Phosphate Ester

Fluids and Lubricants

Supresta: At a Glance
• Leader in phosphorus based flame
retardants, fluids, and lubricants
• Headquartered in Ardsley, New York USA
• ~300 employees worldwide
• Formerly a business unit of Akzo Nobel In addition to providing
Chemicals fire resistance, our flame
retardant plasticizers assist in
• Supresta worldwide includes processing and add malleability.
– Regional sales centers in America,
Europe, and Asia
– Two manufacturing facilities
– Advocacy and government affairs
expertise
– Two research and development
facilities
Supresta: A Global Presence

Amersfoort,
The Netherlands

Bitterfeld, Shanghai,
Germany China

Ardsley, New
York, USA
Gallipolis Ferry,
Deventer,
West Virginia, USA
The Netherlands

Headquarters and
Administrative Office
Regional Sales Center
Research and
Development Facility
Manufacturing Facility
Supresta’s Mission and Vision
• Mission: Phosphorus products for fire safety. We strive toward our mission by supplying
sustainable products for our key markets, including
– Fluids and Lubricants
– Polyurethane foams
– Engineering resins

• Vision: To be Operationally Excellent in sustainable phosphorus products and advocates of

fire safety
Our Products: Built-In Defense against Fire
• More than 80 products with several
more in development
• Product applications
– Flame retardants for rigid and flexible
polyurethane foams
– Flame retardants for engineering
Our flame retardant plasticizers are applied to
resins for electronics and high-end plastic casings for electronic goods.
structural plastics
– Fire resistant hydraulic fluids,
lubricants, cleaners, and anti-wear
additives
– Flame retardant plasticizers that
assist in processing, add malleability,
and provide fire resistance
– Phosphorus organics, inorganics, and
wetting agents Our FyrolflexTM products are commonly used in
electrical connectors and boxes.
Business Brands
Globally recognized brands
Our flame retardant plasticizers are
– FyrolTM flame retardants for rigid and
applied to plastic casings.
flexible foams
– FyrolflexTM flame retardant
engineering resins for electronics and
high-end structural plastics
– FyrquelTM fire resistant hydraulic fluids
– Syn-O-AdTM fire resistant anti-wear
additives
– PhosflexTM flame retardant plasticizers
– VictawetTM flame retardant wetting
agents
Product Families
PCI Chlorine
Chlorine
Phosphorus
Phosphorus PCI33

Intermediate Phosphorous
Raw material Acid
End product Sales
Sales
Application
Oxygen
Oxygen POCl
POCl33

Sales
Sales
Phenol
Phenol
Alcohols
Alcohols
Trialkyl
Trialkyl Triphenyl
Triphenyl
Specialty Phosphates
Phosphates Phosphate
Phosphate Cellulose
Cellulose Flame
Flame
Specialty Retardants
Retardants
Phosphates
Phosphates
Phenol
Phenol // Alcohols
Alcohols Alkylated
Alkylated Phenol
Phenol
Alkyl
Alkyl Diphenyl
Diphenyl POCl Alkylated
Alkylated Triaryl
Triaryl
Phosphates
Phosphates POCl33 Phosphates
Phosphates
Specialty
Specialty Plasticizers
Plasticizers Functional
Functional Fluids
Fluids &&
Plasticizers
Plasticizers
Alkyl
Alkyl Oxides/
Oxides/ Cresylic
Alkylchloride Tricresyl/Trixylenol Cresylic Acid
Acid or
or
Chloroalkyl
Chloroalkyl Oxide
Oxide Alkylchloride Tricresyl/Trixylenol Xylenol
Xylenol
Phosphates
Phosphates Phosphate
Phosphate
Polyurethane
Polyurethane Flame
Flame
Retardants Bisphosphates Functional
Functional Fluids
Fluids
Retardants Bisphosphates

Resorcinol
Resorcinol // BPA
BPA Engineering
Engineering Resins
Resins Phenol
Phenol // Others
Others
Product Families Fluids and Lubricants

PCI Chlorine
Chlorine
Phosphorus
Phosphorus PCI33

Intermediate Phosphorous
Raw material Acid
End product Sales
Sales
Application
Oxygen
Oxygen POCl
POCl33

Sales
Sales
Phenol
Phenol
Alcohols
Alcohols
Trialkyl
Trialkyl Triphenyl
Triphenyl
Specialty Phosphates
Phosphates Phosphate
Phosphate Cellulose
Cellulose Flame
Flame
Specialty Retardants
Retardants
Phosphates
Phosphates
Phenol
Phenol // Alcohols
Alcohols Alkylated
Alkylated Phenol
Phenol
Alkyl
Alkyl Diphenyl
Diphenyl POCl Alkylated
Alkylated Triaryl
Triaryl
Phosphates
Phosphates POCl33 Phosphates
Phosphates
Specialty
Specialty Plasticizers
Plasticizers Functional
Functional Fluids
Fluids &&
Plasticizers
Plasticizers
Alkyl
Alkyl Oxides/
Oxides/ Cresylic
Alkylchloride Tricresyl/Trixylenol Cresylic Acid
Acid or
or
Chloroalkyl
Chloroalkyl Oxide
Oxide Alkylchloride Tricresyl/Trixylenol Xylenol
Xylenol
Phosphates
Phosphates Phosphate
Phosphate
Polyurethane
Polyurethane Flame
Flame
Retardants Bisphosphates Functional
Functional Fluids
Fluids
Retardants Bisphosphates

Resorcinol
Resorcinol // BPA
BPA Engineering
Engineering Resins
Resins Phenol
Phenol // Others
Others
Phosphate Esters: Which Ones Are You Talking About?
• Alkyl Acid Phosphates- These are acids
P2O5 reacted with any alcohol
Applications: metalworking; reacted with neutralizing amines
• POCl3 reactions with (these are not acids)
– Straight chain alcohols (n-butanol)-----
tri-alkyl phosphate (tributyl phosphate)
commercial aviation hydraulic fluid
– Natural based raw materials (xylenols; cresols)
• TCP- (not ToCP) – jet engine lubricant additive
• TXP- ISO 46 hydraulic fluid; lubricant additive
– Synthetic based raw materials (alkylated phenols)
• Butylated phenyl phosphates (ISO 32-100)
» Excellent oxidative stability-tertiary carbon
» Tox profile similar to conventional oils
» FR hydraulic fluids and oil additives
• Propylated phenyl phosphates - oil additives
Fire Resistant Hydraulic Fluids Demonstration
• DVD available; or at watch the demonstration at
www.supresta.com/MASTER2.wmf

FMRC Approved Products

Fire Resistant Hydraulic Fluids Demonstration
 ®
Fyrquel Fluids
• Are difficult to ignite and flame spread is limited in hydraulics and lubricating applications
– Excellent application in critical high pressure applications or high temperature
applications

®
• Wide range of Fyrquel products is available
– Fyrquel products: FR Hydraulic Fluids & Compressor Fluids
ISO 32-ISO 100
– Fyrquel EHC series: FR Electro-Hydraulic Control Fluid
– Fyrquel GT: Gas Turbine Bearing Lubricant ISO 32
– Fyrquel L: Turbine/Hydraulic Fluid
 ®
Syn-O-Ad Lubricant Additives
Additives or basestocks used to promote fire resistance or anti-wear/mild EP properties in
lubricating fluids
– Forms solid boundary lubricant on surfaces following in high temperature lubricant
applications
– Improved film strength without chlorine or sulfur in fill for life applications
®
– Trialkyl Phosphates: Syn-O-Ad 8412 (Tributyl Phosphate)
– Triaryl Phosphates
®
– Syn-O-Ad 8484 (Tricresyl Phosphate)
®
– Syn-O-Ad 8475 (Trixylenyl Phosphate)
®
– Syn-O-Ad 8485, 8478, 8477 (Butylated Triphenyl Phosphates)
®
– Syn-O-Ad 9578 (Propylated Triphenyl Phosphates)
– Next generation triaryl phosphate product
Headquarters and Regional Sales Office Locations
Supresta Headquarters
420 Saw Mill River Road
Ardsley, New York 10502 USA
914.269.5900 fax: 914.674.9736
Americas Sales Office Online at
420 Saw Mill River Road
Ardsley, New York 10502 USA
914.269.5900 fax: 914.674.9735
www. .com
Greater Europe Sales Office
Hoefseweg 1, PO Box 2501
3800 GB Amersfoort, The Netherlands
+31 33 4534580 fax: +31 33 4534578
Greater Asia Pacific Sales Office
Room 606, Pacheer Commercial Center
555 West NanJing Road
Shanghai, 200041 China
+86 21 62560853 fax: + 86 21 62535184