  1 0  1 5 M

Solution: (C)

Q11. Two buffers of (X) and (Y) having pH 4.0 and 6.0 respectively are prepared from acid HA and the salt NaA. Both
the buffers are 0.5 M in HA. What is the ratio of concentration of salt in X and Y? (KHA = 1.0 10-5) 
(A) 1 (B) 0.01 (C) 0.5 (D) 2

Solution: (B)

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Q12. Which of the following act as a BrÖnsted acid as well as BrÖnsted base?

(A) Na2CO3 (B) OH  (C) P O 43  (D) HCO3

Solution: (D)

Q13. 
Saccharin Ka = 2 10
12

is a weak acid respectively by formula HSaC. 4  1 0  4 m o l of saccharin is dissolved in

200cc water of pH 3. Assuming no change in volume, calculate the concentration of saccharin ions SaC in the  
resulting solution at equilibrium.

(A) 2 1012 M (B) 3  1012 M (C) 4 1012 M (D) 5  10 12 M

Solution: (C)

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Q14. Aniline behaves as a weak base. When 0.1 M, 50 mL solution sample of aniline was mixed with 0.2 M, 12.5 mL
solution of HCL, the pH of resulting solution was 8. Then pH of 0.01 M solution of its chloride salt will be

(A) 3 (B) 4 (C) 5 (D) 6

Solution: (C)

Q15. How much water must be added to 10 L of 0.2 M of HA for its degree of ionization to be doubled?
K a 1.8 106 

(A) 10 L (B) 30 L (C) 40 L (D) infinite dilution needed

Solution: (B)

Q16. At 500 K for an isobaric process, ΔSsystem = -10 kJ mol-1 K-1, ΔSsurr = 12 kJ mol-1 K-1. ΔG for the process is

(A) -500 kJ/ mol (B) -1000 kJ/ mol

(C) -600 kJ/ mol (D) -1100 kJ/ mol

Solution: (B)

ΔSUniverse = ΔSsystem + ΔSsurr = 2 kJ mol-1 K-1

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ΔG = -TΔSUniverse = 1000 kJ/ mol

Q17. Two solid compounds X and Y dissociates at a certain temperature as follows


X(s) A (g) + 2B (g) KP1 = 9 10-3atm
 

Y (s) 2B (g) + C (g) KP2 = 4.5 10-3atm
 
The total pressure of gases over a mixture of X and Y is:

(A) 4.5 atm (B) 0.45 atm (C) 0.6 atm (D) None of these

Solution: (B)

Q.18 Rate of diffusion of ozonized oxygen is 0.4 5 times that of pure oxygen. What is the percentage degree of
association of oxygen to ozone assuming pure O2 in the sample initially?

(A) 20 (B) 40 (C) 60 (D) None of these

Solution: (C)

Q.19 In conversion of limestone to lime,

CaCO3 (s) 
 CaO (s) + CO2 (g)

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The values of ΔH° and ΔS° are +179.1 kJ/mol and 160.2 J/K respectively at 298K and 1 bar. Assuming that
ΔH°and ΔS° do not change with temperature above which temperature conversion of limestone to lime will be
spontaneous is:

(A) 1008K (B)1200K (C) 845K (D) 1118K

Solution: (D)

Q.20 pH of an aqueous solution of NaCl at 85°C should be:

(A) 7 (B) >7 (C) <7 (D) 0

Solution: (C)

Q.21 A certain solution has a hydrogen ion concentration 4  1 0  3 M . For the indicator thymol blue, pH is 2.0 when half
the indicator is in unionized form. Find the % of indicator in unionized form in the solution with

H   4 103 M. log2  0.3.log2.5  0.4

(A) 20 (B) 28.5 (C) 25.5 (D) 32.5

Solution: (B)

Q.22 If λ0 is the threshold wavelength of a metal for photoelectric emission and λ is the wavelength of light falling on
surface causing photoemission, then de Broglie wavelength of the emitted electron is

1/ 2 1/2
 h0   h(  0 ) 
(A)   (B)  
 2mc(0   )   2mc0 ) 
1/2
 h  
1/ 2
 h(0   ) 
(C)  0  (D)  
 2 mc   2mc0 ) 
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Solution: (A)

hc hc 1 1 (   )
  KE; KE  hc(  )  hc 0
 0  0 0
1/2
h  h0 
DB   
2.m.KE  2mc(0   ) 

Q23. If the Li atom had electronic configuration of 1s 3 instead of 1s 2 2s1 , it would have been more stable as energy of 1s
is lower than that of 2s . Yet this does not happen, because 1s 3 configuration violates

(A) Bohr’s theory (B) Hund’s rule

(C) Pauli’s principle (D) Aufbau principle

Solution: (C)

Q24. When two moles of Hydrogen atoms join to form one mole of hydrogen molecules in a rigid vessel

H  g   H  g   H2  g 

(A) w  0 (B)  U  negative (C) qsystem  positive (D) qsurrounding  negative

Solution: (B)

Q25. Equal volumes of 10% (v/v) of HCl are mixed with 10% (v/v) NaOH solution. If density of pure NaOH is 1.5
times that of pure HCl, then the resultant solution will be

(A) basic (B) neutral

(C) acidic (D) can’t be predicted

Solution: (A)

Q26. A2 + 2B2 
A2B4; 3/2A2 + 2B2 
A3B4

When A2 is limited it gives A2B4while in excess it gives A3B4. A2B4gets converted to A3B4 by reaction with A2.
Predict the composition of the reaction mixture when 4 mole A2 react with 4 mole B2.

(A) A3B4 = 2, A2 =1 (B) A2B4 = 2, B2 =1

(C) A2B4 = 0.5, A3B4 = 0.5 (D) A2B4 = 0.5, A3B4 = 0.5, B2 = 1

Solution: (A)

Q27. If Hund’s rule were not there (but Aufbau and Pauli principles are followed), B2 molecule would have been

(A) paramagnetic with total spin 1 (B) paramagnetic with total spin 2

(C) paramagnetic with total spin ½ (D) diamagnetic

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Solution: (D)

Q28. On a recently discovered planet, it was found that ideal gases obey the equation P.e V  nC T . A curve is plotted
for 2 mole gas at 500 K between 1 L and 10 L volume. Find the value of gas constant C (in L-atm mol-1 K-1) on
this planet.

(A) e (B) e/1000 (C) 0.001 (D) 0.0821

Solution: (B)

when V = 1, P =1

So, 2*C*500 = e; C = e/1000

Q29. Dipole moment of chlorobenzen (A) is 1.5 D. Dipole moment of hexachlorobenzen (B) will be

(A) 9 D (B) 0.25 D C) 1.5 D (D) O

Solution: (D)

Q30. Which statement is correct about H3BO3in aqueous solution?

(A) it is an Arhenius acid (B) it is a tribasic acid

(C) it is a Lewis acid (D) it is Bronsted base

Solution: (C)

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MATHS
SECTION - I
Single Correct Answer Type
This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.
1.    
If 1,log9 31 x  2 ,log 3 4.3x  1 are in A. P. then x equals
(A) log34 (B) 1 – log34 (C) 1 – log43 (D) log43

Solution : (B)
  
2, log9 31 x  2  1  log3 4.3x  1 
 log3 31 x  2  log 3  4.3  1
3
x

 31 x  2  3(4.3x  1)
3
  2  12.3x  3
3x

let 3x  t   2  12  3
t
3
  12t  5
t
 12t 2  5  3  0
1 3
 t  ,
3 4
3
 3x 
4
3
 x  log3  1  log3 4
4

2. Find the circumradius of the the triangle whose vertices are (8, 6), (8, –2) and(2, –2).

(A) 5 (B) 4 (C) 3 (D) 6

Solution: (A)

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3. If  but  2 = 5  –3 and 2 = 5 – 3 then the equation whose roots are  and



is
 

(A) 3x2 – 25x + 3 = 0 (B) X2 + 5x – 3 = 0 (C) x2 – 5x + 3 = 0 (D) 3x2 – 19x + 3 = 0

Solution: (D)
,  are roots of the equation x2 = 5x – 3

 x 2  5 x  3  0 /\ 
    5,    3
 
 whose roots one and is
 
    
x2     x  0
   
 2   2 
 x 2    x 1  0
  
     2  2   
 x 2    x 1  0
  
 
 25  6 
x2    x 1 0
 3 
3 x 2  19 x  3  0
Answer : D

Q. 4 The sum of integers from 1 to 100 that are divisible by 2 or 5 is


A) 3000 (B) 3050 (C) 3600 (D) 3250

Solution: (B)
Set of numbers divisible by 2  {2, 4, 6,      ,100}
Set of numbers divisible by 5  {5,10,15,      ,100}
Set of numbers divisible by both 2  5  {10, 20,     ,100}
50
Sum of number divisible by
2  2  100 
2
 25 X 102  2550
20
Sum of number divisible by
5  5  100   10 X 105
2
 1050
10
Sum of number divisible by 10  10  100   5 X 110  550
2
Required sum = 2550 + 1050 – 550 = 3050

5. The sum of first n terms of the series


n (n  1) 2
12  2.2 2  3 2  2.4 2         is
2
When n is even. When n is odd the sum is

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2
n (n  1) 2 n 2 (n  1) 3n (n  1)  n(n1) 
(A) (B) (C) (D)  
4 2 2  2 

Solution : (B)
When n is odd, (n + 1) is every and nth term will be n2
 Sn  S n1  n
 n  1 (n  1  1)2
  n2
2
2
 n  1 n  n 1 
  n2  n2   1
2  2 
n 2 (n  1)

2

6. The set S  {1, 2,3,      ,12} is to be partitioned into three sets A, B, C of equal size. Thus
A  B  C  S and A  B  B  C  C  A   . The number of ways to partition S is
12! 12! 12! 12!
(A) 3 (B) 4 (C) 3 (D) 4
 4!  4! 3! 4! 3! 4!
Solution: A
Number of ways =
12C4 X 8C4 X 4C4
12!
 3
 4!
Answer : A

7. The sum of the series 20C0  20C1  20C2  20C3  .........  20C10 is
1 20
(A) 0 (B) 20C10 (C)  20C10 (D) C10
2
Solution:(D)
(1  x)20  20C0  20C1 x  20C2 x2              20C20 x20
Put x = –1, we get
0  2 0 C 0  2 0 C 1  2 0 C 2          2 0 C 10  2 0 C 1 1  20 C 12        2 0 C 20
 2 0 C 0  2 0 C 1  2 0 C 2      2 0 C 9  2 0 C1 0  2 0 C 9  2 0 C 8  2 0 C 7        2 0 C 0  0


 2 20 C0  20 C1  20 C 2      20C 9  20 C10  0 
1 1
 20C0  20 C1  20 C 2      20 C 9  20 C10   20 C10  20 C10  20 C10
2 2
Answer : D

8. If
1 1 1
D  1 1 x 1 for x  0, y  0
1 1 1 y
Then D is
(A) Divisible by x but not by y (B) Divisible by y but not by x
(C) Divisible by neither x nor y (D) Divisible by both x and y
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Solution:
C 2  C 2  C1
C 3  C 3  C1

1 1 1 1 0 0
1 1 x 1  1 x 0
1 1 1 y 1 0 y
 xy
Answer : D

9. Find the equation to the straight line which passes through the point (– 4, 3) and is such that the
portion of it between the axes is divided by the point in the ratio 5 : 3.
(A) 9x – 20y + 96 = 0 (B) 2x – y + 11 = 0
(C) 2x + y + 5 = 0 (D) 3x – 2y + 7 = 0

Solution: (A)

10. A triangle with vertices (4, 0), (–1,–1) (3,5) is


(A) Isosceles and right angled (B) Isosceles but not right angled
(C) Right angled but not isosceles (D) Neither right angled nor isosceles
Solution: A

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11. The lines 2x –3y = 5 and 3x – 4y = 7 are diameters of a circle having area as 154 sq. units. Then the equation of
22
circle is (Take   )
7
(A) x 2  y 2  2 x  2 y  4 7 (B) x 2  y 2  2 x  2 y  4 7
(C) x 2  y 2  2 x  2 y  6 2 (D) x 2  y 2  2 x  2 y  6 2

Solution: (B)
2 2
r 2  154  Xr  15 y
7
 r 2  7 X 7  r  7
Centre is the point of intersection of lines
2x  3 y  5 
  1,1
and 3x  4 y  7 
eq. of circleis
 x  12   y  12   7 2
 x2  y 2  2 x  2 y  47

12. The solution set of the inequetion


1  log 1 x 2

 x  1  0 is
3
(A) (, 2)  (1, ) (B)   1, 2  (C)  2, 1 (D)   ,  
Solution : (C)
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 2

log 1 x  x  1  1
3
1
1
 O  x 2  x  1   
 3
1
1
 x 2  x  1  0 and x 2  x  1   
3
 x  R  x 2  x  1  3
 x 2  x  2  0
  x  2  x  1  0
 x   2, 1

Q.13 The solution set of | x 2  5 x  7 |  | x 2  5 x  1 4 | 2 1 is


(A )   2, 7  (B)   ,  2  U [7,  ) (C) [7,  ) (D ) (  ,  2]

Solution: (A)

Q.14 If both the roots of the quadratic equation x 2  2 k x  k 2  k  5  0 are less than 5, then K lies in the
interval

(A) 6,  (B) 5,6 (C)  4,5 (D) ,4


Solution: (D)

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Q.15 The equations of the perpendicular bisector of the sides AB and AC of a DABC are x – y + 5 = 0
and x + 2y = 0 respectively. If the point A is (1, –2) then the equation of the line BC is :

(A) 14x + 23y = 40 (B) 14x – 23y = 40 (C) 23x + 14y = 40 (D) 23x – 14y = 40

Solution: (A)

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Q.16 The distance of the point (2, 3) from the line 2 x - 3y + 9 = 0 measured along a line x - y + 1 = 0 is
:

(A) 5 3 (B) 4 2 (C) 3 2 (D) 2 2

Solution: (B)

n n
Q.17 If S  1 r tn
n n r 0 Cr
and t n  
r 0
n
Cr
then
Sn
is

1 1 2n  1
(A) n  1 (B) n  1  C n  D
2 2 2
Solution: (C)

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0 1 2 n 1 n
t n  n  n  n  ......  n n
C0 C1 C2 Cn 1 Cn
n n 1 1 n
 tn  n
  ......  
C0 n C1 n
Cn 1 n C0
 1 1 1 
 2t n  n  n  n  .....  n 
 C0 C1 Cn 
 2t n  n.sn
tn n
 
Sn 2

Q.18 Let a, b, c be any real numbers. Suppose that there are real numbers x, y, z not all zeros such that

x  cy  bz, y  az  cx, z  bx  ay then a 2  b2  c2  2abc is equal to


(A) 1 (B) 2 (C) -1 (D) 0
Solution: (A)
x  cy  bz  0
cx  y  az  0 has a non trivial solution
bx  ay  z  0 if
1 c b
 c 1 a 0
b a 1
 11  a 2   c  c  ab   b  ac  b   0
1  a 2  c 2  abc  abc  b 2  0
 a 2  b 2  c 2  2abc  1

Q.19 Find the equation of the bisector of the acute angle between the lines 3x – 4y + 7 = 0 and

12x + 5y – 2 = 0.

(A) 11x – 3y + 9 = 0 (B) 3x + 11y – 13 = 0


(C) 3x + 11y – 3 = 0 (D) 11x – 3y + 2 = 0

Solution: (A)

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Q.20 If the pair of straight lines x 2  2 pxy  y 2  0 and x 2  2 qxy  y 2  0 be such that each pair bisects the angle between
the other pair then,
(A ) p   q (B) pq  1 (C ) p q   1 (D ) p  q
Solution: (C)

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Q.21 The lines ax + by + c = 0, wher e 3a + 2b + 4c = 0 are concurrent at the point:

 1 3 3 1
(A)  ,  (B) (1, 3) (C) (3, 1) (D)  , 
 2 4  4 2

Solution: (D)

Q.22 Given the points A(0, 4) and B(0, -4), the equation of the locus of the point P

(x, y) such that AP  BP  6 is:

(A) 9x 2 - 7y 2 + 63 = 0 (B) 9x 2 - 7y 2 - 63 = 0
(C) 7x 2 - 9y 2 + 63 = 0 (D) 7x 2 - 9y 2 - 63 = 0

Solution: (A)

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Q.23 The value of ‘a’ for which one root of the quadratic equation

a 2
 5a  3  x 2   3a  1 x  2  0 is twice as large as the other is

2 1 1 2
(A) (B) (C) (D)
3 3 3 3
Solution: (D)

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Q.24 The area of a triangle is 5. Two of its vertices are (2, 1) and (3, –2). The thir d vertex lies on y = x
+ 3. Find the third vertex.

 7 13   3 13   3 3  7 3
(A)  ,  (B)  ,  (C)  ,  (D)  , 
2 2  2 2   2 2  2 2

Solution: (A)

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Q.25 The no. of ways in which 6 men and 5 women can dine at a round table if no two women are to sit together is
given by
(A ) 30 (B ) 5!  4! (C ) 7 !  5! (D ) 6!  5!
Solution: (D)

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256
Q.26 The number of integral terms in the expansion of  385 
(A) 33 (B) 34 (C) 35 (D) 32
Solution: (A)

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Q.27 The combined equation of the bisectors of the angle between the lines r epr esented by (x 2 + y 2 ) =
4xy is

(A) y 2 – x 2 = 0 (B) xy = 0
x 2  y 2 xy
(C) x 2 + y 2 = 2xy (D) 
3 2

Solution: (A)

Q.28 2 ta n 5 0 o  tan 2 0 o is equal to

(A) tan 20o (B) tan50o (C) tan70o (D) cot 70o
Solution: (C)

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Q.29 The equation of second degr ee x 2 + 2xy +y 2 + 4x + 4 y = 0 represents a pair of straight lines. The
distance between them is

4
(A) 4 (B) (C) 2 2 (D) 2 3
3

Solution: (C)

Q.30 Locus of centroid of the triangle whose vertices are  a cost, a sin t  ,  b sin t,  b cost  and 1,0
where t is parameter is

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2 2
 A   3x  1   3y   a 2  b 2
2 2
 B   3x  1   3y   a 2  b 2
2 2
 C   3x  1   3y   a 2  b 2
2 2
 D   3x  1   3y   a 2  b 2
Solution: (A)

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