The volume of NaOH solution titrated at various reaction temperatures.

Volume of NaOH titrated (mL)

Time (min) T=30ᵒC T=40ᵒC T=50ᵒC
5 2.1 3.3 4.2
10 8.8 10 11.2
15 11.6 13.9 14.8
20 12.3 14.2 15.9
25 12.7 15 16.3
30 12.9 16.1 17.2

T=30'C
Time (min) Vol of NaOH (mL) V1 (L) V2 (L)
5 2.1 0.0021 0.00084
10 8.8 0.0088 0.00352
15 11.6 0.0116 0.00464
20 12.3 0.0123 0.00492
25 12.7 0.0127 0.00508
30 12.9 0.0129 0.00516

T=40'C
Time (min) Vol of NaOH (mL) V1 (L) V2 (L)
5 3.3 0.0033 0.00132
10 10 0.0100 0.004
15 13.9 0.0139 0.00556
20 14.2 0.0142 0.00568
25 15 0.0150 0.006
30 16.1 0.0161 0.00644

T=50'C
Time (min) Vol of NaOH (mL) V1 V2 (L)
5 4.2 0.0042 0.00168
10 11.2 0.0112 0.00448
15 14.8 0.0148 0.00592
20 15.9 0.0159 0.00636
25 16.3 0.0163 0.00652
30 17.2 0.0172 0.00688
T (K) 1/T K -rA
4.580334E-06
313 0.003194888178914 0.4206
7.953876E-06
323 0.003095975232198 0.4509

Ca rA
0.1184 4.580334E-06
0.1166 7.953876E-06

rA vs CNaOH
9E-06
8E-06
f(x) = − 0.00187419 x + 0.00022648443
7E-06
6E-06
5E-06
rA

4E-06
3E-06
2E-06
1E-06
0
0.1165 0.1170 0.1175
CNaOH
 CNaO
0.0140

0.0120
f(x) = − 0.00037942857142
0.0100

CNaOH (mol/L)
0.0080

0.0060

0.0040

0.0020

0.0000
5 10

V3 (L) n1 (mol) Ca (mol/L) 1/Ca

0.02416 0.000604 0.0121 82.7815
0.02148 0.000537 0.0107 93.1099
0.02036 0.000509 0.0102 98.2318
0.02008 0.000502 0.0100 99.6016
0.01992 0.000498 0.0100 100.4016
0.01984 0.000496 0.0099 100.8065

0.1400

0.1200
V3 (L) n1 (mol) Ca (mol/L) 1/Ca
0.1000 f(x) = − 0.
0.02368 0.00592 0.1184 8.4459

CNaOH (mol/L)
12.0000
0.021 0.00525 0.1050 9.5238 0.0800
0.01944 0.00486 0.0972 10.2881 10.0000 f(x) =
0.0600
0.01932 0.00483 0.0966 10.3520 8.0000
0.0400
0.019 0.00475 0.0950 10.5263 1/CNaOH
0.0200
6.0000
0.01856 0.00464 0.0928 10.7759
0.0000
4.0000
5
2.0000

0.0000
5

V3 (L) n1 (mol) Ca (mol/L) 1/Ca

0.02332 0.00583 0.1166 8.5763
0.02052 0.00513 0.1026 9.7466 0.14
0.01908 0.00477 0.0954 10.4822 0.12
0.01864 0.00466 0.0932 10.7296 f(x) = − 0.00
0.1
CNaOH (mol/L)

0.01848 0.00462 0.0924 10.8225

0.08
0.01812 0.00453 0.0906 11.0375
0.06

0.04

rA vs T 0.02

9E-06 0
5
8E-06
f(x) = 3.373542E-07 x − 0.0001010115306
7E-06 R² = 1
6E-06
 CNaOH (
0.06

0.04

rA vs T 0.02
lnK
9E-06 0
-0.866073015713538 5
8E-06
f(x) = 3.373542E-07 x − 0.0001010115306
7E-06 R² = 1
-0.796509693555099
6E-06
5E-06

rA
4E-06
3E-06
2E-06
1E-06
0
312 314 316 318 320 322 324
T (K)

lnK vs 1/T
-0.76
0.00308 0.0031 0.00312 0.00314 0.00316 0.00318 0.0032
rA vs CNaOH -0.78

-0.8 f(x) = − 703.278230689601 x + 1.38082229000404

187419 x + 0.00022648443
lnK

-0.82

-0.84

-0.86

-0.88
1/T
.1170 0.1175 0.1180 0.1185
CNaOH
 CNaOH vs Time
0.0140

0.0120
f(x) = − 0.000379428571429 x + 0.011814666666667
0.0100

0.0080

0.0060

0.0040 1/CNaOH vs Time

0.0020 120.0000
0.0000
5 10 100.0000 15 20
f(x) = 3.23914143281083 25 30
x + 84.485139214481

80.0000 Time (min)

1/CNaOH

60.0000

40.0000

20.0000

0.0000
5 10 15 20 25 30
Time

CNaOH vs Time
0.1400

0.1200
1/CNaOH vs Time
0.1000 f(x) = − 0.004531428571429 x + 0.116693333333333
CNaOH (mol/L)

12.0000
0.0800
10.0000 f(x) = 0.420600012633568 x + 8.51322763003619
0.0600
8.0000
0.0400
1/CNaOH

0.0200
6.0000

0.0000
4.0000
5 10 15 20 25 30
2.0000 Time (min)

0.0000
5 10 15 20 25 30
Time
CNaOH vs Time
0.14

0.12

0.1 1/CNaOH
f(x) = − 0.004651428571429 vs Time
x + 0.114746666666667
CNaOH (mol/L)

12.0000
0.08
f(x) = 0.450891175426543 x + 8.65433929746374
0.06 10.0000

0.04 8.0000
1/CNaOH

0.02 6.0000
0
5 4.0000 10 15 20 25 30
5306 Time (min)
2.0000
 f(x) = 0.450891175426543 x + 8.65433929746374

CNaOH (
0.06 10.0000

0.04 8.0000

1/CNaOH
0.02 6.0000
0
5 4.0000 10 15 20 25 30
5306 Time (min)
2.0000

0.0000
5 10 15 20 25 30
-rA
Linear (-rA) Time

322 324

s 1/T
314 0.00316 0.00318 0.0032 0.00322

601 x + 1.38082229000404

1/T