UNIFIED COUNCIL

A n I S O 9 0 0 1 : 2000 C e r t i f i e d O r g a n i s a t i o n

NATIONAL LEVEL SCIENCE TALENT SEARCH EXAMINATION - 2011

SOLUTIONS FOR CLASS : 11-PCM

Mathematics ⇒ a 4 − b4 = −4acb 2
1. (D) P = {1, 2} or {1, 2, 3} or {1, 2, 4} or {1, 2, 5} ⇒ a 4 = b 2 ( b 2 − 4ac ) = b2 ∆
or {1,2,3,4} or (1,2,3,5} or {1,2,4,5} or
{1,2,3,4,5} 7. (A) Using AM > GM, we have
2. (D) Since A is not the union of A1, A2 and A3 (s − b ) + (s − c ) + (s − d )
> {(s − b )(s − c )(s − d )}
1/3
the sets A1, A2, A3 do not form a partition
3
of A.
⇒ 3s − (b + c + d ) > 3 {(s − b )(s − c )(s − d )}
1/3
3. (C) The given relation can be written as
sin x (1 + sin 2 x ) = 1 − sin 2 x = cos2 x
a > 3 {(s − b )(s − c )(s − d )}
1/3
, similarly we have
( 2
sin x 2 − cos x = cos x) 2

b > 3{(s − c )(s − d )(s − a )}

1/3
and
squaring on both sides
c > 3{(s − a )(s − b )(s − d )}
1/ 3
sin 2 x ( 2 − cos 2 x ) = cos 4 x and
2

d > 3 {(s − a )(s − b )(s − c )}

1/3

(1 − cos x )(4 − 4 cos

2 2
x + cos 4 x ) = cos 4 x , multiplying we get
abcd > 81 (s − a )(s − b )(s − c )(s − d )
cos6 x − 4 cos 4 x + 8 cos 2 x = 4
4. (D) Range = greatest no - smallest no 8. (D) We have,
21 = 25 – b 31! 1 1
E= = =
b = 25 – 21 = 4 231 (32! ) 231 (32 ) 2 36
5. (C) We have, for Z ∈ C
= 2−36 = (23 )
− 12
|2i| = |Z + (2i –Z) | ≤ |Z| + |2i – Z| = 8 −12
2 ≤ |Z| + |Z – 2i| Thus, x = – 12
Thus maximum value of |Z| + |Z – 2i| is .. 5
2 and it is attained for any Z lying on the 55
5.

segment joining Z = 0 and Z = 2i. 9. (C) Note that 5 (23 times 5) is an odd
number which is natural.
b c
6. (B) cosec θ + cot θ = −
a
, cosec θ cot θ =
a ∴ x = 52m +1 = (25m )5
As cosec2 θ – cot2 θ = 1, we get Where m is a natural number. Thus
x = (24 + 1)m 5 = 5 + a multiple of 24. Hence
a the desired number is 5.
cosect θ –cot θ = − .
b
10. (A) 5
C1 + 5 C 2 + 5 C3 = 25
1b a 11. (C) Let O be the centre of the circle of unit
∴ cos ecθ = −  + 
2a b  radius and the coordinates of A0 be (1, 0)
1 a b  coordinates of A1 are
and c o t θ = −

2 b

a  (cos60 , sin 60 ) = (1 / 2,
0 0
3/2 )
1  a2 b2  c A3 are (–1, 0)
Thus, − 4  b 2 − a 2  = a
  A 4 are ( −1 / 2, − 3/2 ) and A 5 are

(1 / 2, − 3 / 2)
website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions
 A0A1 = 1 17. (A) Let the edges be
A0A2 = 3 =A0A4 a
, a, ar where r > 1
r
so that ( A 0 A 1 )( A 0 A 2 )( A 0 A 4 ) = 3
a
12. (D) A 1B1 = 4 + 4 = 2 2 .a.ar = 216, i.e., a3 = 216, i.e., a = 6 and
r

AB = 2 2 − 2 = 2 ( 2 −1 ) a a 
2  .a + a.ar + .ar  = 252;
 r r 
Thus equation of required circle is
1 7 1
( ) ∴ + r + 1 = ⇒ r = ,2
2
x2 + y2 = 2 −1 =3−2 2 r 2 2
∴ a = 6, r = 2, so the longest side = ar = 12
3tan α − tan 3 α 18. (B) Total number of coins = 2 + 2 + 3 + 1 = 8
tan 3α cot α =
13. (B) tan α (1 − 3tan 2 α ) 2 coins are of 10 paise, 2 are of 20 paise,
3 are of 25 paise and 1 is of 50 paise
3 − tan 2 α
= =x ∴ required number of ways
1 − 3 tan 2 α
8!
x − 3 (3x − 1 )( x − 3 ) = = 8 × 7 × 6 × 5 = 1680
tan α = 2
= 2!× 2!× 3!× 1!
(3x − 1 )
2
3x − 1
19. (C) Let the equation of the ellipse be
since tan α is non negative, either
2
x2 y 2
+ = 1 . As it passes through (4, –1)
x < 1 / 3 or x ≥ 3 so x cannot lie between a 2 b2
1/3 and 3. 16 1
14. (A) Let A(5,2,4), B(6,–1,2), C(8,–7,k) be the + = 1 (or) a2 + 16b2 = a2b2
a2 b2
given points
since x +4y – 10 = 0 touches the ellipse
Direction ratios of AB are
2 2
6 – 5, –1 –2, 2 – 4 (i.e.) 1, –3, –2  10  21
  = a   + b ⇒ a + 16b = 100
2 2 2

Direction ratios of BC are  4 4

 
8–6, –7 + 1, k –2 (i.e.) 2, –6, k–2 a2b2 = 100 and the required equation can
Since A, B, C are collinear
x2 y 2
be + =1
2 −6 k − 2 20 5
= =
1 −3 −2
t7 = n C6 ( 21 / 3 ) (3 )
n−6 −1 / 3 6
k – 2 = –4 ⇒ k = 2 – 4 = –2 20. (D)
15. (D) Since the numerator tends to 0 as x → 0
and t n − 5 = n C n − 6 ( 21 / 3 ) (3−1 / 3 )
6 n −6
so
1 lim  α e x − e x − 1 
α
1 αx Given t7 : t n − 5 = 1 : 6
lim
x →0
x2
( e − e x
− x ) 2 x → 0 
=
x


( 2 ) (3 )
1 / 3 n −6 6
−1 / 3
for the last limit to exist we must have 1
⇒ =
lim
x →0 (α eαx − e x − 1 ) = 0 ( 2 ) (3 )
1/3
6
−1 / 3
n −6
6

∴ α – 1 – 1 = 0 ⇒ α =2. For α = 2 , the

⇒ ( 21 / 3.31 / 3 )
n −12
= 1 / 6 = 6 −1
1 lim  2e 2x
− e −1 
x

last limit is equal to 2 x →0  x

 =n=9
 
1
1 lim 3
x →0 ( 4e − ex ) =
2x 21. (B) Replacing x by in the given equation
= x
2 2 we get,
−2 (sin a + sin b ) 2 (cos a + cos b )
1 1 1 − x2
16. (B) 2sin (a − b )
×
2cos (a − b )
= −1 2f  2  + 3f (x 2 ) = 2 − 1 =
x  x x2
2 (sin a + sin b )(cos a + cos b ) solving the given functional equation and
the last equation
= 2sin (a − b ) cos (a − b ) we have

sin 2a + sin 2b = sin 2 (a − b ) − 2sin (a + b ) 3 (1 − x 2 )

9f ( x 2 ) − 4f ( x 2 ) = − 2 (x 2 − 1 )
x2

website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions
 28. (A) Here, 8! = 27. 32.51.71
(1 − x )(3 + 2x )
2 2

= (1 − x 2
) ((3 / x ) + 2 )
2
=
x2
obviously, the factors are not multiple of
either 2 or 3. So the factors may be 1, 5, 7,
35 of which 5 and 35 are of the form
(1 − x )(3 + 2x )
2 2

( )
f x2 =
5x 2
3m + 2.
So, the sum = 40
22. (D) 29. (C) We have,
23. (B) Since, (2 cos x – 1) (3 + 2 cos x) = 0 a r = a 2n −r for 0 ≤ r ≤ 2n
3
since cos x ≠ − n −1 n −1
2 ⇒ ∑ a r = ∑ a 2n −r
r =0 r =0
1
therefore, cos x = ⇒ a 0 + a1 + ..........a n −1 = a 2n + a 2n −1 + .....a n +1
2
π  2n n
x = 2nπ ± ,n ∈ I ⇒ ( 0+ 1+ n −1 ) + n = ∴ ∑ a r = 3 
n
2 a a ......a a 3
3  r =0 
and given 0 ≤ x ≤ 2 π
1 n
π 5π
⇒ a 0 + a 1 + ..... + a n −1 =
2
(3 − a n )
∴x = , ( for n = 0, 1)
3 3
lim xf (x ) − 2f (x )
7 5 1 1 30. (C) x→2
x − , x − 3, x − , x − 2, x − ,x + , x−2
24. (D)
2 2 2 2
xf (2 ) − 2f ' ( x )
x + 4, x + 5 =
lim
x →2
1
1  1  5 (using L-hospitals rule)
Median = ( x − 2) +  x −   = x −
2  2  4 = f(2) – 2 f ' (2)
25. (A) = 4 – 2× 4
26. (B) P ( A ∪ B ) = 0.6 =–4
31. (D) We have α =1200 and β = 60 0
P ( A ∩ B ) = 0.2
1
∴ cos α = cos1200 = −
( ) ( )
P A + P B = 1 − P ( A ) + 1 − P [B] 2
1
= 2 −  P ( A ) + P (B ) and cos β = cos 60 =
0

2
= 2 − P ( A ∪ B ) + P ( A ∩ B ) But cos 2 α + cos 2 β + cos 2 γ = 1
= 2 – 0.6 – 0.2 2 2
 1 1
 −  +   + cos γ = 1
2
= 1.2
 2 2
27. (C) Let first term = a, common ratio = r,
where –1 < r < 1 1 1 1
cos 2 γ = 1 − − =
4 4 2
a a3
Then, = 2 and = 24 1
1− r 1 − r3 cos γ = ±
2
1 − r3 1
∴ = ∴ γ = 45 0 or 1350
( − ) 3
3
1 r
32. (A) Let the middle point of the chord is (h, k)
i.e., 1 - 2r + r2 = 3(1 + r + r2)
∴ T = S1
or 2r2 + 5r + 2 = 0
3xh – 2yk + 2(x + h) –– 2k2 + 4h – 6k
1 3h + 2
∴ r = –2 or − slope of this chord = = 2(given)
2 2k + 3
As –1 < r < 1
or 3h + 2 = 4k + 6
1 ⇒ 3h – 4k = 4
∴ we have r = −
2 Hence, locus of middle point is
Putting this value of r, we get a = 3 3x – 4y = 4
3 3 3 33. (B) Clearly a ≠ 0
∴ The series is 3 − + − ...
2 4 8 cot α + tan α = m ⇒ 1 + tan 2 α = m tan α
website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions
 ⇒ sec 2 2 = m tan α .......(1) (a + b + c )
2
(2S )
2
S2
∴A ≤ = =
1 4×3 3 4×3 3 3 3
and − cos α = n ⇒ sec 2 α − 1 = n sec α
cos α
S2
∴A ≤
⇒ tan α = nsec α ⇒ tan α = n sec α
2 4 2 2
3 3
⇒ tan4 α = n 2m tan α [by (1)] λZ2 + Z3
38. (D) As, Z1 =
⇒ tan 3 α = n 2 m ⇒ tan α = ( n 2 m ) λ +1
1/3

Which show Z1, divides Z2, Z3 in the ratio

sec 2 α = m ( n 2 m ) of 1 : λ
1/3
[by (1)]
Thus the points are collinear
Now sec α − tan α = 1
2 2
∴ Distance of A from line BC is zero.

( ) ( ) We have, ( A ∪ B ) ∩ B' = A − ( A ∩ B' )

1 /3 2/3
⇒ m n2m − n2 m =1 39. (B)
since A and B are disjoint
⇒ m ( mn 2 ) − n ( nm 2 )
1/3 1/3
=1
∴A ∩B =φ
 1  1 ⇒ (A ∪ B) ∩ B' = A
34. (B) Sn = (2 − 1) +  2 −  + ..... +  2 − 
 2  n
∴ (( A ∪ B ) ∩ B' ) ∪ A ' = A ∪ A ' = N
= 2n – Hn
35. (B) Normal at (at 2, 2at) on the parabola 40. (C) If x ∈ Q, then f(x) = x
y2 = 4ax is y + tx = 2at + at3 ∴ fof(x) = f{f(x)} = f(x) = x
Suppose normal equation (i) cuts the curve If x ∉ Q, then f(x) = 1 – x
again at (at1 , 2at1 ) , then
2
fof (x) = f{f(x)}=f(1 – x) = 1 –(1 –x) = x

2at1 + att12 = 2at + at 3 (∴ x ∉ Q ⇒ 1 − x ∉ Q )

Thus, fof(x) = x for all x ∈ [0,1]
⇒ 2a (t − t1 ) + at ( t 2 − t12 ) = 0
Physics
or 2 + t(t + t1) = 0
41. (B) Distance travelled in last 3 seconds
(∴ a(t – t1) ≠ 0)
= area of ∆ BEC
2
∴ t1 = − t − 1
t = × EC × BE
2
 2
= − t +  1
 t = × 3 × 24
2
36. (B) Required line is ax + by + K = 0
= 36 m
∴ it passes through (c,d)
Distance travelled in 8 s = area of ∆ OAD
⇒ ac + bd + K = 0 + area rectangle ∆ ABED + area of ∆ BEC
⇒ K = −ac − bd
1 
∴ The equation of the line is =  × 3 × 24  + ( 24 × 2 ) + (36 )
ax + by – ac – bd = 0 2 
a(x – c) + b(y – d) = 0 = 36 + 48 + 36 = 120 m
1 Ratio = 36 : 120 = 3 : 10
37. (B) 2S = a + b + c ⇒ S = (a + b + c ) 42. (B) As area = length × breadth
2
= 4.321 × 4.055
1 1
S − a = ( b + c − a ) ,S − b = (a + c − b ) Area = 17.521655
2 2
The area of the sheet upto four significant
1
and S − c = (a + b − c ) figures is 17.52 m2
2 43. (B) Mass of a particle = m
A2 = S(S-a)(S-b)(S–c)
Force = p
1 1
(a + b + c ) (a + b + c ) Time = t
3
≤
16 27
Here, initial velocity u = 0
p = ma where a is the acceleration

website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions
 p  1  3 1
or a = =  1 −  =  1 −  = × 100 = 25%
m  γ  4 4
1 2 48. (B) Displacement equation of S.H.M is y = a
using, s = ut + at
2 sin ωt .
1 p  Therefore velocity is obtained by
s = 0 × t +   t2 differentiating it.
2 m 
dv
1 pt 2 (v ) = = aω cos ωt = aω 1 − sin 2 ωt
s= dt
2 m
According to work energy theorem, y2
= aω 1 − = ω a2 − y2
Kinetic energy = p × S a2
49. (D) Let a be the radius of sphere.
 1 pt2 
= p 2 m  4π 3
 
Mass of sphere = ad
3
p2 t 2
= 4π 3
2m Weight = = a dg
3
44. (B) Let T the tension in the string. Let the
bodies B and C accelerate downwards with 4
acceleration a. Then the body A move Upward thrust due to liquid w = πa 3 ρg
upwards with acceleration a. 3
4
Resultant weight = π a 3 g (d − ρ )
3

force
T ∴ Resultant acceleration =
mass
a T
A
4
B a π a 3 g (d − ρ )
3
T1
= 4
T1 πa 3 d
C 3

Therefore, For motion of body A, g (d − ρ)

=
T – mg = ma .......... (i) d
For motion of body B and C,
1 mg – T = 2 m × a .......... (ii) 50. (A) Energy stored per unit volume
Adding (i) and (ii), we get 1 1 stress 1 S2
2 mg - mg = 3 ma or a = g/3 = × stress × strain = × stress × =
2 2 Y 2 Y
For motion of body C, mg – T1 = ma
2S 4S 4 × 0.072
or T1 = m(g – a) = m (g – g/3) 51. (A) P= = = −3
= 240N m−2
r D 1.2 × 10
T1 = 2 mg/3 = 2 × 2 × 9.8/3
1 2
T1 = 39.2/3 = 13 N 52. (B) Using the relation, S = ut = at ,
2
45. (C) The g decreases both when we go below or
above the surface of the earth. Hence, g 1 2
value is maximum on the surface of the we have, h = u cos θ t1 − gt1
2
earth.
46. (A) L = mr2 ω . For given m and ω , L α r2. If r 1 2
and h = u cos θ t2 − gt2
is halved, the angular momentum L 2
becomes one-fourth.
1
or u cos θ × 1 − × 9.8 × 12
47. (A) Heat supplied dQ = nCpdT 2
Heat used for work = dW = nRdT 1
= u cosθ × 3 − × 9.8 × 32
dW R CP − C v C 2
= = =1− v
dQ CP CP CP or u cos θ (3 − 1) = 4.9 × 8

website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions
 4.9 × 8 58. (C) As velocities are exchanged on perfectly
u cosθ = = 4.9 × 4 = 19.6m / s elastic collision, therefore, masses of two
2 objects must be equal.
Maximum height
ma
u 2 cos2 θ (19.6 ) Therefore m = 1 (or) ma = m b
2

= = = 19.6 m b
2g 2 × 9.8
59. (B) Applying theorem of parallel axes,
2π  2π 
53. (D) ωt + φ0 = × t  since ω = ML2 ML2 7
T  T  I = I 0 + M (L / 4 ) =
2
+ = ML2
12 16 48
both t, T represent time.
60. (C) Because water level is higher on the
2π t surface exposed to atmosphere, P 1
Hence, is dimensionless
T (pressure of confined air) is more than P2
(atmospheric pressure).
φ0 − angle so, dimensionless
61. (C) The specific heat at constant pressure is
∴ ωt + φ0 has no dimensions but has more than that at constant volume because
certain magnitude or dimensionally it can additional work is needed to be done for
be represented as M0L0T0. allowing expansion of gas at constant
pressure.
54. (C) Lengths of the two inclined planes are
62. (B) Terminal velocity v ∝ r 2. since volume
h h V = (4/3) πr . Therefore, when the volume
3
l1 = and l2 =
sin θ1 sin θ 2 becomes 8 times, the radius is doubled.
Hence velocity becomes 4 times = 4 × 1 m
Acceleration of the block down the two s–1 = 4 m s–1
planes are:
63. (A) Let massof ice be x
a1 = g sin θ1 and a2 = g sin θ2 Latent heat of ice = 80 cal g–1
1 1 Heat required by ice to convert to water
As l1 = a1 t12 and l2 = a 2 t 22
2 2 = x × 80
Heat lost by water = 160 × 20
l1 a1 t12 t22 a1 l2 g sin θ1 sin θ1
∴ = 2 or
= = × According to principle of calorimetry,
l2 a 2 t2 t12 a 2 l1 g sin θ2 sin θ2
Heat gained =Heat lost
t sin θ1 x × 80 = 160 × 20
∴ 2 =
t1 sin θ 2
160 × 20
x= = 40 g
55. (B) 80
X X
64. (A) For adiabatic compression, PV γ = constant,
2m
dV
X 2 m Hence, dp = −γp ...(1)
V
In half rotation, point ‘X’ has moved For isothermal compression,
πd dV
horizontally = π r = π × 2 = 2π m (since PV = constant, hence dp = p .......(2)
2 V
r = 2 m)
Ratio (1) to (2) = γ
In the same time, it has moved vertically
a distance which is equal to its diameter 65. (B) Let the frequency of first tuning fork be f.
= 2r = 4 m The frequency of other tuning forks are
Therefore, displacement of (f – 3), (f – 2 × 3), ........(f – 17 × 3),
............(f – 25 × 3)
(2π )
2
X= + 42 = 2 π 2 + 4 m
As per given condition
56. (B) Work done = mg × h = weight × height f = 2 (f – 25 × 3) or f = 25 × 6 = 150 Hz

2π R 2π R R The frequency of 18th fork

57. (A) T= = = 2π = f –17 × 3 = 150 – 51 = 99 Hz.
v0 gR g
It is independent of the mass of satellite.

website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions
 Chemistry
66. (C) The melting and boiling points of alkali
metals decrease down the group because
increase in the atomic size in going from
the top to the bottom in the group. Hence,
the melting point of Cs is lower than that
of Na and their salts too due to their
difference in lattice arrangements.
67. (A) Molecular speeds :
73. (C) Brine solution is taken in a saturation
tower of the plant. Ammonia gas
containing little amount of CO2 is passed
into it, first ammonium reacts with CO2 to
form ammonium carbonate. This
ammonium carbonate renders precipitation
of impurities of magnesium, calcium and
iron as carbonates.
2NH 3 + H 2O + CO 2 → (NH4 )2 CO3

3RT OH C2 H5
Urms (root mean square speed) = 1 |2 3 |4 5 6
M 74. (D)
CH3 − CH − CH2 − CH = CH − CH2
8RT
Uav (average speed) = Hence, IUPAC name of the compound is
πM 4–ethyl hex–4–en–2–Ol
2RT 75. (B) Aqueous solution of borax is basic as it
Ump (most probable speed) = turns red litmus paper blue.
M
76. (C)
Thus, Urms : Uav : Ump = 1 : 0.92 : 0.82
CH3 − CH2 − Br + 2Na + Br − CH2 − CH3
⇒ Urms > Uav > Ump
68. (B) Let 2nd oxide be MxOy, At wt of M be M. → CH 3 − CH 2 − CH 2 − CH3 + 2NaBr
n − Butane
1st oxide 2nd oxide
77. (B) CCl4 has regular tetrahedral structure as
16 x 5 the molecules have four bond pairs around
As in MO ; 50% is M 2 40 = × 100
16 x + 16 y its central atom. In CCl4, the four bond
At wt of M = At wt of O dipoles are oriented tetrahedrally to
neutralise each other. As a result, the net
⇒ M = 16 2x + 2y = 5x dipole moment of the molecule is zero.
2y = 3x 78. (C) In pure water, [H+] = [OH–] = 10–7 mol lit–1
On addition of NH3 (a base) to pure water,
x the concentration of hydronium ion
= 2:3
y decreases because in pure water,
∴ MxOy = M2O3 2H2O → H3O + + OH− , on addition of NH3
69. (D) Temperature of the reaction, conditions it accepts hydronium ions from the solution
like constant volume or constant pressure or donates hydroxide ions to the solution.
and the method by which change is brought Thus, raises pH.
about are the factors that influences the
enthalpy of a reaction. r1 x / 5 Mgas Mgas
79. (B) = = =
70. (D) On electrolysis of ionic hydride which r2 x / t MHe 4
contain H– (hydride) ion, a very strong
Bronsted base, it reacts with water, t M gas
liberating H2 gas at anode which escapes =
5 4
out. H– is an anion and moves towards
anode. If t = 20 s
Eg: NaH + H2O → NaOH + H2 ↑ 20 M gas
= ⇒ 16 × 4 = M gas
71. (D) ∆ E for Li+2ion = E2 – E1 is maximum as 5 4
EnLi+2 = EnH × Z2
M gas = 64, Therefore SO2 gas.
72. (D) The oxidation number of the various
elements involved in this reaction are as 80. (D) For an adiabatic expansion of an ideal gas
follows: undergoing reversible process (i.e. no
entropy generation) is:
Cl2 + 2Br− → 2Cl− + Br2
PV γ = constant or P1– γ T γ = constant
( −1)
(0 )
Here, Cl 2 → Cl . So,Cl2 is the oxidant (or) TV γ –1
= constant
( − 1) 81. (C) Gypsum is sparingly soluble in water on
→ Br2( ) . So, Br–
− 0
(oxidising agent) and Br heating it carefully at 100 0C, it partially
1
is the reductant. loses water of crystallisation and becomes
CaSO 4 . 12 H 2O .

website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions
82. (C) Silicate is a metal derivative of silicic acid electron rich benzene ring by the nitronium
which contains silicate as anion. Silicon is ion.
a synthetic organo – silicon polymer, R2SiO
as repeat unit.
+ HNO3 
H2SO4
→ NO2
83. (A)
MnO4 → Mn +2 C 2O4 −2 → 2CO 2 88. (D) The orbitals described by the set of
quantum numbers in given options is:
MnO 4 − → 4Mn +2 + 4H 2O 4s, 3p ; 3d, 3s
−
MnO4 + 8H → Mn + +2
+ 4H2 O Energy of these orbitals follows the order
3d > 4s > 3p > 3s
MnO4 − + 8H + → 5e − → Mn + + 4H 2O
∴ Subshell 3s has the least energy.
− + − +
2MnO 4 + 16H → 10e → Mn +8H2 O + 10CO2 + 5C2 O4 −2

89. (A) 2HI ƒ H2 I2

84. (D) Hydrogen bond is formed between the
molecules in which hydrogen atoms are initial conc. 1 0 0
linked to an atom of highly electro 1 2 1 1
Eq.conc. 1− =
negative element and atom of 3 3 6 6
electronegative element should be small.
In liquid HCl, chlorine is not highly
electronegative to form H-bond. Kc for 2HI ƒ H2 + I2
85. (D) In 98 g of H2SO4 three are 1 g atoms of S.
In 4.9 g H2SO4 has g atom of S [H 2 ][I 2 ]
Kc =
[HI]
2

4.9
= = 0.05 g atoms
98  1  1 
86. (A) Lithium carbonate is the least soluble    1 9 1
6 6
alkali metal. As lithium carbonate is more ⇒ K c =   2  = × =
2 36 4 16
covalent in nature than other carbonates  
of alkali metals down the group. 3
87. (A) In electrophilic (aromatic) nitration, 90. (B) Photo chemical fog is an yellowish colour
aromatic organic compounds are nitrated of NO2 formed by burning of oil, coal, gas
via an electrophilic aromatic substitution in vehicles and industries. The main cause
mechanism involving the attack of the for arise of this smog is due to oxides of
nitrogen (NO and NO2).

website : www.unifiedcouncil.com
(11_Class_PCM)_NAT_Solutions