Diagrama x-y metanol agua

1)Datos de equilibrio para el sistema metanol-Agua

COMPONENTE Rango(°C) A B C
Metanol (A) 20-140 7.8786 1473.1100 230.0000
Agua (B) 60-150 7.9668 1668.2100 228.0000

T °C x y Log P°A Log P°B

100.00 0.00 0.00 3.4147 2.8808
96.40 0.05 0.15 3.3654 2.8244
93.50 0.10 0.28 3.3250 2.7780
91.20 0.14 0.37 3.2924 2.7406
89.30 0.18 0.44 3.2651 2.7093
87.70 0.21 0.49 3.2418 2.6826
84.40 0.29 0.60 3.1932 2.6268
81.70 0.36 0.67 3.1526 2.5803
78.00 0.46 0.76 3.0958 2.5151
75.30 0.55 0.82 3.0535 2.4666
73.10 0.62 0.87 3.0185 2.4264
71.20 0.69 0.90 2.9878 2.3912
69.30 0.77 0.93 2.9568 2.3556
67.60 0.85 0.96 2.9287 2.3233
66.00 0.92 0.98 2.9019 2.2926
65.00 0.97 0.99 2.8850 2.2733
64.50 1.00 1.00 2.8766 2.2635

2)Capacidad calorifica

C1 C2 C3 C4 C5
metanol 1.06E+05 -3.62E+02 9.38E-01 0.00E+00 0.00E+00
agua 2.76E+05 -2.09E+03 8.13E+00 -1.41E-02 9.37E-06

3)Calores latentes de vaporizacion

C1 C2 C3 C4 Tc (K)
metanol 5.24E+07 3.68E-01 0.00E+00 0.00E+00 512.64
agua 5.21E+07 3.20E-01 -2.12E-01 2.68E-01 647.13

4) Datos de entalpia de mezcla

n=Xagua Q(KJ/gmol me Xmetanol Hs

 0.00 0.00 1.00 0.00
0.05 -0.07 0.95 -67.45
0.10 -0.15 0.90 -135.90
0.15 -0.25 0.85 -213.35
0.20 -0.36 0.80 -284.80 Diagrama de calor de mez
0.25 -0.47 0.75 -354.75 0.00
0.30 -0.59 0.70 -415.80 0.00f(x) =0.10
− 6348.62 x⁶ + 10345.6
0.20 0.30 x⁵0.40
+ 5571.56
0.5
-100.00 + 2.62293
0.35 -0.72 0.65 -470.60 R² = 0.999827128471436
0.40 -0.87 0.60 -519.60
-200.00
0.45 -1.01 0.55 -557.15
0.50 -1.19 0.50 -596.50 -300.00
0.55 -1.40 0.45 -630.90
-400.00
0.60 -1.63 0.40 -652.80
0.65 -1.91 0.35 -667.80 -500.00
0.70 -2.26 0.30 -679.20
-600.00
0.75 -2.69 0.25 -672.75
0.80 -3.19 0.20 -637.00 -700.00
0.85 -3.73 0.15 -558.75
-800.00
0.90 -4.35 0.10 -435.20
0.95 -5.00 0.05 -249.85
1.00 0.00 0.00 0.00 T0 (°C)=

5) Entalpia de un liquido saturado o subenfriado

J/Kmol K J/Kmol K J/Kmol K KJ/Kmol K

T (°C) T (K) XA CLAMWA CLBMWB CLMWprom CLMWprom
100 373.15 0.00 1.01E+05 7.60E+04 7.60E+04 76.0139
96.4 369.55 0.05 1.00E+05 7.59E+04 7.71E+04 77.1338
93.5 366.65 0.10 9.91E+04 7.59E+04 7.82E+04 78.1670
91.2 364.35 0.14 9.83E+04 7.58E+04 7.90E+04 79.0018
89.3 362.45 0.18 9.77E+04 7.58E+04 7.97E+04 79.7032
87.7 360.85 0.21 9.72E+04 7.57E+04 8.03E+04 80.3028
84.4 357.55 0.29 9.62E+04 7.57E+04 8.16E+04 81.5683
81.7 354.85 0.36 9.54E+04 7.56E+04 8.26E+04 82.6360
78 351.15 0.46 9.43E+04 7.56E+04 8.42E+04 84.1531
75.3 348.45 0.55 9.35E+04 7.55E+04 8.53E+04 85.3044
73.1 346.25 0.62 9.28E+04 7.55E+04 8.63E+04 86.2729
71.2 344.35 0.69 9.23E+04 7.54E+04 8.71E+04 87.1331
69.3 342.45 0.77 9.18E+04 7.54E+04 8.80E+04 88.0169
67.6 340.75 0.85 9.13E+04 7.54E+04 8.88E+04 88.8286
66 339.15 0.92 9.08E+04 7.54E+04 8.96E+04 89.6118
65 338.15 0.97 9.06E+04 7.54E+04 9.01E+04 90.1110
64.5 337.65 1.00 9.04E+04 7.54E+04 9.04E+04 90.3635
7) Grafica del diagrama Entalpia-Composicion pa

Grafico Enta
50000
45000
40000
35000
30000

H (KJ/Kmol)
25000
20000
15000
10000
5000
0
0.00 0.10 0.20 0.30 0.40
 Grafico de Temperatura -
P°A P°B xA yA 105.00
2598.1266 759.9830 0.00 0.00 100.00
2319.6654 667.3634 0.05 0.15 95.00
2113.3282 599.7585 0.10 0.28 90.00
1960.4680 550.2857 0.14 0.37 85.00

Tmperatura (°C)
1841.0648 512.0277 0.18 0.44 80.00
1745.1561 481.5571 0.21 0.49 75.00
1560.1474 423.4764 0.29 0.60 70.00
65.00
1420.9517 380.4299 0.36 0.67
60.00
1246.8245 327.4487 0.46 0.76
55.00
1131.1161 292.8277 0.55 0.82
50.00
1043.4817 266.9468 0.62 0.87
45.00
972.3588 246.1738 0.69 0.90
40.00
905.2718 226.7823 0.77 0.93 0.00 0.10 0.20 0.30 0.40 0.50
848.5230 210.5422 0.85 0.96
xA , yA
797.8239 196.1672 0.92 0.98
767.4265 187.6120 0.97 0.99
752.5904 183.4543 1.00 1.00
rama de calor de mezcla con Tref=42,37 °C
=0.10
− 6348.62 x⁶ + 10345.6
0.20 0.30 x⁵0.40
+ 5571.56 x⁴ − 21789.7
0.50 0.60 x³ 0.70
+ 18218.6 x² − 6002.38
0.80 0.90 x 1.00
2.62293
= 0.999827128471436

a= -6348.6
b= 10346
c= 5571.6
d= -21790
e= 18219
f= -6002.4
g= 2.6229

42.37 temperatura de referencia donde sacamos los datos de entalpia

6)Entalpia de un vapor saturado o sobrecalentado

KJ/Kmol KJ/Kmol J/Kmol K

Hs HL TrA TrB YA CLAMWA
0.00E+00 4380.6810633 0.72790 0.5766 0.00 1.01E+05
-2.55E+02 4167.5391929 0.72088 0.5711 0.15 1.00E+05
-4.34E+02 3996.6769465 0.71522 0.5666 0.28 9.91E+04
-5.41E+02 3857.6594777 0.71073 0.5630 0.37 9.83E+04
-6.06E+02 3740.4697108 0.70703 0.5601 0.44 9.77E+04
-6.44E+02 3640.124309 0.70391 0.5576 0.49 9.72E+04
-6.80E+02 3428.3153426 0.69747 0.5525 0.60 9.62E+04
-6.73E+02 3250.075135 0.69220 0.5483 0.67 9.54E+04
-6.22E+02 2998.3760026 0.68498 0.5426 0.76 9.43E+04
-5.62E+02 2809.072269 0.67972 0.5385 0.82 9.35E+04
-4.96E+02 2651.1657623 0.67543 0.5351 0.87 9.28E+04
-4.23E+02 2512.0482046 0.67172 0.5321 0.90 9.23E+04
-3.28E+02 2370.2944627 0.66801 0.5292 0.93 9.18E+04
-2.20E+02 2241.1467665 0.66470 0.5266 0.96 9.13E+04
-1.05E+02 2117.5258646 0.66158 0.5241 0.98 9.08E+04
-3.59E+01 2039.2114864 0.65962 0.5225 0.99 9.06E+04
0.00E+00 1999.7439999 0.65865 0.5218 1.00 9.04E+04
diagrama Entalpia-Composicion para el sistema Metanol-Agua

Grafico Entalpia-Composición

HL
Hv

.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
xA , yA
fico de Temperatura -composicion
1.00
0.90
Recta de 45°
0.80

fraccion mol de A en el vapor

0
0.1 0.70
0.2 0.60
0.3 0.50
0.4 0.40
0.5
0.30
0.6
0.20
0.7
0.8 0.10
0.9 0.00
1 0.00 0.10 0.20 0.30

.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00 Fracc

xA , yA
J/Kmol K J/Kmol J/Kmol J/Kmol KJ/Kmol
CLBMWB λAMWA λBMWB Hv Hv
7.60E+04 3.25E+07 4.07E+07 4.51E+07 45096.1187
7.59E+04 3.28E+07 4.09E+07 4.39E+07 43933.8964
7.59E+04 3.30E+07 4.10E+07 4.30E+07 42991.3409
7.58E+04 3.32E+07 4.11E+07 4.23E+07 42301.8455
7.58E+04 3.34E+07 4.12E+07 4.18E+07 41769.1794
7.57E+04 3.35E+07 4.13E+07 4.13E+07 41345.49
7.57E+04 3.37E+07 4.14E+07 4.05E+07 40539.9744
7.56E+04 3.40E+07 4.16E+07 3.99E+07 39945.5502
7.56E+04 3.43E+07 4.17E+07 3.92E+07 39218.4376
7.55E+04 3.45E+07 4.18E+07 3.87E+07 38747.0076
7.55E+04 3.46E+07 4.19E+07 3.84E+07 38397.1242
7.54E+04 3.48E+07 4.20E+07 3.81E+07 38118.2251
7.54E+04 3.49E+07 4.21E+07 3.79E+07 37859.7265
7.54E+04 3.51E+07 4.22E+07 3.76E+07 37644.8478
7.54E+04 3.52E+07 4.22E+07 3.75E+07 37456.0663
7.54E+04 3.52E+07 4.23E+07 3.73E+07 37344.4266
7.54E+04 3.53E+07 4.23E+07 3.73E+07 37290.3816
1.00
0.90
0.80
0.70
0.60
0.50
0.40
0.30
0.20
0.10
0.00
0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 1.00
Fraccion mol de A en el liquido