Curva Potenciométrica 1ª derivada

V(titulante) em ml pH Vmédio titulante ΔpH/ΔVtitulante

0 3.95
0.5 4.05 0.25 0.2
1 4.13 0.75 0.16
1.5 4.2 1.25 0.14
2 4.28 1.75 0.16
2.5 4.33 2.25 0.1
3 4.39 2.75 0.12
3.5 4.5 3.25 0.22
4 4.55 3.75 0.1
4.5 4.62 4.25 0.14
5 4.71 4.75 0.18
5.5 4.79 5.25 0.16
6 4.87 5.75 0.16
6.5 5 6.25 0.26
7 5.12 6.75 0.24
7.5 5.25 7.25 0.26
8 5.43 7.75 0.36
8.5 5.68 8.25 0.5
9 6.33 8.75 1.3
9.5 9.3 9.25 5.94
10 10.87 9.75 3.14
10.5 11.24 10.25 0.74
11 11.43 10.75 0.38
11.5 11.57 11.25 0.28
12 11.65 11.75 0.16
12.5 11.73 12.25 0.16
13 11.8 12.75 0.14
13.5 11.85 13.25 0.1
14 11.91 13.75 0.12
14.5 11.96 14.25 0.1
15 11.97 14.75 0.02

Curva Potenciométrica 7
14
6
12

10 5

8
4
6
3
4

2 2

0 1
0 2 4 6 8 10 12 14 16

0
0 0.5 1 1.5 2 2.5 3 3.5 4 4
 3
4

2 2

0 1
0 2 4 6 8 10 12 14 16

0
0 0.5 1 1.5 2 2.5 3 3.5 4 4

reta 2 derivada

12
10
8 f(x) = − 53.9285714285715 x + 494.857142857143

6
4
2
0
8.95 9 9.05 9.1 9.15 9.2 9.25 9.3
-2
-4
-6
-8
 2ª derivada
ΔpH Vmédio-médio ∆(∆pH/∆V)/∆V (∆pH/∆V) ∆(∆pH/∆V) mcomprimido=
mAAS=
0.1 0.2
0.08 0.5 -0.08 0.16 -0.04
0.07 1 -0.04 0.14 -0.02
0.08 1.5 0.04 0.16 0.02
0.05 2 -0.12 0.1 -0.06
0.06 2.5 0.04 0.12 0.02
0.11 3 0.2 0.22 0.1
0.05 3.5 -0.24 0.1 -0.12
0.07 4 0.08 0.14 0.04
0.09 4.5 0.08 0.18 0.04
0.08 5 -0.04 0.16 -0.02
0.08 5.5 0 0.16 0
0.13 6 0.2 0.26 0.1
0.12 6.5 -0.04 0.24 -0.02
0.13 7 0.04 0.26 0.02
0.18 7.5 0.2 0.36 0.1
0.25 8 0.28 0.5 0.14
0.65 8.5 1.6 1.3 0.8
2.97 9 9.28 5.94 4.64
1.57 9.5 -5.6 3.14 -2.8
0.37 10 -4.8 0.74 -2.4
0.19 10.5 -0.72 0.38 -0.36
0.14 11 -0.2 0.28 -0.1
0.08 11.5 -0.24 0.16 -0.12
0.08 12 0 0.16 0
0.07 12.5 -0.04 0.14 -0.02
0.05 13 -0.08 0.1 -0.04
0.06 13.5 0.04 0.12 0.02
0.05 14 -0.04 0.1 -0.02
0.01 14.5 -0.16 0.02 -0.08

1a derivada
7

12
6
10

5 8
6
4 4
2
3 0
0 2 4
-2
2
-4
-6
1
-8

0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 12 12.5 13 13.5 14 14.5 15 15.5
3 0
0 2 4
-2
2
-4
-6
1
-8

0
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 12 12.5 13 13.5 14 14.5 15 15.5

n(NaOH)=n(AAS)
C(NaOH)xVe3=C(AAS)xV(AAS)
0,05x9,18x10^-3=n(AAS)
0.000459 n(AAS)
Ve1=9,50
Ve2=9,25 n(AAS) = m(AAS)/M(AAS)
Ve3=9,18 m(AAS) = 0.0827

0.0827 ************** 0.1008

x ************** 0.5848

x=0,480 g
 0,5848 g
0,480 g

2a derivada
12
10
8
6
4
2
0
0 2 4 6 8 10 12 14 16
-2
-4
-6
-8
0
0 2 4 6 8 10 12 14 16
-2
-4
-6
-8

9 9.28
9.5 -5.6
 TABELA1: Variação do E(mV) com adição de KCl
Vadicionado (μL) Vtotal(mL) [K+](mol/L) E (mv) log C Vadicionado (mL)
Solução de KCl 0,001 mol/L
0 50 0 65.2 Err:502 0
10 50.01 2E-07 62.7 -6.69905685455 0.01
10 50.02 3.998E-07 61.6 -6.39811369173 0.01
20 50.04 7.994E-07 60.5 -6.09725730969 0.02
20 50.06 1.199E-06 60.3 -5.92133959489 0.02
20 50.08 1.597E-06 60.2 -5.79657433321 0.02
20 50.1 1.996E-06 59.7 -5.69983772587 0.02
100 50.2 3.984E-06 61.4 -5.39967372148 0.1
100 50.3 5.964E-06 62.5 -5.22444673034 0.1
100 50.4 7.937E-06 63.5 -5.10037054512 0.1
100 50.5 9.901E-06 63.7 -5.00432137378 0.1
200 50.7 1.381E-05 65 -4.85990991932 0.2
300 51 1.961E-05 68.1 -4.7075701761 0.3
1000 52 3.846E-05 74.6 -4.41497334797 1
1000 53 5.66E-05 87.6 -4.24715461488 1
1000 54 7.407E-05 91.2 -4.1303337685 1
1000 55 9.091E-05 99.4 -4.04139268516 1
Solução de KCl 0,10 mol/L
500 55.5 0.000991 150.5 -3.00393029363 0.5
500 56 0.001875 166.5 -2.72699872794 0.5
1000 57 0.0035965 182.5 -2.44412099462 1
1000 58 0.0052586 192 -2.27912815422 1
1000 59 0.0068644 199.6 -2.16339698843 1
1000 60 0.0084167 204.5 -2.07485987226 1
 250

200

150
E (mV)

100

50

0
-7 -6 -5 -4 -3 -2 -1
log (C) (mol/L)

250

200
f(x) = 58.1037502950002 x + 324.880929378661
R² = 0.999729603055392
150
Axis Title

100

50

0
-3.2 -3 -2.8 -2.6 -2.4 -2.2 -2
Axis Title

y= m + b

250
LPD
200
f(x) = 58.1037502950002 x + 324.880929378661
R² = 0.999729603055392

150

100

f(x) = 2.40340939806648 x + 74.4417174131609 50

R² = 0.59616294974821

0
-6.4 -6 -5.6 -5.2 -4.8 -4.4 -4 -3.6 -3.2 -2.8 -2.4 -2 -1.6

x interceção -4.4961
LPD 3.1908031E-05 mol/L
LIRL 9.0909091E-05 mol/L
S 58.104
E(vinho) 179.8 mV
log [K+] vinho -2.496902107
[K+] vinho c/dil 0.0031849153 mol/L
[K+] vinho s/dil 0.0191094921 mol/L
m [K+] 747.18114019 mg/L
747.2 mg/L