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Dr. S. K. Behera
School of Chemical Engineering
VIT, Vellore, TN, India – 632 014.
Module 7
– Moderately hard
• The calorific value of this coal is about 5500 kcal/kg (on air dry basis).
In India, it is found in Nilgiri Hills (South India).
Classification of coal:
Lignite:
• It is considered as the second stage of coalification of wood. It
contains less moisture than peat coal.
• Their calorific value is higher than peat and lignite coals. This value
varies from 7000 to 8500 kcal/kg.
• These coals are very much used in industries, household needs and
in the manufacturing of metallurgical coke and coal gas.
Classification of coal:
Anthracite:
• Anthracite is the coal of the highest rank. It is considered as the
purest form of the coal.
• It contains (on air dry basis) 92-96% carbon and has the lowest
amount of volatile matter.
• Coking Quality
Coke is obtained by high carbonization process of coal which is heated
in large size ovens in the absence of air (pyrolysis). Then coal is
converted into soft, plastic and tube of large coherent masses which
are known as coking coals.
• Moisture Content
A good quality coal should have low percent of moisture to prevent the
heat loss.
Selection of coal:
• Ash Content
The ash content of coal should be low so that cost of coal
transportation and disposal of ash is less. Low ash content coal gives
more heating value.
• Size of Coal
To give maximum heat, the size of the coal should be uniform.
• Moisture content:
About 1g of finely powdered air dried coal sample is weighed in a crucible
and is placed inside an electric hot air oven for an hour maintained at 105-
1100C. It is cooled in a desiccator and weighed. The loss in weight is the
moisture content on percentage basis.
• Volatile matter:
Fresh sample of crushed coal is weighed, placed in a covered crucible, and
heated in a furnace at 950±15 0C for 7 min. The sample is cooled and
weighed. Loss of weight represents both moisture and volatile matter.
Deducting the moisture content (as found from moisture test) would give
the amount of volatile matter in the coal.
Analysis of coal:
Proximate analysis:
• Ash content:
It is the weight of residue obtained after burning a weighed amount of dry
coal in an open crucible at 700-750 0C for 30 min in a muffle furnace. The
weight of residue remaining in the crucible is reported as ash content on
percentage basis.
• Fixed carbon:
It is the quantity of carbon in coal that can be burnt by a primary current of
air drawn through the hot bed of fuel. The percentage of fixed carbon is
determined by subtracting the value of moisture, volatile matter and ash
from 100.
The contents of the flask are heated in a long necked flask called
Kjeldahl’s flask till the solution becomes clear.
Ultimate analysis:
Analysis of coal:
Relationship between Proximate analysis & Ultimate analysis:
Heating value -- CFRI Formulae --
Low Moisture Coal (M < 2% ) -- CV (Kcal/kg) = 71.7 FC + 75.6 (VM-
0.1 A) - 60 M
High Moisture Coal (M > 2%) – CV (kcal.kg) = 85.6 {100 -
(1.1A+M)} - 60 M
• In this process, the coal is fed through the opening at the top and the
charge is leveled to provide about 0.6 m deep layer.
• The air is sent through the side opening and the coal is ignited. The
volatile matter is allowed to escape through the partly closed opening
on the side.
• The hot coke is raked out through the side and quenched with water.
The yield is about 80%.
• These are erected side by side with vertical flues between them to
form a sort of battery.
• To introduce the charge, every oven has a hole at the top of it and
there is a refractory lined cast iron door at each end for coke
discharge.
Metallurgical Coke:
Otto Hoffmann’s Byproduct Oven Process
Metallurgical Coke:
Otto Hoffmann’s Byproduct Oven Process
• In this process, finely powdered coal is introduced through the hole
(at the top) of oven chamber which is then tightly closed so that the
supply of air may be prevented at both ends.
• Then, the ovens are heated to about 1200 oC using producer gas.
The required air for the combustion of the coal is preheated in
regenerators flanking the retorts.
• At the same time flue gases leave their acquired heat to one
generator, the other heater is used for preheating the incoming air.
• This cycle continues until all the volatile matter gets away. It takes
nearly 18-20 hours for the carbonization of the coal on the completion
of this carbonization process.
Metallurgical Coke:
Otto Hoffmann’s Byproduct Oven Process
• The red hot coke is taken out into a truck by massive ram.
• It is then quenched with water. The coke may also be cooled down
with the help of inert gases in a separate chamber.
• Recovery of Ammonia:
The gases coming out from chamber are allowed to pass through
another tower where water is sprayed. The gaseous ammonia gets
absorbed in water and becomes available as NH4OH
• Recovery of Naphthalene :
Naphthalene gets condensed when gases are allowed to come in
contact with cold water after the recovery of ammonia.
Metallurgical Coke:
Otto Hoffmann’s Byproduct Oven Process
• Recovery of H2S:
The gases are allowed to pass through a column packed with moist
Fe2O3 which retains H2S . This can be represented as follows :
• Recovery of Tar:
The tar is recovered after ammonia recovery.
Other industrial solid fuels:
Charcoal
• Out of the mentioned various manufactured fuels, the charcoal occupies the
first place in India.
• In some parts of the country, e.g. Mysore, huge quantities of charcoal are
being used till today in blast furnaces for reducing iron ores, etc. and in many
homes charcoal is used for cooking purposes.
• Charcoal is a product derived from destructive distillation of wood, being left
in the shape of solid residue.
• Charcoal burns rapidly with a clear flame, producing no smoke and
developing heat of about 6,050 cal/kg.
Other industrial solid fuels:
Briquettes
• The term briquettes is used in respect of the dust, and other small size waste
remains of lignite, peat, coke, etc. compressed into different shapes of
regular form, with or without binder.
• Good briquettes should be quite hard as possible. They must withstand the
hazards of weather, and must be suitable for storing and general handling in
use.
• Amongst the binders, asphalt and pitch are most commonly used, giving fine
results.
Other industrial solid fuels:
Bagasse
• Bagasse is the residue of sugarcane, left as waste in the sugar mill
after extraction of sugar juice.
• Bagasse is the main fuel satisfying the needs of sugar industries and
efforts are being made for decreasing the percent moisture of
bagasse with the help of flue-gas waste heat dryers.