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Research Article Vol. 5, No.

2 / February 2018 / Optica 175

Enhancing thermal radiation with nanoantennas to


create infrared sources with high modulation rates
EMILIE SAKAT,* LÉO WOJSZVZYK, JEAN-PAUL HUGONIN, MONDHER BESBES, CHRISTOPHE SAUVAN,
AND JEAN-JACQUES GREFFET
Laboratoire Charles Fabry, Institut d’Optique Graduate School, CNRS, Université Paris Saclay, Palaiseau, France
*Corresponding author: emilie.sakat@institutoptique.fr

Received 9 October 2017; revised 28 November 2017; accepted 21 December 2017 (Doc. ID 308746); published 2 February 2018

In recent decades, researchers have demonstrated incandescent sources that exhibit monochromatic, directional, and
even fast modulated infrared emission. Most of the researchers achieve this type of emission by heating the whole
device. Here, we propose heating only nanovolumes that can be cooled in a few tens of nanoseconds. This approach
could enable high-speed modulation. To compensate for the weak thermal emission of such isolated nanoemitters, we
propose inserting the hot nanovolume in the gap of a cold nanoantenna. We calculate the resulting emission enhance-
ment by using a generalized version of Kirchhoff’s law, and demonstrate that careful design of the complete antenna–
nanoemitter system can result in emission enhancements of more than four orders of magnitude. © 2018 Optical
Society of America under the terms of the OSA Open Access Publishing Agreement

OCIS codes: (140.3490) Lasers, distributed-feedback; (060.2420) Fibers, polarization-maintaining; (060.3735) Fiber Bragg gratings.

https://doi.org/10.1364/OPTICA.5.000175

1. INTRODUCTION approach that consists of heating only nanoscale volumes whose


The control of the emission of incandescent sources in the infrared cooling times can be extremely fast. Indeed, the thermal diffusion
is of great importance for various applications, such as energy con- time constant of an object of size h is proportional to h2 ∕D, with
version [1–3], gas detection [4], or radiative cooling [5,6]. These D as the thermal diffusion coefficient. Hence, a cubic volume of
applications need to precisely tailor the spectrum, directivity, and matter with a 100 nm size has a characteristic diffusion time in the
polarization of thermal emission. Such a control can only be ob- range of a few tens of nanoseconds—the diffusion coefficient
tained by engineering the emissivity of the structure. In the last 15 being on the order of 10−6 m2 · s−1 for most nonmetallic materi-
years, several demonstrations have completely changed our perspec- als. Such short thermal timescales should enable modulation
tive on what can be achieved with incandescent sources. Resonant speeds as fast as a few tens of megahertz.
nanostructures allow control of the temporal coherence of the
source, thus obtaining the narrowband emission spectrum [7–11]. 2. RESULTS
Taking advantage of the spatial coherence of surface waves, highly In contrast to previous works, the approach proposed in this paper
directional sources have also been demonstrated [12–14]. A new relies on the use of anisothermal structures where only the nano-
challenge in this area is the high-speed modulation of the flux emit- scale volumes are heated while the rest of the device remains at a
ted by a thermal source [15]. Indeed, it would be particularly useful lower temperature. The usual Kirchhoff ’s law is established for
for short-range communications applications, such as remote con- thermodynamic equilibrium and cannot predict the thermal
trol or wireless LAN communication systems. emission of complex structures composed of different parts at dif-
According to Kirchhoff ’s law, thermal emission is the product ferent temperatures. In this case, the theoretical study has to be
of the absorptivity and the blackbody spectral radiance at the realized in the framework of a generalized version of Kirchhoff ’s
working temperature. Modulation of thermal emission can thus law. It is indeed possible to establish the equality between the local
be obtained by dynamically tuning either the absorptivity of the emission rate in one specific direction, wavelength, and polariza-
device [16–18] or its temperature [19]. Electrical modulation of tion and the local absorption rate for the same wavelength, polari-
the emissivity of a stack of quantum wells has allowed the modu- zation, and direction for any finite-sized body with arbitrary
lation of thermal emission at a record rate of 600 kHz [18]. The geometry [20,21]. In this generalized version of Kirchhoff ’s
modulation speed, however, is limited by parasitic resistances and law applied to an anisothermal structure where only a small part
capacitances in the semiconductor layers. The modulation of is hot while the rest of the device is cold, the key physical quantity
thermal emission at a rate faster than a few hundred kilohertz is an absorption cross section. Since the temperature to be taken
is a further challenge that has not yet been achieved. To reach into account is the temperature at the point of interest, we must
higher modulation speeds, we propose what we believe is a novel consider the absorption cross section associated with the hot

2334-2536/18/020175-05 Journal © 2018 Optical Society of America


Research Article Vol. 5, No. 2 / February 2018 / Optica 176

nanovolume and not the cross section of the whole structure. It is (a)
given by
Z
ω
σ abs u; ω  ImεjEj2 d3 r; (1)
2P 0 V e
where ω is the frequency, P 0 is the norm of the Poynting vector of (b)
the incident plane wave, ε is the dielectric permittivity of the
material, E is the total electric field, and V e is the volume of in-
terest (i.e., the nanoscale volume that will be heated). We can
define the local absorption cross section as
ω ImεjEj2
αabs r; u; ω  : (2)
2P 0 Fig. 1. (a) Cubic nanoemitter of width wn inserted in the gap of a
dimer nanoantenna made of two gold nanorods and deposited on a sub-
The power emitted by the hot nanovolume V e is then given by strate of refractive index nsub  1.28. The nanorods have a length Lant
Z
and a square section wn × wn . (b) Near-field enhancement jEj∕jEinc j cal-
P e u; ω  αabs r; u; ωI B ω; T rd3 r; (3) culated for a normal incident plane wave with a polarization parallel to
Ve
the antenna axis for λ  13.24 μm, Lant  3.6 μm and wn  200 nm.
where I B ω; T r is the spectral radiance of a blackbody [20,21]. The nanoemitter is in SiNx [relative permittivity in Fig. 3(a)].
If we assume a constant temperature in the nanovolume V e ,
we obtain P e  σ abs I B T . It shows that to increase the extrac-
tion of thermal power from a given object, one must increase its chooses the absorbing material alone with a permittivity that be-
absorption cross section. Therefore, in the following discussion, comes too high, the electric field inside the material is screened and
we focus on the calculation of σ abs given by Eq. (1). Hereafter, we the absorption cross section decreases. Conversely, one cannot
refer to the volume V e as the nanoemitter. choose the nanoantenna alone without considering the nanoemit-
Absorption by deeply subwavelength and isolated objects is ter. An impedance-matching condition must be fulfilled to maxi-
extremely weak. For instance, the absorption cross section at λ  mize the power transfer between the nanoantenna and the
10 μm of a small cube of silicon nitride with a 200 nm side is on nanoemitter [25,26]. For the nanoemitter material, we have chosen
the order of 0.01 μm2 (i.e., only 25 percent of its geometrical to exploit the phonon resonance in the SiNx , which is situated in
surface). To take advantage of the short thermal timescales offered the targeted 8–14 μm wavelength range, as shown in Fig. 3(a).
by small objects, we must significantly increase the absorption in a Figure 1(b) highlights the field enhancement jEj∕jEinc j in the
given object whose typical size is on the order of 100 nm. In prin- SiNx nanoemitter with a size of 200 nm. Calculations have been
ciple, the maximum absorption cross section for a small object realized with the aperiodic Fourier modal method (a-FMM) [27]
behaving as a pure electric dipole is 3λ2 ∕8π  12 μm2 at at λ  13.24 μm for a plane wave with a normal incidence and a
λ  10 μm. However, reaching this upper bound with a sub- polarization parallel to the antenna axis. The refractive index of
wavelength nanosphere with a polarizability given by the quasi- gold has been taken from [28]. The antenna length is Lant 
static limit requires the use of a material with a relative 3.6 μm and corresponds to the length that maximizes the absorp-
permittivity close to −2. In practice, obtaining an absorption cross tion cross section, as shown in Fig. 2, which shows the absorption
section of 3λ2 ∕8π at λ  10 μm with a sphere of radius cross section of the SiNx nanoemitter as a function of the antenna
100 nm in air requires filling the nanosphere with a relative per- length and wavelength. The blue cross indicates the maximum of
mittivity equal to −2.0095  0.0005i. Such a precise value is the absorption cross section σ abs  14.21 μm2 for a wavelength
impossible to find with realistic materials. It has been shown re- of 13.24 μm and an antenna length of 3.6 μm. Figure 3(b) shows
cently that absorption cross sections close to 3λ2 ∕8π or even the absorption cross section spectrum obtained for the optimum
larger can be obtained with realistic materials [22], but with big-
ger objects that do not behave as pure electric dipoles and have
longer thermal timescales.
To enhance the power extraction from a small emitter, it has
been shown that one can use a hemisphere with large refractive
index n [23]. The enhancement is limited by a factor n2. Here, we
propose to insert the nanoemitter in the gap of a dimer nanoan-
tenna made of two gold nanorods on a substrate, as shown in
Fig. 1. Enhancement of the absorption assisted by a nanoantenna
has already been used for bolometers [24]. To optimize the ab-
sorption cross section of the nanoemitter in the presence of the
antenna in the mid-infrared wavelength range, one has to care-
fully choose both the material composing the emitter and the an-
tenna geometry. According to Eq. (1), it appears that the electric Fig. 2. Absorption cross section of a cubic SiNx nanoemitter with
field in the nanoemitter and the imaginary part of the permittivity wn  200 nm inserted in the gap of a dimer nanoantenna as a function
must be as large as possible to maximize the absorption cross sec- of the wavelength and the antenna length. Calculations are performed
tion. However, maximizing these two quantities independently is at normal incidence with a polarization parallel to the antenna axis.
counterproductive because they are highly correlated. If one The cross shows the location of the maximum.
Research Article Vol. 5, No. 2 / February 2018 / Optica 177

antenna length Lant  3.6 μm. The dashed red curve displays the that strongly depends on the antenna length. These resonances
cross section calculated without the antenna; the data have been arise from the presence of two modes in the whole system
multiplied by a factor 100 for a better visibility. The presence of nanoantenna–nanoemitter. We have calculated the eigenfrequen-
the nanoantenna leads to an enhancement by more than four cies of these two modes as a function of the antenna length by
orders of magnitude. The maximum of the ratio between the cross looking for the poles of the scattering matrix in the complex fre-
sections with and without the antenna is as high as 11600 at quency plane [29]. The corresponding wavelengths are superim-
λ  14.64 μm, as shown in Fig. 3(c). Note that the ratio of these posed in Fig. 4 with dashed blue lines. They can be attributed
cross sections integrated over the wavelength range 8–20 μm to one mode intrinsic to the SiNx nanoemitter and one mode
(effective emissivity) is equal to 2480. This result demonstrates of the nanoantenna that are coupled. Our calculations reveal a
the capability of the antenna to enhance the weak absorption strong coupling behavior; see Fig. 4, which shows the clear anti-
(and thus the thermal emission) of the nanoemitter. crossing between the dashed lines. We have checked that the line-
The absorption cross section spectrum in Fig. 3(b) is very broad widths of the modes are smaller than the splitting between the
and presents two different peaks, whereas the dimer nanoantenna eigenfrequencies. The nanoantenna resonance red-shifts when
should support a single mode in this spectral range. To understand the antenna length increases, as expected from the bounding dipole
this feature, we have calculated the average field enhancement in- mode of the dimer. For the resonance of the nanoemitter, it appears
side the nanoemitter. It is represented in Fig. 4 as a function of the that the field enhancement spectrum inside the nanoemitter alone
wavelength and the length of the antenna. Note that, since the field (i.e., without nanoantenna) exhibits a resonance at λ  9.2 μm
is almost constant within the volume of the nanoemitter as shown (spectrum not shown here). This wavelength corresponds to
in Fig. 1(b), we have calculated the average field from the cross the cancellation of the real part of the SiNx permittivity; the
section as jEav j2  2P 0 σ abs ∕ω ImεV e . Two resonances can nanoemitter resonance is thus an epsilon-near-zero resonance
be observed: a first one around λ  9 μm, which varies weakly [16,30,31]. The presence of the two resonances explains the broad
with the antenna length; and a second one, at larger wavelengths, absorption spectra visible on Figs. 2 and 3(b). Indeed, σ abs is the
product of the field enhancement of Fig. 4 and the imaginary part
of the SiNx permittivity plotted on Fig. 3(a) (red dashed curve).
Finally, we describe an example of the implementation of a fast
(a) and local heating of the nanoemitter and also provide a full ther-
mal study of the corresponding system. The heating system con-
sists of a metallic wire with a varying width, as shown in Fig. 5(a).
The width is narrower below the nanoemitter so that the electric
resistance locally increases, allowing it to dissipate heat by Joule
effect at this precise location. We have performed numerical sim-
ulations with the finite element method to evaluate the temper-
ature profile along the antenna axis x as a function of time. After a
voltage is applied during 6 ns, the system should be allowed to
(b)
relax and cool down. This duration is twice the diffusion time
(w2n ∕D  3 ns) in the nanoemitter and has been chosen to ensure
uniform heating of the nanoemitter. Figure 5(b) shows that dur-
ing such a short heating time only the emitter is significantly
heated. With the injected electrical power, the temperature
inside the nanoemitter reaches 550 K after 6 ns. This maximal
temperature could be increased with an higher voltage. On the con-
trary, the nanoantenna is still cold. In fact, the temperature of the
(c)
antenna increases only very close to the nanoemitter. The system

Fig. 3. (a) Real (solid curve) and imaginary part (red dashed curve) of
the relative permittivity of silicon nitride SiNx as a function of the wave-
length. (b) Absorption cross section of the 200 nm side SiNx nanoemitter
alone (red dashed curve; data have been multiplied by 100 for better
visibility) or inserted in the gap of the optimal dimer nanoantenna with
Lant  3.6 μm (solid curve). Calculations are performed at normal inci- Fig. 4. Average field enhancement jEav j2 ∕jEinc j2 inside the SiNx nano-
dence with a polarization parallel to the antenna axis. (c) Enhancement emitter inserted in the gap of the dimer antenna as a function of the
factor defined as the ratio of the cross section of the SiNx nanoemitter wavelength and the length of the antenna Lant . The average field has been
with and without antenna. calculated as jEav j2  2P 0 σ abs ∕ω ImεV e .
Research Article Vol. 5, No. 2 / February 2018 / Optica 178

(a) REFERENCES
1. S. V. Boriskina, M. A. Green, K. Catchpole, E. Yablonovitch, M. C. Beard,
Y. Okada, S. Lany, T. Gershon, A. Zakutayev, M. H. Tahersima, V. J.
Sorger, M. J. Naughton, K. Kempa, M. Dagenais, Y. Yao, L. Xu, X.
Sheng, N. D. Bronstein, J. A. Rogers, A. P. Alivisatos, R. G. Nuzzo,
J. M. Gordon, D. M. Wu, M. D. Wisser, A. Salleo, J. Dionne, P.
Bermel, J.-J. Greffet, I. Celanovic, M. Soljacic, A. Manor, C. Rotschild,
A. Raman, L. Zhu, S. Fan, and G. Chen, “Roadmap on optical energy
conversion,” J. Opt. 18, 073004 (2016).
2. E. Rephaeli and S. Fan, “Absorber and emitter for solar thermo-photo-
voltaic systems to achieve efficiency exceeding the Shockley–Queisser
(b)
limit,” Opt. Express 17, 15145–15159 (2009).
3. A. Lenert, D. M. Bierman, Y. Nam, W. R. Chan, I. Celanovic, M. Soljacic,
and E. N. Wang, “A nanophotonic solar thermophotovoltaic device,” Nat.
Nanotechnol. 9, 126–130 (2014).
4. D. Costantini, A. Lefebvre, A.-L. Coutrot, I. Moldovan-Doyen, J.-P.
Hugonin, S. Boutami, F. Marquier, H. Benisty, and J.-J. Greffet,
“Plasmonic metasurface for directional and frequency-selective thermal
emission,” Phys. Rev. Appl. 4, 014023 (2015).
5. Z. Chen, L. Zhu, A. Raman, and S. Fan, “Radiative cooling to deep
sub-freezing temperatures through a 24-h day–night cycle,” Nat.
Commun. 7, 13729 (2016).
6. T. Liu and J. Takahara, “Ultrabroadband absorber based on single-sized
embedded metal-dielectric-metal structures and application of radiative
cooling,” Opt. Express 25, A612–A627 (2017).
7. P. J. Hesketh, J. N. Zemel, and B. Gebhart, “Organ pipe radiant modes of
periodic micromachined silicon surfaces,” Nature 324, 549–551 (1986).
Fig. 5. (a) Scheme of an exemple of implementation of an electrical 8. I. Puscasu and W. L. Schaich, “Narrow-band, tunable infrared emission
heating system. (b) Time dependent temperature profile T x; z  wn ; t from arrays of microstrip patches,” Appl. Phys. Lett. 92, 233102 (2008).
along the x axis as a function of time for a bias ΔU  2 V applied during 9. X. Liu, T. Tyler, T. Starr, A. F. Starr, N. M. Jokerst, and W. J. Padilla,
6 ns. After t  6 ns, the system cools down. The nanoemitter is located “Taming the blackbody with infrared metamaterials as selective thermal
in the center of the picture and is surrounded by the dimer antenna. emitters,” Phys. Rev. Lett. 107, 045901 (2011).
(More details on the calculations can be found in Supplement 1.) 10. M. Makhsiyan, P. Bouchon, J. Jaeck, J.-L. Pelouard, and R. Haïdar,
“Shaping the spatial and spectral emissivity at the diffraction limit,”
Appl. Phys. Lett. 107, 251103 (2015).
11. O. Ilic, P. Bermel, G. Chen, J. D. Joannopoulos, I. Celanovic, and M.
then cools with a similar duration (6 ns) since both heating
Soljačić, “Tailoring high-temperature radiation and the resurrection of
and cooling timescales are driven by diffusion. Numerical simula- the incandescent source,” Nat. Nanotechnol. 11, 320–324 (2016).
tions thus confirm the possibility to reach modulation rates above 12. J.-J. Greffet, R. Carminati, K. Joulain, J.-P. Mulet, S. Mainguy, and Y.
tens of MHz. The details on the thermal calculations can be Chen, “Coherent emission of light by thermal sources,” Nature 416,
found in Supplement 1. We have checked that the addition of 61–64 (2002).
13. N. Dahan, A. Niv, G. Biener, Y. Gorodetski, V. Kleiner, and E. Hasman,
small metallic wires dedicated to heating does not affect the optical
“Enhanced coherency of thermal emission: beyond the limitation im-
performances. posed by delocalized surface waves,” Phys. Rev. B 76, 045427 (2007).
14. S. Campione, F. Marquier, J.-P. Hugonin, A. R. Ellis, J. F. Klem, M. B.
Sinclair, and T. S. Luk, “Directional and monochromatic thermal emitter
3. CONCLUSION from epsilon-near-zero conditions in semiconductor hyperbolic metama-
terials,” Sci. Rep. 6, 34746 (2016).
In conclusion, we have theoretically demonstrated a thermal emis- 15. J.-J. Greffet, “Controlled incandescence,” Nature 478, 191–192 (2011).
sion enhancement for a SiNx nanoemitter higher than four orders 16. S. Vassant, A. Archambault, F. Marquier, F. Pardo, U. Gennser, A.
of magnitude, thanks to a carefully designed dimer nanoantenna. Cavanna, J. L. Pelouard, and J. J. Greffet, “Epsilon-near-zero mode
This result opens the way to the realization of arrays of nanoemit- for active optoelectronic devices,” Phys. Rev. Lett. 109, 237401 (2012).
17. S. Vassant, I. M. Doyen, F. Marquier, F. Pardo, U. Gennser, A. Cavanna,
ters that could be heated locally and inserted in the gap of cold J. L. Pelouard, and J. J. Greffet, “Electrical modulation of emissivity,”
resonant nanoantennas, allowing a high modulation rate together Appl. Phys. Lett. 102, 081125 (2013).
with an enhanced thermal emission. Moreover, various kinds of 18. T. Inoue, M. D. Zoysa, T. Asano, and S. Noda, “Realization of dynamic
nanoantennas can be placed on the metasurface, which allows thermal emission control,” Nat. Mater. 13, 928–931 (2014).
the active tuning of the emission of the nanoemitter in directivity, 19. J. Hildenbrand, J. Korvink, J. Wollenstein, C. Peter, A. Kurzinger, F.
Naumann, M. Ebert, and F. Lamprecht, “Micromachined mid-infrared
wavelength, and polarization by specifically heating the emitters emitter for fast transient temperature operation for optical gas sensing
related to one antenna or the other. This approach will enable systems,” IEEE Sens. J. 10, 353–362 (2010).
the design of cheap, compact and dynamic IR sources. 20. S. M. Rytov, Y. A. Kravtsov, and V. I. Tatarskii, Principles of Statistical
Radiophysics 2: Correlation Theory of Random Processes (Springer-
Funding. Direction Générale de l’Armement (DGA). Verlag, 1988).
21. J.-J. Greffet, P. Bouchon, G. Brucoli, E. Sakat, and F. Marquier,
“Generalized Kirchhoff law,” arXiv: 1601.00312 (2016).
Acknowledgment. The authors thank F. Marquier for 22. V. Grigoriev, N. Bonod, J. Wenger, and B. Stout, “Optimizing nanoparticle
helpful discussion. Author Léo Wojszvzyk is grateful to the designs for ideal absorption of light,” ACS Photon. 2, 263–270 (2015).
DGA for Ph.D. funding. 23. Z. Yu, N. P. Sergeant, T. Skauli, G. Zhang, H. Wang, and S. Fan,
“Enhancing far-field thermal emission with thermal extraction,” Nat.
See Supplement 1 for supporting content. Commun. 4, 1730 (2013).
Research Article Vol. 5, No. 2 / February 2018 / Optica 179

24. F. González and G. Boreman, “Comparison of dipole, bowtie, spiral 28. E. D. Palik and G. Ghosh, Handbook of Optical Constants of Solids
and log-periodic IR antennas,” Infrared Phys. Technol. 46, 418–428 (Academic, 1998).
(2005). 29. Q. Bai, M. Perrin, C. Sauvan, J.-P. Hugonin, and P. Lalanne, “Efficient
25. A. Alu and N. Engheta, “Tuning the scattering response of optical nano- and intuitive method for the analysis of light scattering by a resonant
antennas with nanocircuit loads,” Nat. Photonics 2, 307–310 (2008). nanostructure,” Opt. Express 21, 27371–27382 (2013).
26. J.-J. Greffet, M. Laroche, and F. Marquier, “Impedance of a nanoantenna 30. A. Alù, M. G. Silveirinha, A. Salandrino, and N. Engheta, “Epsilon-near-
and a single quantum emitter,” Phys. Rev. Lett. 105, 117701 (2010). zero metamaterials and electromagnetic sources: tailoring the radiation
27. J. P. Hugonin and P. Lalanne, “Perfectly matched layers as nonlinear phase pattern,” Phys. Rev. B 75, 155410 (2007).
coordinate transforms: a generalized formalization,” J. Opt. Soc. Am. 31. S. Campione, I. Brener, and F. Marquier, “Theory of epsilon-near-zero
A 22, 1844–1849 (2005). modes in ultrathin films,” Phys. Rev. B 91, 121408 (2015).

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