06-03-20 03:05 AM C:\Users\CCAMPOS PR...\ejemplo15_4.

m 1 of 2

clc,close all
%PRINCESS AMPARO CAMPOS CALLEJAS
q=[45.5 91.5 113 121 125 126 126]';%cm3CH4/gcarbon
p=[40 165 350 545 760 910 970]';%psia
%Isoterma de Freundlich
disp('Isoterma de Freundlich')
disp('q=k*p^1/n')
lq=log10(q);
lp=log10(p);
f=polyfit(lp,lq,1);
disp(' b a')
disp(f)
k=10^f(2);
n=1/f(1);
disp('k=')
disp(k)
disp('n=')
disp(n)
qF=k.*(p.^(1/n));
%Isoterma de Langmuir
disp('Isoterma de Langmuir')
disp('q=k*p*qm/1+k*p')
p_q=p./q;
g=polyfit(p,p_q,1);
disp(' b a')
disp(g)
qm=1/g(1);
K=1/(qm*g(2));
disp('qm=')
disp(qm)
disp('K=')
disp(K)
qL=(K.*p.*qm)./(1+K.*p);
disp(' q qF qL |[cm3CH4/gcarbon] ')
disp([q qF qL])
plot(p,q,'k--o',p,qF,'b--o',p,qL,'r--o')
xlabel('p[psia]')
ylabel('q,qF,qL cm3CH4/gcarbon')
legend({'q','qF','qL'},'Location','southwest')

% Isoterma de Freundlich
% q=k*p^1/n
% b a
% 0.3101 1.2133
%
% k=
% 16.3423
%
% n=
% 3.2244
%
% Isoterma de Langmuir
% q=k*p*qm/1+k*p
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% b a
% 0.0073 0.5682
%
% qm=
% 136.9609
%
% K=
% 0.0128
%
% q qF qL |[cm3CH4/gcarbon]
% 45.5000 51.3068 46.4975
% 91.5000 79.6237 93.0662
% 113.0000 100.5377 112.0473
% 121.0000 115.3394 119.8475
% 125.0000 127.8695 124.2391
% 126.0000 135.2161 126.1709
% 126.0000 137.9205 126.7888
%