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AIAA/SAE/ASME
18th Joint Propulsion Conference
une 21 -23, 1982/Cleveland, Ohio
For permission to copy or republish, contact the American Institute of Aeronautics and Astronautics
1290 Avenue of the Americas, New York, NY 10104
DIFFERENCES BETWEEN ACTUAL AND PREDICTED
PRESSURE-TIME HISTOKIES OF SOLID ROCKET MOTORS
Thomas E. Kallmeyer*
L a r r y H. Sayer**
Thiokol Corporation/Wasatch D i v i s i o n
P.O. Box 524, Brigham C i t y , Utah 84302
Abstract
g A t Pref
Conventional methodology assumes t h e d e n s i t y ( p )
P
of t h e p r o p e l l a n t t o be c o n s t a n t throughout the
g r a i n . The c h a r a c t e r i s t i c v e l o c i t y (C*) is a weak
f u n c t i o n of p r e s s u r e and i s u s u a l l y i n p u t i n t h e
form.
~ . , ~ ~~~~~~~ _ - ~ ~
~:--t-
I
,
1,000 2, OOF 3,000 4,000 5,000
*Supervisor, Ballistics S e c t i o n , Thiokol
C o r p o r a t i o n , Wasatch Division,Member A I M
**Manager, Motor Performance Department, T h i o k o l
PRESSURE (PSIA) d
C o r p o r a t i o n , Wasatch D i v i s i o n Fig. 1 Cured S t r a n d Burn Rate V a r i a t i o n With Pressure
Copyright 0 Arnrrican Instiluleof AeroniUIiEEBnd
AslronaUlicS. Inr.. 1982. All righli reserved.
p e l l a n t , at h i g h p r e s s u r e , is shown t o b e a func- B a l l i s t i c Nonuniformity i n End Burning G r a i n s
t i o n of p r e b a t c h t i m e . In t h i s case, s u b s c a l e
motors cast a t v a r i o u s times w i t h i n t h e f i r s t 50 A s i n d i c a t e d e a r l i e r , s p a t i a l changes i n burn-
h o u r s a f t e r p r e h a t c h , and t e s t e d a t h i g h p r e s s u r e , i n g rates w i t h i n a p r o p e l l a n t g r a i n can occur due
would i n t r o d u c e s i g n i f i c a n t Scatter i n burn r a t e t o p r o c e s s i n g or p r o p e l l a n t i n g r e d i e n t m i g r a t i o n .
scale f a c t o r s . There are numerous t e c h n i q u e s which can be u t i l i z e d
t o q u a n t i f y t h e m i g r a t i o n e f f e c t on b u r n i n g r a t e .
I
L i q u i d p r o p e l l a n t s p e c i e s , i n c l u d i n g some
/a
.4 0'
" commonly used p l a s t i c i z e r s and c a t a l y s t s , can move
HIGH PRESSURE from t h e p r o p e l l a n t i n t o m a t e r i a l s a t t h e propel-
l a n t i n t e r f a c e s such as i n s u l a t o r s , i n h i b i t o r s ,
l i n e r s , RW coated t o o l i n g , e t = . L a b o r a t o r y
samples can be made, aged, and then a n a l y z e d t o
determine mobile s p e c i e c o n c e n t r a t i o n s YS d i s t a n c e
from t h e i n s u l a t i o n l p r o p e l l a n t i n t e r f a c e . These
can then be modeled t o determine d i f f u s i v i t i e s . A
developed model YS a c t u a l t e s t d a t a are shown i n
Fig. 3.
I
0 100 203 300 403 500 600 700 -1 I
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Fig. 2 E f f e c t s of P r e b a t c h S t o r a g e Time on S u b s c a l e
Motor Burn Rate
T h e r e a r e two b a s i c c o n s i d e r a t i o n s r e l a t i v e t o
r e f e r e n c e burn rate. One is t h e bulk burn r a t e
scale f a c t o r and the o t h e r is the v a r i a t i o n of b u r n
r a t e w i t h i n t h e c u r e d p r o p e l l a n t g r a i n . T h i s spa-
tial d i s t r i b u t i o n can b e caused by p r o c e s s i n g ( f l o w I
c o n d i t i o n s ) a n d / o r m i g r a t i o n of l i q u i d s p e c i e s t o
propellant interfaces. Burning r a t e u n a f f e c t e d by
f l o w o r m i g r a t i o n i s g e n e r a l l y termed t h e h u l k
burning rate. Burning r a t e s o c c u r r i n g a t t h e pro- 0.21 I
0.0 0.I 1.0 1.5 2.0
p e l l a n t l l i n e r i n t e r f a c e i n end b u r n i n g g r a i n s are
DISTANCE FROM lNSULAllON ilN.1
d e s i g n a t e d as edge b u r n i n g r a t e s w i t h t h e r a t i o of
edge t o bulk b u r n i n g rate being termed E/B. Fig. 3 Comparison o f S e l e c t e d Computer Model
and Measured D i f f u s i o n P r o f i l e s
Bulk burn r a t e s c a l e f a c t o r s e x i s t between
p r o p e l l a n t samples ( t e s t e d i n s u b s c a l e motors) Wigration and its impact on p r o p e l l a n t b u r n i n g
o b t a i n e d from s u b s c a l e mixers and f u l l scale mix- r a t e can a l s o be a f u n c t i o n of t h e p r e s s u r e a t
ers; t h i s i a o f t e n n e g l i g i b l e b u t h a s been observed which t h e motor o p e r a t e s . T h i s has been e v i d e n t i n
t o be as g r e a t as 3 or 4%. The s c a l e f a c t o r be- s e v e r a l s t u d i e s performed a t Thiokol. I n one
tween s u b s c a l e and f u l l scale motors is t y p i c a l l y s t u d y , a m a t r i x of s u b s c a l e p r o p e l l a n t mixes was
w i t h i n +2%, b u t has been observed t o be as g r e a t as made v a r y i n g t h e p l a s t i c i z e r and c a t a l y s t concen-
-
+6%. T h i s s c a l e f a c t o r u n c e r t a i n t y r e p r e s e n t s a t r a t i o n s . Subscale motors and s t r a n d s were then
p o t e n t i a l a m p l i t u d e error i n t h e p r e d i c t e d p r e s s u r e made and t e s t e d a t two p r e s s u r e l e v e l s . A l i n e a r
l e v e l , b u t i s not time o r burn d i s t a n c e dependent. r e g r e s s i o n of t h e s e d a t a e s t a b l i s h e d t h e burning
r a t e , a t two d i f f e r e n t p r e s s u r e s , as a f u n c t i o n of
The burn r a t e v a r i a t i o n w i t h i n t h e c u r e d pro- p l a s t i c i z e r and c a f a l y s t levels. T h i s d a t a
p e l l a n t g r a i n p r e s e n t s a more complex problem s i n c e e v a l u a t i o n i n d i c a t e d t h a t a t low p r e s s u r e t h e
i t i s n o t p r e d i c t a b l e i n advance and can c r e a t e a enhancement of burning r a t e by t h e c a t a l y s t i s
d i s t o r t i o n i n t h e s u r f a c e area vs burn d i s t a n c e a p p r o x i m a t e l y twice t h e d e p r e s s a n t e f f e c t of t h e
r e l a t i o n s h i p p r e d i c t e d on t h e b a s i s of uniform plasticizer. A t high pressure, the depressant
burnback. The mass g e n e r a t i o n r a t e , and hence t h e e f f e c t of t h e p l a s t i c i z e r is approximately f i v e
pressure t i m e curve, w i l l d e v i a t e f r m c l a s s i c a l t i m e s t h e enhancement e f f e c t of t h e c a t a l y s t . T h i s
p r e d i c t i o n s because of both t h e burn rate and sur- i n d i c a t e s t h a t , a t t h e lower p r e s s u r e , m i g r a t i o n of
f a c e area d e v i a t i o n s . This phenomenon h a s been p l a s t i c i z e r and c a t a l y s t t o t h e l i n e r would leave
r e f e r r e d t o by v a r i o u s terms such as: Hump, BARF t h e p r o p e l l a n t edge with a burn rate equal t o or
( B u r n i n g - r a t e Anomalous Rate F a c t o r , SBRE (Surface- s l i g h t l y lower than t h e bulk burn rate. X i g r a t i o n
Burn Rdte E r r o r ) , and R e s i d u a l s . In general, a l l of c a t a l y s t t o t h e l i n e r l i n s u l a t i o n system leaves a
p r e d i c t a b i l i t y errors which are r e f l e c t e d i n t h e p r o p e l l a n t w i t h a lower burn r a t e , while m i g r a t i o n
curve shape d e v i a t i o n s are lumped i n t o " f a c t o r s " t o of p l a s t i c i z e r leaves a p r o p e l l a n t w i t h a h i g h
compensate f o r t h e s e d e v i a t i o n s . T h i s f a c t o r i s burning r a t e . A t t h e h i g h p r e s s u r e , t h e dominant
t h e r a t i o of t h e actual t o t h e p r e d i c t e d p r e s s u r e , m i g r a t i o n v a r i a b l e is t h e p l a s t i c i z e r which w i l l
t a k e n t o t h e 1-n power, t o r e l a t e i t t o an e f f e c - produce an edge burning rate which is h i g h e r t h a n
t i v e s u r f a c e area o r e f f e c t i v e burn rate a t a g i v e n t h e bulk burning r a t e .
time or web d i s t a n c e burned. This e f f e c t i v e sur-
f a c e a r e a l b u r n r a t e f a c t o r w i l l be r e f e r r e d t o i n Subscale end burning motors (5-1". d i a m e t e r )
t h i s paper as Hump o r t h e Hump f a c t o r . were b u i l t and e x t i n g u i s h e d by r a p i d l y depressur-
i z i n g t h e motor w h i l e f i r i n g i n an a l t i t u d e c e l l .
These s u b s c a l e motors were i n t e r n a l l y s t r e s s re-
lieved as depicted in Fig. 4 . These tests verified
the hypothesis of chamber pressure dependent con-
ing. A comparison of extinguished grain profiles
fired at high pressure and at l o w pressure is
presented in Fig. 5. The progression of coning in
an end burning grain is depicted in Fig. 6 where
L
A -
.
identical tests have been extinguished at different
times during motor operation. These high pressure
extinguishment tests showed the case insulation
interface burning rate to be approximately 3 %
higher than the bulk rate and the inhibitor
interface to be approximately 6 %higher than the
bulk rate. Typical end burning pressure vs time
traces are presented in Figs. 7 and 8 , which
illustrate the relative neutrality of the low
pressure burning and the progressivity created by
coning at the high pressure levels, respectively.
TIME (SEC)
Fig. 7 Typical Low Pressure Extinguishment
Pressure Trace
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TIME (SEC)
-
CROSS StCTION FOR HIGH PALSSURE Fig. 8 Typical High Pressure Extinguishment
Pressure Trace
FACTUAL
INHIBITOR
EXTINGUISH
Nr 0.8 SEC 1.61 SEC 2.42 SEC
TIMES
HIGH PRESSURE
TIME
Fig. 6 Grain Surfaces of Extinguishment Motor
at Various Times Fig. 9 Typical Hump Characteristic
m e ignition transient and tailoff transient, often large solid rocket motors ranging in diameter from
slower than expected, may be affected by the param- 37 to 260 in. Many of these motors were segmented,
eters causing Hump. The pressure-time curve shape some had steel eases, and some had flexible cases.
for a given system, although not predictable in Most motors contained state-of-the-art hydrocarbon
advance and different from that predicted by uni- propellants; a few contained nitratoplasticized
form burnback models, has proven to be reproducible formulations. Virtually all of these motors ex-
once it is established. Each motorlpropellant hibited some degree of Hump, hut there were no
system is unique in the extent and detail in which identifiable parameters to correlate to the degree
it deviates from theoretical; i.e., each motor (amplitude) or type of Hump trace. Most of these
system has its own fingerprint or signature rela- motors were one of a kind. However, several are
tive to theory. high production rate motors for which statistical
performance variations are available. The caef-
The Hump phenomenon has usually been associat- ficients of variation in pressure for the high
ed with large solid motors rather than tactical production rate motors have typically been less
systems. One contributing reason is that tactical than 22, most of which is attributed to bulk burn
motors often have high length to diameter ratios rate variation, indicating that little is due to
( L I D ) , which frequently leads to high gas velocity Hump factor variations.
enhancement of burning rate; < . e . , erosive burn- 1.06
ing. Erosive burning does contribute to spatial I I I I I I I I I I
nonuniformity of grain surface regression and does
result in a deviation from predictions, particular-
ly in the later phase of motor burn, if it is not
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. ..
DIJIoI-rs *r-Carr CeosELrY WEB FRACTION
strain COVld ,"*we 8"'" Rare DevlariDn Fig. 10 Thiokol Experience With Segmented Motors
~ropellanr/Procer.lng ChdracrerisiIcJ
.
w sarric19 size oirtrlbur'onlorlentarion Befree" Core and Caee m 1 1
.. sropenanr Yisco*ify
P186flEIZET Ylgrarla"
.. P0i)p.C Type
-. .
cvre sresBYre
,iamogene*cy Of Propellanr
. ""stable Conb"sLL*"
LOCI, cas " e h c l r y E f l P I I *
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.P 1.0
To quantify the Hump factor after static test WtB FRACTION
data have been acquired, known deviations from pre-
fire predicted values are identified. This in- Fig. 11 Industry Experience With Large
volves such parameters as throat erosion rate, C*, Segmented Motors
and bulk burn rate. A post-prediction is made to
correct for these known and accountable deviations,
and a comparison is then made between this post-
prediction and the actual pressure trace. The
residual pressure deviations are then most commonly
translated into an effective (or pseudo-) surface
area. From these pseudo-surfaces, a Hump factor
can be derived in terms of % IAb predicted
vs percent web burned. Sinceeta:d%& and surface
area are synonymous relative to their effect on
pressure [P = f(Ab x rh)l, this Hump factor vs
percent web burned can be viewed as a surface area
deviation, a burn rate deviation or a combination
of the two.
I I
8 16 24 32 40 48
WtBBURNDlSlANCEIIN 1
P r o p e l l a n t p r o c e s s i n g and i n g r e d i e n t m i g r a t i o n
a r e an i n s e p a r a b l e p a r t of s o l i d r o c k e t motor in-
ternal b a l l i s t i c analysis. A s p a t i a l burning r a t e
v a r i a t i o n can o c c u r i n r o c k e t motors due t o t h e
manner i n which p r o p e l l a n t is i n t r o d u c e d a t t h e
c a s t i n g l o c a t i o n and t h e flow of p r o p e l l a n t i n t o
t h e r o c k e t motor case. A d d i t i o n a l l y , m i g r a t i o n of
s o l i d p r o p e l l a n t l i q u i d species i n t o i n e r t i n t e r -
f a c e m a t e r i a l s c r e a t e s a s p a t i a l p r o p e l l a n t burn
rate v a r i a t i o n . I n d e s i g n i n g a new motor, c a r e
should be exercised i n evaluating t h e p o t e n t i a l f o r
Hump. I f a similar motor is not a v a i l a b l e t o s c a l e
from, t h e n t o o l i n g and b a l l i s t i c performance s h o u l d
b e designed w i t h s u f f i c i e n t f l e x i b i l i t y t o accommo-
d a t e 8ome Hump e f f e c t .
Reference