ision of Oil and Gas Resources Management Radiation Safety Section Interoffice Memorandum To: Richard J. Simmers, Chief THROUGH: Scott Kell, Assistant Chief FROM: Chuck McCracken, Manager, Radiation Safety Section chop. DATE: uly 26, 2017 RE: ASSESSMENT OF RA226 & RA228 RADIOACTIVITY IN AQUASALINA As requested, an analytical assessment of the radioactive content of Nature's Own Source / AquaSalina and the vertical well brine associated with its production was initiated on May 24, 2017. During the month of June 2017, Radiation Safety Section (RSS) staff partnered with Environmental Safety Section staff to collect 14 samples from 6 locations in Ohio. All samples were sent to PACE, Radiological Analytical Laboratory with the last of the analytical results being received back from PACE on July 5, 2017. ‘The attached radiological survey report no. 2017-044 details the RSS radiological assessment process and the results achieved. Based on the findings in this assessment, the following recommendations are being made for your consideration: 1, Advise Nature's Own Source/AquaSelina that our assessment finds that they are producing TENORM however, we require additional details about their production process to be absolutely certain, (NOTE: We may need to collect additional pre and post samples) 2. Advise Nature's Own Source/AquaSalina that the average radioactivity in AquaSalina exceeds the 40 CFR 141.66 Drinking Water limits for combined Ra-226 and Ra-228 by a factor of 300, ‘thus humen consumption of any amount of AquaSalina is highly discouraged, 3. Advise Nature’s Own Source/AquaSalina that the radioactivity in AquaSalina exceeds State of Ohio discharge to the environment limits for Ra-226 and Ra-228 as delineated in Ohio Administrative Code 3701:1-38-12, Appendix C, Table I, Effluent Concentrations, 4. DOGRM should continue to analyze the radioactive concentrations in vertical formation brine to create an Ohio specific data set that can be used to further assess impacts to humans and the environment from the uso of vertical brine from the oil and gas industry for dust suppression and road stability, cf Erie Vendel, Legal CounselDIVISION OF OIL & GAS RESOURCES MANAGEMENT, RADIATION SAFETY SECTION Report No: Permit No(s): Location(s): Counties: Date(s): Inspector: RADIOLOGICAL ASSESSMENT SPECIAL REPORT 2017-044 Chief's Order 2004-82 Nature’s Own Source/AquaSalina 246 North Cleveland Avenue Mogadore, OH 44260 Nature's Own Source/AquaSalina 2850 W. 3°Street Cleveland, OH 44113 Guernsey, Summit, Tuscarawas, Cuyahoga June 2, 2017, June 5, 2017, June 12, 2017, June 15, 2017 and June 21, 2017 Inspector: Arbext:Lascly, Date: o7/2072017 Robert Leidy Senior Health Physicist Paul Carder Date: 07/26/2017 Supervisor: Paul Carder Senior Health Phy: hop Date: 97/26/2017 (Chuck McCracken Section Manager10 2.0 Purpose At the request of the Chief, Division of Oil & Gas, an analytical assessment of the radioactive content of Nature's Own Source / AquaSalina and the vertical well brine associated with its production was conducted, Scope of Action / Sampling Methodology ‘May 24, 2017 Two Ohio Department of Natural Resources, Division of Oil & Gas Resources Management (00GRM) staffs were assigned to go to Nature’s Own Source /AquaSalina facility located at 246 North Cleveland Avenue, Mogadore, OH 44260 to collect pre and post-production samples of their liquid deicer, AquaSalina. Upon arrival staff was met by Stephanie Moore. The property owner, Jeff Moore, spoke to staff by phone and requested that they communicate directly with Mr. Dave ‘Mansbery, the owner of Nature’s Own Source/AquaSalina. Staff spoke with Mr, Mansbery, who was attending an Ohio DOT trade show. Mr. Mansbery said that AquaSalina is out of season and not currently in production but there is product on site. Mr. Mansbery offered to make arrangements for a qualified individual to be onsite to assist DOGRM staff by providing access and collecting split samples of AquaSalina. Staff suggested to Mr. Mansbery that he coordinate a return, Visit to the Mogadore facility with DOGRM Management. No samples were collected this day. June 2, 2017 ADOGRM Columbus office staff member collected two 1-liter samples from a container of AquaSalina that was in storage at the DOGRM Environmental Analytical Laboratory located at 325, N. 7th St., Cambridge, Ohio 43725. Each sample was preserved with HNO3. A chain of custody was created and the samples were delivered to the Pace Analytical Laboratories Service Center located ‘at 4860 Blazer Pkwy, Dublin, OH 43017, June 2, 2017 ADOGRM Uniontown office staff member was assigned to go to Hartville Hardware located at 1315 Edison St., NW, Hartville, OH 44632. Staff purchased a 1.74 gallon container of AquaSalina at this, location. Staff then went to Lowe's Home Center located at 940 Interstate Parkway, Akron, OH 44312 and at 12:20 pm, purchased a 2.11 gallon container of AquaSalina. Two ‘liter samples were collected from each of the 2 containers of AquaSalina, Each sample was preserved with HNO3. A ‘chain of custody was created and the samples were delivered to the Pace Analytical Laboratories Service Center located at 4860 Blazer Pkwy, Dublin, OH 43017, June 12, 2017 ‘Two DOGRM staff members were assigned to go to the ODOT Tuscarawas County Garage located at 384 Stonecreek Road SE, New Philadelphia, 44663 to collect samples of brine that was made by adding halite salt to tap water. Two 1-liter samples were collected and each sample was preserved with HNO3. A chain of custody was created and the samples were delivered to the Pace Analytical Laboratories Service Center located at 4860 Blazer Pkwy, Dublin, OH 43017. June 12, 2017 Two DOGRM staff members were met in Mogadore by representatives for Nature’s Own3.0 Source/AquaSalina, Larry Gibler, Jim Hogue and Precision Analytical staffer, Jeremy Bratnick Samples were collected by DOGRM and Precision Analytical of pre and post-production liquid. Each DOGRM sample was preserved with HNO3 and tamperproof seals were placed on the sample containers. A chain of custody was created and the DOGRM samples were delivered to the Pace Analytical Laboratories Service Center located at 4860 Blazer Pkwy, Dublin, OH 43017. DOGRM staffs were then directed to the Nature’s Own Source/AquaSalina’s Cuyahoga County facility located at 7033 Mill Road, Brecksville, OH 44141 to collect additional samples. Upon arrival staff was told that the location was a corporate office only and AquaSalina was not produced there. Staff was told that the Cuyahoga County production facility is located on the Arcelormittal Stee! Mill, property located at 2850 W. 3rd St., Cleveland OH. Staff was then informed that DOGRM's legal department needed to contact Nature’s Own Source/AquaSalina’s lawyer, Scott Doran, to discuss obtaining samples. No samples were collected. June 15,2017 Two DOGRM staff members were met at the Nature’s Own Source/AquaSalina production facility on the Arcelormittal Steel Mill property by company representatives, Larry Gibler, Jim Hogue and Precision Analytical staffer, Jeremy Bratnick. Samples were collected by DOGRM and Precision Analytical of pre and post-production liquid. Each DOGRM sample was preserved with HNO3 and tamperproof seals were placed on the sample containers. A chain of custody was created and the DOGRM samples were delivered to the Pace Analytical Laboratories Service Center located at 4860 Blazer Pkwy, Dublin, OH 43017 ne 21, 2017 DOGRM staff returned to the ODOT Tuscarawas County Garage to collect samples of the raw water used to create the brine mixture sampled on June 12, 2017. Each sample was preserved with HNO3. A chain of custody was created and the samples were delivered to the Pace Analytical Laboratories Service Center located at 4860 Blazer Pkwy, Dublin, OH 43017. Observations / Analytical Results ‘Sample Collection Location | Collection | Ra226 Results [Ra228 Results (pCi/I)"] Combined Results Date (pcs (eci/* Lowes — Canton [purchase] 6/2/47 1,059 + 136] 604 # 113) 1,663 + 249] Hartville Hardware [purchase] | 6/2/17 1,158 £144 1,333 + 241] 2,491 + 384) DNR Cambridge Lab 6/2/17 791 + 41.3) 604 + 25.7] 1,395 + 67.5| [Aquas Mogadore - PRE 6/12/17 925 + 116] 373+ 69.8) 1,298 + 185.8| = POST 6/12/17 1,010 £12 432 80.1) 1,482 = 206.1| fAquaSCleve = PRE (1) | 6/15/17 595 + 772| 568 + 127] 1,163 2 899] = Post (1) | 6/15/17 949 + 478| 734 + 129] 1,683 + 607] =PRE (2) | 6/15/17 501 # 463| 387475) 888 + 537| = Post (2) | 6/15/17 997 + 545| 713 + 102] 1,710 +647] ODOT tap water - PRE 6/23/17 1.90 0.3) 0.922 + 0.4) 28 212 [ODOT mixture _- POST 6/12/17, 2.77 #1.58| 5.78 + 7.67] 8.55 £9.27] * Analytical laboratory results reports are attached.4a Findings, Discussions & Conclusions indings '* All post-samples collected in this study were found to be increased in radioactivity activity from theirrespective pre-samples. ‘+ There was an 11% increase in combined radium Ra226/Ra228 concentration between the pre and post-samples collected from the Nature’s Own Source/AquaSalina Mogadore production facility. ‘* There was a 45% increase in combined radium Ra226/Ra228 concentration between the pre (1) and post (1) samples collected from the Nature's Own Source/AquaSalina Cleveland production facility. © There was a 92% increase in combined radium Ra226/Ra228 concentration between the pre {2} and post (2) samples collected from the Nature's Own Source/AquaSalina Cleveland production facility. '* The combined radium Ra226/Ra228 concentration in the Nature's Own Source/AquaSalina container purchased from Hartville Hardware was the highest identified in this study at 2,491. pCifl © The combined radium Ra226/Ra228 concentration in all samples of post-production AquaSalina (except the Hartville Hardware container sample) averaged within 10% of each other at 1578.6. pCi/l. ‘© There are no production dates, lot numbers or other unique identifiers on the purchased containers of Nature's Own Source/AquaSalina, Discussions ‘+ Formation brine is Naturally Occurring Radioactive Material (NORM). Technologically Enhanced NORM (TENORM) is NORM that has been increased in radioactivity by or as a result of human activity’. It would appear that Nature’s Own Source/AquaSalina is producing TENORM however, without additional batch. processing information from them, it cannot be determined with 100% certainty that the sampled pre-production brine has been increased in radioactivity due to the AquaSalina production processes. * The USEPA National Primary Drinking Water Regulation, 40 CFR 141.66 limits combined Ra- 226 and Re-228 in drinking water to 5.0 pCi/l. ‘* The State of Ohio discharge to the environment limits for Ra-226 and Ra-228, as delineated in Ohio Administrative Code 3701:1-38-12, Appendix C, Table Il, Effluent Concentrations, are 60 pCi/Ifor each (120 pCi/I for combined Ra226 & Ra228 and the unity rule applies). 1 Abbreviated TENORM defen, Full defi fund in ORC 3748.01 as stated in ORC 150.078 (Ct)* The Pennsylvania Department of Environmental Protection (PADEP) TENORM Study Report, Revision 1, dated May 2016 assessed radiation exposure to humans from road spreading of conventional (vertical) well brine. - The assessment was based on surface soil samples taken from roads where brine spreadingis known to have occurred. The specific radioactive concentration of the brine that was spread on these roads was not considered in the assessment. ~ Theestimated total dose toa recreationist was. modeled to be 0.441 mrem/yr, which is well below PADEP’s 100 mrem/yr public exposure regulatory limit. ~The report concluded that while limited potential was found for radiation exposure to recreationist using roads treated with brine from conventional (vertical) gas wells, further study of radiological environmental impacts from the use of brine from the oil and gas industry for dust suppression and road stabilization should be conducted. ‘* Other states in our region of the U.S. that allow road spreading of ve brine include Michigan, illinois, Pennsylvania and West Virginia, 1 oil anc gas well Conclusions ‘+ Analytical results suggests that Nature's Own Source/AquaSalina is producing TENORM however, without additional batch processing information, it cannot be determined with 100% certainty that the sampled pre-production brine has been increased in radioactivity due to the AquaSalina production processes. © Allsample results (except the DOT tap water) exceed the USEPA 40 CFR 141.66 Drinking Water limits of combined Ra-226 and Ra-228 at less than or equal to 5.0 pCi/|. > None of the sampled liquids (except DOT tap water) in this assessment are meant for human consumption. ‘© Allsample results (except the DOT samples) exceed State of Ohio discharge to the environment limits for Ra-226 and Ra-228 as delineated in Ohio Administrative Code 3701:1-38-12, Appendix C, Table Il, Effluent Concentrations. These liquid effluent concentration limits were originally codified by the U.S. Nuclear Regulatory Commission to limit public radiation exposure to 50 millirem per year from ingestion of radioactive material discharged into rivers, streams and other bodies of water by companies and facilities licensed to possess and handle radioactive materials > None of the sampled liquids (except DOT tap water) in this assessment are meant for human. consumption, ‘© Using the assumptions and findings in the PADEP study, RSS evaluated the post-processing sample results from this assessment and determined that it is unlikely that radiation exposure to Ohioans from road spreading of vertical brine would exceed the 100 mrem/yr public dose limit.Ba Recommendations . Advise Nature's Own Source/AquaSalina that our assessment finds that they are producing TENORM however, we require additional details about their production process to be absolutely certain, (NOTE: We may need to collect additional pre and post samples) . Advise Nature's Own Source/AquaSalina that the average radioactivity in AquaSalina exceeds the 40 CFR 141.66 Safe Drinking Water limits for combined Ra-226 and Ra-228 by a factor of 300, thus human consumption of any amount of AquaSalina is highly discouraged, |. Advise Nature's Own Source/AquaSalina that the radioactivity in AquaSalina exceeds State of Ohio discharge to the environment limits for Ra-226 and Ra-228 as delineated in Ohio Administrative Code 3701:1-38-12, Appendix C, Table lt, Effluent Concentrations. |. DOGRM should continue to analyze the radioactive concentrations in vertical formation brine to create an Ohio specific data set that can be used to further assess impacts to humans and the environment from the use of brine from the oil and gas industry for dust suppression and road stabilizationATTACHMENT ae Radiological Analytical Results for: JODNR Cambridge LabPace Analytical Serdces, LLC 196 Roseytoun Row Suns 2.34 ‘Greonsbug, PA 18801 (7249508500 June 19, 2017 Ms. Michelle Taylor Microbac Laboratories, Inc. 158 Starlite Drive Marietta, OH 45750 RE: Project: Aqua Pace Project No.: 30220752 Dear Ms. Taylor: Enclosed are the analytical results for sample(s) received by the laboratory on June 06, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Hyou have any questions concerning this report, please feel free to contact me. Sincerely, (Lovrrin dee. Robbin Robl robbin.robl@pacelabs.com (724)850-5613 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS “Tere aa note repreducod. xcopin ia the tn consent cf Pace Anaya! Sodas LLC Page 1 of12(a ical” CERTIFICATIONS Project aqua Pace Projet No: 90220762 Pennsylvania Certification IDs 41836 Roseyioun Rd Sule 2,384, Greensburg, PA 15501 LAB DOD ELAP Aceraltaton #12417 Alabama Cartcaton #41590, ‘zona Cariication #: AZO734 ‘Ackaneas Certfenfon Caiforis Conification #0422208 Colorado Cetineation Connects Caricaion # PH.0694 Delaware Certification Flos TI Certification # £87682 Georgia Certticaton #: C40 ‘Guam Certification Hawai Ceiation ‘aho Certiation Itinois Certfeaton Ilana Cerseation fowa Certfcaton #: 991 ansas/TNI Certifcation # E-10358, Kentucky Cortfestion #: 00183 Louisiana OHH/TNI CartNeaion # LA140008, Louisiana DEQITNICerttcaon # 4088 Maine Certfication &: PAQ0001 Manland Certfcaion #: 308 Massacrusets Cetifoation & MLPA1A5? MichiganPADEP Cestcaton Missouri Cericaton #235 _Wyorning Certction#: SMS. Montana Cortfcation #: Cort 0082 Nebraska Certification NE-05-20-14 Nevada Certfcaton # PROIAS7Z015-1 New Hamrpshice/TNI Certicalion #: 2876 New Jersey/TNI Ceniication#: PAGS New Meco Certification # PADIAS7 New York/TNI Cation #: 10888. North Caran Certcaion & 42706 North Dakota Certfation #: R190, ‘Oregar/TNI Centieation #: PAZCOOO Pennsyivania/TWl Cention #: 65-00282 Puerto Riza Cerifcatin #: PAOT4S7 Rhode island Cerifiaton &,86-00282 ‘South Dakota Ceriication ‘Tennassee Certification & TN2867 ‘Texas/TNi Catioation #: T104704188-16.8 Uieh TW Centcation # PADTABT2015-5 USDA Sol Permit # P390-14-00213 ‘Vermont Dept. of Heal: ID# VT-0282 \rginIstand.PADEP Certtcaton \VeginarVELAP Certification #: 420108 ‘Washington Certfeation#: C868 ‘Wost Viginis DEP Certfcation#: 143 ‘West Viginia DHHR Certncation & 9958 Wisconsin Cartcation REPORT OF LABORATORY ANALYSIS “This feor hat nate reproduced xcept fl Pace Araya! Serews, LLC 1698 Reseyoun Road Sule 23:4 ‘Greensburg PA 15801 (reqpesosen0 Page 2 of 12Pace Anaya Services, LLC ° 168 Rosstown Reed» Suls 2: Analytical ors | vemepanscen (724pes.s600 ‘SAMPLE SUMMARY Project ‘Aqua Pace Projet No: 30220752 Lab 1D ‘Sample 1D Matrix Date Collected —_Dete Received | ‘30720762001 Aqua.t-226 water cena? 200 ower? 1015 | 30220782002 Aqua2.228 Water con2n7 1200 oausrt7 1045 | REPORT OF LABORATORY ANALYSIS. “hia op shal notte produced, excepto, uot tn itn concent Pace nail Sandee LAC Page 3 0f12aco Analytical Servos, LLC 1698 Roseriwn Raed Sue 2.84 ‘Gresnaburg, PA 18001 i ono agen | ‘SAMPLE ANALYTE COUNT | Propet eu Pace PrectNo: 20020752 nates Labi Samle Metro Analyte _ Reportod doanorsaoor Aqua-taze camo wane 7 soazors2one — Aquaa.zae ePaouo ave 1 REPORT OF LABORATORY ANALYSIS. “hop aha nat be reproduced xcoptin i, witht the wien cuneen ef Pace Anat! Sonics, LLC Page 4 of 12ac Anahel Sns, LL6 Analytical ser, Pan ‘wnnpaecon (72qso-se00 PROJECT NARRATIVE Project Aqua Pace Projecto: 90220752 EPASORA 103.1 Raclum 226 IMlrobae Laboratries, nc-OH ‘dune 19,2017 General formation: 4 sample was analyzed for EPA003.1. Al eamplos were received in aceaptabie condton wth any exceptions noted below or onthe Charof custody andor the sample canton pen reset form (SCUR) atlached at he end ofthis report. Hole Time: The samples ware analyzed witin the method requied hold tes with any excepions noted below. Method Blank: All analyies ure below the epor limit in the method blank, where apical wt any exceptions noted below Laboratory Control Spike: [ilaboratory eat! epike compounds were within QC its wth any exoaptions noted below Matrix Spikes: [All percent recoveries and relative perertalerences (RPDs) were within acceptance criteria wih any exceptions nated Below ‘Additional Comments: REPORT OF LABORATORY ANALYSIS ‘Tie repot onal note epee exept witout te win consent Pas aise Senco, LLC Page $0112Pace Amis Sess Le ; sexe Ronpown Rand Some 23.8 Analytical Gren oa 508 ‘mi sense PROJECT NARRATIVE Project: Aqua Pave Project No: 30220752 Method: EPASOAD Description: 904.0 Radhn 228 Client: Mlorobac Laboratories, Inc-OH Date: une 19, 2017 ‘General Information: { samp was analyzed for EPA 906.0, Al samplos were resived in acceptable condition wth any exceptions noted below or on the ‘Sham-of custody anor the sample condition upon ceil form (SCUR) allached atthe ene of te reper. Hold Time: ‘The samples were analyzed win the method required hold tines with ary exceptions noted below. Moths Blank: A analytes were below the report it inthe method blark, where apelcabe, with any exceptions noted below. Laboratory Control Spike: A laboratory conto spike compounds were wihin QC lini with any exceptions noted below Matex Spik [A porcent recovers and relative percent aiflerences (RPDs) were win acceptance ceria wih any exceptions noted below, ‘Adsitional Comments: ‘Anayte Conmens (0c Baten 261657 ‘4c: During he ingronthing process, pat ofthe MB vias ost. and the resting chomioalyold is below 10% and the associsad MB. MDC fs grater than 1.0 pCIL- individual sample results are nck impacted by te sevated MOC or low MB yield * BLANK (ab 0: 1268491) + Rachum228 ‘This data package has been reviewed for quality and completeness ad's approved for relesbe. REPORT OF LABORATORY ANALYSIS “Ths pot she rot be reprodued excaptin t, snout wien const of Pace Anaya! Serves LLC age 6012epoca Projet ‘Aqua ace Projet No 90220762 ace Anaiyteal Servos, LLC 1658 Reooyoun Road Sule 23.4 ‘resrsbrg, PA 15508 (7appese.se0a ANALYTICAL RESULTS - RADIOCHEMISTRY Sampler Aquat-228 TabiO: 30250752001 Cofecies: OB/0RIT7 1200 Recehed: OBIDG/I7 10:18 Matric Water Siew: ‘Sample Type: Pas: rameters Method Acts Une (MDC) Car Tac Unis Arayeed —_CASNo Qual Racoma26 Pawo Teiaais (68a) POUL GBrNBN7 102 13982655 AT9% ‘Sanplar Aquad25 TabiD: 90220752002 Golected: 06102117 72500 Received OB1ENT 10:15 Waibe Water Pw: Stoo: ‘Sample Type: Parametars ethos ‘Act = Une MDC) Cart Trac Unis Anayzed _CASNo. Qual Racha 238 Paseo Sons wB7 (118) POW OBM/IT 10:80" 15262204 2h Te REPORT OF LABORATORY ANALYSIS ‘This tport hal rete reproduced, ncetin fl winouttno writen consent Pace Aaitcal Serves, LC Page 7 of 12Pace Anaya Services, LLC 1698 Roeyown Road Sutae 23.4 ‘Greanabizg, PA 15501 vonepossean (72gpesoseoo ‘QUALITY CONTROL - RADIOCHEMISTRY Project aqua ce Project No 90220782 aC Bates 251687 ‘Analysis Moth: EPADDAD (OC Baten tenes: EPARO.O ‘Analysis Descripton: 904.0 Radium 228, ‘Astociated Lab Samples: 30220752002 METHOD BLANK: 1288401 TWatioe Water ‘Associated Lab Samples: 0220782002 Parameter ‘Act Une (MDC) Car rae Unis ‘naiyzes Qualifiers aaa 228 DangE ae (@I9)C7E FIM POV. 8/1917 1030 Te nents preceric oe th pageare lh nts ella th"Unt” cola excel ere sara ul peso he RT REPORT OF LABORATORY ANALYSIS Tha eportehl nabs reproduced, eect winou he writen consentot Paes Anges Senior, LC Page 8 0112Pace Aneel Sercss, LLG 1 Reeetoun Roal- Sus 23.4 ‘Analytical (reensbug PA 18804 wegen «2syssost00 QUALITY CONTROL - RADIOCHEMISTRY Project: Aqua Pece ProfectNo: 90220752 ‘GC Baier 251616 ‘araysis Method: EPAGDOA (OC Batch Method: EPA903-1 ‘Analysis Desciplin: 903.1 Radium-220 ‘Associated Lab Samples: 30220752001 METHOD BLANK 1207918 Mabie: Wator ‘Associated Lab Samples: 30220782001 Parameter ‘et Une (WDC) Car Trae Units ‘Analyzos —_Quatfers dium 228 ‘006220284 (0.578) CNATOT% pou OaraniT Oz Ross pened nh ape rh nts iat “Ucn exept wee aerate i reed go ee. REPORT OF LABORATORY ANALYSIS ‘This rpot aha not bo roproduced, xcept fl ‘winouthe wrsen consent of Pace Anya Sania, LC. Page 0 of 12Pece Analiial Soros, LLC al ‘eon necjoun Road 234 ce Analytical ‘Greonsburn, PA 18801 mpi (raneens609 QUALIFIERS Project: Aqua Pave Projecto: 20220782 DEFINITIONS. DD - Ditlon Factor, if reported, represents he factor appied Io the reported data due o dition ofthe sample sliquo. [ND - Not Detected ai cr above adjusted reporting Et .J- Estimated concentration above the adusted method detection Int and below the adjusted reporing limit MOL -Adjusted Method Detection Limi POL - Practical Quantation Limit. RL - Reporting Lima. S- Surogate| 1 2.Dipharyitydrazine decomposes to and cannot be soparated fom Azobenzens using Method 8270. The result for each analy is combined concentration Consistent with EPA gudetnes,unrourded data ere displayed and have been used to calle % recovery and RPD values, LCS(O)- Laboratory Contiot Sample upate) MIS(O)- Matrx Splke (Cupteate) DUP - Sample Duplicate RPO - Relative Percent Derence NC-Not Calevabe. ‘SG -Stica Gel - Clean-Up U- Incicates the compound was analyze for, but pot detected. N-Nitosaxiphenylamine decompases and cannot be separated from Diphenylamine using Metiod 8270. The result repoces for ‘ach analyte is 3 combined concertatcn, ‘Act -Actvty Une Uncertainty: SOWA 1.96 sigma count uncedany all ather matrices = Expandod| Uncetainy (05% contdanes iteve ‘Gamma Spee = Expanded Uncertainty (05.4% Canfdence Inara) (400) - Minimum Detectable Concentration Trac Tracer Recovery (4) Car - Carer Reoavary (8) Pace Analytical TNI accredited. Contact your Pace PM forthe curent tof accredited ana TNI-The NELAC Insitute ANALYTE QUALIFIERS. te ‘Dixing he ingronthing proces, part ofthe ME was los, and he resuting chemical leas below 10% and he associated ME MDC & greater than 1.0 pOVL. Indhidual sampie resus are not impacted by the elevated MDC or low us vita REPORT OF LABORATORY ANALYSIS. ‘Thi repot aha nota reprodced eactio ate: 061072017 02:82 Pal wincu ne aia consantof Pasa Anite Sanons, LLC Page 10.0f 12ne Page 11 of 12 2 aman os) cys (S08 Hp i) LI-F-F DPPH Bebe Ol] Leg) apy i orois) arpa | au, | oo a Irani Lown) Wear-eee-008- 264 al, Heorese-or4 ‘utd OF rn ieo) EA womans |e ear 5 el] 8] asl al |B Veo EY lealglelal (b “=o ey letteveld) 2 pan ee ae Ey a) i eyal TaXpEDSIN HUD 07) gy Lea] i z fpetng Pabia ees. £) 2) = 58D 10 40 UOING-UNGONG FOSS Cstaactsnaedednaig To eDVIOUIING ong SHES est a ogter'v ON 509(frbaweet crock Name: Miceobac Project #. 30220752 - courier Bec ex Cl urs Fuses () cles (commercial) Pace ober Tracking “72 7B OF 34 423: Custody Saal on Cooler/Box Prasent: 2 ‘C] no Seals intact “Slee 0 —_ cooler Temperature Observed Tamp "© Correction Fadlogee—— "© Final Temp: “Tema shouldbe above hssinge PC Daa aaae ones NL aoe hy ‘Comments: [Yes] No [NA aes ; eae seeca be Esa once E tea cok |Sampla Labels match COC: << ES ane aa a E [Short Hold Time Analysis (<72hr remaining): (7. I eteriareras f | Sufficient Volume: Jo. See 7 eee feaiaeeaac i nun comes oto ae rn Here volume soceived for Dissolved tests 14. } a a cummins Bf | | PH <2 seston: VOA. etn, 706, 089, Prost legs /4C Gees | eae sets ita oni eh a i Faure fs | greener ji Se aay ee SGT eaeeecoceaaes a me ee Secu : TE A cc in this box ndicatas that addline! information hasbeen stored in eropors. i note: Moree thle e dseepency sacra North Crna compe saris, scopy fw sent as Narh Caratna DEHN Dereon oe (im tof ie cara peseNaie, ce! rp nearest arr) : “Patrevous carn suareriey IMS. When be Prog Maen cisee fe SRE Reverses LOIS, The een ain the Sus sosfon tha sero Ea Seren, nonoCeeebocuren ManapanensSarse Metarale Condon Upen Resi PHAN OHS THO Bang 49 of 42ATTACHMENT 2 Radiological Analytical Results for: Lowes — Canton [purchase] Hartville Hardware [purchase]Pace Anata Sevces LC fal” 1630 Roseviown Rond Sues 23.4 ice Analytical (Greensburg PA 150% ‘weapon (rases0s000| June 19, 2017 Ms. Michelle Taylor Microbac Laboratories, Inc. 158 Starlite Drive Marietta, OH 45750 RE: Project: 2017-Aqua-NE Pace Project No.: 30220748 Dear Ms. Taylor: Enclosed are the analytical results for sample(s) received by the laboratory on June 08, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Ifyou have any questions concerning this report, please feel free to contact me. Sincerely, Gooorin. Gee. Robbin Robl robbin robl@pacelabs.com (724)850-5613 Project Manager Eneloeures REPORT OF LABORATORY ANALYSIS “isopot she robe reproduced, except in wtnauthe writen consent of Pace Ansel Sane, LC. Page 1 of 12Pace Analy! Saris, LLC ce Analytical” ren tot ‘eee com (72speso.sco0 CERTIFICATIONS i Projet: 2017-Aqua NE | Pace Projecto: 90220748 Pennsylvania Corlifcation IDs 163 Roseytown Ra Suites 2.384, Greensburg, PA 16601 Montana Gocticaton#: Cert 0082 LAB DOD ELAP Accreditation #: L247 [Nebraska Cestinttion #: NE-05-28-14. ‘Alabama Contteation #41800 ‘Nevada Certification &: PA0T4572015- | ‘Aneona Certiaton : AZOTSA "New Hampehi/TNl Certtaton : 2976 ‘Arkansas Certification ‘New JerseyITNI Corttcaton # PA O5t ! Calfomia Certfcstion #: 042220, ‘New Mexico Cateston # P80 1487 ‘Colorado Certieaton New Yor/TNI Gerifcation #10888 Connect Cetticatlon#:PH.0694 North Carina Centicaton #42706 I Delaware Certification North Dakota Certication #: R-190, Florida TN Carticaton # £87683 Oregon/TN Centcation a: PA200002 | Georgia Certicaton #: Co4a Pennsylvania Certification # 85-00282 Guam Certication Pueto Rica Cerifcaton #: PADT487 HawallCerfcatin Rhode lland Certiceton 86-00282 Ieaho Gartiation South Dakota Gertitcaton Iino Certieaton ‘ennesse9 Cerfeaton &: TN2867 Inlans Ceatteaton ‘Texas/ IN Cortfcation #:T104704108-14-8 awa Cenfictien 391 Utah7Tl Cartfcation #:PADIAS72015-5 Kansas/TNI Certicaton # F-10958 USDA So Porm: P330-14-00213 Kentucly Certfestion #: 90193, Vermont Dept. of Heath I0# VT-0282 Lauisiana DHH/TW Certionion # LA140008 Virgin IsiandPADEP Cesticaton | Louisiana DEQITMICartfction # 4086 \VirgniaVELAP Centfcaton : 480108 |! Maine Certification : PA0000% Washington Cerifeation#: C868 Maryland Gertfcation#: 208 ‘West Viginia DEP Certfication #148 Massacrusetts Centfcaion & MLPA1&57 ‘west Viginia DHHRCeriicaton # 98840 Micigan/PADEP Certiication Wisconsin Ceification Missouri Cericaton #235 REPORT OF LABORATORY ANALYSIS. “Thi repot hal rete reprotuced, cp hou te writin congentt Pace Patent Sener, UC. Poge 2 of 12ace Anaya! Servos, LLC Anaya” seotootn ia ert (7249505600, ‘SAMPLE SUMMARY Project 2or7-Aqua NE: Pave Project Nos 30220748 Lab 10 ‘Sample 1D Matrix ___Deto Collected _Date Recetved ‘30720748001 Lowes-4 ‘Water 06105117 0800 O8t08/17 10:18 30220748002 Lowes-2 Water vsins7 0802 — vawsrt7 10:16 ‘0220748003 HH Water 08)05/17 0804 08/08/17 10:16 | sozzovagone HH.2 water osiosi17 0808 oB/OB/I7 1015 REPORT OF LABORATORY ANALYSIS “hierar shal not epoca accept itu th win concent Pace Ansytal Senses, LAC Page 3 of 12(a ical” ‘SAMPLE ANALYTE COUNT Pace anata! Serves, LLC 1498 Reselown Road Sus 23.4 Greensburg, PA 15201 (e24esoss00 Project 2or7-Aque NE Pace ProjoctNo: 30220748 Analytes Lebo Sample 1D Method Analysts Reported 30720748001 Lowest PAGS. RR 1 ‘90220749002 Lowee-2 EPAGO4O aw 1 30220743003 HH PAGS: war 1 30220748008 HH2 PAGO sow 1 REPORT OF LABORATORY ANALYSIS Thisropor sheet bo produced, oxceptin ful, inoue unten consent of Pane Ana! Senn, LLC. Page 4 of 12ace Analytical Serves, LLC af? 1626 Roseytown Road Suet 23.4 sapien PROJECT NARRATIVE Project por AqENE Pece Project No. 90220748 Method: EPASO31 Dseripton: 803.1 Radium 228 Clients Micratee Laboratres,Ine-OH Date: June 19, 2017 General Information: 2 sample were analyzed for EPA 003.1. All eamples wore recelyed in acceptabie condtion win any exceptions noted below or onthe ‘hairot exsody andlor the sample condiion yponreceo! form (SCUR) atached al he end oF is report. Hola Teo: ‘The samples were analyzed wit the method required hold times with ary exceptions nated below. Mothod Blank: All anaes were below the repo init inthe method bnk, where applicable, wit ary exceptions noted below, Laboratory Control Spike: ‘laboratory cata spike compounds were wihin QC ts wth any exceptions noted below. Matrix Spikes: ‘All percent recoveries and relave peroet aferances (RPDS) were winin acceptance entra with any exceptons noted below. ‘Additional Comments: REPORT OF LABORATORY ANALYSIS. ‘Thisrepo shal not be reproduced veoptin a, witht the wisn cinean of Pace Ania! Serve, LLC. ‘Greonabrg, PA 15808 (72450-5600 Page 50112Pace Anaya Soe, LLE inal” ‘8 Roeyown Road Sues 254 ‘Analytical rene. 15801 ‘epee PROJECT NARRATIVE Project 2or7-Aque NE Pave PiojestNos 90220748 (72«150-5600 EPAD0LO 906.0 Recium 228 Mirobae Laboraeres,inc-OH June 18, 2017 ‘Gonoral information: 2 semplee were analyzed fr EPA.004.0, All camplos Were reosived in acceptable condition with any excepons noted below or onthe ‘halmof custody andlor the sampie canon upon rept frm (SUR) atlached at the end of tis report. Hold Time: ‘The samples wore analyzed within te method required hold times wth ary exceptions noted below. Method Bt ‘Al anaiyes wace below the por int nthe method blank, where applicable, with any exceptions notd below. Laboratory Control Spike: Alllaboratery conto! spike compounds were win QC limits with any exceptions noed below, Mati Spikes: ‘Al parcant recoveries and colatve percantdterences (RPDS) were wihin acceptance cera With any exceptions aod below. Additional Commonts: Analyte Comments: 2c Baten: 261687 ‘1c: During the Ingronthing process, pat f the MB was lost and te resting chemical ye is below 10% and the assocites NS MDGs greater thon #0 pvt, Indouel sample resus ae not impacted by the sevated MDC o low MB yield, BLANK, (2b ID: 1288601) * Racam-222 ‘Thib data package has been reviewed for quelly and completeness and is approved for release, REPORT OF LABORATORY ANALYSIS ‘Thi tepot hal note reprsced, scptin fl siete weton consent Pace Anatol Senices, LLC, Page of 12Pace Anaya Services, LLC 1698 Reseyown Rass Sutee 23.4 ‘Greanabig, PA1530¢ (r2msosso0 ANALYTICAL RESULTS - RADIOCHEMISTRY Project 2017 Aqua-NE Pace ProjectNo: 20220748 ‘Sampler Lowes-t TLabib; 30G207A01 Coleciod OSUBNTOROD Recaved OBDGIT 10.15 Mato Veter Pus: ‘Ske 1: ‘Sample Type Paametors Matos ‘Acts Une (NDC) Carr Trac Units pnayzed _CASNo._ Qual Raaum226 EeAG031 “Toses 136 (117) pon oarien7 12 1sB6z083 GINA T71% TabiD; 30220748002 Golected: OBST7 0802 Receved: OBST 10:15 Matic Water ‘Ste D: ‘Sample Type: Parametors metros ‘ets Unc (MDG) Cart Trac Unis Analyzed CASNo._ Qual | Racianaa6 EPAGAO Gosetn tay pov Oa/iert7 W080 15262-20-1 cer 00% {Lab IO: 30220748008 Colecied: OBIOSI7 O8G4 Racaled OBOETT 1075 Matra; Water ‘St 1: Sample Type: Parameters Mathod ct Une (MOC) Car Trae Units ‘Anayzed__CASNo. Qual Roaion-228 EPRa0aT Tasba ta 7.1) pon Oanen7 1042 19882693 NAT 95% TLabID: JOZZOTAB004 Colocies! OB/OB/IT O8OS Recehes: OBOGT 10:15 Matibc Wat Ste 0: ‘Sample Type" Method ‘t's Une (MDO) Carr Trac Unis ‘Analyzed —_CASNo. Qual adiam-228 EPADOAO yaaa zat (148) pon. Oe? 10:00 16262204 75% TSH REPORT OF LABORATORY ANALYSIS “Tarot ha nat be reproduced. excep wit thewaen caneant et Pace Anaiyteal Santen LC, Page 7 of 12Pace Aralyteal Services, LLC a sts oso Red Sue 234 “Analytical rena Patt ono 800 QUALITY CONTROL - RADIOCHEMISTRY Project 2OIT-Aqua-NE Pace Project No: 30220748, weRae 261687 Talis Method EPAGDAD (OC Baten Method: EPAS04.0 Analysis Deseipien: 904.0 Radium 228 ‘Associated Lab Samples: 30220748002, 90220744008 TETHOD BLANK 1266457 atx, Waker ‘Associalad Lab Samples: 30220748002, 30220748004 Prater ‘Act: Unc (MDO) Car Trac Units Anayzed ——_Quattors Radian 225 0286888 (0:19) 0.76% 17% por Osan? 10380 Te eves pee ti pge a the usd the "Un" cm sep ran attracted the rah of he REPORT OF LABORATORY ANALYSIS “Theres ah no Be eproduced, xcept nt vith he wile consent of Pace Aneta Serves, ULC Page 8 of 12Pace Anajesl Senos, LLC Araytica” a pie anene (72seso.se00 erases QUALITY CONTROL - RADIOCHEMISTRY Project 2o17-AquaNE. Pace Project No: 30220748 ‘G6 Bate: Baise ‘Anaiais Metod EPAwaT (QC Batch Method: EPA S08. ‘Anaiyels Desoition; 909-1 Radium 228 Associated Leb Samples: 30220748001, 30220748003, WETHOD BLANK 1287010 ‘wane Water ‘ssocatod Lab Samples: 30220748001, 30220748003, Parameter ‘ets Une (MOC) Care Trae nis Anayzed ——_Qualifors Radian 228 ‘a6a2 F024 (0578) GNATOT pov OB/TONT 10:12 ost pesrndon ts pig i ns Ite he“Ua ele except a leat paved th ah of een. REPORT OF LABORATORY ANALYSIS. Ths ep shal nthe epesucedexcoptin tl tut the witen consent Pa nail Sences, LC. Page 9 of 12Pace Araya Services, LLC at ‘eather Roe. Sen 234 Analytical rena, Pet vec roan QUALIFIERS Prec zoiraqete Pave Projecto: 0220748 DEFINITIONS. DF - Dion Factor, if reported, represents the factor appliad lo the reported data duo to laton ofthe sample aliquot. [ND - Not Detected ator above adjusted reporting Bt J Estimates concentration above the adusied mettiod detection Im and below he agusted reporting it [MOL Adjusted Metnod Detection Limt POL - Practica Quantitation Limit RL-Reporting Limit S-Surogete “12.Diphenytrycraine decomposes to and cannot be separated fam Azabenzene using Method 8270. The result for each analyte ie combined concertraon Consistent with EPA guidelines, unrounded data are displayed and have been used to caleulte recovery and RPO values LCSD) - Laboratory Control Sample (Dupicate) MS(D) - Matix Spike (upicate) DUP- Sampie Duplicate PD - Relative Percent oierence NC - Not Celouabie, 8G - Stica Gel-CleanUp U.-ndicates te compound was analyzed for, but not detacte. N-Nitosadiphenytamine decempases and canaot be separated from Dipherylamine using Method 8270, The result reported for ‘each analyte ie a combined concentration. Act -Aetvty Une Uncertainy: SOWA. 198 sigma court uncertainty, al other mattices = Expanded Uncetany (05% contdence interval) ‘Gamma Spee Expanded Uncoraint (95.4% Confidence Interv) (MDC) - Minimum Detectable Conceniraton ‘rae Tracer Recovery (%) Cart - Carer Recovery) Pace Anaiyticalis TN! accreted. Contact your Paoe PM forte cuent ist of accvedtad analytes. ‘TNL- The NELAC Inst, ANALYTE QUALIFIERS: te During the ingrowtning procese, part ofthe ME was lost, andthe resulting chemical il Is below 10% and the sociated MB MOC fs geatar han 1.0 SC. Individual serge resus ae not impacted bythe elevated MOC or low syle REPORT OF LABORATORY ANALYSIS ‘This reportshat note reproduced except ntl Date 08/192017 08:5 PA winourthe ton consent Pace Analyt! Sonics, LC, Page 100112co wounn (os omnes SPS ERE. = 3 l set] 9-9 A Hanae] 21 | 2159 | EI sens fe «| oa antes apes PS) ie Pema LCS] WP Sema F - < ae ak s rit RP T hey oe am cee c — Tee pss PO AF Bie Se TOLL a TH ES x Cee eee ——— ioe sy TpoE pase Lor 7 | ae seep = | ™ | el = swarauncan JE) | FZ is . se wens | FE [Oe —arwei| |b) FER EE An a =n e Fg #| Bbworemoes ot} fe if a) |e = _suounninupow | a es ERIE| [E z FSS TaRpEOM FD oo a BNE EL 18] 5/8) 8) 8 siti 2 i SS HIS Hane SO FES suey at vaarsis08 mL eocpunmenaadaal ozs = I Lor seeore sums eDVEONDING = “THESE ater v0N 909,Sample Condition Upon Receipt Pittsburgh "ti 30220748 s i Client Name: _V\\erobec Project # corer gates vss Feet Ch exnmas D pce citer Tracking een as “TJ no Seals intact See On NAA ie wat one ia ‘Thenmemetar Used Cooter Temporatra —opvenedTonp N/A *© Conecton Factor _“% Final temp; =< ** “ep shogdbaanove Resting 2 TTR comments: Yes] No [WA [onan of Custody Present [chan of Custody Fed Out [cain of Custody Rebrgulsed srpler Name & Signature on COO: fo [same Labels match COC: loctudes datetime ate, [Semces Anived wih Hold Time ls [shor Hola Timo Analyels(<72hromelning: h. a fo [push Tura Around Time Requestoc: cutie Volume: [Coreet Centainars Used Pace Contnners Used: rm 2. ia [conser intact lorrophoephate fs terod (Organic Samples checked for dechorinaton: [ritorea voume receive fr Dissolved ests fal containers have been aheaked for prosarvstion. he PH < 2 lt cosines medina presario ar bund bia (erlanes h EPA aera. ieee ses forrest [mse 6 i, lecepions: VOA, color, TOC, O86, Fhienoics Hentepace in VOA Vials (> ep Bank Present {rip Gleic Custody Seal Prose Rad Aqueous Sarnos Serone omen] LSC YRS 77 Toe aCe ‘Giant Notcation! Resolution: Person Contacts ‘commen Resour: otertine ortacted By C1 Accheck in this box indicates that additional information has been stored In ersports. tite: Wherever teresa dseeseny alot Noth Carne casos saree, ocpy os fer lb ee he Nat Caretoa DEH Certcalon acs ., et of bal onas presente, cu a nie anne) “or revews dcumsise secret nS. Yi th Pro Manager lose th GRF Ravel tye ear Estero, edhe LMS. The renew ain tbe Sis eeclen rrortanaperestsanpl MoSeneie Canon psn Recap iti (20-4 IEDecEO1) enecienarDocu Page 12 of 12 i | | | | | | | ' i | i |ATTACHMENT 3 Radiological Analytical Results for: (AquaSalina / Mogadore - PRE - POST (AquaSalina / Cleveland -PRE (1) - POST (1) -PRE (2) - POST (2) (ODOT salt mixture brine - POSTPace Analytical Servees, LLC Analytical aleearsirenre ‘meagan (7zseso.ss00 June 30, 2017 Ms. Michelle Taylor Microbac Laboratories, Inc. 188 Starlite Drive Marietta, OH 45750 RE: Project 2017-AQUA-MOG Pace Project No.: 30221492 Dear Ms. Taylor: Enclosed are the analytical results for sample(s) received by the laboratory between June 14, 2017 and June 16, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Revision 1 - This report replaces the June 30, 2017 report. This report has been reissued fo include the additional COC and SCUR. Please replace the original report with the revised report enclosed. RLR 6/30/17 If you have any questions concerning this report, please feel free to contact me. Sincerely, Goorin. Hee, Robbin Rob! robbin.robl@pacelabs.com (724)850-5613 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS ‘Toisrepat shal not bo roproduoed xceptin fl ‘winouthe wnt cnsentof Pace Antica Scns, MC Page of18(ott Project Pave Project No, 2017-AQUAMOS. 0221492 Pennsylvania Certification IDs 41698 Roseytown Rd Suites 2,384, Greensburg, PA 15601 LAB DOD.ELAP Accrodtaion # 12417 ‘Aavama Ceniieaton# 41500 ‘aizona Cartcation # AZOTSS ‘Ackanaas Cerifation Caitfornia Ceniicaton : 0422268 Colorado Cartcaion Coanectien Cetfeation &: FH-0698 Delaware Cerification Fleida/TNi Cortiaton #: £87853 Goorgia Centieaion#: COA (Guam Certification awal Certification Idaho Gertiaton nos Certcation Indiana Certification Jawa Centeation #: 384 Kansas/TN Certfcation#: E-10358 Kentucky Certication#: 90133 Lousiana DHHITN! Cerfeation &: UAt4n008 Lousiana DEQITN Certfcation #4088 sine Certieaton #: PAQD091 Maryland Centfiestion #308 Massachusetts Ceticalon # W.PA1457 \MichigaryPADE? Certeation Missouri Certification # 235, CERTIFICATIONS Montana Cericaton#: Cet 0082 Nebraska Certication # NE-05.2944 Nevada Cotitcaton : PADIAS72016« ‘New Hampetve/TNI Certfcaion#: 2578 Now Jersey!TNI Ceattcaton # PAS New Mexion Certiation #: PAD‘4S7 New York Certieaion 10888 Noth Carona Certtcaton #: 42708 [Nort Dakata Certicaton # R180 ‘Oregon TNI Cercatin & PAZOCCO2 Pennsyanla/TNI Certication #: 65-00282 Puerto Rico Cortficabon# PAQAS7 Rhode flana Certsestion 2: 65-00282 South Oakota Catifcaion Tennessee Certfcation # TNZB67 Texas/TN Cenionion#: T104704186-14.8 Utah IN Certicaton #. PA014572015-5, USDA Sal Perit & P330-14-00213 ‘vermont Dep. of Health: # VT-02B2 igi slend PADEP Cestication \VirgiaVELAP Certiicaton#: 480108 ‘Washington Cetfestion 4: C868 West Viginis DEP Certieaton #: 143 ‘West Viginia DHHR Ceriicaton #: 99640 ‘Wisconsin Cerieation ilealin &: BTMS. REPORT OF LABORATORY ANALYSIS “rept shal ett reprise eat fe out ne write cnsertof Pace Antal Sonica, UC. Pace Anajtes Sones, LLC 1638 Rosejtown Road -Sus 2.34 (Geoonsbrg, PA 1860 ‘aqesoeeao Page2 0 18ice Analytical” mepiien SAMPLE SUMMARY Project 2017-AQUAMOG Pace Project No: 022402 Labi Semple D Matix __Date Collectod_Dato Received ‘0221492001 ODOT.01 Water osit2n7 oes oanant7 1150 30221492002 oDoT-02 water ost2n7 0838 oanart7 1150 30221492003 AS.AHOG PRE O1 iat oortan7 1207 canary 11:50 40721492004 AS-M40G POST 01 wate oartart7 1290 ognart7 11:50 30221492008 AS-CLE-PRE.O1 Water cansit7 10-24 oaneit7 1018 30221482006 AS-CLE-PRE-O2 wate onsrt7 10:22 ognert7 10:18 30221492007 AS-CLE-POST-Ot water vans? 1058 oanert7 1045, 30221482008 AS.CLE-POST-02 water ounsrt7 10:58 ane? 10:15, REPORT OF LABORATORY ANALYSIS “This teport hal sl Be teposuced, excep without the writen cansentaf Pace Analyal Serves, LC, Pace Anata! Sores, LLC 1658 Rasejoun Road Sues 23,4 ‘Grong, PA 18601 ‘a2qecoss00 Page 3 of 18Pace Anaya! Services, LLC ‘o1s Rosotoun Road - Suits 2.3.4 (eorsbrg PA 15001 mmparbescon (724505800 | | ‘SAMPLE ANALYTE COUNT | Project 2017-AQUA-MOG Pace Project No; 30221492 Analytes. Lab ID ‘Sampto 1D Method Analysts Reported 30221492001 ODOT-01 EPAGO3.1 WRR 1 30221492002 OD0T-02 PAGO sow 1 30221482003 AS.MOG PRE Ot EPASO9.1 WAR 1 PASO saw 1 30221492004 AS.MOG POST Ot EPAGIA uw 1 30221492008 AS.CLE-PREO1 EPASO1. MAH 2 : 30221492008 AS.CLE-PRE02 EPASOI. MAK 2 30221492007 AS-CLE-POST.O1 EPASOIA MAH 2 | 30221482008 AS-CLE-POST02 ERAGON MAH 2 REPORT OF LABORATORY ANALYSIS “Toler shl ptt reproduced, excaptin a vith the wien exnsentf Pace Anayal eres. AC. Page 4 of 18Pace Atte Saree “Analytical ee ambon ot wong ce! (r2s-s600 PROJECT NARRATIVE Project 2o17-AQUANOG Proce Prot No: 30221482 Method: EPASOIA Description: 901.1 Gamme Spee Clients, Microbac Laborateries, Ine-OH Date: June 20, 2017 General Information: 4 samples were analyzed for EPA 901.1, Al samples were eoeived in acoaplable condition vith any exceptions noted below or onthe ‘hanofcustedy andlor the sample cention upc acalt form (SCUR) attached atthe enc of is reper. oid Timo: The samples wore analyzed within the method requ hold times with any exceptions noted below. ethos Blank: ‘All analytes were below the por linitn the method blank, where applicable, wth any exceptions nated below, Laboratory Contr spike: Al laboratory canto! spike compounds were wihin QC limits with any exceptions noted below Matrix Spikes: ‘All pefcent recovetles and relative peroet differences (RPDS) were within acceptance criteria with any exceptions noted below ‘Additional Commonts: REPORT OF LABORATORY ANALYSIS This epochal nat eprocucel exept fl sutne writ consantof Pace Anil Sences, LC. Poge 5 of 18Pace Anatol Series, LLC / Pace Analytical” mga PROJECT NARRATIVE Project: 2017-AQUAMOG Pace Projecto: 30221492 1608 Reesjoun Road - Suites 23, “Greoneaig, PA 15601 (qaspso.ss00 Method: EPAS03.1 Description: 903.1 Radium 225, Gliont: ——Miccabac Laboratories, Inc-OH Date: une 30,2017 General information: 2 samples wete analyzed for EPA.O03.1. All samples were receive in acceptable condition wth any exceptions noted baw or onthe ‘cain-f custody andlor tha sama condllon upon racolt form (SCUR) attached atthe end ofthis report Hota Time: ‘The samples wore analyzed within the method required hod times with any exceptions noted below. Mothod Blank: ‘Allanalytes were below repo Emit inthe mothod blank, where aprllcable, wih any excapions noted below. Laboratory Control Spi ‘Alaboratery contra spe comocunds were witin QC limits with any exceptions noted below. Matrix Spikes: ‘All percent recoveries and relative percent dilerences (RPDS) were within acceptance citeia with any exceptions noted below {Adaitional Comments: REPORT OF LABORATORY ANALYSIS. ‘Tis repo sna not eproauces,excatin wiheutne wit consent Pace AnaiyeclSanicns, LC Pages of18: Pace Anata Services, LLC Analytical ‘628 Rosayown Rea Sten 234 mses PROJECT NARRATIVE Project 2O1T-AQUAMOG Pace Project to: 30221482 (roeratry PA 15801 ‘28505800, Mothod: EPASOAO Daseription: 204 0 Radium 228 Client: Microbac Laboratories, Inc-OH Date: June 30, 2017 General Information: samples were analyzed for EPA S060, samples wore (eceved in aeceptale conltion with any exceptions noted Below or on the ‘ham-of custody andlor the eample canal upon recep frm (SCUR) attacsed a the ened oF tas repo. Hold Time: ‘The samples were analyzed within the method required hols ies with any exceptions noted below. Method Blank: ‘All analyes were below the repo iit in the method bank, where aplcable, with any exceptions noted below. Laboratory Control Spike ‘Allaboratery contel spike compounds were within QC fits wih any exceptions notes below. Matix Splkos: All parcent recoveries and relative percent dflerences (RPDs) were win aceptance criteria wih any exceptions noted below. ‘Additional Comments: This data package has been reviewed for quality and completeness ands approved for release. REPORT OF LABORATORY ANALYSIS. “Thieapst stl not be reproduced excep a, trot the wien conse Pace Anaya! Seve, LLC Page 7 of 18pace Anaya! Services, LLC inal? tse Ronson Read Suen 236 “ace Analytical Gresnaburg, PA 16601 ‘mpc roossott0 ANALYTICAL RESULTS - RADIOCHEMISTRY Project 2017-AQUAMOG Pace Projet Nos _202atas2 ‘Sample: 00074 Cabin! Sozztaes00? Colada GONOHT ORGS Receiea OOTAT TBO Wale Wale Pus Ste 1D Samal pe Parameter Mebes ‘Act#UneQ4D6)Car'Tie _Unks__—_—Anayros_—_CASNo. Qual Raden arama arate (145) pon baa TOs 902-693 GMa Tar Sampler oDOT-02 TabiO: S0271492002 Goleclod OB/IAT7 O98 Recewed OananT a ation Water ews: Sie: ‘Semele Type Parameters eto [att Une (MDC) Care Trae Uns Araiyeed _CASNo. Qual Raciam-22e PAGED B7e2 7.60 (165) pou OBRBNIT 222 16262-20-1 Cia 3% ‘Sample! ASMOG PRE OT TabiD: S02ET4S2009 Caleded: OSN2AT 1207 Recehed: OBNANT 17.50 Wake Water Pas: ‘Site 1: ‘Sample Type: ‘Comments: + Low volume Parameters Method At Une (MOO) Carr Trac Unite ‘Aneyzod __CASNo.__Qual Rasum 226 EPABIOA aa52 116 (107) POHL OBRTITTTS5 13087823 GINA TOI Racum-228 EPASGAO 373260.8 (150) POV, oBReN7 1222 15282-20-1 c75% 731% ‘Sampler ASMOG POST OT Tabib; 30221482008 Colecieds OWTEAT TOS) Recehed OSTWIT 1150 Matic Water Pas: ‘Sto: ‘Sample Type: (Comments: + Low Volume Parameters Metros ‘ts Une (HDC) Cart Trac Units Anayeed —_CASNo. Qual Radum 228 EPRSDAO Fazer (133) POW OWRG/IT 1222 15262204 75% T34% Raolum 228 EPASOS.1 401024126 (1.61) PCH «OBRINT 9. 19082698 INA T:99% Semple: ASCLEPREOT Tablb; 30251492008 Colacied: OTST 102 Recaved OBNG/IT 10.8 Mati: Water Pws: ‘ie 0: ‘Sampe Type ‘Comments: +Low Volume Parameters Method ‘ct Une (M00) Care Trae units Anayred —_CASNo. Quel Racum 228 EpaoOIT '95.2602772.180 (927-900) Pon OBr2e7IT 0.06 13082593 IANA Rasium 228 PASO. '568.050 2 127.480 (123.800) POM, 0628/17 10.05 15262-20-4 1A TENA REPORT OF LABORATORY ANALYSIS ‘Ths rpot sat not reproduced xcept fl ‘itctthe writen consent of Pace Anas! Seren, LLC, Page 8of 18Pace Ana! Serves, LLC 1628 Roeeytoun Roa Stee 234 Greenabig, PA 15601 mpi (@24yasose00 ANALYTICAL RESULTS - RADIOCHEMISTRY Project 2017-AQUAMOG Paco Project No 30221402 “ASCLEPREG? Tab ib; S0zz452006 Colaciod! USTGAT 1022 Recaved: OSAG/T 10.718 Matic Water ‘Site 0: ‘Sample Type Comments: + Low Volume . Parameters ethos ‘at ¢ Unc (MDC) Car’ Trac nts Anaiyzed CASO _Qual Radian 228 EpAGoT “or.8203 462.880 (552.800) Pov OaerT teat 13882053 CENA TNA aglum-228 PASO! 387340275616 (64.860) pen. Oer2aNT Te:A1 15282-20-1 CENA TINA, Sampler ASCLE-POSTOT TLabib: 30221492007 Colesied: OSTBAT 10186 Recaved DENOAT 1078 Waite Wetor Pus: ‘Sto 0: Sample Type: Comments: + Low Volume Parameters Method ‘Acts Uns (DO) Care Trac Units Anayzed _CASNo. Qual ' Radium 228 Epasor ‘349.3902 478.660 (661.700) POV caRnT 1207 13582638 GINA TNA Ragium 228 EPAQOI.1 7340807 129.300 (78.240) pov caren 1207 15262-20-1 GINATINA, | ‘Sample: ASCLEPOSTOZ TabID: 30221492008 Golecied OB/1G7 1056 Received: OGNENT 1015 Matix Water | Pas: ‘Ste 0: Sample Type: Comments: + Low Volume Parameters ethos ‘Act £ Une (MDG) Cart Trae nts Anayzed —_CASNo. Qual Rasim 228 PAGO 97 6702 $48,050 (695.800) POUL OGG/t7 Ted 19082608 GINA TNA Radium 228 EPAQDt.t 713.7602 102.920 (64.890) OWL osra07 16:42 15062-20-1 GINA TNA, REPORT OF LABORATORY ANALYSIS “Th rpor he po be proceed, seep int the writ consent Pace Anaya Sanvony, LC. Page 90118Pace Analytical Serves, LLC Analytical” amaareneee ence (caqesoseo0 QUALITY CONTROL - RADIOCHEMISTRY Project 2017-AQUAMOS Pace ProjecNo: 30221492 oc aaey 75iGas ‘raise Method EPABOST (0c Baten Method: EPA.G03.1 ‘Analysis Deception: 903.1 Radhim-225 ‘Associated Lab Samples: 90221492001 WETHOD BLANK 1289TA2 Matix: Water ‘Associated Lab Samples: 20221492001 rameter ‘Acts Unc (MDC) Care Trac nis Anayeed ——_Quaiiors Radium.228 047320491 (0752 CHATS BON OBRONT 10-15 ass preeri aa pagoere ihe isnt he "Ud" en xc wars tur on preceeoth ght of e e. REPORT OF LABORATORY ANALYSIS ‘Ts fepart sat not be reproduced, except wihoutthe wit consent of Pace Anacl Services, LC, Page 100 18Pace Anatol Sarees, LLC Analytical” Senta Grses rn seznam (aasso.seo0 ‘QUALITY CONTROL - RADIOCHEMISTRY Project 2o17-AQUAMOS Pace Projet No: 30221482 ‘ecwacr 26848 ‘naisis Nethor EPAGOTT (QC Batch Method: EPASOTA ‘Aoalyes Description: $01.1 Gamma Spee ‘Associated Lab Samples: 20221492006, 30221492006, 30221482007, 20221492008, WETHOD BLANK 1287752 Wats Water ‘Associated Lab Samples: 90221492005, 30221492006, 30221492007, 20221492008, Parameter ‘ts Une (MDC) Care Trac Usits Anayeed Quali: | diane 228 0.5002 102.870 (219.900) GNATNA pov —OsReNT 1248 | dium 228 0.0006.03 (87.220) CNATNA pow = oszat7 1248 ‘ent prenetdon gage itt na net “Unt” clam axcep wharoan senate an pact ight hah REPORT OF LABORATORY ANALYSIS Tis opot sha not be roprouced except what the ttn consent Pace Anayial Sense LLC. Page 11 of 18co Analyal Servis, LE Analytical” emaariasrent ens nngtabacom «qasyss0se00 QUALITY CONTROL - RADIOCHEMISTRY 2017-AQUAMOG un24ce Paras ‘arable Mather EPABIST (QC Batch Method: EPA9O.1 ‘Analysis Description: 908.1 Radium 226 ‘Assoclated Lab Samples; 30221482008, 30221492004 WETHOD BLANK ‘Associated Lab Semles: 30221482005, 90221492004 Tears alias Water Parereter ‘Act Une (MDO) Cart Trac units Analyzed Quatiers 0.0089 +0399 (0.705) GNATOT pon —‘OnR NAT Th6 ‘en proved on tie pgs nh isin th "Unt chen xcept heron tt unin proce eerhoh REPORT OF LABORATORY ANALYSIS. thou the wit eset Pace Priel Senicey LLC Page 12.0118Pace Anica Serves, LLC ay? ‘ence ond oe 2 Analytical ‘Greonabirs, A 15 opens (rages QUALITY CONTROL - RADIOCHEMISTRY Project 2o17-AQUAMOS. Pace Project No: 30221492 ceRan Teioa6 ‘Analysis Motiod EPRODAD OC Baten Metros: EPA.004.0 Analysis Desciption: 004.0 Radium 228 Associated Lab Samples: 30221497002, 30221492009, 30221492008 TWETHOD EINE TaasTaS TMatine Water ‘Associated Lab Samples: 0z2tas2002, 20221492000, 90221402004 Perameler Acts Une (M00) Gar Trac Unis Anayres —_Qualfers Radium 228 0107 £0318 (0773) CTE T7% por OaRenT 1292 Fast preserndon npg a inthe untainted h"Ua ein neg wha eli pres th ght fea REPORT OF LABORATORY ANALYSIS Ths oper sht at eprucse, eect noite wien consent ot Pace Anaya Serves, LL. Page 13 of 18Pace Analytica! Soren, LLC ceAnaltical” ‘tsa Ramee Rou Sus 284 ‘Gresnabug, PA 15501 era stsbsesn QUALIFIERS Project. 2017-AQUAMOG ove ProjectNo= 30221462 DEFINITIONS. [DF - Dauion Facto, reported, represents the factor applied te the reported data due to ation ofthe sample aiquot. IND- Not Detect at or above adjusted reporting limit 4J- Estimated concentration above the adjusted method detection irl and beow the adjusted reporting Hn MOL Adjusted Wethod Detection Lit POL Practical Quanitation Lint, FRL- Reporting Limit. 8 Surogate 42.phenytydrazine decomposes to and canno! be seperated fom Azobenzene ust Menod 8270. The result for each analy Is ‘combed concentration ‘Consistnt with EPA guidelines, unrourded data are displayed and heve been used to calculate recovery and RP vals. LOS{0) - Laboratory Control Sample (Duplicate) MS(O)- Matrbe Spike (Oupticate) DUP - Sample Duptesta PD - lative Percent Difference NC- Not Calcul SG- Siice Get- Clean Up U--Indcates the compound was analyzed for, bu nt detected. NNivosodiphenylamine decamzoses and cannct be separate from Dipherslamine using Method 8270, The result reported for ach analyfe a combined concertration. ty: SOWA-= 1.96 sigma count uncertain, al oer matioes = Expanded Unoetainty (95% confidence interval. ‘Gamma Spec Expanded Uncertainty (954% Confgonce interval) (WDC) - Minium Detectabie Concentation ‘Trae Tracor Recovery (8) (Garr Cerrier Recovery (%) ‘Pace Analytical fs TNI acredted, Contact your Pace PU forthe currant ist of accreted analytes. TWI-The NELAC inet, REPORT OF LABORATORY ANALYSIS ‘Ths tego shal net veproed, cap fo ate: a8a0v2017 02:44 Pla wc the wen consent Pace Arye! Serves (LC (r2spesosso0 Page 14 0f18Peer eeree eam 60 mow fos) aaseea pRos “is) 908 UA) mA, or Crna FOP TPP, smug ou, a me | ova L apterous agence Zs TPES ects cs eae) ee een fesee wu | oe sad SAV AFH foaecs “wd 109 | Po nd ug WO | Fees lg aroiag ected tT E { T Ee eee "3 T COA OTA PREIOAST_| fe ont 1 r [Steg] i a zl el EERE Halelee ae eat Same = somauen (F] | [2] 8 EE EER Oath sar le S| BEE 27s S812) |g —somrti| | PR ERE EYE) lee] 8 OW SY lor | a e iE E Flele Z 3 [promo a ae HEE? Tom snaps po =< a 8)3) 8 CICS pi By} | BE HE: pewter | ~ i e t “SED BNO IO UOSAGUNGONO HAS sau nanes “ Sa ovese sort AE AE eDVAOUDING =— “~*ToHESEn “O918¥°0N 900 Page tsofie |Sample Condition Upon Receipt Pittsburgh a i Client Name: Nycreione. Project# 30221492 ¥ courier Fed x 1 ues Cuses Octet CD cormarcit (I Pace ober Be Teaching“) 2-1 ¥ GUIS Listy Custody Seal on GoolerBox Present’ [Ayes C] no Sasbinc: 7 9e6 () no Thermometer Used —_V9 “Type ofles: Wet Bue Cooler Temperature Observed Tome N° conecton Facio; Ait *¢ Finetteme: AJA “© Teo stlte stove nang °C TE. comments Yes [RoW [onan ot cui Present h cron orci Fed Os 5 [onan of sed Retna a sampler Name & nate on COS: le. song tates match COC: fs Includes datefimelD mabinc if Semel ed iti Hot Tne le snor Hott Tan Anat (ahr reaning bE van Tun Around Tie Roqostc ls outers Vou alow voigme, Samfas Opat cou have on SL caret Containers Use Z ta. -Peoe Conners Use contin ic: Z In. lomepnesonat tt mores 2, lorgane Samples checked fer dechlcdnat a [tered ven esd fr isohd its te fice atte cea poe + Ja catia ac oer ret carats GPa ecoreatto, Jeccoptens: VOA, eco, TOC, 086, Pend cored SOY leer eadspacaa VOA Vals (my 16 rip Blank Present: Ni. ap stn Custody Seale Prosar ie Acie Serie seened> sven} —| >] PE exc yy Client Notification! Resolution: Poon Contacto, Dotortine: contected By. Comments Resolon: OA check in this box indicates that additional information has been stored in ereports, ote: Wena: tha ina damep ty cg Neth Cactna cmpnce sues, ayo hi ora sent ha Neh Carling ON (exscaton Gee (ie, eutet ha nearest esanatva ak oonp,resect ont) “a ever eral lia LMS nan Poet lento oes the SRE Ren achat AS. Thorasews ne Stas eon ha Wotecar Et sen, JanacttasrDecurin MaragenatsmeMgSarpl Corcton Upon Resp tbr (005-4 18060016) Page 16 0118pa a7 An UPI To ESTAS] PES ARE AT ST ee 1 Sa eee oD Cre Oa OBE TST CBP 486 Toe east TOBE "SES T_| iF] AG ae 3 g 8 AB wo 18/8 og sueananons {2 4 BST i : "woe | 3 3/3] [8 TPIS 8] | fa 3 3|2 ad HEHE ft a] E (Olac WOOY: Ciez =O B/E] Ig TB SY, IME ES 700) ar B -syounanbou punaiy wns | ot 38 oD ie 3 i os 5 525 110 30 UOISAIG-UNG-O140 40 IES ue sun ag 7A ep ni€COE wareze900 mem Saas owes xo moo TAU Mgr eLeOrL ‘OK eOVEOUDING = ~oomrIsest o9itrV'0N 000Project # Saaivia _ e- couier: (2-Fesec C} urs CO) uses D) cian Ll conmerciat C] pace omer “den Tracking V2ET O39 42 Custoty Seaton CootrBoxerosont: Efex C] om Sassinact Dm Thormometorused 4310 Type often: Wet tue Cuore “e Cooler Temperatura Observed Temp "C Comection Factor "© Final Tere: SETA i Comments: [Ye[Reywa eth cran ot cto Prnone Z i [Chain of Custody Filed Out. “ 12, | Gown roy Rane ls [Samper Name & Suratre on COO vk | [Sample tevets mates COC: ay LAI [, We-dare aie eH Lele m include datesime/IO Movie wf Ne time en COC, Gme on \ootlps ever i Sarge Aves abn al Te ls pice ices [Short Hola Time Analysis <72hr remaining): v[ fk Pmker- ise | Rush Tara Around Time Requestod: wet tay Zam { feyaien va : le Pasvor- 168to | [comes Comanes Uses i BY Pace Consors Us z b Conner tc mn | (cthoohopat et eee he ; |Organle Samples cheeked for dechirination: hs. t tos vr es fr Osos ts ha cbs at cha i Gaew | [corse nentes pexenatinare maa ven [ 7 esnnnvn on carers i wen iti [centr VOA, cao, TOC, 086, Penofer [ei nde faecteae iedepocin VOA Vals (>on 10 | fp ck Pet a | Ip stare cs eal Present / | Fe asus Sante Sonenet>asmeeané| | >] REE hap ‘liont Notiteatiol Resolution: Porson Contacte DetarTine: Contaced By Comments Resolubons O Accheck in this box indicates that adaltional Information has been stored in ereports. Note: Whenever thre a circany facing Hoth Carin corplarc srs, a ory em ibe sn fe Neth Crain DEHN Cartas Or (Ln. oot hol, eel presen e p, wcrace "i rviwsdecmartascloserzaty i UME. We th Projet Manage eos tha GRE Rao cede RIS, The est Ss secon te Water Es Seen “akachlatrDnet MingeneGenpe tarde Clon an Res Ph C4 EDE2H) pons spf 1BATTACHMENT 4 Radiological Analytical Results for: ODOT tap water -PREPc Analytical Series, LLC inal 1808 Reseyioun Road Sutes 23.4 e Analytical Geoensurg A 15801 onepcncom (c2sasosso0 July 05, 2017 Ms. Michelle Taylor Microbac Laboratories, Inc. 158 Starlite Drive Marietta, OH 45750 RE: Project: 2017-AQUA SAUNA-TUSC Pace Project No.: 30222632 Dear Ms. Taylor: Enclosed are the analytical results for sample(s) received by the laboratory on June 26, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNVNELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Ifyou have any questions concerning this report, please feel free to contact me. Sincerely, Kboirin Be. Robbin Rob! robbin robl@pacelabs.com (724)850-5613 Project Manager Encloaures REPORT OF LABORATORY ANALYSIS ‘This rept shal node weproducod excep al, wut th wlan caneent of Pace Ansytal Servis, 4 Page 1 of 12(Aa Projet 12017-AQUASAUNATUSC Pece Projoct No> 30222652 Pennsylvania Certification IDs 1636 Roseyiown Ra Sues 2,284, Groonsburg, PA 1560 LAB DOD-ELAP Acereaston#: 2617 ‘Alabama Cerifeation & 41900 ‘nrzena Cetiieation & AZOTO ‘Arkansas Certifcaton Caltfornia Certification #: 0472204, Colorado Gertication ‘Connecticut Cerffaton & PHOS Delaware Certification Flonea/TN Ceniaton & £87653 ‘Georgia Catineation #: COA ‘Guam Certification Hawt Cectiteation Ieano Gertcation iiaos Certiaton Inaiana Certifcaton Iowa Centicaton & 394 Kaneae/TM Certfcaton#: E-10958 Kentucky Gertfeaton #: 90133 Louisiana DHHTNI Certifeation #: LA‘s0008 Louisiana OEQ/TN Certfcaion#: 4086 Maine Certication #: P0001 Maryland Cericstion #: 308 ‘Massacnusetis Cetfeaton #: M-PAIAS7 \WitigarvPADEP Cetieation Missouri Cetfcation #: 235 CERTIFICATIONS Montana Certfcation #: Cea 0082 Nebraska Cartfcation #: NE-O5:20-14 Nevada Cartiealon # PAO}4572015-1 Now Hampshie/TNI Ceriication #: 2978, New Jeraey/TN| Ceniication #: PA O54 New Meco Ceriicaion # PAO457 New YorvTNI Cation #: 10888 North Caralina Cortifcalion # 42708, North Dakota Cecfeaton R180 (regan/TNI Certiicaton # PAz00002 PennsyivanaiTN Certteation#: 66-00282 Puerto Rico Ceriicaton &: PAO T4857 Rhode lland Certfcation # 65-00282 ‘South Dakota Ceritcation Tennessee Centneston #: TN2867 ‘Texan/TNICerticaion #:T104704188-14-8, UtatvTN Ceritcaon # PAO14572016-5 USDASo! Pari i: P330-14-002%3 Vermont Dept of Heath: bt VT-0282 igi sland PADEP Centication \ViginlalVELAP Certification #480108 \weshington Ceifcaton # C8368 \West Virginia DEP Certicaton #: 143 \West Virginia OHHR Cartan #: 99640 Wisconsin Certifcation Wyoming Ceriication # BTML REPORT OF LABORATORY ANALYSIS “This report shal note reprodued, capt fu, ithet he writen cnsentof Pace Anil Senices, LC. Pace Analytical Senses, LLC 1698 Roseyown Row Suites 2.3.4 (raspso-seo0 Poge2 of 12Paco Anata Services, LLC 1608 Roseytonn Road = See 234 Groonsburg PA 18801 @asasoseco ‘SAMPLE SUMMARY Projet: 2017-AQUASAUNA-TUSC Pace Projecto: 9022268 Labo ‘Sample 10 Matix Date Collected Date Received 30222832001 DOTTUSC RAW-01,02 Water wein7 12:52 06r26/17 08720 REPORT OF LABORATORY ANALYSIS Ths report shal rete reproduced xcept al wihout ne writen coeantof Pac Anttel Serves, LLC. Page S012Paco Anaya! Series, LLC Analytical” nn Pt isi pied SAMPLE ANALYTE COUNT Projet 2017-AQUA SAUNA-TUSC Pace ProjectNo 30222632 Anatyios Lab10 Sample 10 Motnod Analysts Reported 30222632001 DOTTUSC RAW-01,02 PAGO wRR 1 EPAGOAO aw 1 REPORT OF LABORATORY ANALYSIS Tis report shal pot be opecueed exert fil went he writin consent Paon Antal Sones, LC Pages of12 |Pace Analytical Services, LLC ‘al? texan Rand ute 284 ‘Analytical aba O54 PROJECT NARRATIVE Picject! 2017-AQUA SAUNA-TUSC Pace Project No: 90222882 ‘@asjesose00 Mothod: EPA S021 Description: 803.1 Radium 226 Client! Meroe Laboratories, nc-OH Dates July 06, 2017 ‘General formation: 1 sample was analyzed for EPA 903.1, All samplos wore received in accootable cendon with any exceptions net below ore the OE mreavir xeon low 2-26 fF Gientnoteaton Rao Perna Catactet Deter contacted ye Comment Resch: 1D Accheck in this box indicates thet additional information has been stored in ereports Ate: Wav o e istepsay sola Roh Cacina compl samp, cyt nn bot! oe Me Cain DEHN atten Of (Lm eto, earl eter ou fp hes¥eet eae) “Piven docunmand toa a LMS Wan th Prof Marsan don te GR Resin LMS, Te een fs eon ote ere \aAccUAssslBocmet ManapeneriSaale Nyse Conon on Roca Ptebagh (C84 E0428) Page 1201p |@ ‘pwasT ‘000° sones Hg BOL eALoReL SiN Nanas BOON samara 9% dus iepvons beswoe-ore — :arrdues.qe) Wiw2se080r = caisum aizioo— :quarenado aH arwounnsy, OBSLBE cLoz-UNrgL —:e1eq VoRD=fU) cemsiarivosinacsapmomiitee ae FEY%ehea sv 9F dus ispHOM, squoreiedg _ THHIO/Y rire mate rosovasunt term ame naves% wemoa sv ‘0000 wowed 1G Mol YA uorROful CAUNSWISELASOWNONOES —:a EHD $2 suds enHoA veseo-ore = :qlerdwes ey wirvezseor-ore caisun 1200 sah areedo. Sdby ql yuownasuy OSYS:LL LlO-UNEL — :21eq uoRDefU (Tsz091 90214 Be08-9190C LOZEdHIPMMIEAWONSWEIUESVNWOIDN, veg eq PLAY) ZeLeel Looe 72 UOSHOY WOH OeLeL cLozunea sre uodousx ) © todo00dix: 7 tex Tomo NvOs SrilpbO690L a ea tO) 965 SUUUNYO woroue ssw amp zieozze ‘pouen rhea sw coo} soe 40 ROL oR uoRDOA SaRGnINeAanOENE.\ -gnueio 5 fh rds ervHt vinegars -aterogan HEVTOLeOre ans, cavereedo "arweunasa, cezoziuiceurst -aegvoroln crosiovetreoLsesio0ziozzavrnsequong one MMOH “ogee thawed eavOUNAS) eezvu0 LioeunnnZ 72 uOHEY WON sez0°01 chor-une1z 18a vod Loy MATos OH OOM Comm ComSCot! oto oseGas Chromatographs of pre-treatment and post-treatment of brine tanks of Duck Creek Energy and ODOT tank containing AquaSalina The Division of Oil and Gas Resources Management (DOGRM) sampled the pre-treatment and post-treatment brine tanks at Duck Creek Energy's Cleveland and Mogadore facilities. In addition, DOGRM sampled a tank containing AquaSalina delivered to an ODOT facility. The samples were provided to TestAmerica for gas chromatography (GC) analysis. In these samples, GC analysis was used to determine if volatile organic compounds (VOC) and semi-volatile organic compounds (SVOC) were present in the brine sampled. Each peak or mound on an analysis represents the presence of VOC or SVOC as indicated on the analysis. Note that a mound indicates that multiple VOCs and SVOCs are present in the mound, but the analysis/equipment was unable to separate the VOCS or SVOCS into individual peaks. If VOCs or SVOCs were not present in the brine, no peaks would appear on an analysis. The table below is a summary GC analysis of the tanks sampled. Pre-Treatment Cleveland Post-Treatment Cleveland Pre-Treatment Mogadore Post-Treatment Mogadore ODOT tank of AquaSalina ala|sia]s 4is|siais *The DOGRM did not use the GC analysis to substantiate the peaks identified in the analyst Rather, it was used to determine if VOCs and SVOCs were present in the tanks sampled.