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Maysa Rizk
Professor Carlin
GEOL 381
18 December 2019
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ABSTRACT
Watersheds play a huge part in the ecosystem of the area it is located in, by providing water
and food sources to the inhabits around it. Anthropogenic activities throughout a watershed can
have major impacts on water quality and it is uncertain how these activities can influence different
areas in the Santa Ana Watershed. Given this uncertainty, the objective of this study is to better
understand how various parameters around the Santa Ana River Watershed affects water quality.
We collected water samples from 17 locations throughout the Santa Ana River Watershed and
measured: bed type, temperature, TDS and velocity. Those water samples were then analyzed for
Nitrate levels. TDS and Nitrates showed a general downward trend, that the further down the
locations were located in the watershed, the more influence of stream order and land types had.
Temperature and Velocity showed a general downward trend as the water flowed through modified
bed types and urban developed areas. Temperatures generally had a downward trend, when the
same water samples were taken later in the water season, while it had little effect on the amount
of TDS in the water. Spatial controls, such as stream order and land types, affected TDS and
Nitrates as the water flows from the top of the watershed to the bottom. Anthropogenic influences,
such as modified bed types and urban area development, affect temperature and velocity as the
water flows through less shady areas and basin areas. Seasonal effects, such as taking samples at
different times in the water season, affect temperature but has little effect on TDS, which is more
affected by the localized change. Overall, the negative effects on the water in the watershed could
potentially have negative effects on animals and humans in the future, if nothing is done to stop it.
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1.0 INTRODUCTION
Watersheds are an important part of a region’s landscape; they provide water and nutrients
to the organisms around it. As humans, we use the water from watersheds to use for drinking water,
agricultural and industrial use. The water quality in these watersheds need to have a certain level
of contaminates so that it doesn’t have negative effects when it is being used. There are many
factors that can affect water quality in a watershed: climate of the region the watershed is located
in, the land types that are surrounding the watershed, etc.
As previously stated, the Santa Ana River is located in a Mediterranean climate and has
multiple land types that it passes through. This is important because the water in the Santa Ana
River Watershed is mainly used as a source for drinking water for the residents in this area. The
Santa Ana River Watershed is located in a region that consists of different land types. The different
land types are Natural, Residential, Industrial/Commercial and Agricultural. These play an
important role in influencing the water quality in the watershed. Anthropogenic activities
throughout a watershed can have a major impact on water quality, but as the increase in urban
development continues, it is uncertain how this can influence different areas in the Santa Ana River
Watershed.
The goal of this study is to see how these different parameters around the watershed affect
the water quality in the Santa Ana River Watershed. The time period of this study took place
between September through November of 2019. Those water samples were then analyzed for
TDS, Temperature, Velocity, and Nitrate. The study also collected Strahler Order, Shreve
Magnitude, channel width and distance from the mouth. We then assessed how TDS, temperature,
velocity, and Nitrate are impacted by elevation, land use, stream order, Shreve magnitude and
2.0 BACKGROUND
Watersheds are regions of land that separate smaller bodies of water (i.e. streams) that drain
into a larger body of water (i.e. river or ocean). Watersheds and rivers in California respond to
unique climate settings. For instance, there is a watershed in California called the Upper Feather
River which is located in the Sierra Nevada Mountains (Huang et al., 2012). Since this watershed
is in California, it experiences a Mediterranean climate, which consists of cold moist winters and
springs and temperate summers (Huang et al., 2012). Subsequently, the Upper Feather River
watershed is also located in a mountain range, which means that its water flow is impacted by
melting snow. The amount of precipitation and the amount of snow melting results in the change
of Streamflow percentage to relatively increase (Huang et al., 2012). This means that the extra
water from the melting snow and precipitation adds to the rate of the streamflow. Watersheds in
different parts of the country can be located in different climates. For instance, there is a watershed
in Tifton, Georgia, U.S. called Little River Experimental (Pan et al., 2011). The Little River
Experimental Watershed is situated in the Gulf-Atlantic coastal Plain where the weather conditions
are humid (Pan et al., 2011). Another example of a watershed in a different climate is in North
Danville, Vermont, U.S. and it is called the Sleepers River Experimental (Pan et al., 2011). The
Sleepers River Experimental Watershed is situated in a glacial upland area, where the weather
conditions for this area of the U.S. are continentally humid (Pan et al., 2011). This means that there
different types of climates. The location of the Santa Ana River Watershed is also affected by its
location. The Watershed is located in the high mountains of San Bernardino, passes through
riverside, Corona and a wide variety of different areas. Part of the watershed is also situated in the
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Northern area of Orange County, Ca (Ding et al., 1999). The mouth of the watershed drains into
the Pacific Ocean in Huntington Beach. Approximately 3 huge precipitation events help to add
about 50% of the yearly precipitation that the Santa Ana River Watershed receives (Cannon et al.,
Although the whole Santa Ana River Watershed covers a huge portion of land, the sub-
basins and sampling locations help narrow down the portions of the watershed that we are focusing
on. The Santa Ana River watershed is divided into 5 different sub-basins. The first sub-basin is
located in the mountainous area of San Bernardino County, CA. The second sub-basin is still
located in the mountainous area of the San Bernardino area, but about half of the sub-basin is in
the city area. The third basin is the largest of the sub-basins and it covers an area from Corona, CA
to right before Palm Springs, CA. The fourth basin area spans from Mount Baldy, CA all the way
to the Prado Dam in Corona CA. The final basin begins at the southeastern edge of the Chino Hills
State Park and ends when the mouth of the river reaches the Pacific Ocean in Huntington Beach.
Certain locations were selected for sampling in the Santa Ana River Watershed, which
would give a small representation of the area it was taken from. The only sample that was taken
from the first sub-basin was SAR-HW. Samples that were taken from the second sub-basin
included: LT, LT-B, CJC, CJC-B, TC, CC, and STC. Samples that were taken from the fourth sub-
basin included: SAC, CUC, CHC, SAR-N, and SAR-UP. Samples that were taken from the fifth
3.0 METHODS
There was a total of 17 locations that were sampled. However, 4 locations were sampled
twice to see how the effect of time has on samples. The sampled locations were chosen based on
their positions in the 10 sub-basins throughout the Santa Ana River Watershed. The SAR-HW
location was sampled near the top of the Upper San Bernardino Mountain sub-basin. The STC
sampled location was sampled near the bottom of the San Timoteo Creek sub-basin. The TC and
CC sampled locations were sampled in the Western San Bernardino Mountain sub-basin. The LT,
LT-B, CJC, and CJC-B sampled locations were sampled in the Eastern San Gabriel Mountain sub-
basin. The SAC and CHC sampled locations were sampled in the Eastern San Gabriel and Chino
sub-basin. The CUC sampled location was sampled in the Cucamonga Basin sub-basin. The SAR-
N and SAR-UP sampled locations were sampled in the IE SAR Basin sub-basin. The SAR-LP,
SAR-YB, and SAR-O sampled locations were sampled in the Upper OC Basin sub-basin. The
We collected the samples between the time period between the middle of September to the
middle of November in 2019. Samples were chosen based on where they were located in the Santa
Ana River Water Shed. SAR-HW, LT, LT-B, CJC, CJC-B, and SAC were chosen because they
represented the pure water that comes from the melted snow in the mountains. TC, CC, and STC
were chosen because they were on the edge of the mountain area that meets the urban areas. CUC,
SAR-N, CHC, SAR-UP, SAR-LP, SAR-YB, and SAR-O were chosen because they are in the
center of highly urban and commercial areas. SAR-HB was chosen because it was the closest to
The sampled locations were then plotted in Google Earth to determine Strahler Stream
Order and Shreve Magnitude. Google Earth was set up with the entire Santa Ana River Watershed,
the main stem of river and tributaries color-coded. The Strahler Stream Order was then determined
by following the tributaries from the top of the watershed until the mouth of the river was reached.
Then every stream/creek was labeled with either 1, 2, 3 or 4. Where 1 is where the furthest
tributaries are and increases until 4 which is closer to the mouth of the Santa Ana River. Shreve
Magnitude was also determined in a similar manner. However, Shreve magnitude is counting the
number of tributaries from the top of the watershed, counting all the way to the mouth of the Santa
Ana River. Google Earth was also used to determine Channel Width (m) and Distance from the
At the sampled locations bed type, velocity, bed elevation, temperature, and TDS were
determined. The bed type was determined by using a meter stick with black tape every 10 cm. For
every 10 cm marked was passed, it would count as 10% of the bed type. Velocity was then
determined by using a current meter. The current meter was placed in the middle of the stream to
get a better representation of the velocity, which was measured in m/s. The bed elevation was
measured was a GPS device and it also provided the latitude and longitude for each location. The
temperature was taken in the river using a thermometer in ℃. TDS was taken in the river using a
At each of the sampled locations, approximately 1 L of water was taken for further tests.
Most of the water sample were easily taken from the rivers. However, some samples had to be
taken from a bridge as some locations were hard to access, for instance, CHC and CUC. For those
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samples, a retrieval apparatus was hung at the top of the bridge and lowered to the source of water.
Prior to analyses, the collected water samples were stored in a completely dark container. So that
All water samples were tested for their Nitrate levels with the Nitrate testing kits by
LaMotte. 5 ml of the water from each of the water samples were tested. Each of the water samples
changed color after the testing, which indicated the ratio of Nitrate to Nitrogen (ppm). The colors
of the water samples were then compared to the Comparator that was included in the kit. The scale
on the Comparator ranged from 0.0 to 15.0 of Nitrate to Nitrogen (ppm). The divisions on the
Comparator were as follows: 0.0, 1.0, 2.0, 4.0, 6.0, 8.0, 10.0, and 15.0. Where 0.0 indicated zero
of the ratios of Nitrate to Nitrogen and 15.0 indicated high amounts of the ratio of Nitrate to
Nitrogen. After each of the water samples had their respective Nitrate to Nitrogen number. Those
numbers were then multiplied by 4.4 to get the actual Nitrate levels in ppm for each of the water
samples.
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4.0 RESULTS
4.1 Station Locations and Channel Parameters
4 SAR-O SAR-LP
SAR-HB SAR-YB
SAR-UP
3
Strahler Stream Order
SAR-N
CHC TC LT-B
2 STC
0
0 20 40 60 80 100 120 140 160
Distance from Mouth (km)
Figure 1. Graph of Strahler Stream Order versus Distance from the Mouth (km).
The data shows a slight trend that when Strahler Stream Order decreases, the
distance from the mouth also increases.
Out of the sampled locations, the Strahler Stream Order ranged from 1 to 4. There was a
slight trend that Strahler Stream Order decreased as the distance from the mouth increased. SAR-
HB, SAR-O, and SAR-YB were < 40 km from the mouth and had a Strahler Order of 4. Locations
that had a Strahler Order of 1, ranged from > 60 km to <150km from the mouth of the river.
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70
SAR-HB
60
SAR-O SAR-LP
50
SAR-YB
Shreve Magnitude
40
SAR-UP
30
SAR-N
20
10 CHC
CUC SAC TC LTCJC-B SAR-HW
LT-B
0 STC
CJC
0 20 40 60 80 100 CC 120 140 160
Distance from Mouth (km)
Figure 2. Graph of Shreve Magnitude versus Distance from Mouth (km). The data
shows a noticeable trend that when Shreve Magnitude increases, the distance from
the mouth decreases.
Out of the sampled locations, the Shreve Magnitude ranged from 1 to 61. There was a
noticeable trend as Shreve Magnitude increased the distance from the mouth decreased. Locations
that were < 40 km from the mouth of the river had a Magnitude > 50. SAR-HB had a Shreve
Magnitude of 61 and was 4 km from the distance of the mouth. The outliers are CUC with a Shreve
Magnitude of 2 and was 65.3 km from the mouth and CHC with a Shreve Magnitude of 4 and was
56 km from the mouth. Since other locations at a similar distance had a Shreve Magnitude of
around 30.
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SAR-HW
1900
1700
1500
1300
Bed Elevation (m)
1100
LT
900 SAC
CJC CJC-B
700
500 TC
LT-B
STC
300 SAR-LP
SAR-YB CUC CC
100 SAR-HB
CHC SAR-N
SAR-LP
-100 0 20SAR-O 40 60 80 100 120 140 160
Distance from Mouth (km)
Figure 3. Graph of Bed Elevation (m) versus Distance from Mouth (km). The
data shows a noticeable trend as the bed elevation increases, so does the distance
from the mouth.
Out of the sampled locations, the bed elevations ranged from -6 m to 1869 m. There was a
noticeable trend as the bed elevation increased, so did the distance from the mouth. SAR-HW had
the highest bed elevation of 1869 m and was 144 km from the mouth of the river. SAR-HB had
the lowest bed elevation of -6 m and was 4 km from the mouth of the river. One outlier was SAC,
which had a bed elevation of 738 m and was 84.4 km from the mouth.
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100%
90% SAR-O SAC LT-B
80% CHC
Bed Type (% Coarse)
70%
60% CC LT
50% SAR-HW
40% CJC
30%
20%
10% SAR-HB CJC-B
SAR-YB SAR-N STC
0% CUC TC
0 20 40SAR-UP 60 80 100 120 140 160
Distance from Mouth (km)
Figure 4. Graph of Bed Type (% coarse: gravel, pebble, cobble and boulder)
versus Distance from Mouth (km). The data shows no noticeable trend. SAR-UP
was excluded from figure, as the bed type was not determined.
Out of the sampled locations, the bed type ranged from boulder to sand. However, Figure
4 focused on the percent coarse, which included gravel, pebble, cobble, and boulder. There was no
noticeable trend from this data. SAR-O, SAC, and LT-B all had 100% coarse but were spread out
throughout the watershed. Locations that were > 120 km from the mouth of the river, all had
greater than or equal to 50% coarse. Sample locations that were 0% coarse had bed types made of
35
SAR-HB CUC
30
SAR-UP STC
25 SAR-YB
SAR-O CC
Temperature (℃)
CHC TC CJC
20 SAR-LP SAR-N
SAC CJC-B
SAR-HW
15 LT-B LT
10
0
0 20 40 60 80 100 120 140 160
Distance from Mouth (km)
Figure 5. Graph of Temperature (℃) versus Distance from Mouth (km). The
data shows a noticeable trend temperature increases as the distance from the
mouth also increases.
Out of the sampled locations, the temperature ranged from 14℃ to 29.8℃. There was a
noticeable trend the temperature increased as the distance from the mouth increased. CUC had the
highest temperature of 29.8℃ but was 65.3 km from the mouth of the river. SAR-HW had the
lowest temperature of 14℃ and was 144 km from the mouth of the river.
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0.9
LT
0.8
0.7
0.6
Velocity (m/s)
SAR-HW
0.5 SAR-UP TC
0.4 SAR-N
0.3 CJC
SAR-O CC CJC-B
0.2
SAR-LP
SAR-HB STC
0.1 SAR-YB CHC LT-B
SAC
0
0 20 40 60 80 100 120 140 160
Distance from Mouth (km)
Figure 6. Graph of Velocity (m/s) versus Distance from Mouth (km). The data
shows a slight trend as velocity increases, so does the distance from mouth. CUC
was excluded was from this figure, since velocity couldn’t be determined.
Out of the sampled locations, the velocity ranged from 0.03 m/s to 0.81 m/s. There was a slight
trend that the velocity increased when the distance from the mouth increased. LT had the highest
velocity of 0.81 m/s and was 123 km from the mouth of the river. SAC had the lowest velocity of
0.03 m/s. CUC was excluded from this figure since the velocity couldn’t be determined.
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700
SAR-LP
600 SAR-N
500 SAR-UP CJC
TDS (mg/L)
400 SAR-YB
CHC
300 CUC
SAC LT
CC
200 SAR-HW
STC
SAR-O TC
100 CJC-B
LT-B
0
0 20 40 60 80 100 120 140 160
Distance from Mouth (km)
Figure 7. Graph of TDS (mg/L) versus Distance from Mouth (km). The data shows
a noticeable trend as the distance from the mouth increases, so does the amount of
TDS. SAR-HB is excluded from this figure, as it contains saltwater instead of fresh
water.
Out of the sampled locations, the TDS ranged from 13.3 mg/L to 591 mg/L. There was a
noticeable trend when the Distance from the mouth increased so did the amount of TDS. SAR-LP
had the highest amount of TDS with 591 mg/L and was 46 km from the mouth of the river. LT-B
had the lowest amount of TDS with 13.3 mg/L and was 119 km from the mouth of the river. SAR-
HB was excluded since it contained ocean water that would skew our data.
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45 CHC
40
SAR-N
35 SAR-UP
30
Nitrates (ppm)
25
SAR-YB SAR-LP CJC-B
20
SAR-O CJC
15
SAR-HB
10 STC
CUC SAC LT
5 SAR-HW
TC
LT-B
0 CC
0 20 40 60 80 100 120 140 160
Distance from Mouth (km)
Figure 8. Graph of Nitrates (ppm) versus Distance from Mouth (km). The data
shows no noticeable trend.
Out of the sampled locations, the nitrates ranged from 0 ppm to 41.25 ppm. There was no
trend for those data points. Most of the sampled locations had a nitrate level of below < 20 ppm.
CHC was 56 km from the mouth and had the highest level of nitrates, 41.25 ppm. LT-B was 119
km from the mouth and had the lowest level of nitrates, 0 ppm. There was a huge increase of 31.16
5.0 DISCUSSION
Stream Order (Figure 1) has a substantial influence on TDS (Figure 7) because lower-order
streams are located in “pristine locations” and higher-order streams are located in urban areas.
CJC-B (36 mg/L) and SAR-HW (136 mg/L) have a stream order of 1 and also contain low amounts
of TDS. SAR-LP has a stream order of 4 and has the highest TDS level of 591 mg/L. However,
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SAR-O is considered an outlier, since it has a stream order of 4 but has a low TDS level of 60
mg/L. This might due to the fact that this sample was taken from an area of the stream where there
wasn’t an accurate TDS measurement. CJC is also an outlier has it had a spike in TDS but is
located in a lower stream order. This may due to the fact that there was a homeless encampment
Stream Order (Figure 1) and Shreve Magnitude (Figure 2) didn’t have an important
influence on Nitrates (Figure 8), whereas land type does have a significant influence because of
the runoff of fertilizers and other contaminates. CHC (41.25 ppm) and SAR-UP (32.32 ppm) are
located in areas of residential, commercial and agricultural and contain two of the highest levels
of Nitrate. The samples with the three highest Nitrate levels are all right before the Prado Dam.
While the sample locations after the dam, SAR-YB, SAR-LP, and SAR-O have drastically lower
Channel bank vegetation and shade play a more important role in temperature (Figure 5),
then modified bed types (Figure 4) have. The bed types of SAR-YB and SAR-N are 100% cement
and CUC and CHC are 100% concrete. The temperature drops 10.9 ℃ from CUC to SAR-N, but
then slightly increase by 4.35 ℃ from SAR-N to CHC and then decreases by 0.7 ℃ from CHC to
is located in a natural area and consists of 40% boulders, 50% mud, and 10% cobble and CC is
located in a transition zone from natural to residential and consists of 40% boulders and 60% sand.
However, CUC could also be considered as an outlier, since it has the highest temperature and is
Velocity (Figure 6) decreases in urban areas because of the impact of modified channels
and widened channels that are built as you get closer to the mouth of the river. As the water gets
closer to the mouth of the river, it has to go through urban areas, that will not have the same slope
or paths like that of the nature areas. Natural areas are located at higher elevations (Figure 3), while
as the locations are closer to the mouth of the river, the elevation decreases. Sample locations that
are ~110 km and below are decreasing in velocity in urban areas. SAC, CHC, SAR-YB, and SAR-
HB are closer to the mouth of the river than some of the other sample locations and they also are
the sample locations that had the lowest velocity. SAC had a velocity of 0.03 m/s, CHC had 0.05
m/s, SAR-YB had 0.055 m/s and SAR-HB had 0.07 m/s. However, there is an outlier, SAR-UP,
that is the fourth highest velocity, but it is less than 60 km from the mouth of the river.
Temperature is one of the most sensitive water parameters that can change through time
because of changes in weather and different times during the water year. Four sample locations
were resampled in November and they all experienced a drop-in temperature (Figure 9). In the
middle of September, STC had a temperature of 31.8 ℃, but then in November the temperature
dropped 15.3 ℃ and was 16.5 ℃. However, some of the new sampled locations had around the
same temperature ranges, compared to the other sample locations that were measured earlier in the
year. For instance, SAR-O had a temperature of 23.7 ℃, which is similar to CC who had a
temperature of 24.2 ℃.
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35 800
STC
*STC
30 700
SAR-YB
SAR-UP
SAR-YB 600
25 CHC
*SAR-UP
Temperature (℃)
TDS (mg/L)
20
400
*STC
15 STC SAR-UP *SAR-YB
300
10
200
5 100
*SAR-YB *CHC
0 0
9/2/19 9/12/19 9/22/19 10/2/19 10/12/19 10/22/19 11/1/19 11/11/19 11/21/19
Time (m/dd/yy)
Figure 9. Graph of Temperature (℃) versus TDS (mg/L) versus Time (m/dd/yy). The
Temperature data set shows a noticeable trend, as time increases, the temperature decreases.
The TDS data set shows no noticeable trend. If the location name has a (*), then that means
that was the second time the location was sampled.
TDS (Figure 9) is more influenced by local changes that occur over time rather than
seasonal because of the different localized conditions at each resample location. In the middle of
September, SAR-YB had a TDS of 599 mg/L, but then in November the TDS dropped 534 mg/L
and was 65 mg/L. However, STC had a TDS of 340 mg/L in September but then increased by 416
mg/L and was 756 mg/L. Out of the four resampled locations, two decreased in TDS and the other
two increased in TDS. This could be due to the fact that some locations might have had more
precipitation than others, which would wash some of the TDS away.
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6.0 CONCLUSION
In closing, anthropogenic influences have major effects on the water in the Santa Ana River
Watershed. Sample locations in natural areas had lower Nitrate levels, lower TDS levels, and lower
temperature levels. While sample locations in urbanized areas had relatively higher Nitrate levels,
higher TDS levels, and higher temperature levels. When water passes from natural areas into
urbanized areas, the water quality becomes contaminated from the localized runoff from these
areas. As the rate of urbanization increases, it is important to keep track of the impacts it has on
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1781–1794., doi:10.1016/s0045-6535(99)00072-7.
Huang, Guobiao, et al. 2 Feb. 2012. Hydrological Response to Climate Warming: The Upper
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