Max Marks: 75 Note: Attempt six questions in all. Q. No. 1 is compulsory. 1. Answer any five of the following (limit your answer to 50 words). (4x5=20) a) Discuss in detail about Film theory of mass transfer coefficient. b) Explain selection criteria for choice of solvent for absorption. c) What is the Knudsen Diffusion Coefficient? How does it vary with Temperature & Pressure? d) Differentiate between packed column and tray column. e) Explain the terms- (i) Break through curve (ii) BET isotherm. f) Explain the following terms with respect to tray towers: (i) Flooding (ii) Coning (iii) Weeping (iv) Dumping (v) Theoretical Tray. g) Discuss types of adsorption and nature of adsorbent. h) Describe rate of drying curve in detail.
2. Prove that the NTU for unimolal unidirection diffusion I
given by the following approximate expression. The approximation can be obtained by using arithmetic mean in place of logarithmic mean. (10) yA2 dy A 1 1 - y A1 ( NTU )G = � + ln y A1 ( y - y * ) 2 1 - yA2 A A
3. A solute gas is to be absorbed in a counter-current packed
tower using a solute free liquid. The equilibrium relationship is given by Ye = mX. Obtain an expression for the number of units if the inlet and exit gas composition are Y1 & Y2 respectively. If a recovery of 90% of the solute is required and the liquid is 1.5 times the minimum. Calculate the number of transfer units. (10) 4. 1400 Kg (bone dry) of granular solid is to be dried under constant drying condition from a moisture content of 0.2 Kg/Kg dry solid to a final moisture content of 0.02 Kg/Kg dry solid. The drying surface is given as 0.0615 m 2/Kg. Under the same conditions, the following rates where previously known. Calculate the time required for drying. (10) X, (kg/kg 0.3 0.2 0.14 0.096 0.056 0.046 0.026 0.016 dry solid) Rate,N 1.71 1.71 1.71 1.46 1.29 0.88 0.54 0.376 (kg/m2.h)
5. How the drying equipments are classified & explain any one with neat sketch. (10)
6. Derive equations to calculate rate of steady state diffusion of
‘A’ through non-diffusing ‘B’ and also for steady state euimolal counter diffusion in case of gases. (10)
7. Discuss about principles, techniques, and applications of ion-
exchange in detail. (10)
8. Calculate the rate of diffusion of methanol at 20 0C under
unidirectional steady state condition through a 20 mm thick film of water when the concentrations of methanol at the opposite sides of the film are respectively 10% to 4 % methanol by weight. The diffusivity of methanol in water solution is 5.9*10-6 cm2/s. The density of 10% & 4% methanol solution at 20 0C may be taken as 0.951 and 0.986 g/cc respectively. (10)