Total No. of Questions : 06] [Total No.

of Printed Page : 03
EXAMINATION – JUNE 2019
MASTER OF SCIENCE (M.Sc. Chemistry)
Final Year - Semester-IV 4M.Sc. 2
Photo Chemistry & Solid State Chemistry

Time : 3 Hours Max Marks : 70

Min. Marks : 25
Note : Question No.1 is compulsory. Question No.2 to6 carries equal marks

Q.1. Choose the correct answer- 10

(A) Dimerisation of cyclopentadiene yields a stable compound represented
by –
(i) (ii)

(iii) (iv)

(B) Photochemical cyclisation of 1-6 Diene to give:

(i) (ii)

(iii) (iv)

1
 (C) Oxetones can be prepared by photochemical reaction between- OR
(i) Carbonyl compounds and olefins
(a) Write photochemistry of aromatic compounds. 6
(ii) Carbonyl compounds and alkanes
(iii) Alcohols and olefins
(b) Explain photochemistry of vision. 6
(iv) Alcohols and alkanes
Q.4. (a) Describe kinetics of solid state reaction. 6
(D) Irradiation of benzene in liquid phase at 166nm-200nm gives- (b) Write factor affecting the reactivity of solid state reaction. 6
(i) Benzvalene (ii) Dewar benzene
OR
(iii) Fulvene (iv) All of these
(a) Discuss on types of solid state reaction. 6
(E) Product P is - (b) Explain phase transition reaction. 6

Q.5. (a) What is band theory? Write band structure of metals. Insulator
(i) (ii) and semiconductors. 6
(b) Explain about p-n junction. 6
OR
(iii) (iv)
(a) Write free electron theory and its application. 6
(b) Describe the photoconduction and photoelectric effect. 6
Q.2. (a) Write following Photochemical reaction- 6
(i) Gas phase photolysis Q.6. Write about purification and crystal growth. 12
(ii) Photo oxidation OR
(iii) Photo substitution
(iv) Photo addition Write preparation of organic semiconductors for device application.
(b) Write the effect of light intensity on the rate of photochemical reaction.

OR 6
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(a) Write geometrical isomerism and cyclisation reaction of alkenes. 6
(b) Rearrangement of 1,4-diene. Explain this. 6

Q.3. (a) What are − − cleavage? Explain. 6

(b) Write these reactions- 6
(i) Dimerisation
(ii) Oxitone formation
2 3