COMPONENTE Columna1 a b c TEMP

1 13.96 2826.26 224.1 150

2 13.9926 3295.12 217.55

Columna1 PSAT xi yi p(Kpa)

PSAT(1) 604.96771131 0 0 152.552197
PSAT(2) 152.55219738 0.2 0.49784349 243.0353
700 p(x,y)
600
0.4 0.72555842 333.518403
0.6 0.85608334 424.001506 500
0.8 0.94069708 514.484609 400
1 1 604.967711 300
200
100
0
0 0.2 0.4 0.6 0.8
p(x1) p(y1)

b)
PSAT
80
PSAT 1 PSAT 2 x1 y1 T(c*)
TSAT 80 13.094511 1 1 70.979125
TSAT 1) 70.979125009 90.993283 15.3199799 0.85472706 0.97218027 75
TSAT 2) 125.31403888 123.530313 22.229973 0.57028463 0.88059299 85
164.519197 31.4973316 0.36462177 0.74984102 95
215.326259 43.6741981 0.21162462 0.56960422 105
354.75583 80 0 0 125.314039
 a)

p(x,y)

0.4 0.6 0.8 1 1.2

p(x1) p(y1)

1
140
120
100
80
60
40
20
0
0 0.2 0.4 0.6 0.8 1 1.2
Columna1 a b c PT T ecuacion a resolver
1 13.8594 2773.78 220.07 120.690188 96.7157846 -220.069759
2 14.0094 3103.01 219.79

componente tsat p1sat p2sat x1 y1

1 85.8782703 120.690188 47.3629037 1 1.40536351
2 116.901807 117.58084 45.997497 1.04343675 1.01655463
138.170454 55.1154731 0.78953379 0.9038866
144.181607 57.8096954 0.72802015 0.86972369
164.052572 66.8099722 0.55408037 0.7531541
205.722908 86.0995028 0.28916318 0.49289418
278.080372 120.690188 0 0
cuacion a resolver
componente Columna1
x1 0.55
y1 0.75
t(c°) x2 0.45
85.8782703 y2 0.25
85
90.5119463
92
96.6
105
116.901807
 a) calcular P y {yi} para T = 353.15 K y x1= 0.26

datos Columna1 CALCULO COEFICIENTES WILSON Columna1

T 353.15 A12 0.1258487312
X1 0.25 A21 0.7292408905
a12 437.98 ϒ1 2.1242565503
a21 1238.00 ϒ2 1.190387904
v1 76.92
v2 18.07 Calculo p sat (Kpa) Columna1
R 1.99 p1 sat 92.592233519
X2 0.75 p2 sat 47.375686734

calculo de Y celda variable

y1 0.53758563

Ecuacion incognita (igualada a x1) 0.2500000468

a partir del calulo de la fraccion y1 calculo P

P= 91.468990037

P y {xi}, para T = 353.15 K y y1 = 0.60

datos Columna1 CALCULO COEFICIENTES WILSON Columna1
T 353.15 A12 0.1258487312
Y1 0.60 A21 0.7292408905
a12 437.98
a21 1238.00
v1 76.92
v2 18.07 Calculo p sat (Kpa) Columna1
R 1.99 p1 sat 92.592233519
Y2 0.40 p2 sat 47.375686734
 T y {yi}, para P = 101.33 kPa y xl = 0.85

datos Columna1
p(kpa) 101.33
x1 0.85
a12 437.98
a21 1238.00
v1 76.92
v2 18.07
R 1.99
x2 0.15

componente a b c
1 16.678 3640.2 53.54
2 16.2887 3816.44 46.13

d) T y {xi}, para P = 101.33 kPa y y1 = 0.40.

datos Columna1
p(kpa) 101.33
y1 0.40
a12 437.98
a21 1238.00
v1 76.92
v2 18.07
R 1.99
y2 0.60

componente a b c
1 16.678 3640.2 53.54
 2 16.2887 3816.44 46.13

e) P AZ, la presión azeotrópica, y x1 AZ = y1 AZ, la composición azeotrópica, para T = 353.15 K.

datos Columna1
T(K) 353.15
a12 437.98
a21 1238
v1 76.92
v2 18.07
R 1.987

componente a b c
1 16.678 3640.2 53.54
2 16.2887 3816.44 46.13

ϒ1 az /ϒ2 az=p2sat/p1sat

Y1 AZ=

LN(ϒ1 az /ϒ2 az)=

Columna1 Columna2 Columna1 calculos resultados
Y1 0.6 P(kpa) inicial (ideal) 67.009871088
Y2 0.4
x1 0.4342256486
p1 sat 92.592233519 x2 0.5657743514
p2 sat 47.375686734
ϒ1 1.4271343138
A12 0.1258487312 ϒ2 1.4561577304
A21 0.7292408905 P(kpa) inicial (ideal) 67.009871088

Lnϒ1 0.3335220261
Lnϒ2 0.3933131848

ϒ1 1.3958757919
ϒ2 1.4818824198

p 96.71321373
x1 0.448968353
x2 0.551031647

parametros inicColumna2 Columna3

t1sat 355.39037007
t2sat 373.15109482

1er aprox T 358.05447878

calculo p1 sat yp2 sat con antoine

P1sat #DIV/0! x1 0.85
p2sat #DIV/0! x2 0.15

A12 #DIV/0!
A21 #DIV/0!

Lnϒ1 #DIV/0!
Lnϒ2 #DIV/0!

ϒ1 #DIV/0!
ϒ2 #DIV/0!

calculo psat
p1sat #DIV/0! y1 #DIV/0!

T #DIV/0!

calculo t inicial
t1sat 355.39037007
t2sat 373.15109482

t inicial 366.04680492

psat iniciales antoine

P1sat 152.87393877
p2sat 78.196392866

calculo psat
p1sat 124.41749993
 T 360.61696355

P1sat 124.41749993
p2sat 63.640662486

A12 0.1274857488
A21 0.756373353

X1 0.063885063
x2 0.936114937

Lnϒ1 1.6291186411
Lnϒ2 0.0203212945

ϒ1 5.0993783551
ϒ2 1.0205291778

calculo p1 y p2 sat (antoine)

p1sat 92.592233519
p2at 47.375686734

calculo de coef A12 A 21 (solo dependen de T)

A12 0.1258487312
A21 0.7292408905

ϒ1 inf 10.416944393
ϒ2 inf 3.286760505

alfa12 x1=0 20.359138077

alfa12 x1=1 0.5946357041

1 az /ϒ2 az=p2sat/p1sat 0.5116594009

Uso funcion buscar objetivo, igualando a LN(ϒ1 az /ϒ2 az)
LN(ϒ1 az /ϒ2 az -0.670096108

x1 AZ 0.7173800677
x2 0.2826199323

1 az /ϒ2 az)= -0.670096233

Lnϒ1 0.0752173797
Lnϒ2 0.0203212945

ϒ1 1.0781184864
ϒ2 1.0205291778

PAZ= 99.825398658
 5) Para el sistema acetona (1) + agua (2). Basándose en la ecuación de Wilson, calcule: a) P. BURBUJA: t = 6O°C, x1 = 0.3
datos Columna1 Columna2
T en c° y k° 60.00 333.15 CALCULO COEColumna1
X1 0.30 A12 0.157159683
a12 291.27 A21 0.4598103693
a21 1448.01 ϒ1 2.1722580684
v1 74.05 ϒ2 1.2541205552
v2 18.07
R 1.99 Calculo p sat (Kpa)Columna1
X2 0.70 p1 sat 115.68157568
p2 sat 19.923719331
COMPONENT A B C
1 14.3916 2795.82 230 calculo de Y celda variable
2 16.262 3799.89 226.35 y1 0.8116802344

Ecuacion incognita (igualada a x1)=0,3 0.2999999568

a partir del calulo de la fraccion y1 calculo P

P= 92.87779552
b) P. ROCÍO: t = 6O°C, y1 = 0.3.

datos Columna1 Columna2

T en c° y k° 60.00 333.15 CALCULO COEColumna1
y1 0.30 A12 0.157159683
a12 291.27 A21 0.4598103693
a21 1448.01
v1 74.05 Calculo p sat (Kpa)Columna1
v2 18.07 p1 sat 115.68157568
R 1.99 p2 sat 19.923719331
y2 0.70
em 1er it supongo solucion ideal ϒi=1
COMPONENT A B C
1 14.3916 2795.82 230 P= 28.263564687
2 16.262 3799.89 226.35
x1 0.0072802935
X2 0.9927197065

lnϒ1 2.309343431
lnϒ2 0.0002945403

ϒ1 10.067812271
ϒ2 1.0002945837
 c) Si existe un azeótropo a t = 6O°C, encuentre Paz y x1 az = y1 a

datos Columna1 Columna2

T en c° y k° 60.00 333.15 p1sat 115.68157568
a12 291.27 p2sat 19.923719331
a21 1448.01
v1 74.05 A12 0.157159683
v2 18.07 A21 0.4598103693
R 1.99
lnϒ1 inf 2.3906825323
lnϒ2 inf 1.6197814322

COMPONENT A B C ϒ1 inf 10.920945298

1 14.3916 2795.82 230 ϒ2 inf 5.0519859942
2 16.262 3799.89 226.35
evaluo si existe azeotropo
alfa12 x1=0 63.409453774
alfa12 x1=1 1.1492953311

no existe azeotropo?¿

datos Columna1 Columna2

T en c° y k° 60.00 333.15 CALCULO COEColumna1
X1 0.30 A12 0.157159683
a12 291.27 A21 0.4598103693
a21 1448.01
v1 74.05
v2 18.07
R 1.99 Calculo p sat (Kpa)Columna1
X2 0.70 p1 sat 115.68157568
p2 sat 19.923719331
COMPONENT A B C
1 14.3916 2795.82 230 calculo de Y celda variable
2 16.262 3799.89 226.35

a partir del calulo de la fraccion y1 calculo P

P. BURBUJA: t = 6O°C, x1 = 0.3

raccion y1 calculo P
 x1 x2 ϒ1 ϒ2 y1 P= Ecuacion incognita (igua
0 1 10.9209453 1 0 #DIV/0! 0
0.2 0.8 2.99002022 1.12855152 0.79363564 87.1660074 0.19999998
0.3 0.7 2.17225807 1.25412056 0.81168023 92.8777955 0.29999996
0.4 0.6 1.72195344 1.42032283 0.82434114 96.658181 0.40000005
0.6 0.4 1.26351746 1.93026978 0.85076774 103.082675 0.60000002
0.8 0.2 1.06232734 2.89352624 0.89503267 109.843321 0.80000006
1 0 1 5.05198599 1 115.681576 #DIV/0!

raccion y1 calculo P
Ecuacion incognita (igualada a x1)
 5) Para el sistema acetona (1) + agua (2). Basándose en la ecuación de NRTL, calcule: a) P. BURBUJA: t = 6O°C, x1 = 0.3
datos Columna1 Columna2 Calculo p sat (Kpa)Columna1
T en c° y k° 60.00 333.15 p1 sat 115.681576
X1 0.30 p2 sat 19.9237193
b12 631.05
b21 1197.41
α 0.53 τ12 0.9532923
R 1.99 τ21 1.808861
X2 0.70
G12 0.6008724
G21 0.38040124

COMPONENT A B C LNϒ1 1.09

1 14.3916 2795.82 230 LNϒ2 0.24998605
2 16.262 3799.89 226.35
ϒ1 2.96153285
ϒ2 1.2840075

y1= 0.8516187
y2 0.1483813

Ecuacion incognita (igualada a x1)=0,3 0.30000002

P burb 120.685978
b) P. ROCÍO: t = 6O°C, y1 = 0.3.

datos Columna1 Columna2 Calculo p sat (Kpa)Columna1

T en c° y k° 60.00 333.15 p1 sat 115.681576
y1= 0.30 p2 sat 19.9237193
b12 631.05
b21 1197.41
α 0.53 τ12 0.9532923
R 1.99 τ21 1.808861
y2 0.70
G12 0.6008724
G21 0.38040124

COMPONENT A B C P 28.4166947
1 14.3916 2795.82 230
2 16.262 3799.89 226.35 X1 0.0016226
X2 0.9983774

LNϒ1 3.82
LNϒ2 1.48411E-05
 ϒ1 45.4170508
ϒ2 1.00001484

c) Si existe un azeótropo a t = 6O°C, encuentre Paz y x1 az = y1 a

datos Columna1 Columna2 Calculo p sat (Kpa)Columna1
T en c° y k° 60.00 333.15 p1 sat 115.681576
b12 631.05 p2 sat 19.9237193
b21 1197.41
α 0.53
R 1.99 τ12 0.9532923
τ21 1.808861

G12 0.6008724
G21 0.38040124

COMPONENT A B C lnϒ1 inf 1.57280704

1 14.3916 2795.82 230 lnϒ2 inf 1.0322769
2 16.262 3799.89 226.35
ϒ1 inf 4.82015958
ϒ2 inf 2.80745085
P. BURBUJA: t = 6O°C, x1 = 0.3
 k Rk Qx νk(1) νk(2)
CH3 1 0.9011 0.848 2 2
CH2 2 0.6744 0.54 1 5
CH2NH 33 1.207 0.936 1 0

r1 3.6836
r2 5.1742

q1 3.172
q2 4.396

eki
k/m i=1
1 0.53467844
2 0.1702396
33 0.29508197

sabiendo que T(k) 308.15

10

11

12
 0.96122719 -0.03954448
0.96122719 -0.03954448
i=1 1.22918598 0.20635214

k=1 0.438469336
k=2 0.458506849
k=3 0.056917731

1.0186514 0.0184796
1.0186514 0.0184796
i=2 0.88975161 -0.11681295

k=1 0.435127482
k=2 0.467414002
k=3 0.085276214
 fraccion Columna2
x1 0.4
x2 0.6

q y r son propiedades moleculares, indp de comp

igual que la de la izquiera pero transpuesta

eki k/m 1 2 33
i=2 i=1 0.53467844 0.1702396 0.29508197
0.38580528 eki i=2 0.38580528 0.61419472 0
0.61419472
0

a _mk

255.7

65.33

τ_m,k
k τ_1,1=τ_1,2=τ_2,2=τ_33,33
m
 m 1 2 33 τ_1,33=τ_2,33
1 1 1 0.43614057 τ_33,1=τ_33,2
2 1 1 0.43614057
33 0.8089589221 0.80895892208 1
i 1
Bik k=1 0.94362722
i k=1 k=2 k=33 Bik k=2 0.94362722
1 0.9436272229 0.94362722291 0.60252532 k=33 0.60252532
2 1 1 0.43614057

k=1 θ1 0.43415933
θk k=2 θ2 0.46999795
k=33 θ3 0.09584272

k=1 s1 0.9816901
Sk k=2 s2 0.9816901
k=3 s3 0.49018239

J1= 0.80463787364
J2= 1.13024141757

L1= 0.81200081917
L2= 1.12533278722

S1= 1.21953571878 0.9816901

S2= 0.98169010353

lnϒ1 c -0.0213448305
lnϒ2 c -0.0076016687
lnϒ1 r 0.1462485

lnϒ2 r 0.0535534

lnϒ1 0.12490367
lnϒ2 0.04595173

ϒ1 1.1330393
ϒ2 1.04702387
1
0.43614057
0.80895892

2
1
1
0.43614057
Columna1 Columna2 Columna3
T= c y k 50 325.15 ϒ1 1.33016965
x1 0.3 ϒ2 1.05476021
x2 0.7

lnϒ1 inf 0.5883420662 A12

lnϒ2 inf 0.5782973389 A21 0,3= 0.29999958

P1 SAT 81.984 y1 0.44383417

P2 SAT 55.525 y2 0.55616583

P BURB= 73.7117387
x1=x2*ϒ2*p2sat*y1/(y2*ϒ1*p1sat)
Columna1 Columna2 Columna3
T 70 343.15
X1 0.252
X2 0.748
r1 2.1055
r2 0.92
q1 1.972
q2 1.4

a) Фi 1 UNICUAC

j1=
j2=

L1
L2

Ѳ1
Ѳ2
τji/sj i

j 1
2
1.72759541
0.75487427

1.27708297
0.90665119

0.32182491
0.67817509
 τji i
τ11 1
τ12 0.37452903 j 1
τ21 1.09197444 2
τ22 1

S1 1.06237477
S2 0.79870786

lnϒ1 c 0.3181972
lnϒ2 c 0.07454072

1 2 i1 0.6209387
0.94128741 1.02786179 i2 1.17988182
0.46891867 1.25202223

lnϒ1 r 0.62818957
lnϒ2 r 0.06282949
lnϒ1 0.94638678 ϒ1 2.57638377
lnϒ2 0.13737021 ϒ2 1.1472528

x1=x2*ϒ2*p2sat*y1/(y2*ϒ1*p1sat)

x1= 0.25200001

y1 0.63760418
y2 0.36239582

P BURB= 73.620415

P 73.6204141

cuando Փ1 0.9955
Փ2 1.0068

P 73.3305823
 1 2
1 0.37452903
1.09197444 1
at*y1/(y2*ϒ1*p1sat) p1sat= 72.3
p2sat= 31.09

con fugacidad=1