Chem 26 Practicals Reviewer  Use methyl orange, yellow to near orange, stop

titration and boil, resume titration until orange

Exp 1
 Soda ash – titrated with HCl using
 Coins weighing by difference phenolphthalein, the methyl orange, same as
standardization
Exp 2

 Dilution factor
o total volume of soln/volume aliquot
o To determine original
 Aliquot factor
o Volume aliquot/total volume soln
o To determine diluted Exp 7 - Quantitative Determination of Total Hardness in
 Acid to water Drinking Water by Complexometric EDTA Titration
 NaOH is hygroscopic
 H2EDTA (Na2H2EDTA 2H2O) + MgCl2 crystals +
Exp 3 – Iodine Clock Reaction NaOH pellets
 S2O82-(aq) + 2I-(aq) → 2SO42-(aq) + I2 (aq)
 2S2O32-(aq) + I2(aq) → S4O62-(aq) + 2I-(aq)
 Beaker A – KI + KCl
 Beaker B – S2O82-, SO42-, S2O32-, starch
 CuSO4 - catalyst

Exp 4 - Common Ion Effect and Buffers

 Primary std CaCO3 dissolve in dH2O then HCl

 Solution 1: 30.0 mL 0.10 M CH3COOH
 Solution 2: 15.0 mL 0.20 M CH3COOH – 15.0 mL
0.20 M NaCH3COO
 Solution 3: 30.0 mL 0.10 M NH3
 Solution 4: 15.0 mL 0.20 M NH3 – 15.0 mL 0.20
M NH4Cl
 NH3 NH4+ buffer
 Further dilution of EDTA and Ca soln
 Standardization – use caco3 soln + dH2O +
buffer + EBT
 Wine red to clear blue
 Titrate 50 mL of water sample + buffer + EBT
Exp 8 - Quantitative Determination of Dissolved Oxygen
Content by Winkler Redox Titration

Exp 5 – Determination of Ksp of Ca(OH)2

 Primary standard sodium carbonate Na2CO3

 Ca(OH)2 titrated with HCl ind phenolphthalein
 CaCl2 common ion
 KCl ionic strength
Exp 6 - Quantitative Determination of Soda Ash
Composition by Double Indicator Titration
 Use boiled dH2O to dissolve carbon dioxide
 Standardization of HCl using Na2CO3 ind methyl
orange
 Standardization of Na2S2O3
o Dissolve KIO3, take 3 aliquots and
dilute, add 1g KI and 10 ml 0.5M H2SO4
o Titrate with Na2S2O3 until pale yellow,
add starch, titrate until blue color
disappears
 Water sample
o Add MnSO4 + NaOH with KI and NaN3
o Add H3PO4 to dissolve ppt
 o Shake and let it stand for 10 mins

Exp 9

 Galvanic cu + zn/ cu+fe graphite electrode

 Electrolytic KBr/KI generate Br2/I2 for 1 min
using dry cell series connection
 Galvanic cell to determine v

Exp 10

 Titrated with NaOH, standardize using KHP

 1 ml increment beginning
 +- 5ml – 0.5 increment
 +-3ml – 0.2
 +-2ml – 0.1
 Continue until pH 11

Exp 11

 Copper nitrate + NH3

 Measure analytical wavelength
 Calibration curve
 Highest conc -> press 2 -> enter wavelength
range -> start
 Blank -> Press 1 -> GOTO WL ->enter
wavelength -> enter -> autozero -> insert other
cuvettes

Exp 12

 Dowex 50 cation exchange resin

 pH eluate = pH dH2O
 titrated eluent with NaOH
 Standardize with KHP