Time : 1 hrs Max.

Marks: 98
Single correct [11 × 3=33]

Q.1

Above compound is hydrated maximum at which position?

(A) 1 (B) 2 (C) 3 (D) equal

NaOH , KOH , 
Q.2 MeCHO    A A  
 B

B is :
(A) Me(CH=CH)3CHO (B) MeCH=CHCHO
(C) Me(CH=CH)2–CHO (D) Me (CH  CH
) 4CHO

Q.3 Zn
Hg A
HCl

Final major product of this reaction is

14 14 14 14
(A) CH3 CH 2 CH3 (B) CH 3 CH2CH3 (C) CH3 CH 2 – CHO (D) CH 3 – CH2– CHO

Q.4 On oxidation of alcohol with HK2Cr2O7, maximum yield of carbonyl compound will be obtained in
(A) 1° alcohol (B) 2° alcohol (C) 3° alcohol (D) equal in 1° & 2° alcohol

3CH ONa
3  H 2SO 4
Q.5 HNO
   mononitration product  

 (B).


Product (B) is

(A) (B) (C) (D)

Q.6 HBF
4 

Product of this reaction is:

Page No.1
 (A) + (B) +

(C) + (D)

O3 conc. NaOH CH COCl

Q.7  (P)    (Q) LiAlH
 4  (R) 3 (S)
Zn ( excess)

Molecular weight changed from (R) to (S)

(A) 43 (B) 42 (C) 86 (D) 84

Q.8 H  Major product is:

2 (1 eq )

Ni

(A) (B) (C) (D)

Q.9 Correct statement about Kolbe's electrolytic synthesis is

(A) pH of reaction mixture increases as reaction goes on
(B) pH of reaction mixture decreases as reaction goes on
(C) pH of reaction mixture remain same as reaction goes on
(D) pH of reaction mixture first increases and then decreases

Assertion Reason
Q.10 Statement-1 : NH2 – NH2 gives Prussian blue colour during Lassaigne test (element detection
test).
Statement-2 : NaCN gives Prussian blue colour of Fe4[Fe(CN6)]3 with FeSO4, FeCl3 .
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

Q.11 Statement -1 : Heat of hydrogenation of 1-butene is more than 2-butene.

Statement -2 : With 6-H 2-butene is more stable than 1-butene with only 2-H.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is false, statement-2 is true.
(D) Statement-1 is true, statement-2 is false.
Comprehension
Paragraph for question nos. 12 to 14
An optical inactive compound (A), which gives (+) iodoform test and gives coloured compound with
braddy's reagent. When it is treated with hydroxyl amine in mild acidic medium. It produces two different
compounds (B) & (C). Each when further heated with conc.H2SO4 produces (D) & (E) respectively.
Further hydrolysis of (D) & (E) both produces mixture of a carboxylic acid and an amine. Acid produce
by hydrolysis of (D) is most acidic among its isomers and the amine produce by hydrolysis of (E) is least
basic among its positional isomers. [3 × 3 =9]
Q.12 Identify (A) among the following.
O OH
C–CH OH O
3 CH–CH 3
CH–CH3 C–CH3
(A) (B) CH3 (C) CH3 (D)

CH3 CH3
Q.13 Select incorrect statement.
(A) Acid produced by hydrolysis of D will give effervescence of CO2 with NaHCO3 faster than the acid
produced by hydrolysis of E
(B) Base produced by hydrolysis of D will be more basic than the base produced by hydrolysis of E
(C) Reaction involves formation B & C can also be carried out with NH2NH2.
(D) Reaction involves formation D & E can also be carried out with PCl5.

Q.14 Compound D & E are related with each other as

(A) Positional isomers (B) Functional isomers (C) Metamers (D) Geometrical isomers

More than one may be correct [5 × 4 = 20]


H 3O
Q.15   (A) + (B) formed cannot be differentiated by
(A) Iodoform (B) Fehling (C) NaHSO3 (D) 2,4-DNP

Q.16 Which of the following will produce chiral molecule(s) after reaction is completed.

CHO CHO
O
COOH
(A) 

 (B) conc
 . NaOH




CHO
CHO
O
HCN
(C) CH3CHO  (D) dil
.KOH


Q.17 Which of following reaction product is Diastereomer.

Br
(
i ) NaCN
(A) 2
 (B) 
CCl 4 (ii ) H 

(C) HBr
 (D) CH 3  CH  CH  CH  Ph HCl

CCl4 peroxide
|
Et
Q.18 Select correct statement :
(A) Methane cannot be prepared by catalytic hydrogenation of alkene
(B) All isomers of the formula C6H14 can be prepared by catalytic hydrogenation of alkene
(C) All isomers of the formula C5H12 can be prepared by catalytic hydrogenation of alkene
D
(D) H
2
product obtained show no optical rotation
Ni
D

O
N2
(i)  (i) SOCl2
(A) (B)
Q.19 (ii) HOH (ii) NH2–NH2
(iii) NaNO2/HCl,

Which is / are correct statement(s) about the product (A), (B) and involved reactions ?
(A) Product (B) gives iso cyanide test.
(B) Product (A) is a carboxylic acid containing six carbon atoms.
(C) Rearrangement is the RDS during formation of (A) and during formation of (B) from (A).
(D) Arndt Eistert, Curtius, Diazotisation reactions are involved in above interconversion.

Match the column

Q.20 Column I Column II [12]
(Reagent) (Used for separating binary mixture containing)

(A) NaHCO3 solution (P) 1-pentyne and 2-pentyne

(B) NaHSO3 (Q) Water insoluble amides and water insoluble amines.

(C) dil. HCl (R) CH3CH2OH and CH3CHO

(D) Tollen's reagent (S) Ethanoic acid and phenol

(T) Ethanal and acetone

Q.21 Column I Column II [12]

(A) Nitrating
  (P) p-substitution
mixture

Cl
(B) 2
 (Q) m-substitution
FeCl 3

(C) dil
. HCl

 (R) ipso-substitution

(D) H S O (S) substitution at faster rate than benzene

2 
2 7


Q.22 Match the column.

Column I Column II [12]

Cl

(A) (P) Group attached to benzene ring is a +M group here.

O
NH–C–Me
(B) (Q) Group attached to benzene ring is a –M group here.

(C) N (R) Electrophile would attack on ortho or para

position.

(S) Rate of electrophilic substitution is less than that

of benzene.
 Answers
1. B 2. A 3. B 4. B

5. C 6. D 7. D 8. C

9. A 10. D 11. A 12. C

13. C 14. C 15. B, C, D 16. B, C, D

17. A, B, D 18. A, B, D 19. A, C

20. A) S, (B) R, (C) Q, (D) P 21. (A) P, S (B) P (C) R (D) P

22. (A) P,R,S (B) P,R (C) Q,S

23. 0 24. 1