Académique Documents
Professionnel Documents
Culture Documents
CBSE
Chemistry
TOPPER PreBoad Exam 2011
General Instructions:
2. Question nos. 1 to 8 are very short answer questions and carry 1 mark each.
3. Question nos. 9 to 18 are short answer questions and carry 2 marks each.
4. Question nos. 19 to 27 are also short answer questions and carry 3 marks each.
5. Question nos. 28 to 30 are long answer questions and carry 5 marks each.
Q 5. Name the reagent you will use for the reaction of oxidation of primary alcohol
to an aldehyde
Q 7. Give one chemical test to distinguish between ethylamine and aniline. Write
the chemical reaction also.
Q 8. Why vitamin C cannot be stored in our body?
a) ZnS b) AgBr
Q 10. Concentrated nitric acid used in laboratory work is 68% nitric acid by mass in
aqueous solution. What should be the molarity of such a sample of the acid if the
density of the solution is 1.504 g mL−1 ?
OR
Q 10. A solution is obtained by mixing 300 g of 25% solution and 400 g of 40%
solution by mass. Calculate the mass percentage of the resulting solution.
Q 12. A reaction is second order with respect to a reactant. How is the rate of
reaction affected if the concentration of the reactant is doubled?
Q 17. Convert:
(b)
(c)
NaBH4
CH3 − CH2 − CH − CHO →
l
CH3
Q 20. Arrange the following in the order of the property indicated and give reasons:
Q 21. What happens when D-glucose is treated with the following reagents? Name
the products and write the reactions involved.
Q 22. (a) Give two points to distinguish between the terms homopolymer and
copolymer.
(c) What happens when sulphur dioxide is passed through an aqueous solution of
Fe(III) salt?
Q 25. (a) How is nitrogen prepared in the laboratory? Write the chemical equations
of the reactions involved.
OR
Q 27. For a first order reaction, show that time required for 99% completion is
twice the time required for the completion of 90% of reaction.
Calculate the standard Gibbs energy and the equilibrium constant of the cell
reaction. Given: F = 96487 C mol-1, R = 8.314 J K-1 mol-1
(b)If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how
many electrons would flow through the wire?
OR
Q 28. (a) The molar conductivity of 0.025 mol L−1 methanoic acid is
(b)The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 Scm−1. Calculate its
molar conductivity.
Q 29. (a) Which is a stronger reducing agent Cr2+ or Fe2+ and why?
(b) What are interstitial compounds? Why are such compounds well known for
transition metals?
(c) Describe the oxidising action of potassium dichromate and write the ionic
equations for its reaction with H2S.
OR
(a) Transition metals and many of their compounds show paramagnetic behaviour.
(d) Transition metals and their many compounds act as good catalyst.
(b)An organic compound with the molecular formula C9H10O forms 2, 4-DNP
derivative, reduces Tollens’ reagent and undergoes Cannizzaro reaction. On
vigorous oxidation, it gives 1, 2-benzenedicarboxylic acid. Identify the compound.
Give the structure and IUPAC name of the compound.
OR
(i)
(ii)
(b) Which acid of each pair shown here would you expect to be stronger?
(ii)