RESUME CONTOH SOAL DAN PEMBAHASAN AKTIVITAS ION

KELOMPOK 10

1. Dewi Zulaikhoh (12212183013)

2. Vida Amalia Fitriani (12212183024)
3. Andiana Nurwanda (12212183038)

1. Determine the mean ionic molality and activity for a 0,200-molal solution of Cr(NO3)3 if its

mean activity coefficient ᵧ ± is 0,285.

Diketahui :
Cr(NO3)3 → Cr3+ + 3NO3-
m = 0,20 molal

ᵧ± = 0,285

Ditanya :

a) m ±

b) a ±

jawaban
a) m + = 1 x 0,200 molal
= 0,200 molal
m- = 3 x 0,200 molal
= 0,600 molal
n+ =1
n- =3
1
m± = ( m+ n+ x m-n-)
𝑛+ +𝑛−
1
= ((0,200)1 x (0,600)3)
4
 1
= (0,200 x 0,216)
4
= 0, 45590 molal

m+
a± =( ±xᵧ 𝑚𝑜
)n±

= (0,285 x 0,45590)4

= (0,1299315)4

= 2,85 x 10-4

2. What are the mean ionic molality and activity for a 0,050-molal solution of CuSO4 if its

mean activity coefficient ᵧ ± is 0,223?

Diketahui :
CuSO4 → Cu2+ + SO4 2-
m = 0,050 molal

ᵧ ± = 0,223
Ditanyakan :
a. m ±
b. a ±
jawaban
a. m + = 1 x 0,050 molal
= 0,050 molal

m- = 1x 0,050 molal

= 0,050 molal

n+ =1

n- =1
 1
m± = ( m+ n+ x m-n-)
𝑛+ +𝑛−
= (( 0,050)1 x (0,050)1 ) ½
= (0,050 x 0,050)2
= (0,0025) ½
= 0,05 molal

m+
b. a ± ᵧ
=( ±x
𝑚𝑜
)n±

= ( 0,223 x 0,05 )2
1
2
= (0,01115)
= 1,24 x 10 -4

3. Calculate the ionic strengths of 0,100 m NaCl,Na2SO4 and Ca3(PO4)2.

Diketahui :

NaCl 0,100 molal

Na2SO4 0,100 molal

Ca3(PO4)2 0,100 molal

Ditanyakan?

a) I NaCl …?
b) I Na2SO4…?
c) I Ca3(PO4)2
Jawab :

NaCl → Na+ +Cl-

I = ½ Σ mizi2

= ½ ( (1,00) x 12 +(0,100) x 12
 = ½ ( (1,00) x 1 +(0,100) x 1 )

= ½ (1,00 +0,100 )

= ½ (0,200)

= 0,100 m

NaSO4 → Na+ + SO4-

I = ½ Σ mizi2

= ½ ( (0,100) x 12 + +(0,100) x 12 ) + +(0,100) x 22 )

= ½ ( (0,100) x 1 + +(0,100) x 1 ) + +(0,100) x 4)

= ½ (0,100 + 0,100 + 0,400 )

= ½ (0,600 )

= 0,300 m

Ca3(PO4)2 → 3 Ca2+ + 2 PO 3-

I = ½ Σ mizi2

= ½ ((0,100) x 22 + (0,100) x 22 + (0,100) x 22 + (0,100) x 32 + (0,100) x 32 )

= ½ ((0,100) x 4 + (0,100) x 4 + (0,100) x 4 + (0,100) x 9 + (0,100) x 9 )

= ½ (0,400 + 0,400 + 0,400 + 0,900 + 0,900)

= ½ (3,00 )

= 1,5 mol

4. What molality of Na2SO4 is needed to have the same ionic strength as 0,100 m Ca3 (PO4)2?
Diketahui :
Ca3 (PO4)2 0,100 molal
Ditanyakan?
Berapa molalitas Na2SO4 yang dibutuhkan untuk memiliki kekuata n ion yang sama
dengan 0,100 molal CO3 (PO4)2 ...?

Jawab :
CO3 (PO4)2 0,100 molal
Ca3 + 2 (PO 4) 3-

I = ½ Σ mizi2

= ½ ((0,100) x 22 + (0,100) x 22 + (0,100) x 22 + (0,100) x 32 + (0,100) x 32 )

= ½ ((0,100) x 4 + (0,100) x 4 + (0,100) x 4 + (0,100) x 9 + (0,100) x 9 )

= = ½ (0,400 + 0,400 + 0,400 + 0,900 + 0,900)

= ½ (3,00 )

= 1,500 m

I CO3 (PO4)2 = I Na2SO

1,500 m = 1,500 m

Na2SO → 2Na + SO4 -

I = ½ Σ mizi2

1,500 m = ½ (m+) x 12 + (m+) x 12 + (m-) x 22 )

1,500 m = ½ (m+) x 1+ (m+) x 1 + (m-) x 4 )

 1,500 m = ½ (m+ m+ + 4 m- )

1,500 m = ½ ( 6 m±)

1,500 m = ½ 3 m ±)

1500
m±
3
=

= 0,500 molal

5. Determine ionic strengths for the following solutions. Assums that they are 100% ionized.

(a) 0,0055 molal HCl,

(b) 0,075 molal NaHCO3,

(c) 0,0250 molal Fe(NO3)2,

(d) 0,0250 molal Fe(NO3)3.

Jawaban:

Diketahui:

a.) 0,0055 molal HCl

b.) 0,075 molal NaHCO3

c.) 0,0250 molal Fe(NO3)2

d.) 0,0250 molal Fe(NO3)3

Ditanyakan:

a.) I HCl =.....?

b.) I NaHCO3 =.....?

c.) I Fe(NO3)2 =....?

d.) I Fe(NO3)3 =....?

Jawab:

a.) 0,0055 molal HCl

HCl →H+ + Cl-

I = ½ Σ × mi × zi2

= ½ ((0,0055) × 12 + (0,0055) × 12)

= ½ ((0,0055) × 1 + (0,0055) × 1)

= ½ (0,0055 + 0,0055)

= ½ (0,011)

= 0,0055 m

b.) 0,075 molal NaHCO3

NaHCO3 → Na+ + HCO3 -

I = ½ Σ × mi × zi2

= ½ ((0,075) × 12 + (0,075) × 12)

= ½ ((0,075) × 1 + (0,075) × 1)

= ½ (0,075 + 0,075)

= ½ (0,15)

= 0,075 m

c.) a.) 0,0250 molal Fe(NO3)2

Fe(NO3)2 → Fe2+ + 2 NO3 -

I = ½ Σ × mi × zi2

= ½ ((0,0250) × 22 + (0,0250) × 12 + (0,0250) × 12)

= ½ ((0,0250) × 4 + (0,0250) × 1 + (0,0250) × 1)

= ½ (0,1 + 0,0250 + 0,0250)

 = ½ (0,15)

= 0,075 m

d.) 0,0250 molal Fe(NO3)3

Fe(NO3)3 → Fe3+ + 3NO3 -

I = ½ Σ × mi × zi2

= ½ ((0,0250) × 32 + (0,0250) × 12 + (0,0250) × 12 + (0,0250) × 12)

= ½ ((0,0250) × 9 + (0,0250) × 1 + (0,0250) × 1 + (0,0250) × 1)

= ½ (0,225 + 0,0250 + 0,0250 + 0,0250)

= ½ (0,3)

= 0,15 m

6. Hitunglah kekuatan ion dari KCl 0,06 M

Jawaban:

Diketahui: KCl 0,06 M

Ditanyakan : I KCl = ...?

Jawab:

KCl → K+ + Cl -

[K+] = [KCl] = 0,06 M

[Cl-] = [KCl] = 0,06 M

I KCl = ½ Σ × mi × zi2

= ½ ([K+] × (+1)2 + [Cl-] × (-1)2)

= ½ (0,06 × 1 + 0,06 × 1)

= ½ (0,06 + 0,06)

= ½ (0,12)
 = 0,06 M

7. Hitung koefisien aktivitas rata-rata dari larutan CaCl2 yang berkonsentrasi 0,005 m dan bersuhu
25◦C

Dik :

CaCl 0,005 m

Suhu 25◦C

Dit: ᵧ ±…?
Jawab:

I = ½ Σ mizi2

= ½ [(0,005) x 22 + (0,005) x 12 + (0.005) x 12]

= ½ [0,03]

= 0,015

Log ᵧ± = -0,509 │z+ z-│(I) ½

Log ᵧ± = -0,509(2) (0,015)

= -0,125

ᵧ± = 0,750