400

350

300
E, mV

250

200

150

100

50

0
0 1 2 3 4 5 6
Volum, mL
 330

310

290
E, mV

270

250

230

210

190

170

150
0 0.5 1 1.5 2 2.5 3 3.5
Volum, mL
 Jacobs Kronung Irish (Florian)
Volume Potential Volume Potential
V/ml U0/mV V/ml U0/mV

0 103.7 0 190.5
0.2 101.5 0.2 223.5 165
0.4 201.5 0.4 225.3 9
0.6 206.5 25 0.6 233.9 43
0.8 208.7 11 0.8 262 140.5
1 214.6 29.5 1 274.4 62
1.2 213.8 -4 1.2 287 63
1.4 213.6 -1 1.4 297.6 53
1.6 216.3 13.5 1.6 303 27
1.8 218.1 9 1.8 305.3 11.5
2 222.7 23 2 310.6 26.5
2.2 222.4 -1.5 2.2 312.5 9.5
2.4 222.4 0 2.4 317.5 25
2.6 224 8 2.6 318.7 6
2.8 238.1 70.5 2.90 2.8 319.8 5.5
3 238.6 2.5 3 321.4 8
3.2 252 67 3.2 323.4 10
3.4 259.5 37.5 3.4 324.5 5.5
3.6 267.2 38.5 3.6 326.2 8.5
3.8 275.8 43 3.8 327.5 6.5
4 281.9 30.5 4 329.7 11
4.2 285.9 20 4.2 330.4 3.5
4.4 290.6 23.5 4.4 331.3 4.5
4.6 294.6 20 4.6 332.4 5.5
4.8 298.1 17.5 4.8 333.6 6
5 301.2 15.5 5 334.7 5.5
5.2 303.8 13 5.2 335.5 4
5.4 305.9 10.5 5.4 336.4 4.5
5.6 306.2 1.5
5.8 306.3 0.5
6 306.4 0.5
6.2 306.5 0.5
6.4 308 7.5
6.6 311.8 19
6.8 313.6 9
7 315.2 8
7.2 317 9
7.4 318.3 6.5
7.6 319.8 7.5
7.8 321 6
8 322.2 6
8.2 323.5 6.5
8.4 324.6 5.5
8.6 325.8 6
8.8 326.8 5
9 327.8 5
9.2 328.8 5
9.4 329.6 4
9.6 330.5 4.5
9.8 331.4 4.5
10 332.3 4.5
10.2 333.1 4
Florian) Irish 5 mL + 0,5 mL HNO3 Cafea verde 5 mL + 0,5 mL HNO3
Volume Potential
V/ml U0/mV Volume Potential
V/ml U0/mV
0 212.6
0.1 224.4 118 0 216.4
0.2 230 56 0.1 232.9
0.3 242.9 129 0.3450617 0.2 255.4
0.91 0.4 246.9 40 0.3 262.7
0.5 254.7 78 0.4 268.1
0.6 263.2 85 0.5 274.2
0.7 269 58 0.6 278
0.8 275.3 63 0.7 282.5
0.9 279.6 43 0.8 286.1
1 283 34 0.9 289.2
1.1 286.7 37 1 292
1.2 288 13 1.1 294.6
1.3 289.4 14 1.2 297.2
1.4 291.3 19 1.3 299.3
1.5 293.1 18 1.4 301
1.6 295 19 1.5 302.9
1.7 296.8 18 1.6 304.6
1.8 299.1 23 1.7 306.3
1.9 300.8 17 1.8 307.8
2 302.5 17 1.9 309.2
2.1 303.9 14 2 310.6
2.2 305.7 18
2.3 306.9 12
2.4 308.1 12
2.5 309.5 14
2.6 310.7 12
2.7 311.7 10
2.8 313 13
2.9 314 10
3 314.8 8
3.1 315.9 11
3.2 316.8 9
ea verde 5 mL + 0,5 mL HNO3 Dolce baccio Ch. Coffe 5 mL+ 0,5 mL HNO3 Jacobs Kronung 5 mL + 0,5 mL

Volume Potential Volume

V/ml U0/mV V/ml

0 194.9 0
165 0.1 219.7 248 0.1792332 0.1
225 0.2283019 0.2 238 183 0.2
73 0.3 251.7 137 0.3
54 0.4 262.4 107 0.4
61 0.5 269.8 74 0.5
38 0.6 275.5 57 0.6
45 0.7 280.3 48 0.7
36 0.8 284.6 43 0.8
31 0.9 288.1 35 0.9
28 1 291.3 32 1
26 1.1 293.4 21 1.1
26 1.2 295.9 25 1.2
21 1.3 298.4 25 1.3
17 1.4 300.4 20 1.4
19 1.5 301.9 15 1.5
17 1.6 303.9 20 1.6
17 1.7 305.6 17 1.7
15 1.8 306.9 13 1.8
14 1.9 308.5 16 1.9
14 2 310 15 2
Jacobs Kronung 5 mL + 0,5 mL HNO3 Lavazza Dek Intenso 5 mL + 0,5 mL HNO3

Potential Volume Potential

U0/mV V/ml U0/mV

200.2 0 183.2
218.9 187 0.1869767 0.1 216.2 330 0.1741573
234.8 159 0.2 237.7 215
250.4 156 0.3 254.6 169
261 106 0.4 261.1 65
269.4 84 0.5 270.8 97
275.6 62 0.6 276.3 55
279.9 43 0.7 280.8 45
284.3 44 0.8 286.9 61
287.9 36 0.9 289.1 22
290.4 25 1 291.8 27
293.1 27 1.1 294.3 25
295.7 26 1.2 297.2 29
297.9 22 1.3 299.2 20
300.2 23 1.4 301.1 19
302 18 1.5 303.7 26
303.5 15 1.6 304.7 10
305.2 17 1.7 306.6 19
306.7 15 1.8 307.9 13
308 13 1.9 309.2 13
309.6 16 2 310.8 16
 Grand Mer 5 mL + 0,5 mL HNO3 L'or 5 mL + 0,5 mL HNO3

Volume Potential Volume Potential

V/ml U0/mV V/ml U0/mV

0 99.3 0 179.7
0.1 107.4 81 0.1 213.5 338 0.1695473
0.2 164.3 569 0.2707246 0.2 232.5 190
0.3 201 367 0.3 249.5 170
0.4 232.9 319 0.4 263 135
0.5 249 161 0.5 270 70
0.6 261.7 127 0.6 277.3 73
0.7 268.9 72 0.7 281.6 43
0.8 275.6 67 0.8 285.2 36
0.9 280.6 50 0.9 288.4 32
1 284.3 37 1 292.1 37
1.1 287.5 32 1.1 294.6 25
1.2 291.3 38 1.2 296.8 22
1.3 293.7 24 1.3 299.4 26
1.4 295.9 22 1.4 301.2 18
1.5 298.7 28 1.5 302.9 17
1.6 300.5 18 1.6 305 21
1.7 302.7 22 1.7 306.4 14
1.8 304.3 16 1.8 307.8 14
1.9 305.8 15 1.9 309.5 17
2 307.2 14 2 310.6 11
 Doncafe Selected 5 mL + 0,5 mL HNO3

Volume Potential
V/ml U0/mV

0 186
0.1 209.3 233 0.1841155
0.2 228.2 189
0.3 250.5 223
0.4 261.6 111
0.5 269.5 79
0.6 275.2 57
0.7 279.8 46
0.8 284.9 51
0.9 288.1 32
1 291.1 30
1.1 293.7 26
1.2 296.2 25
1.3 298.9 27
1.4 300.8 19
1.5 302.9 21
1.6 304.6 17
1.7 306.1 15
1.8 307.4 13
1.9 308.9 15
2 310.6 17
 350

300

250

200
E, mV

150

100

50

0
0 0.5 1 1.5 2
V, mL
 Dolce Bacio Chocolate Coffee

VAgNO3,
E, mV f’ =D pE/D V f’’ = D 2E/D V2
mL
0 194.9
0.1 219.7 248 0.1792332268
0.2 238 183
0.3 251.7 137
0.4 262.4 107
0.5 269.8 74
0.6 275.5 57
0.7 280.3 48
0.8 284.6 43
0.9 288.1 35
1 291.3 32
1.1 293.4 21
1.2 295.9 25
1.3 298.4 25
1.4 300.4 20
1.5 301.9 15
1.6 303.9 20
1.7 305.6 17
2 2.5 1.8 306.9 13
1.9 308.5 16
2 310 15