BS EN 197-1:2011

Incorporating corrigenda November 2011 and October 2015

BSI Standards Publication

Cement
Part 1: Composition, specifications and
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conformity criteria for common cements

 BS EN 197-1:2011 BRITISH STANDARD

National foreword
This British Standard is the UK implementation of EN 197-1:2011. It
supersedes BS EN 197-1:2000, BS EN 197-4:2004 and BS 1370:1979
which are withdrawn.
The UK participation in its preparation was entrusted by Technical
Committee B/516, Cement and lime, to Subcommittee B/516/6, Cement
specifications.
A list of organizations represented on this subcommittee can be
obtained on request to its secretary.
When reference to this Standard has been published in the Official
Journal of the European Union (OJEU), compliance with it will confer a
presumption of conformity with the Construction Products Directive.
The detailed requirements for evaluating the conformity of common
cements with this standard are given in BS EN 197-2 Cement — Part 2:
Conformity evaluation. In addition, these same provisions describe all the
tasks that are required for demonstrating legal attestation of conformity
to a system 1+ for CE marking purposes.
This British Standard does not include in its scope the additional special
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properties of pozzolanic pulverized-fuel ash cement, conforming to

BS 6610, or other types of cement where hardening is not primarily due
to the hydration of calcium silicates.
National annex NA (informative) details the exchange of additional
information between the cement manufacturer and user, including the
provision of information for alkali contents.
National annex NB (informative) gives recommendations for sampling
and testing for acceptance inspection at delivery.
National annex NC (informative) gives a national recommendation for
the loss on ignition property of a siliceous fly ash constituent.
National annex ND (informative) provides guidance on the general use
of common cements, including health and safety aspects.
National annex NE (informative) lists publications referred to in national
annexes NA – ND.
This publication does not purport to include all the necessary provisions
of a contract. Users are responsible for its correct application.
© The British Standards Institution 2015.
Published by BSI Standards Limited 2015
ISBN 978 0 580 91964 0
ICS 91.100.10
Compliance with a British Standard cannot confer immunity from
legal obligations.
This British Standard was published under the authority of the Standards
Policy and Strategy Committee on 30 September 2011.
Amendments/corrigenda issued since publication
Date Text affected
30 November 2011 National foreword revised and addition of National
Annexes NA, NB, NC, ND, and NE
31 October 2015 Correction to supersession details in national foreword
   BS EN 197-1:2011

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 BRITISH STANDARD NA to BS EN 197-1:2011

National Annex NA (informative) Information to be provided

NA.1 General
In accordance with Note 1 to Clause 1, the provisions for the exchange
of additional information between the manufacturer and the user
should be made in accordance with, but not limited to, this annex.

NA.2 Conditions of supply – packed/bagged cement

Where cement is supplied in a bag for manual handling, the nominal
quantity should be marked on the bag. The nominal quantity should
be 25 kg, or less, within permitted tolerances.

NA.3 Test report

NA.3.1 General
The information in NA.3.2 – NA.3.5, concerning test results on samples
of the cement, should be included in a test report, if requested from
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the manufacturer, relating to the material delivered.

NA.3.2 All CEM cements

a) compressive strength at either 2 days or 7 days, as appropriate,
and also at 28 days (see 7.1);
b) initial setting time (see 7.2.1.);
c) soundness (see 7.2.2);
d) chloride content (see 7.3).

NA.3.3 Portland-slag (CEM II/A-S and II/B-S) and blastfurnace

cements (CEM III/A, CEM III/B and CEM III/C)
The proportion of blastfurnace slag, as a target mean, reported to the
nearest 1 % by mass.

NA.3.4 Portland-fly ash cements (CEM II/A-V and II/B-V)

a) the proportion of siliceous fly ash, as a target mean, reported to
the nearest 1 % by mass;
b) the loss on ignition of the siliceous fly ash if greater than 7.0% by
mass (see Annex NC).

NA.3.5 Portland-limestone cements (CEM II/A-L, CEM II/A-LL,

CEM II/B-L and CEM II/B-LL)
The proportion of limestone, as a target mean, reported to the
nearest 1 % by mass.
NOTE The notation, CEM II/A-LL, indicates that the total organic carbon
(TOC) content of the limestone constituent does not exceed 0,20 % by mass,
whereas the notation, CEM II/A-L, indicates that the TOC of the limestone
does not exceed 0,50 % by mass (see 5.2.6).

© BSI 2011 • 39
 NA to BS EN 197-1:2011 BRITISH STANDARD

NA.4 Additional information

NA.4.1 General
The information in NA.4.2 and in NA.4.3, appropriate to the type
of cement, should be made available, if requested at the time of
ordering, relating to the material delivered.

NA.4.2 All CEM cements

a) the type and quantity of any minor additional constituent;
b) the fineness as determined by specific surface or sieve residue;
c) the silicon dioxide, aluminium oxide, iron(III) oxide, calcium oxide
and magnesium oxide contents of the clinker;
d) the sulfate content expressed as SO3 (see 7.3);

NA.4.3 Alkali information

NA.4.3.1 Declared mean alkali content

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Alkali information is given as the declared mean alkali content of

the cement.
NOTE 1 No provision is made in this British Standard for standardizing
low alkali CEM cements to a guaranteed alkali limit. Availability and supply
of such CEM cements is agreed between purchaser and manufacturer.
a) The declared mean alkali content, is an alkali content expressed
as the sodium oxide equivalent, which is not exceeded without
prior notice from the manufacturer. It is a certified average alkali
content plus a margin that reflects the manufacturer’s variability
of production.
NOTE 2 It is the declared mean alkali content, rather than the certified
average alkali content, which is used for purposes of classification and
calculation of contributions of alkali from CEM cements to the alkali
content of concrete.
b) A certified average alkali content, expressed as the sodium
oxide equivalent, is an average of the manufacturer’s latest 25
consecutive determinations on spot samples, taken in accordance
with a statistically based sampling plan e.g. autocontrol.
c) The variability of a certified average alkali content is represented
by the standard deviation of the manufacturer’s latest 25
consecutive determinations.

NA.4.3.2 Alkali contributions from blastfurnace slag and siliceous fly

ash constituents
The alkali contributions, from blastfurnace slag or siliceous fly ash
constituents of CEM cements, which are taken into account by the
manufacturer when calculating the declared mean alkali content of
the cement, are given in Table NA.1.

40 • © BSI 2011
 BRITISH STANDARD NA to BS EN 197-1:2011

Table NA.1 Alkali contributions

Main Notation Proportion Proportion of

type by mass 1) of declared mean
(see blastfurnace alkali content of the
Clause 6) slag or siliceous blastfurnace slag
fly ash or siliceous fly ash
(%) taken into account
(%)
CEM II Portland-slag cement CEM II/A-S 6 to 20 100
CEM II/B-S 21 to 25 100
CEM II/B-S 26 to 35 50
Portland-fly ash cement CEM II/A-V 6 to 20 100
CEM II/B-V 21 to 25 20
CEM II/B-V 26 to 35 0
CEM III Blastfurnace cement CEM III A 36 to 41 50
CEM III A 42 to 65 0
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CEM III B 66 to 80 0
CEM III C 81 to 95 0
CEM IV Pozzolanic (siliceous fly ash) cement CEM IV A 11 to 20 100
CEM IV A 21 to 25 20
CEM IV A 26 to 35 0
CEM IV B 36 to 55 0
NOTE Where a CEM I cement contains blastfurnace slag or siliceous fly ash as a minor additional constituent,
100 % of the alkali content of the constituent is taken into account.
1)
The proportions in the table are based on the sum of the main and minor additional constituents (formerly called
cement nucleus).

NA.4.4 Chloride information

The manufacturer might declare a chloride content that should not
be exceeded without prior notification. If such a declaration is made,
then the basis on which it is derived should also be stated.

National Annex NB (informative) Sampling and testing for acceptance

inspection at delivery
NB.1 For acceptance at delivery, when requested, a spot sample of
the cement should be taken in accordance with 3.6 and 6.2, 6.3, 6.4
or 6.5 of BS EN 196-7:2007 either before or at the time of delivery.
A laboratory sample should be prepared and packed in accordance
with Clauses 8 and 9 of BS EN 196-7:2007. A sampling report should
be completed at the time of sampling and should be attached to the
laboratory sample in accordance with Clause 10 of BS EN 196-7:2007.
NOTE Testing may be delayed for up to three months from the time of
sampling provided that there is confirmation that the sample has been
stored continuously in the manner described in 9.2 of BS EN 196-7:2007.
NB.2 When the cement is tested for strength (see 7.1), it is
recommended that the pit/quarry from which the CEN Standard

© BSI 2011 • 41
 NA to BS EN 197-1:2011 BRITISH STANDARD

sand (see BS EN 196-1) is obtained and the compaction procedure to

be used should be those in use by the manufacturer at the time the
cement was originally tested.
NOTE It should be noted that the source of CEN Standard sand and the
compaction procedure can, within permitted limits (see BS EN 196-1),
influence the strength achieved.
NB.3 When the cement is tested for chemical properties (see 7.3) the
test sample should be prepared by the method described in Clause 6
of BS EN 196-2:2005.
NB.4 Testing should be carried out in accordance with the relevant
methods in the BS EN 196 series of standards.
NB.5 The limiting values applicable to acceptance inspection of
cement should be those given in Table NB.1.
NOTE The acceptance inspection limits are in general those given as limit
values for single results in Table 10 of this standard. However, Table 10
does not give values for loss on ignition or insoluble residue.

Table NB.1 Acceptance inspection limits

Property Strength class

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32,5N 32,5R 42,5N 42,5R 52,5N 52,5R

Early strength (MPa) 2 day — 8,0 8,0 18,0 18,0 28,0
lower limit value 7 day 14,0 — — — — —
Standard strength (MPa)
28 day 30,0 30,0 40,0 40,0 50,0 50,0
lower limit value
Initial setting time (min)
60 50 40
lower limit value
Soundness (mm)
10
upper limit value
CEM I
CEM II
4,0 4,5
Sulfate content CEM IV
(as % SO3 by mass) CEM V
upper limit value
CEM III/A
4,5
CEM III/B
CEM III/C 5,0
Chloride content (% by mass)
0,10 1)
upper limit value
Loss on ignition (% by mass)
5,1
upper limit value
Insoluble residue (% by mass)
5,1
upper limit value
Pozzolanicity positive at 15 days
1)
Where a CEM III cement has been declared by the manufacturer to contain more than 0,10% chloride, the
acceptance inspection limit in this table does not apply.

42 • © BSI 2011
 BRITISH STANDARD NA to BS EN 197-1:2011

National annex NC (informative) National recommendation for the loss on

ignition of a siliceous fly ash constituent
In the UK, the loss on ignition of a siliceous fly ash constituent should
not exceed 7,0 % by mass, as a characteristic value.
NOTE In the case of a fly ash with a loss on ignition between 5,0% and
7,0% by mass, the maximum limit 7,0% is stated on the packaging and/or
the delivery note of the cement.

National annex ND (informative) Product guidance

ND.1 General
Guidance on the use of cements in concrete can be found in BS EN 206-1,
BS 8500-1, BS 8500-2, BS 8000-2-1 and BS 8000-2.2.
Guidance on the use of cements in building mortars can be found
in the National Annex to BS EN 1996-1-1, as well as BS EN 998-1,
BS EN 998-2, PD 6678, BS 8000-3, BS EN 13914-1, BS EN 13914-2,
BS EN 13813, BS 8204-1 and BS 8204-2.
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ND.2 Safety warning

ND.2.1 Manual handling of bags

Manual handling activities are subject to the Manual Handling
Operations Regulations 1992 (as amended) [1]. Where manual
handling operations cannot be avoided, the Regulations require that
the risks be assessed and reduced so far as is reasonably practicable.
Guidance on how to assess and reduce risk, is given by the Health and
Safety Executive (HSE), the UK’s regulatory authority, in its booklet,
Manual Handling (Manual Handling Operations Regulations 1992 (as
amended)) [2], Guidance and Regulations L23 (HMSO). In addition,
the HSE in its Construction Information Sheet No. 26 (revision 2) [3],
recommends that cement should be supplied in 25 kg bags or ordered
in bulk supply, in order to reduce the risk of injury.

ND.2.2 Safety in use

ND.2.2.1 Regulations
Work with cement is subject to the Control of Substances Hazardous
to Health Regulations (COSHH) 2002 (as amended) [4]. Furthermore,
Portland cement has been classified as an irritant under The Chemicals
[Hazard Information & Packaging for Supply] Regulations (CHIP 4)
2009 [5]. In addition, requirements to limit the water-soluble
chromium (VI) content to no more than 2ppm (0,0002%) by total dry
weight of cement and the provision of Safety Data Sheets (SDS), are
both covered by the REACH Regulation [6].

ND.2.2.2 Hazards
When cement is mixed with water, for example when making concrete
or mortar, or when cement becomes damp, a concentrated alkaline
solution is produced. Where this comes into contact with the eyes or

© BSI 2011 • 43
 NA to BS EN 197-1:2011 BRITISH STANDARD

skin it can cause serious burns and ulceration. The eyes are particularly
vulnerable and injury will increase with contact time.
Concentrated alkaline solutions in contact with skin tend to damage
the nerve endings first before damaging the skin. Chemical burns can
develop without pain being felt at the time.
In addition, cementitious grouts, cement-mortar and concrete mixes can,
until they have set, cause both irritant and allergic contact dermatitis:
a) Irritant contact dermatitis results from a combination of the
moisture content, alkalinity and abrasiveness of the construction
materials.
b) Allergic contact dermatitis is mainly a consequence of the
sensitivity of an individual’s skin to hexavalent chromium salts in
solution.
Frequently repeated exposures to airborne cement in excess of the
Occupational Exposure Standard (OES) [7] have been linked with
rhinitis and coughing.

ND.2.2.3 First aid measures

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a) In the event of eye contact, wash eyes immediately with copious

amounts of clean water for a period of at least fifteen minutes
and seek medical advice without delay;
b) In the event of skin contact, wash the affected area thoroughly
with soap and water before continuing the activity. If irritation,
pain or skin trouble occurs, seek medical advice;
c) In the event of ingestion, do not induce vomiting but wash out
the mouth with water and give plenty of water to drink. If pain
occurs, seek medical advice.
Clothing or footwear contaminated by wet cement, cementitious
grout, cement-mortar or concrete should be removed and washed
immediately and thoroughly before being re-used.

ND.2.2.4 Use of personal protective equipment (PPE)

a) Where the risk of cement becoming airborne can neither be
prevented nor completely controlled, appropriate respiratory
protective equipment should be worn to ensure that exposure is
less than the regulatory limit [Occupational Exposure Standard
(OES)]; and, in addition, dust-proof goggles should be worn in
order to protect the eyes;
b) Where the risks from contact with wet cement or wet
cement-containing construction materials can neither be
prevented nor completely controlled, appropriate protective
equipment should be worn as follows:
1) Protective clothing should be worn in order that cement, or
any cement/water mixture, e.g. concrete or mortar, does not
come into contact with the skin. In some circumstances, such
as when laying concrete, waterproof trousers and wellington
boots may be necessary. Particular care should be taken to
ensure that wet concrete does not enter the boots and that
individuals do not kneel on wet concrete. Should wet concrete
(mortar or grout) enter boots, gloves or other protective
clothing, then the item(s) of clothing should be removed

44 • © BSI 2011
 BRITISH STANDARD NA to BS EN 197-1:2011

immediately and the skin thoroughly washed with soap and

water. Items of clothing should be washed before re-use.
2) Where this takes the form of eye protection, wherever there
is a risk of cement, or any wet cement mixture entering the
eye, dust-proof goggles should be worn.

ND.3 Storage
To protect cement from premature hydration after delivery and to
optimize the activity of any reducing agent added to the cement to
reduce the water-soluble chromium (VI) content to no more than 2ppm
(0,0002%), bulk silos should be waterproof and internal condensation
should be minimized. Where reducing agents are used, manufacturers
are required, under Annex 17 of the REACH Regulation [6] to mark
delivery documents with the despatch date and the storage period
appropriate to maintaining the activity of the reducing agent required
to keep the content of soluble chromium (VI) below the regulatory limit.
Cement in paper bags should be stored unopened, clear of the ground,
not more than eight bags high, in cool dry conditions protected from
excessive draught and additionally protected by a waterproof structure
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where storage is external to buildings. As significant strength losses

begin after four weeks to six weeks of storage in paper bags in normal
conditions, and considerably sooner under adverse weather conditions
or high humidity, deliveries should be controlled and bags used in order
of receipt. Where reducing agents are used, manufacturers are required,
under the REACH Regulation to legibly and indelibly mark bags with
information on the packing date and the storage period appropriate
to maintaining the activity of the reducing agent required to keep the
content of soluble chromium (VI) below the regulatory limit.

National annex NE (informative) Publications referred to in national annexes

NE.1 Standards publications

BS 8000-2.1, Workmanship on building sites – Part 2: Code of practice
for concrete work – Section 2.1: Mixing and transporting concrete
BS 8000-2.2, Workmanship on building sites – Part 2: Code of practice
for concrete work – Section 2.2: Sitework with in situ and precast work
BS 8000-3, Workmanship on building sites – Part 3: Code of practice
for masonry
BS 8204-1, Screeds, bases and in situ floorings – Part 1: Concrete bases
and cementitious levelling screeds to receive floorings. Code of practice
BS 8204-2, Screeds, bases and in situ floorings – Part 2: Concrete
wearing surfaces. Code of practice
BS 8500-1, Concrete. Complementary British Standard to BS EN 206-1–
Part 1: Method of specifying and guidance for the specifier
BS 8500-2, Concrete. Complementary British Standard to BS EN 206-1 –
Part 2: Specification for constituent materials and concrete
PD 6678, Guide to the specification of masonry mortar
BS EN 196-1:2005, Methods of testing cement – Part 1: Determination
of strength

© BSI 2011 • 45
 NA to BS EN 197-1:2011 BRITISH STANDARD

BS EN 196-2:2005, Methods of testing cement – Part 2: Chemical

analysis of cement
BS EN 196-7:2007, Methods of testing cement – Part 7: Methods of
taking and preparing samples of cement
BS EN 206-1, Concrete – Part 1: Specification, performance, production
and conformity
BS EN 998-1, Specification for mortar for masonry Part 1: Rendering
and plastering mortar
BS EN 998-2, Specification for mortar for masonry Part 2: Masonry
mortar
NA to BS EN 1996-1-1, UK National Annex to Eurocode 6. Design
of masonry structures – Part 1-1: General rules for reinforced and
unreinforced masonry structures
BS EN 13813, Screed material and floor screeds. Screed material.
Properties and requirements
BS EN 13914-1, Design, preparation and application of external
rendering and internal plastering – Part 1: External rendering
BS EN 13914-2, Design, preparation and application of external
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rendering and internal plastering – Part 2: Design considerations and

essential principles for internal plastering

NE.2 Other publications

[1] GREAT BRITAIN. Manual Handling Operations Regulations 1992
(as amended). London: The Stationery Office.
[2] GREAT BRITAIN. Manual Handling Operations Regulations 1992
(as amended), Guidance and Regulations booklet L23. London:
The Stationery Office.
[3] Health and Safety Executive (HSE) – Health and Safety Executive.
Construction information sheet No. 26, (revision 2), London: HSE
books, 2002
[4] GREAT BRITAIN. Control of Substances Hazardous to Health
Regulations (COSHH) 2002 (as amended). London: The Stationery
Office.
[5] GREAT BRITAIN. The Chemicals [Hazard Information and
Packaging for Supply] Regulations (CHIP 4) 2009. London: The
Stationery Office.
[6] EUROPE. Regulation (EC) No. 1907/2006 of the European
Parliament and Council of 18 December 2006 concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals
(REACH), establishing a European Chemicals Agency, amending
Directive 1999/45/EC and repealing Council Regulation (EEC) No.
793/93 and Commission Regulation (EC) No. 1488/94 as well as
Council Directive 76/769/EEC and Commission Directives 91/155/EEC,
93/67/EEC, 93/105/EC and 2000/21/EC. Brussels: OJEU L 136
[7] FAIRHURST, S., et al. – Portland Cement Dust Criteria document,
for an occupational exposure limit, (HSE EH65/12), London: HSE
books, 1994.

46 • © BSI 2011
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