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dlp.allen.ac.in, dsat.allen.ac.in
1. Locus of the points which are at equal distance 1. ml fcUnq dk fcUnq i Fk tks fd ljy js [ kkvks a
from 3x + 4y -11 = 0 and 12x + 5y + 2 = 0 and 3x + 4y -11 = 0 o 12x + 5y + 2 = 0 ls leku nw j h ij
which is near the origin is fLFkr gS ,oa ewy fcUnq ds lehi g]S
(1) 21x - 77y + 153 = 0 (2) 99x + 77y - 133 = 0 (1) 21x - 77y + 153 = 0 (2) 99x + 77y - 133 = 0
(3) 7x - 11y = 19 (4) None of these (3) 7x - 11y = 19 (4) buesa ls dksbZ ugha
2. From the origin chords are drawn to the circle 2. ewy fcUnq ls gksdj tkus okyh] o`Ùk (x - 1)2 + y 2 = 1 dh
(x - 1)2 + y 2 = 1 . The equation of the locus of the thokvksa ds e/; fcUnqvksa dk fcUnqiFk gS
middle points of these chords is (1) x 2 + y 2 - 3x = 0 (2) x 2 + y 2 - 3y = 0
(1) x 2 + y 2 - 3x = 0 (2) x 2 + y 2 - 3y = 0
(3) x 2 + y2 - x = 0 (4) x 2 + y2 - y = 0
(3) x 2 + y 2 - x = 0 (4) x 2 + y2 - y = 0
3. The equation of the common tangent to the 3. oØ y2 = 8x rFkk xy = –1 dh mHk;fu"B Li'khZ dk lehdj.k
curves y 2 = 8x and xy = –1 is gS
(1) 3y = 9x + 2 (2) y = 2x + 1 (1) 3y = 9x + 2 (2) y = 2x + 1
(3) 2y = x + 8 (4) y = x + 2 (3) 2y = x + 8 (4) y = x + 2
x2 x2
4. Tangent is drawn to ellipse + y2 = 1 4. nh?kZo`Ùk + y 2 = 1 ds fcUnq (3 3cos q, sinq) ij Li'khZ
27 27
at (3 3cos q, sinq) where qÎ (0, p/2) . Then the [khaph x;h gAS tgk¡ qÎ (0, p/2) rc q ds fdl eku ds fy,
value of q such that sum of intercepts on axes Li'khZ }kjk v{kksa ij dkVs x;s var%[k.Mks dk ;ksx U;wure gksxk
made by this tangent is minimum, is (1) p/3 (2) p/6
(1) p/3 (2) p/6 (3) p/8 (4) p/4
(3) p/8 (4) p/4
Kota/00DE314025 1/32
Target : JEE (Main) 2015/08-02-2015
1 1 1 1
5. 4tan -1 - tan -1 is equal to 5. 4tan -1 - tan -1 cjkcj gS %&
5 239 5 239
p p
(1) p (2) (1) p (2)
2 2
p p p p
(3) (4) (3) (4)
3 4 3 4
6. If the angles of a triangle are in the ratio 4:1:1, 6. ;fn fdlh f=Hkqt ds dks.kksa esa 4:1:1dk vuqikr gks] rks f=Hkqt
then the ratio of the longest side to the perimeter dh lcls cM+h Hkqtk rFkk ifjeki dk vuqikr gksxk
is
(1) 3 : (2 + 3) (2) 1 : 6
(1) 3 : (2 + 3) (2) 1 : 6
7. What is the standard deviation of the following 7. fuEufyf[kr Js.kh dk ekud fopyu gS
series ekisa 0-10 10-20 20-30 30-40
Measurements 0-10 10-20 20-30 30-40
ckjEckjrk 1 3 4 2
Frequency 1 3 4 2
(1) 81 (2) 7.6 (1) 81 (2) 7.6
9. The function f(x) = (x 2 -1) | x 2 - 3x + 2 | +cos(| x |) 9. Qyu f(x) = (x 2 -1) | x 2 - 3x + 2 | +cos(| x |) x ds fdl
is not differentiable at eku ij vodyuh; ugha gS
(1) –1 (2) 0 (1) –1 (2) 0
(3) 1 (4) 2 (3) 1 (4) 2
2/32 Kota/00DE314025
Enthusiast Course/Score-II/08-02-2015
10. If f is an even function defined on the interval 10. ;fn f ,d varjky (–5, 5), esa ifjHkkf"kr le Qyu g]S rks
(–5, 5), then four real values of x satisfying the
æ x +1 ö
æ x +1 ö
lehdj.k f(x) = f ç ÷ dk larq"V djus okys x ds pkj
equation f(x) = f ç è x+2ø
÷ are
è x+2ø
okLrfod eku gksaxs
-3 - 5 -3 + 5 3 - 5 3 + 5 -3 - 5 -3 + 5 3 - 5 3 + 5
(1) , , , (1) , , ,
2 2 2 2 2 2 2 2
-5 + 3 -3 + 5 3 + 5 3 - 5 -5 + 3 -3 + 5 3 + 5 3 - 5
(2) , , , (2) , , ,
2 2 2 2 2 2 2 2
3 - 5 3 + 5 -3 - 5 5 + 3 3 - 5 3 + 5 -3 - 5 5 + 3
(3) , , , (3) , , ,
2 2 2 2 2 2 2 2
(4) -3 - 5, -3 + 5, 3 - 5, 3 + 5 (4) -3 - 5, -3 + 5, 3 - 5, 3 + 5
ò
x
ò
x
t dt t dt
p/2
11. The value of limp p/2
is :- 11. lim dk eku gS :-
x® sin(2x - p) x®
p sin(2x - p)
2 2
p p p p p p
(1) ¥ (2) (3) (4) (1) ¥ (2) (3) (4)
2 4 8 2 4 8
12. The radius of the cylinder of maximum volume, 12. vf/kdre vk;ru okys csyu dh f=T;k D;k gksxh tks R f=T;k
which can be inscribed in a sphere of radius R okys xksys ds Hkhrj lekfgr gks ldrk gS :-
is :-
2 2 3 3
2 2 3 3 (1) R (2) R (3) R (4) R
(1) R (2) R (3) R (4) R 3 3 4 4
3 3 4 4
13. The curve given by x + y = exy has a tangent 13. fdl fcUnq ij oØ x + y = exy dh Li'khZ y-v{k ds lekUrj
parallel to the y-axis at the point gksxh
(1) (0, 1) (2) (1, 0) (1) (0, 1) (2) (1, 0)
(3) (1, 1) (4) (–1, –1) (3) (1, 1) (4) (–1, –1)
Kota/00DE314025 3/32
Target : JEE (Main) 2015/08-02-2015
14. The vectors b and c are in the direction of 14. Lkfn'k b rFkk c Øe'k% mÙkj&iwoZ rFkk mÙkj&if'pe fn'kkvksa
north-east and north-west respectively and
esa lfn'k gaS rFkk |b|=|c|= 4 rc lfn'k d = c – b dk ifjek.k
|b|=|c|= 4. The magnitude and direction of the
rFkk fn'kk gS
vector d = c – b, are
(1) 4 2, mÙkj dh vksj (2) 4 2, if'pe dh vksj
(1) 4 2, towards north (2) 4 2, towards west
(3) 4, iwoZ dh vksj (4) 4, nf{k.k dh vksj
(3) 4, towards east (4) 4, towards south
15. If the lines 15. ;fn js[kk;sa
x - 1 y + 1 z -1 x -3 y - k z x - 1 y + 1 z -1 x -3 y - k z
= = = = = = and = =
and 2 3 4 1 1 1
2 3 4 1 1 1
intersect, then k = izfrPNsn djrh g]S rks k =
2 9 2 9
(1) (2) (1) (2)
9 2 9 2
(3) 0 (4) None of these
(3) 0 (4) buesa ls dksbZ ugha
16. Let f be a positive function. Let 16. ekuk f ,d /kukRed Qyu gS rFkk
I1 = ò x f {x(1 - x)} dx ,
k
I1 = ò x f {x(1 - x)} dx ,
k
1-k 1-k
I2 = ò f {x(1- x)} dx
k
f {x(1- x)} dx
k
I2 = ò 1-k
1-k
1 1
(3) (4) None (3) (4) dksbZ ugha
3 3
SPACE FOR ROUGH WORK
4/32 Kota/00DE314025
Enthusiast Course/Score-II/08-02-2015
18. If for a real number y, [y] is the greatest integer 18. ;fn fdlh okLrfod la[;k y, ds fy,
y, [y] og egÙke iw.kkZd
less than or equal to y, then the value of the 3p / 2
dk eku gS
(1) –p (2) 0
p p
p p (1) –p (2) 0 (3) - (4)
(3) - (4) 2 2
2 2
19. The solution of the differential equation 19. vody lehdj.k x dy + y dx - 1 - x 2 y 2 dx = 0 dk
x dy + y dx - 1- x 2y 2 dx = 0 is gy gS
(1) sin -1 xy = c - x (2) xy = sin(x + c) (1) sin -1 xy = c - x (2) xy = sin(x + c)
Kota/00DE314025 5/32
Target : JEE (Main) 2015/08-02-2015
22. The coefficient of x in the equation 22. lehdj.k x2 + px + q = 0 dks gy djrs le; x dk xq.kkad
x2 + px + q = 0 was taken as 17 in place of 13, 13 ds LFkku ij 17 j[k fn;k x;k] ftlls lehdj.k ds ewy
its roots were found to be –2 and –15. The roots
–2 rFkk –15 izkIr gq,A lehdj.k ds lgh ewy gaS :-
of the original equation are :-
(1) 3, 10 (2) –3, –10
(1) 3, 10 (2) –3, –10
(3) –5, –8 (4) None of these (3) –5, –8 (4) buesa ls dksbZ ugha
23. The number of triangles that can be formed by 23. 12 fcUnqvksa ds ,d leqPp; ls] ftuesa 7 lejs[kh; ga]S dqy
choosing the vertices from a set of 12 points, fdrus f=Hkqt cuk;s tk ldrs gaS
seven of which lie on the same straight line, is
(1) 185 (2) 175 (3) 115 (4) 105
(1) 185 (2) 175 (3) 115 (4) 105
24. The term independent of y in the expansion of 24. (y -1/6 - y1/3 ) 9 ds foLrkj esa y ls Lora= in gS
(y -1/6 - y1/3 ) 9 is (1) 84 (2) 8.4
(1) 84 (2) 8.4 (3) 0.84 (4) – 84 (3) 0.84 (4) – 84
25. If the system of equations, x + 2y – 3z = 1, 25. ;fn lehdj.k fudk; x + 2y – 3z = 1, (k + 3) z = 3,
(k + 3) z = 3, (2k + 1)x + z = 0 is inconsistent, (2k + 1)x + z = 0, vlaxr gks rks k dk eku gksxk :-
then the value of k is :-
(1) –3 (2) 1/2 (3) 0 (4) 2
(1) –3 (2) 1/2 (3) 0 (4) 2
é cos a sin a ù ék 0ù é cos a sin a ù ék 0ù
26. If A = ê ú and A adj A= ê ú, 26. ;fn A = ê – sin a cos a ú o A adj A= ê 0 k ú , rc
ë – sin a cos a û ë0 k û ë û ë û
then k is equal to :- k cjkcj gksxk :-
(1) 0 (2) 1 (1) 0 (2) 1
(3) sina cosa (4) cos2a (3) sina cosa (4) cos2a
27. If z1 = a + ib and z 2 = c + id are complex 27. ;fn z1 = a + ib o z 2 = c + id lfEeJ la[;k;sa bl çdkj
numbers such that | z1 | = | z 2 |= 1 and gaS fd | z1 | = | z 2 |= 1 o R(z1 z 2 ) = 0, rks lfEeJ la[;kvksa
R(z1 z 2 ) = 0, then the pair of complex numbers dk ;qXe w1 = a + ic o w 2 = b + id larq"V djrk gS
w1 = a + ic and w 2 = b + id satisfies
(1) | w1 |= 1 (2) | w 2 |= 1
(1) | w1 |= 1 (2) | w 2 |= 1
(3) R(w1 w 2 ) = 0, (4) mijksä lHkh
(3) R(w1 w 2 ) = 0, (4) All the above
SPACE FOR ROUGH WORK
6/32 Kota/00DE314025
Enthusiast Course/Score-II/08-02-2015
28. A vector n of magnitude 8 units is inclined to 28. 8 bdkbZ ifjek.k okyk ,d lfn'k n x-v{k ij 45°, y-v{k
x-axis at 45°, y-axis at 60° and an acute angle ij 60° rFkk z-v{k ij U;wudks.k cukrk gAS ;fn ,d lery
with z-axis. If a plane passes through a point
fcUnq ( 2, -1, 1) ls gksdj xqtjrk gS o n ds fy;s vfHkyEc
( 2, -1, 1) and is normal to n, then its equation
g]S rks lfn'k :i esa bldk lehdj.k gS
in vector form is
(1) r.( 2i + j + k) = 4 (2) r.( 2i + j + k) = 2 (1) r.( 2i + j + k) = 4 (2) r.( 2i + j + k) = 2
(3) r.(i + j + k) = 4 (4) None of these (3) r.(i + j + k) = 4 (4) buesa ls dksbZ ugha
29. The probability of a bomb hitting a bridge is 29. ,d iqy dks ce }kjk Vdjkus dh izkf;drk 1/2 gS ;fn iqy
1/2 and two direct hits are needed to destory it. Bhd 2 fu'kkus esa fxjrk gks] rks ;fn iqy ds u"V gksus dh izkf;drk
Find the least number of bombs required so that
0.9 ls vf/kd gks rks U;wure ceksa dh la[;k gksxh. :-
the probability of the bridge being destroyed is
greater than 0.9. :- (1) 1 (2) 2
Kota/00DE314025 7/32
Target : JEE (Main) 2015/08-02-2015
PART B - PHYSICS
31. The four identical capacitors in the circuit shown 31. uhps ifjiFk esa n'kkZ;s vuqlkj ifjiFk esa pkj le:i la/kkfj=
below are initially uncharged. The switch is then
tksfd izkjEHk esa vukosf'kr gAS igys dqUth dks fLFkfr A djrs gaS]
thrown first to position A, and then to position
B. After this is done: rFkk ckn esa fLFkfr B ij djrs gaAS blds djus ds i'pkr%
Note: V1,2,3,4 are the potential differences across uksV % V1,2,3,4, C1,2,3,4 ij foHkokUrj rFkk Q1,2,3,4, C1,2,3,4
C1,2,3,4 and Q1,2,3,4 are the final charges stored in
ij lapf;r vfUre vkos'k gAS
C1,2,3,4 respectively.
A B A B
C2 C2
+ +
v0 C1 C3 v0 C1 C3
C1=C2=C3=C4 C1=C2=C3=C4
C4 C4
(1) V1 = V0 (1) V1 = V0
(2) V1 > V2 > V3 >V4 (2) V1 > V2 > V3 >V4
(3) V1 +V2+V3 =V4=V0 (3) V1 +V2+V3 =V4=V0
(4) Q1 = 3Q3 (4) Q1 = 3Q3
8/32 Kota/00DE314025
Enthusiast Course/Score-II/08-02-2015
32. Current I is flowing through the two materials 32. fp=kuqlkj] fo|qr pkydrk s1 rFkk s2 ds nks inkFkksZa ls /kkjk
having electrical conductivities s 1 and s 2 çokfgr gksrh gaS rc] inkFkksZa dh laf/k fcUnq ij vkos'k dh ek=k
respectively (s1 > s2 ) as shown in the figure. gksxh &
The total amount of charge at the junction of
the materials is
I Î0 (1/s 2 – 1/s1 )
I Î0 (1/s 2 – 1/s1 ) (1) I Î0 (1/s2 – 1/s1) (2)
(1) I Î0 (1/s2 – 1/s1) (2) 4
4
(3) 4I Î0 (1/s2 – 1/s1 ) (4) none of these (3) 4I Î0 (1/s2 – 1/s1 ) (4) buesa ls dksbZ ugha
33. Three equal charges are placed at the corners of an 33. rhu leku vkos'k ,d leckgq f=Hkqt ds 'kh"kksZ ij O;ofLFkr
equilateral triangle. Which of the graphs below gAS f=Hkqt ds ry esa leku nwjh ij lefoHko i`"Bksa dk o.kZu
correctly depicts the equally-spaced equipotential
surfaces in the plane of the triangle? (All graphs have
dkSulk vkjss[k djsxk\ (lHkh vkjs[kksa dk ,dleku ieS kuk g)S
the same scale.) 4 4
4 4 3 3
3 3 2 2
2 2 1 1
1 1 0 0
0 0 -1 -1
-1 -1 -2 -2
-3 -2 -1 0 1 2 3 -3 -2 -1 0 1 2 3
-2 -2
-3 -2 -1 0 1 2 3 -3 -2 -1 0 1 2 3 (a) (b)
(a) (b) 4 4
4 4
3 3
3 3
2 2
2 2
1 1
1 1
0 0
0 0 -1 -1
-1 -1
-2 -2
-2 -2 -3 -2 -1 0 1 2 3 -3 -2 -1 0 1 2 3
-3 -2 -1 0 1 2 3 -3 -2 -1 0 1 2 3 (c) (d)
(c) (d) (1) a (2) b (3) c (4) d
(1) a (2) b (3) c (4) d
SPACE FOR ROUGH WORK
Kota/00DE314025 9/32
Target : JEE (Main) 2015/08-02-2015
34. A proton sits at coordinates (x, y) = (0, 0), and 34. ,d izksVkWu dk funsZ'kkad (0, 0) gAS ,d bysDVªkWu dk funsZ'kkad
an electron at (d, h), where d >> h. At time (d, h) gAS tgk¡ d >> h t = 0 le; ij ,d vKkr fo|qr
t = 0, a uniform electric field E of unknown
{ks= dks y-fn'kk esa pkyw fd;k tkrk gAS 'd' bruk vf/kd gS fd
magnitude but pointing in the positive y direction
izksVªkWu vkSj bysDVªkWu ds e/; vUrjfØ;k ux.; gAS leku le;
is turned on. Assuming that d is large enough
that the proton-electron interaction is negligible, ij nksuksa d.kksa dk y-funsZ'kkad cjkcj gksxk
the y coordinates of the two particles will be equal (1) tc y = h/2000
(at equal time)
(1) at about y = h/2000 (2) Kkr ugha dj ldrs D;ksafd E vKkr gAS
a a a a
+Q a +Q a
2a 2a
10/32 Kota/00DE314025
Enthusiast Course/Score-II/08-02-2015
36. The diagram shows magnetic field lines. We 36. fp= esa pqEcdh; {ks= js[kk,sa n'kkZ;h xbZ gAS ge Åij ls uhps
move from above to below and back. rFkk ihNs dh vksj pyrs gAS
Below shows the graph of variaton of mag- uhps pqEcdh; ¶yDl dk le; ds lkFk ifjorZu vkjs[k fn;k
netic flux with time. x;k gAS
(A) (A)
(B) (B)
(C) (C)
(D) (D)
Kota/00DE314025 11/32
Target : JEE (Main) 2015/08-02-2015
37. A conducting rod with resistance r per unit length 37. çfr bZdkbZ yEckbZ çfrjks/k r dh ,d pkyd NM+ ,d Å/okZ/kj
r r
is moving inside a vertical magnetic field B at speed pqEcdh; {ks= B eas pky v ls nks {kSfrt lekukUrj vkn'kZ
v on two horizontal parallel ideal conductor rails. pkyd jsyksa (rails) ij xfr djrk gaAS jsyksa ds fljsa çfrjks/k R
The ends of the rails are connected to a resistor
ls tqM+s gAS jsyksa ds e/; nwjh d gaAS NM+ rFkk jsyksa ds e/; dks.k
R. The separation between the rails is d. The rod
maintains a tilted angle q to the rails. Find the q gAS NM+ dks xfr'khy j[kusa ds fy, vko';d cká cy dh
external force required to keep the rod moving. x.kuk fdft,A
v v
B d B
d R R
q q
v v
2 2
Bd v B2 d 2 v B2 d 2 v B2 d 2 v
(1) F = (2) F = (1) F = (2) F =
(R + dr) (R + dr / sin q) (R + dr) (R + dr / sin q)
3 4
3 4
12/32 Kota/00DE314025
Enthusiast Course/Score-II/08-02-2015
39. A satellite of mass m is at a distance a from a 39. nz O ;eku M ds rkjs ls nz O ;eku m ds mixz g dh nw j h
star of mass M. The speed of satellite is u.
a g S A mixz g dh pky u g SA ekuk lkoZ f =d xq : Roh;
Suppose the law of universal gravity is
Mm Mm Mm
Mm fu;e F = –G ds LFkku ij F = –G 2.1 g]S tc
F = –G 2.1
instead of F = –G 2 , find the r 2
r
r r
speed of the statellite when it is at a distance b rkjs ls bldh nwjh b gS rks mixzg dh pky Kkr djks\
from the star.
æ 1 1 ö
æ 1 1 ö (1) u 2 + 2GM ç 1.1 - 1.1 ÷
(1) u + 2GM ç 1.1 - 1.1 ÷
2
èb a ø
èb a ø
æ 1 1 ö
æ 1 1 ö (2) u 2 + GM ç 1.1 - 1.1 ÷
(2) u + GM ç 1.1 - 1.1 ÷
2
èa b ø
èa b ø
æ 1 1 ö 2 æ 1 1 ö
2
u + GM ç 1.1 - 1.1 ÷
2 (3) u2 + GM ç 1.1 - 1.1 ÷
(3)
1.1 èb a ø 1.1 èb a ø
æ 1 1 ö 2 æ 1 1 ö
u2 +
2
GM ç 1.1 - 1.1 ÷ (4) u2 + GM ç 1.1 - 1.1 ÷
(4)
2.1 èb a ø 2.1 èb a ø
40. A single circular loop of radius 1.00 m carries 40. 1.00 eh- f=T;k ds ,d o`Ùkh; ywi esa 10.0 mA dh /kkjk
a current of 10.0 mA. It is placed in a uniform dk ogu gksrk gSa bls 0.500 T ifjek.k ds ,d le:i
magnetic field of magnitude 0.500 T that is
pqEcdh; {ks= esa j[kk x;k gSa] tks fd ywi ds ry ds lekukUrj
directed parallel to the plane of the loop as
suggested in the figure. The magnitude of the gSaA rc] pqEcdh; {ks= ds }kjk ywi ij vkjksfir vk?kw.kZ dk
torque exerted on the loop by the magnetic field ifjek.k gksxk&
is. (1) 1.57 × 10-2 N × m 10.0 0.500T
-2
(1) 1.57 × 10 N × m 10.0 0.500T (2) 3.14 × 10-2 N × m
(2) 3.14 × 10-2 N × m 1.00
(3) 6.28 × 10-2 N × m
(3) 6.28 × 10-2 N × m 1.00
(4) 9.28 × 10-2 N × m
(4) 9.28 × 10-2 N × m
SPACE FOR ROUGH WORK
Kota/00DE314025 13/32
Target : JEE (Main) 2015/08-02-2015
41. An impulse laser may be treated as a source of 41. ,d vkos x ys t j dks QksV ksu L=ksr ds leku ekuk tkrk g]Sa
photons that are emitted during the time interval
ml le;kUrjky esa mRlftZr gksr s gSa ] tks dh tc Qks V ks u
of the pulse which is followed by a time interval
when no photons are produced. Pulses are mRikfnr ugh gksrs gSa] O;kl d = 10 ekbØksu dh ,d ys tj
periodically repeated. A laser beam of diameter che Åij dh vks j vxz lj gSa rFkk ,d iryh ijr lrg
d = 10 microns is directed upward and is ds yEcor~ g aS] ftldk ijkorZ uka d r = 0.50 gSa ( ç;ks x
perpendicular to the thin foil surface which has
dk fp= nsf[k,A) lrg dk ijkorZukad] ijkofrZr ÅtkZ rFkk
an index of reflection r = 0.50 (see the sketch
of the experiment). The index of reflection of the çHkko ÅtkZ dk vuq i kr gaSA 0.13 ms dh ,d iYl dh
surface is the ratio of the reflected energy to the dq y ÅtkZ 10 J gSaA rc] ystj che ds çdk'k nkc ds }kjk
impact energy. A pulse with duration of 0.13 ms iwjh rjg ls ok;q esa fLFkr ijr (foil) ds VwdM+s dk nzO;eku
has a total energy of 10 J. What is the mass of
D;k gksx k ?
the piece of foil that can be supported in the air
solely by the light pressure of the laser beam?
14/32 Kota/00DE314025
Enthusiast Course/Score-II/08-02-2015
43. A river is flowing with velocity 5km/hr as shown 43. ,d unh 5km/hr osx ls izokfgr gks jgh gAS ,d uko fcUnq
in the figure. A boat starts from A and reaches A ls pydj foifjr fdukjs ij U;wure nwjh r; djds igq¡prh
the other bank by covering shortest possible gAS uko dk osx fLFkj unh esa 3km/hr gAS uko }kjk r; dh
distance . Velocity of boat in still water is 3km/
x;h nwjh gksxh
hr. The distance boat covers is.
B
B
b=300m
b=300m
A
A
(1) 500m (2) 400 2 m (1) 500m (2) 400 2 m
0.05mm 0.05mm
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46. A uniform rod AB of weight 100 N rests on a 46. ,d leku NM+ AB ftldk Hkkj 100 N gS og C ij
rough peg at C and a force F acts at A as shown fdyfdr gS vkjS og fojke esa gS tSlk fd fp= esa n'kkZ;k gSA
in figure. If BC = CM and tana = 4/3. The ;fn BC = CM gS vkjS tana = 4/3. C ij U;wure ?k"kZ.k
minimum coefficient of friction at C is dk eku gksxk
B B
C C
M F M F
A A
(1) 9/8 (2) 3/2 (3) 8/7 (4) 4/3 (1) 9/8 (2) 3/2 (3) 8/7 (4) 4/3
47. A light wave travels through three transparent materials 47. ,d izdk'k rjax] leku eksVkbZ dh rhu ikjn'khZ inkFkksZ ls xfreku
of equal thickness. Rank in order, from the highest gAS vf/kdre ls fudVre ds Øe esa viorZukadks n1, n2 rFkk
to lowest, the indices of refraction n1, n2 and n3. n3 dk Øe gksxk &
n1 n2 n3 n1 n2 n3
(1) n3 > n1 > n2 (2) n1 < n3 < n2 (1) n3 > n1 > n2 (2) n1 < n3 < n2
(3) n3 < n1 > n2 (4) n2 > n3 > n1 (3) n3 < n1 > n2 (4) n2 > n3 > n1
48. The diagram to the right shows the lowest four 48. fn;s x;s fp= esa] fdlh dkYifud ijek.kq esa bysDVªkWu ds fy,
energy levels for an electron in a hypothetical atom. fuEure pkj voLFkk,sa crkbZ xbZ gSA bysDVªkWu ijek.kq ds –1 eV
The electron is excited to the –1 eV level of the atom voLFkk rd mÙksftr gksrk gaS rFkk dsoy nks QksVksu mRlftZr djds
and transitions to the lowest energy state by emitting
;g fuEure voLFkk esa laØe.k djrk gaAS fuEu esa ls dkSulh
only two photons. Which of the following energies
could not belong to either of the photons? ÅtkZ] nksuksa QksVksuksa ls lEcfU/kr ugh gaS ?
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49. For the decay of nucleus, the possible reason 49. ukfHkd ds {k; ds fy, tks dkj.k lEHko ugha gS
which is not true
(1) cgqr vf/kd U;wVªkWu&izkVs kWu vuqikr
(1) Neutron proton ratio too high
(2) Neutron proton ratio too low (2) cgqr de U;wVªkWu&izkVs kWu vuqikr
(3) Size of nucleus very large (3) cgqr cM+k ukfHkd dk vkdkj
(4) Binding energy of nucleus is more than
(4) vius mRiknksa ls vf/kd ukfHkd dh cU/ku mGtkZ
that of its products
50. Objects A and B that are initially separated from 50. nks oLrq ; sa A vk Sj B iz kjEHk es a ,d nwl js ls vyx gAS oLrq;s
each other and well isolated from their ifjos'k ls foyfxr gAS oLrqvksa dks ,d nwljs ds rkih; lEidZ
surroundings are then brought into thermal esa yk;k tkrk gAS izkjEHk esa T A= 0ºC rFkk TB = 100ºC
contact. Initially TA= 0ºC and TB = 100ºC. The A dh fof'k"V mG"ek B ls de gAS dqN le; ds i'pkr~ fudk;
specific heat of A is less than the specific heat lkE;koLFkk esa vk tkrk gAS vafre rkieku gksxsa :
of B. After some time, the system comes to an
equilibrium state. The final temperatures are :
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51. Infinite numbers of blocks are placed on a table 51. vuUr la[;k esa CykWdksa dks ,d est ds i`"B ij fp=kkuqlkj j[kk
edge as shown in the diagram. x;k gAS
What is the minimum value of L so that the L dk U;wure eku] ftlls CykWd est ls fxjus ds fy, 'kq: gks
blocks are just going to topple over the table ? tkosA
(1) x/3 (2) 2x/5 (3) 3x/7 (4) 4x/9 (1) x/3 (2) 2x/5 (3) 3x/7 (4) 4x/9
52. A rod (AB) is attached to a fixed point (C) using 52. ,d NM+ (AB) fdlh fLFkj fcUnq (C) ij ,d gYdh jLlh
a light rope (AC). The other end of the rod (B) is (AC) ds iz;ksx ls tqM+h gAS NM+ dk nwljk fljk (B) cQZ ij
sitting on ice with negligible friction and the system
ux.; ?k"kZ.k ds lkFk j[kk gS rFkk fudk; fLFkj voLFkk esa gSA
is in stationary position. Which of the following can
be the equilibrium configuration of this system? bl fudk; ds fy, fuEu esa ls dkSulk lkE; vfHkfoU;kl esa
C gks ldrk gAS
C
A C A
A C A
(1) (2)
B
(1) (2)
B
B
B
C C
C C
A
A A A
(3) (4) (3) (4)
B B
B B
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53. A smooth sphere is moving on a horizontal
53. ,d fpduk xksyk ,d {kSfrt lrg ij osx lfn'k 3iˆ + ˆj ds
surface with velocity vector 3iˆ + ˆj immediately
lkFk] ,d Å/okZ/kj fnokj ls Vdjkus ls igys xfr'khy gAS fnokj]
before it hits a vertical wall. The wall is parallel
lfn'k ˆj ds lekukUrj gSa rFkk fnokj o xksys ds e/; izR;koLFkku
to the vector ˆj and the coefficient of restitution
1
1 xq.kkad gAS rks xksys ds fnokj ls Vdjkus ds ckn bldk osx
between the wall and sphere is . The velocity 3
3
vector of the sphere after it hits the wall is lfn'k gksxk &
1 1
(1) ˆi + ˆj (2) 3iˆ - ˆj (3) -ˆi + ˆj (4) ˆi - ˆj (1) ˆi + ˆj (2) 3iˆ - ˆj (3) -ˆi + ˆj (4) ˆi - ˆj
3 3
54. A simple pendulum of length L is constructed 54. yEckbZ L ds ,d ljy yksyd dks nzO;eku m ds fcUnqor fi.M
from a point object of mass m suspended by a rFkk nzO;ekujfgr Mksjh ds lkFk fdyfdr fcUnq }kjk yVdkdj
massless string attached to a fixed pivot point.
cuk;k tkrk gSA ,d [kqaVh dks nwjh 2L/3 ls lh/ks gh uhps dh
A small peg is placed a distance 2L/3 directly
below the fixed pivot point so that the pendulum vksj yxk;k tkrk gS rkfd yksyd fp=kkuqlkj>wy ldsA nzO;eku
would swing as shown in the figure below. The dks m/okZ/kj ls 5 fMxzh ij] NksM+ fn;k tkrk gAS bls viuh
mass is displaced 5 degrees from the vertical and izkjfEHkd fLFkfr ij vkus esa fdruk le; yxsxk\
released. How long does it take to return to its
fixed pivot point
starting position?
fixed pivot point
L
small peg
L
small peg
point object
of mass m
point object
of mass m Læ 2ö Læ 2 ö
(1) p çç 1 + ÷ (2) p ç 2+ ÷
Læ 2ö Læ 2 ö gè 3 ÷ø gè 3ø
(1) p çç 1 + ÷ (2) p ç 2+ ÷
gè 3 ÷ø gè 3ø
L æ 1ö Læ 1 ö
(3) p ç1 + ÷ (4) p ç 1+ ÷
L æ 1ö Læ 1 ö g è 3ø gè 3ø
(3) p ç1 + ÷ (4) p ç 1+ ÷
g è 3ø gè 3ø
SPACE FOR ROUGH WORK
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55. A small body slips, subject to the force of 55. ,d NksVk fi.M ?k"kZ.k cy gksus ds ckotwn Hkh fcUnq A ls fcUnq
friction, from point A to point B along two B rd leku f=T;kvksa ds nks oØh; i`"Bksa ds vuqfn'k fQlyrk
curved surfaces of equal radius, first along route
g]S igyk iFk 1 ds vuqfn'k rFkk nwljk iFk 2 ds vuqfn'k gAS
1, then along route 2. Friction does not depend
on the speed and the coefficient of friction on ?k"kZ.k pky ij fuHkZj ugha djrk gS rFkk nksuksa iFkksa ij ?k"kZ.k xq.kkad
both routes is the same. In which case will the leku gAS fdl fLFkfr esa B ij fi.M dh pky vf/kd gksxhA
body’s speed at B be greater?
56. The minimum value of ‘F’ so that block is in 56. ‘F’ dk og U;wure eku tksfd CykWd dks lkE;koLFkk esa j[krk
equilibrium is gS &
3 3
F F
60º 60º
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57. A block of mass M1 is hanged by a light spring 57. nzO;eku M1 ds ,d CykWd dks fdlh gYdh fLizax ftldk cy
of force constant k to the top bar of a reverse U- fu;arkd k }kjk nzO;eku M2 ds fdlh myVs U-Ýse ds xqVds
frame of mass M 2 on the floor. The block is
dh Nr ls yVdk;k gAS CykWd dks bldh lkE;koLFkk ls nwjh
pooled down from its equilibrium position by a
distance x and then released. Find the minimum x dk og U;wure eku Kkr djks rkfd myVk U-Ýse Q'kZ dks
value of x such that the reverse U-frame will {kf.kd :i ls NksM+ nsA
leave the floor momentarily. M2
M2 k
k
M1
M1
(1) x = (M1 + M2)g/k (2) x = (2M1 + M2)g/k
(1) x = (M1 + M2)g/k (2) x = (2M1 + M2)g/k
(3) x = (M1 + 2M2)g/k (4) x = M1g/k (3) x = (M1 + 2M2)g/k (4) x = M1g/k
58. A small ball is projected up a smooth inclined plane 58. ,d NksVh xsan dks fdlh fpdus ur lery ij Åij dh vksj
with an initial speed of 10m/s along the direction at izkjafHkd osx 10m/s ds lkFk <ky ds ikn ds fdukjs ls dks.k
30º to the bottom edge of the slope. It returns to the
30º ds vuqfn'k iz{ksfir fd;k tkrk gSA ;g fdukjs ij iqu%
edge after 2 s. The ball is in contact with the inclined
plane throughout the process. What is the inclination 2 s i'pkr vkrh gAS bl izfØ;k esa xsan ur lery ls lEidZ
angle of the plane? esa cuh jgrh gAS lery dk ur dks.k fMxzh esa fdruk gAS
(1) 15º (2) 60º (3) 37º (4) 30º (1) 15º (2) 60º (3) 37º (4) 30º
59. An ideal Carnot heat engine with an efficiency 59. vkn'kZ duksZV batu dh n{krk 30% gAS og xeZ mG"ek HkaMkj
of 30%.It absorbs heat from a hot reservoir at ls 727°C ij mG"ek vo'kksf"kr djrk gAS BaMs mG"ek HkaMkj dk
727°C. The temperature of the cold reservoir is rkieku gksxk
(1) 509°C (2) 427°C (3) 273°C (4) 218°C (1) 509°C (2) 427°C (3) 273°C (4) 218°C
60. The relative error in resistivity of a material where 60. izfrjks/k = 1.05 + 0.01 W
resistance = 1.05 + 0.01 W O;kl = 0.60 + 0.01 mm
diameter = 0.60 + 0.01 mm yEckbZ = 75.3 + 0.1 cm is
length = 75.3 + 0.1 cm is rks rRo dh izfrjks/kdrk esa lkisf{kd =wfV gksxh
(1) 0.04 (2) 0.40 (3) 0.08 (4) 0.01 (1) 0.04 (2) 0.40 (3) 0.08 (4) 0.01
SPACE FOR ROUGH WORK
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PART C - CHEMISTRY
61. Which of the following statements is not correct 61. (A), (B) rFkk (C) ds ckjs esa dkSulk dFku lR; ugha gS -
about (A), (B) and (C) -
CHO H
CHO H
H OH HOCH 2 CHO
H OH HOCH 2 CHO
CH 2OH OH
CH 2OH OH (A) (B)
(A) (B)
CH2OH CH2OH
OH H OH H
CHO CHO
(C) (C)
(1) A and B are enantiomers (1) ArFkk B çfrfcEc leko;oh gS
(2) A and C are identical (2) ArFkk C leku gS A
(3) B and C are enantiomers (3) BrFkk C çfrfcEc leko;oh gS
(4) A and C are enantiomers (4) ArFkk C çfrfcEc leko;oh gS
62. Decide the correct order of stability of following 62. fuEu iztkfr;ksa ds fy, LFkkf;Ro dk lgh Øe gS :-
carbocation :- Å Å
Å Å CH 2 CH 2
CH 2 CH 2
(a) (b)
(a) (b)
NO2
NO2
Å Å Å Å
CH 2 CH 2 CH 2 CH 2
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OH OH
conc. H 2SO4 / D conc. H 2SO4 / D
63. ¾¾¾¾¾® ? 63. ¾¾¾¾¾ ® ?
Number of possible product (s) formed in above mijksDr vfHkfØ;k esa laHko mRiknksa dh la [;k gksxh :-
reaction :- (1) 2 (2) 3
(1) 2 (2) 3 (3) 4 (4) 5
(3) 4 (4) 5
O O
I2/NaOH Ag - powder I2/NaOH Ag - powder
64. CH3–C–CH3 (A) D (C) 64. CH3–C–CH3 (A) D (C)
Yellow compound ihyk ;kSfxd
+ +
(B) (B)
Dil H2SO4/HgSO4 Dil H2SO4/HgSO4
D D
A, C & D are :-
A, C o D gaS :-
(1) Iodoform, Acetylene & Acetaldehyde
(1) vk;MksQkWeZ, ,lhfVyhu o ,lhV,fYMgkbM
(2) Sodium acetate, Ethyne & Acetone
(2) lksfM;e ,lhVsV, bFkkbu o ,lhVksu
(3) Iodoform, Ethyne & Butenyne (3) vk;MksQkWeZ, bFkkbu o C;qVhukbZu
(4) Sodium acetate, Ethyne & Butenyne (4) lksfM;e ,lhVsV, bFkkbu o C;qVhukbZu
65. By which of the following sequence of steps can 65. ,Ydksgksy RCH2CH2OH(X) dks RCH2CH2COOH(Y)
the alcohol RCH2CH2OH(X) be converted into esa fuEu esa ls dkSuls vfHkfØ;k Øe ds }kjk ifjofrZr fd;k
RCH2CH2COOH(Y)? tk ldrk gS ?
+ +
(1) X ¾PBr
¾ ¾¾® ¾H¾3O¾® Y
¾3 ® ¾KCN (1) X ¾PBr
¾ ¾¾® ¾H¾3O¾® Y
¾3 ® ¾KCN
(2) X ¾PBr
¾¾3 ® ¾¾® ¾H¾2 /¾
¾KCN Pt
®Y (2) X ¾PBr
¾¾3 ® ¾¾® ¾H¾2 /¾
¾KCN Pt
®Y
+ +
¾¾® ¾H¾3O¾® Y
(3) X ¾KCN ¾¾® ¾H¾3O¾® Y
(3) X ¾KCN
+ +
(4) X ¾HCN
¾¾® ¾¾¾® ¾H¾3O¾® Y
PBr3 (4) X ¾HCN
¾¾® ¾¾¾® ¾H¾3O¾® Y
PBr3
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the nitration will mainly take place at position – ukbVªhdj.k fuEu esa ls eq[;r% dkSulh fLFkfr ij gksxk –
(1) 1 (2) 2 (1) 1 (2) 2
(3) 3 (4) 4 (3) 3 (4) 4
67. Which of the following represent glyptal - 67. fuEu esa ls dkSu fXyIVy ds çnf'kZr djrk gS -
O O O O
(1) ––O–CH2–CH2–O–C C––– (1) ––O–CH2–CH2–O–C C–––
n n
O O O O
(2) ––NH–(CH ) –NH–C––(CH ) –C––– (2) ––NH–(CH ) –NH–C––(CH ) –C–––
2 6 2 4 2 6 2 4
n n
O O O O
O O
(3) O n (3) O n
O O
(4) N
n
(4) N
n
H H
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68. Which of the following are non reducing sugars- 68. fuEu esa ls dkuS lh vuvipk;h 'kdZjk gS -
CH2OH H OH CH2OH H OH
HO O OH HO O OH
H O OH H H O OH H
(i) OH H H (i) OH H H
H HH O H H HH O H
H OH CH2OH H OH CH2OH
CH2OH CH2OH
H O H H O H
H H
OH H OH H
OH OH
H OH O H OH O
HOH2C O HOH2C O
(iii) (iii)
CH 2OH CH 2OH
H H OH H H OH
OH H OH H
CH2OH H OH CH2OH H OH
H O H H O H
H OH H H H OH H H
OH H O H OH H O H
(iv) H
O OH (iv) H
O OH
OH OH
H OH CH2OH H OH CH2OH
(1) (i) & (iv) (2) (i), (ii) and (iv) (1) (i) & (iv) (2) (i), (ii) and (iv)
(3) (iii) (4) (iii) & (iv) (3) (iii) (4) (iii) & (iv)
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Cl2 /hn Alc. KOH (i) O3 Cl2 /hn Alc. KOH (i) O3
69. A B X 69. A B X
D (ii) H2 O/Zn D (ii) H2 O/Zn
X is - X gS -
(1) CHO – (CH2)3 – CHO (1) CHO – (CH2)3 – CHO
(2) CHO – (CH2)2 – CHO (2) CHO – (CH2)2 – CHO
(3) CHO – (CH2)3 – CH3 (3) CHO – (CH2)3 – CH3
(4) CHO – CHO (4) CHO – CHO
70. CH3NH2 + CHCl3 + 3KOH ® X + Y + 3H2O; 70. CH3NH2 + CHCl3 + 3KOH ® X + Y + 3H2O;
compounds X and Y are : ;kSfxd X rFkk Y gS :
(1) CH3CN + 3KCl (1) CH3CN + 3KCl
(2) CH3NC + 3KCl (2) CH3NC + 3KCl
(3) CH3CONH2 + 3KCl (3) CH3CONH2 + 3KCl
(4) CH3NC + K2CO3 (4) CH3NC + K2CO3
71. For an electron, with n = 3 has only one radial node. 71. n = 3 okys bysDVªkWu ds fy, ] dsoy ,d f=T; uksM gAS
The orbital angular momentum of the electron will be bysDVªkWu dk d{kh; dks.kh; laoxs gksxk
h h
(1) 0 (2) 6 2p (1) 0 (2) 6 2p
(4) 3 æç ö÷ (4) 3 æç ö÷
h h h h
(3) 2 2p (3) 2 2p
è pø
2 è 2p ø
72. For the reaction (1) and (2) : 72. (1) rFkk (2) vfHkfØ;k ds fy, %
A B+C ....(1) A B+C ....(1)
D 2E ....(2) D 2E ....(2)
Given K P : K P : : 9 : 1
1 2
fn;k x;k gaS K P : K P : : 9 : 1
1 2
If the degree dissociation of A and D be same then ;fn A rFkk D dh fo;kstu dh ek=k leku gks rks lkE;
the total pressure at equilibria (1) and (2) are in the (1) rFkk (2) ij nkc dk vuqikr fuEu gaS
ratio (Assume reaction are started with equal (;g ekudj fd vfHkfØ;k A rFkk D ds izkjEHk esa leku
number of moles of A and D). eksyksa dks fy;k x;k gaS)
(1) 3 : 1 (2) 36 : 1 (1) 3 : 1 (2) 36 : 1
(3) 1 : 1 (4) 0.5 : 1 (3) 1 : 1 (4) 0.5 : 1
SPACE FOR ROUGH WORK
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73. For the following parallel chain reaction. 73. fuEu lekUrj J`a[kyk vfHkfØ;k ds fy,
—1
—3 4B —1
10 s —3
s 4B
K 1=2×
=2×10
K1
A A
3C 3C
What will be that value of overall half-life of A in A dh lEiw.kZ v¼Z&vk;q dk eku fefuV esa D;k gksxkA
é [B] 16 ù é [B]t 16 ù
minutes? êGiven that [C] = 9 ú
t
ê fn;k x;k = ú
ë t û ë [C]t 9 û
693 693
(1) 693 (2) (1) 693 (2)
210 210
693 693 693 693
(3) (4) (3) (4)
30 7 30 7
74. In the Maxwellian distribution of molecular speeds, 74. esDlosy vkf.od osx forj.k ds vuqlkj
shown below
,d fuf'pr eku ls
vf/kd osx ;qDr
v.kqvksa dk va'k
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76. 3 mole of a mixture of FeSO4 and Fe 2 (SO 4 ) 3 76. vEyh; ek/;e esa FeSO4 vkjS Fe2(SO4)3 ds feJ.k ds 3 eksy
required 100 ml of 2M KMnO4 solution in acidic
dks 2M KMnO4 ds 100 mL vko';d gS rc feJ.k esa FeSO4
medium. Hence mole fraction of FeSO4 in the
mixture is dk eksy izHkkt gksxk &
3 2 3 2
(1) (2) (1) (2)
5 3 5 3
2 1
2 1 (3) (4)
(3) (4) 5 3
5 3
77. The face diagonal length of f.c.c. cubic cell is 77. (f.c.c. (Qyd dsUæh; fudk;) ?kuh; lsy esa Qyd fod.kZ
660 2 pm. If the radius of the cation is 110 pm, dh yEckbZ 660 2 pm gaAS ;fn /kuk;u dh f=T;k 110
the radius of the anion is pm g,S rks ½.kk;u dh f=T;k fuEu gaS :)
(1) 249 pm (2) 220 pm (1) 249 pm (2) 220 pm
(3) 608 pm (4) 176 pm (3) 608 pm (4) 176 pm
78. Identify the false statement : 78. vlR; okD; dks igpkfu;s&
(1) The volume of a solution cannot be less than (1) foy;u dk vk;ru] foy;u (nks nzoksa dk f}?kVdh;
the sum of volumes of the pure solvent and foy;u) dks cukusa esa iz;ksx fd, x;s 'kq¼ foyk;d o
solute used to prepare the solution (binary foys; ds vk;ruksa ds ;ksx ls de ugha gks ldrkA
solution of two liquids)
(2) fu;r T o P ij] vkn'kZ foy;u ds fy, DGmix vko';d
(2) At constant T and P, DGmix will be necessarily
negative for an ideal solution :i ls ½.kkRed gksxkA
(3) ,d vkn'kZ f}?kVdh; foy;u (p0A ¹ p0B ) ,d
(3) An ideal binary solution (p0A ¹ p0B ) cannot form
fLFkjDokFkh feJ.k ugha cuk ldrkA
an azeotropic mixture.
(4) f}?kVdh; foy;uksa esa vkn'kZokn ,d fu;e ds ctk;
(4) In binary solutions ideality is more of an
exception rather than a rule. ,d viokn vf/kd gAS
79. Which of the following ions will be most effective 79. As2S3 lksy dks Ldafnr djus eas fuEu esa ls dkSulk vk;u
in coaogulating the As2S3 sol : lokZf/kd izHkkoh gksxk &
(1) Fe3+ (2) Ba2+ (1) Fe3+ (2) Ba2+
(3) Cl– (4) PO 34- (3) Cl– (4) PO 34-
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80. A solution is 500 ml of 2 M KOH is added to 80. 500ml , 2m KOH dks 500 ml, 2 M HCl esa M+kyk tkrk
500 ml of 2 M HCl and the mixture is well shaken. gS rFkk feJ.k dks vPNh rjg fgyk;k tkrk gAS rkieku esa
The rise in temperature T1 is noted. The experiment o`f¼ T1 dks vafdr djrs gSA iz ;ksx dks izR;sd foy;u
is then repeated using 250 ml of each solution and 250 ml dke esa ysrs gq,] fQj nksgjkrs gS rFkk rkieku esa
rise in temperature T2 is again noted. Assume all o`f¼ T2 fQj ls vafdr djrs gAS ;g ekfu;s fd lkjh Å"ek
heat is taken by the solution foy;u }kjk xzg.k dj yh tkrh g]S rc &
(1) T1 = T2 (1) T1 = T2
(2) T1 is 2 times as large as T2 (2) T1 , T2 ls nqxquk gAS
(3) T2 is twice of T1 (3) T2 ,T1 dk nqxquk gAS
(4) T1 is 4 times as large as T2 (4) T1 , T2 ls pkj xquk gAS
81. Which of the following pair differ in geometry and 81. fuEu esa ls dkSulk ;qXe T;kfefr esa fHkUurk rFkk pqEcdh;
resemble in magnetic behaviour. O;ogkj esa lekurk n'kkZrk gS
(1) [Ni(CO)4 ] & [Ni(CN)4]2– (1) [Ni(CO)4 ] o [Ni(CN)4]2–
(2) [Be(H2O)4]2+ & [Zn(CN)4]2– (2) [Be(H2O)4]2+ o [Zn(CN)4]2–
(3) [Fe(CN)6]3– & [FeF6]3– (3) [Fe(CN)6]3– o [FeF6]3–
(4) [Fe(CO)5] & PCl5 (4) [Fe(CO)5] o PCl5
82. Which of the following will be optically inactive 82. fuEu esa ls dkSulk izdkf'kd vlØh; gksxk \
NH3 en en NH3 en en
H2O NH2 H2O NH2
CO CO CO CO
C5H5N OH2 C5H5N OH2
en en
C5H5N C5H5N
(A) (B) (A) (B)
(py) (py)
en en
H3N H2O H3N H2O
CO CO CO CO
NH3 NH3 NH3 NH3
(py) en en (py) en en
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83. Na and Li are placed in dry air. We get 83. 'kq"d ok;q esa Na rFkk Li dks j[kus ij izkIr gksrk gS
(1) NaOH, Na2O, Li2O (1) NaOH, Na2O, Li2O
(2) Na2O, Li2O (2) Na2O, Li2O
(3) Na2O, Li2O, Li3N, NH3 (3) Na2O, Li2O, Li3N, NH3
(4) Na2O, Li3N, Li2O (4) Na2O, Li3N, Li2O
84. Match the following columns :- 84. fuEufyf[kr LrEHkksa dk feyku dhft, %&
Column–I Column–II LrEHk–I LrEHk–II
(P) PCl5 ® PCl3 + Cl2 (i) Change in
(P) PCl5 ® PCl3 + Cl2 (i) ladj.k esa ifjorZu
hybridisation
(Q) SO3 ® SO2 + 1/2O2 (ii) Change in bond (Q) SO3 ® SO2 + 1/2O2 (ii) ca/k dks.k esa ifjorZu
angle (R) NH3 + H ® NH4
+ +
(iii) vkÏfr esa ifjorZu
(R) NH3 + H+ ® NH4+ (iii) Change in shape (S) H2O + H ® H3O
+ +
(iv) vkWDlhdj.k voLFkk esa
(S) H2O + H+ ® H3O+ (iv) Change in oxidation ifjorZu
state
(1) (P)®i, ii, iii, iv ; (Q)®ii, iii, iv ; (R)®ii, iii ;
(1) (P)®i, ii, iii, iv ; (Q)®ii, iii, iv ; (R)®ii, iii ;
(S)®ii, iii
(S)®ii, iii
(2) (P)®i, iv ; (Q)®ii, iv ; (R)®i, iv ; (S)®ii, iii, iv
(2) (P)®i, iv ; (Q)®ii, iv ; (R)®i, iv ; (S)®ii, iii, iv
(3) (P)®i, ii, iii, iv ; (Q)®ii, iii, iv ; (R)®ii, iii, iv ; (3) (P)®i, ii, iii, iv ; (Q)®ii, iii, iv ; (R)®ii, iii, iv ;
(S)®ii, iii, iv (S)®ii, iii, iv
(4) (P)®i, iii ; (Q)®ii, iv ; (R)®ii, iii ; (S)®ii, iii (4) (P)®i, iii ; (Q)®ii, iv ; (R)®ii, iii ; (S)®ii, iii
85. Which of the configuration is correct :- 85. fuEu esa ls dkuS lk foU;kl lgh gS :-
(1) CO : sls2 ..... s2pz2, p2py2 (1) CO : sls2 ..... s2pz2, p2py2
(2) CN– : s1s2 ..... s2pz2, p2px2 (2) CN– : s1s2 ..... s2pz2, p2px2
(3) NO : s1s2 ..... p*2px1, p*2py0 (3) NO : s1s2 ..... p*2px1, p*2py0
(4) N2+ : s1s2 ..... s2pz2, p2py1 (4) N2+ : s1s2 ..... s2pz2, p2py1
86. Which of the following process involve change in 86. fuEu esa ls dkuS ls izØe esa ladj.k fcuk ifjorZu ca/kdks.k esa
bond angle with a change in hybridization :- ifjorZu gksrk gS :-
(1) BF3 + F– ® BF4– (1) BF3 + F– ® BF4–
(2) BF3 + BCl3 ® BF2Cl + BFCl2 (2) BF3 + BCl3 ® BF2Cl + BFCl2
(3) BF3 + NH3 ® F3B . NH3 (3) BF3 + NH3 ® F3B . NH3
(4) NH3 + HCl ® NH4+ Cl– (4) NH3 + HCl ® NH4+ Cl–
SPACE FOR ROUGH WORK
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87. Which one is incorrect : 87. dkSulk xyr gS :
(1) Zn + dil. HNO3 ® Zn(NO3)2 + N2O (1) Zn + dil. HNO3 ® Zn(NO3)2 + N2O
(2) Zn + conc. HNO3 ® Zn(NO3)2 + NO2 (2) Zn + conc. HNO3 ® Zn(NO3)2 + NO2
(3) Zn + very dil. HNO3 ® Zn(NO3)2 + NH4NO3 (3) Zn + very dil. HNO3 ® Zn(NO3)2 + NH4NO3
(4) Cu + dil. HNO3 ® Cu(NO3)2 + N2O (4) Cu + dil. HNO3 ® Cu(NO3)2 + N2O
88. For the process 88. A(g) + e– ¾® A–(g); DH = x
A(g) + e– ¾® A–(g); DH = x rFkk A–(g) ¾® A(g) + e– DH = y
and A (g) ¾® A(g) + e
– –
DH = y izØe ds fy, lgh fodYi dk p;u dhft, :
Select correct alternate :
(1) A–(g) dh vk;uu mGtkZ] y gS
(1) Ionisation energy of A–(g) is y
(2) Electron affinity of A(g) is x (2) A(g) dh bysDVªkWu ca/kqrk] x gS
(3) –x = +y (3) –x = +y
(4) All are correct statements (4) lHkh dFku lgh gS
89. Which of the following is correct statement - 89. fuEu esa ls dkuS lk dFku lgh gS -
(1) H3PO3 is dibasic and non-reducing (1) H3PO3 f} {kkjh; gS rFkk vuvipk;d gS
(2) ikbjksflfydsV lk>hr ,d vkWDlhtu ijek.kq ds lkFk
(2) Pyrosilicate is Si2O76– with one oxygen atom shared
Si2O7–6 gksrk gAS
(3) Caro's acid & oleum contains peroxo bond
(3) dSjks vEy rFkk vksfy;e esa ijvkWDlks ca/k gksrk gS
(4) Br-F apical bond length is greater than Br-F (4) BrF5 v.kq dh T;kferh; esa Br-F leryh; ca/k yEckbZ
planar bond length in geometry of BrF5 molecule dh vis{kk Br-F 'kh"kZ ca/k yEckbZ vf/kd gksrh gS
90. Which of the following is the correct prediction about 90. BX3 v.kq esa izfs {kr B-X ca/k yEckbZ ds lanHkZ esa lgh fu"d"kZ g?S
observed B-X bond length, in BX3 molecule ? (1) BF3 esa B-F ca/k yEckbZ l¼ S kfUrd eku ls de ik;h tkrh
(1) B-F bond length in BF3 is found to be less than
theoretical value because electronegativity values gS D;ksafd B (2.04) rFkk F(4.0) ds fo|qr½.kh eku
of B (2.04) and F(4.0) suggest the bond to be ionic ca/k dks vk;fud cukrs gS rFkk bl izdkj foifjr vkosf'kr
and hence the attraction between oppositely vk;uksa ds e/; vkd"kZ.k] ca/k yEckbZ dks de djrk gS
charged ions must decrease the bond length
(2) BF3 and [BF4]– have equal B-F bond length (2) BF3 rFkk [BF4]– esa B-F ca/k yEckbZ leku gksrh gS
(3) The decrease in the B-F bond length in BF3, is (3) BF3 esa B-F ca/k yEckbZ esa deh] B ds fjDr 2p d{kd
due to delocalised pp-pp bonding between rFkk F ds iwfjr 2p-d{kd ds e/; foLFkkuhd`r pp-pp
vacant 2p-orbital of B and filled 2p-orbital of F ca/k ds dkj.k gksrh gS
(4) The correct B-X bond length order is (4) B-X ca/k yEckbZ dk lgh Øe gS
B-F>B–Cl > B – Br > B – I B-F>B–Cl > B – Br > B – I
SPACE FOR ROUGH WORK
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SPACE FOR ROUGH WORK / jQ dk;Z ds fy;s txg
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