A B C B/T+C T Presion

16.4948 3593.39 -35.2249 13.5714801 300 18.6029 METANOL

14.1603 2948.78 -44.5633 11.5440733 300 13.6840 BENCENO
PRESION A GAMMA 1 Y PHI 1
P 14.249
Y1 0.15 0.00806 PRESION DE ROCIO
phi 1 1
gamma 1 1
p1 sat 18.6029
Y2 0.85 0.06212
phi 2 1
gamma 2 1
p2 sat 13.684

1.6144 0.0348
gamma 1 5.0246 gamma 2 1.0354
A1,2 2.1411 A1,2 2.1411
A2,1 1.7905 A2,1 1.7905
x1 0.114 x1 0.114
x2 0.885 x2 0.885

-0.0799368 0.620562

VOLVER A CALCULAR P CON VALORES DE GAMMA MODIFICADO

P 16.234
Y1 0.15 0.00160
phi 1 1
gamma 1 5.0246
p1 sat 18.6029
Y2 0.85 0.05999
phi 2 1
gamma 2 1.0354
p2 sat 13.684

B11 -0.00086
B22 -0.00134
B12 -0.001143

DELTA 12 -8.6E-05
RO 12
 SE
CALCULA PH1 2
PHI 1
1.00075 0.9954

X1 0.026
X2 0.969
DE NUEVO SE CALCULA GAMMA CON X NORMALIZADA
1.9933 0.0019
gamma 1 7.3396 gamma 2 1.0019
A1,2 2.1411 A1,2 2.1411
A2,1 1.7905 A2,1 1.7905
x1 0.026 x1 0.026
x2 0.969 x2 0.969

-0.0182312 0.6794628

SE RECALCULA P
P 16.236 kPa
Y1 0.15 0.00160
phi 1 1.00075del color naranja
gamma 1 7.3396
p1 sat 18.6029
Y2 0.85 0.05999
phi 2 0.9954 color naranja
gamma 2 1.0019
p2 sat 13.684
ANTOINE
 A B C B/T+C T Presion
16.4948 3593.39 -35.2249 13.5714801 300 18.6029 METANOL
14.1603 2948.78 -44.5633 11.5440733 300 13.6840 BENCENO
PRESION A GAMMA 1 Y PHI 1
P 209.400
Y1 0.45 0.00451 PRESION DE ROCIO
phi 1 1
gamma 1 1
p1 sat 99.86
Y2 0.3 0.00025
phi 2 1
gamma 2 2.01
p2 sat 596.86
Y3 0.25 0.00002
phi 3 1
gamma 3 1
p3 sat 13035.4877
ANTOINE

tres componentes
 A B C B/T+C T Presion kPa m^3/mol
16.5362 3985.44 -38.9974 16.3235616 283.15 1.2369 Agua
13.9778 2554.6 -36.2529 10.3468206 283.15 37.7498 Pentano
13.8797 1582.18 -13.7622 5.87324296 283.15 3000.2684 Etano

*C
0
10
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
 Chart Title
0.0120

0.0100

0.0080
itle
 0.0120

0.0100

0.0080

Axis Title
0.0060

0.0040

0.0020

0.0000
0 1 2 3 4 5 6 7 8 9 10

Axis Title
mmhg

A B C B/T+C T Presion kPa m^3/mol

16.5362 3985.44 -38.9974 17.0206951 273.15 0.6160
16.5362 3985.44 -38.9974 16.3235616 283.15 1.2369 Agua
16.5362 3985.44 -38.9974 15.6812875 293.15 2.3512 Agua
16.5362 3985.44 -38.9974 15.0876425 303.15 4.2570 Agua
16.5362 3985.44 -38.9974 14.5373051 313.15 7.3809 Agua
16.5362 3985.44 -38.9974 14.0257031 323.15 12.3110 Agua
16.5362 3985.44 -38.9974 13.5488859 333.15 19.8323 Agua
16.5362 3985.44 -38.9974 13.1034224 343.15 30.9625 Agua
16.5362 3985.44 -38.9974 12.6863187 353.15 46.9875 Agua
16.5362 3985.44 -38.9974 12.29495 363.15 69.4947 Agua
16.5362 3985.44 -38.9974 11.9270058 373.15 100.4032 Agua
16.5362 3985.44 -38.9974 11.5804443 383.15 141.9899 Agua
16.5362 3985.44 -38.9974 11.253454 393.15 196.9098 Agua
16.5362 3985.44 -38.9974 10.9444228 403.15 268.2119 Agua
16.5362 3985.44 -38.9974 10.6519105 413.15 359.3474 Agua
16.5362 3985.44 -38.9974 10.3746272 423.15 474.1733 Agua
16.5362 3985.44 -38.9974 10.1114137 433.15 616.9490 Agua
-38.9974
 Chart Title
0.0250

0.0200

0.0150
xis Title
 0.0250

0.0200

0.0150

Axis Title
0.0100

0.0050

0.0000
10 11 12 13 14 15 16 17 18

Axis Title
7 8 9 10

HR 100% HR 90% HR 80% HR 70% HR 60% HR 50%

HR 40% HR 30% HR 20% HR 10% HR 0%
7.4999758
YS Y'S YS YS'
mmhg P. CDMX 100 100% 90 0.9
4.62004638 585 0.0079603824164 0.0049409270171 0.0071643441748 0.0044468343154
9.277 585 0.0161136518777 0.0100015770276 0.01450228669 0.0090014193248
17.6352218 585 0.0310826870206 0.0192927022886 0.0279744183185 0.0173634320598
31.9299092 585 0.0577321205712 0.0358337300097 0.0519589085141 0.0322503570088
55.3612864 585 0.1045265101849 0.064878523563 0.0940738591664 0.0583906712067
92.340478 585 0.1874326463647 0.1163375046401 0.1686893817282 0.1047037541761
148.754877 585 0.3409892047944 0.2116484719414 0.306890284315 0.1904836247472
232.238128 585 0.658342484408 0.4086263696325 0.5925082359672 0.3677637326693
352.435278 585 1.5154288008346 0.9406109798284 1.3638859207512 0.8465498818455
521.253096 585 8.1769162650748 5.075327336943 7.3592246385673 4.5677946032487
753.086337 585 -4.480354264824 -2.780909543684 -4.032318838342 -2.502818589316
1065.01209 585 -2.218719311116 -1.377136124141 -1.996847380004 -1.239422511727
1476.94592 585 -1.655869363423 -1.027780984194 -1.490282427081 -0.925002885774
2011.75536 585 -1.410021238576 -0.875185596357 -1.269019114718 -0.787667036722
2695.32806 585 -1.277208084336 -0.79274984545 -1.149487275903 -0.713474860905
3556.59362 585 -1.196864065162 -0.742881143893 -1.077177658645 -0.668593029504
4627.49971 585 -1.144712440672 -0.710511170072 -1.030241196605 -0.639460053065

T HR 100% HR 90% HR 80% HR 70%

0 0.0049 0.0044 0.0040 0.0021
10 0.0100 0.0090 0.0080 0.0043
20 0.0193 0.0174 0.0154 0.0084
30 0.0358 0.0323 0.0287 0.0156
40 0.0649 0.0584 0.0519 0.0282
50 0.1163 0.1047 0.0931 0.0505
60 0.2116 0.1905 0.1693 0.0920
70 0.4086 0.3678 0.3269 0.1775
 80 0.9406 0.8465 0.7525 0.4087
90 5.0753 4.5678 4.0603 2.2051
100 -2.7809 -2.5028 -2.2247 -1.2083

Chart Title
0.1200

0.1000

0.0800

0.0600
itle
 0.1200

0.1000

0.0800

0.0600

Axis Title
0.0400

0.0200

16 17 18 19 20 0.0000
30 32 34 36 38 40 42 44 46 48

-0.0200

70% HR 60% HR 50% Axis Title

10% HR 0%
 YS YS' YS YS' YS
80 0.8 70 0.7 60
0.0063683059332 0.0039527416137 0.003458648912 0.0021467476005 0.0042986065049
0.0128909215022 0.008001261622 0.0070011039193 0.0043455127775 0.008701372014
0.0248661496164 0.0154341618309 0.013504891602 0.0083823465116 0.0167846509911
0.046185696457 0.0286669840078 0.0250836110068 0.0155691378663 0.0311753451085
0.0836212081479 0.0519028188504 0.0454149664941 0.0281885998929 0.0564443154998
0.1499461170917 0.0930700037121 0.0814362532481 0.0505466399471 0.1012136290369
0.2727913638356 0.1693187775531 0.148153930359 0.0919576119469 0.184134170589
0.5266739875264 0.326901095706 0.2860384587428 0.1775411123231 0.3555049415803
1.2123430406677 0.7524887838627 0.6584276858799 0.4086792533047 0.8183315524507
6.5415330120598 4.0602618695544 3.5527291358601 2.205142222258 4.4155347831404
-3.584283411859 -2.224727634947 -1.946636680579 -1.208257250014 -2.419391303005
-1.774975448893 -1.101708899313 -0.963995286899 -0.598341902213 -1.198108428003
-1.324695490739 -0.822224787355 -0.719446688936 -0.44655311727 -0.894169456249
-1.12801699086 -0.700148477086 -0.61262991745 -0.38025305221 -0.761411468831
-1.021766467469 -0.63419987636 -0.554924891815 -0.344436139747 -0.689692365542
-0.957491252129 -0.594304915115 -0.520016800725 -0.322769048726 -0.646306595187
-0.915769952537 -0.568408936058 -0.497357819051 -0.308704853204 -0.618144717963

HR 60% HR 50% HR 40% HR 30% HR 20%

0.0027 0.0014 0.0016 0.0006 0.0021
0.0054 0.0028 0.0032 0.0013 0.0043
0.0104 0.0054 0.0062 0.0025 0.0083
0.0194 0.0100 0.0115 0.0047 0.0155
0.0350 0.0181 0.0208 0.0085 0.0280
0.0628 0.0325 0.0372 0.0152 0.0503
0.1143 0.0591 0.0677 0.0276 0.0914
0.2207 0.1141 0.1308 0.0533 0.1765
0.5079 0.2627 0.3010 0.1226 0.4063
2.7407 1.4176 1.6241 0.6615 2.1925
-1.5017 -0.7767 -0.8899 -0.3625 -1.2014

Chart Title
0.2500

0.2000

0.1500

Axis Title
 0.2500

0.2000

0.1500

Axis Title
0.1000

0.0500

42 44 46 48 50
0.0000
50 51 52 53 54 55 56 57 58 59 60

Axis Title
 YS' YS YS' YS YS' YS YS'
0.6 50 0.5 40 0.4 30 0.3
0.0026681005892 0.0022234171577 0.00138005 0.00254732 0.0015811 0.00103759 0.00064402
0.0054008515949 0.0045007096624 0.00279354 0.00515637 0.0032005 0.00210033 0.00130365
0.0104180592359 0.0086817160299 0.00538865 0.00994646 0.00617366 0.00405147 0.0025147
0.0193502142053 0.0161251785044 0.01000873 0.01847428 0.01146679 0.00752508 0.00467074
0.035034402724 0.0291953356034 0.01812124 0.03344848 0.02076113 0.01362449 0.00845658
0.0628222525057 0.0523518770881 0.03249427 0.05997845 0.037228 0.02443088 0.01516399
0.1142901748483 0.0952418123736 0.05911561 0.10911655 0.06772751 0.04444618 0.02758728
0.2206582396016 0.1838818663346 0.11413357 0.2106696 0.13076044 0.08581154 0.05326233
0.5079299291073 0.4232749409228 0.26272238 0.48493722 0.30099551 0.19752831 0.12260378
2.7406767619492 2.2838973016243 1.41759143 2.6166132 1.62410475 1.06581874 0.66154267
-1.501691153589 -1.251409294658 -0.7767368 -1.43371336 -0.88989105 -0.583991 -0.36247718
-0.743653507036 -0.619711255863 -0.38464837 -0.70999018 -0.44068356 -0.28919859 -0.17950257
-0.555001731465 -0.462501442887 -0.28706986 -0.5298782 -0.32888991 -0.21583401 -0.13396594
-0.472600222033 -0.393833518361 -0.24444839 -0.4512068 -0.28005939 -0.18378898 -0.11407592
-0.428084916543 -0.356737430453 -0.22142323 -0.40870659 -0.25367995 -0.16647747 -0.10333084
-0.401155817702 -0.334296514752 -0.20749439 -0.3829965 -0.23772197 -0.15600504 -0.09683071
-0.383676031839 -0.319730026532 -0.19845312 -0.36630798 -0.22736357 -0.14920735 -0.09261146

HR 10% HR 0%
0.0001 0.0013
0.0003 0.0026
0.0005 0.0049
0.0010 0.0092
0.0018 0.0166
0.0032 0.0298
0.0059 0.0542
0.0114 0.1046
0.0263 0.2408
0.1418 1.2993
-0.0777 -0.7119

Chart Title
1.0000

0.9000

0.8000

0.7000

0.6000
Axis Title

0.5000

0.4000
 0.9000

0.8000

0.7000

0.6000

Axis Title
0.5000

0.4000

0.3000

0.2000

0.1000

0.0000
70 71 72 73 74 75 76 77 78

57 58 59 60
Axis Title

HR 100% HR 90% HR 80% HR 70% HR 60% HR 50%

HR 40% HR 30% HR 20% HR 10% HR 0%
 eje de la y
YS YS' YS YS' YS YS'
20 0.2 10 0.1 0 0
0.00343889 0.00213448 0.00022234 0.00013801 0.00203786
0.0069611 0.00432068 0.00045007 0.00027935 0.00412509 0.0025604
0.01342772 0.00833445 0.00086817 0.00053887 0.00795717 0.00493893
0.02494028 0.01548017 0.00161252 0.00100087 0.01477942 0.00917343
0.04515545 0.02802752 0.00291953 0.00181212 0.02675879 0.0166089
0.0809709 0.0502578 0.00523519 0.00324943 0.04798276 0.0297824
0.14730734 0.09143214 0.00952418 0.00591156 0.08729324 0.05418201
0.28440395 0.17652659 0.01838819 0.01141336 0.16853568 0.10460835
0.65466524 0.40634394 0.04232749 0.02627224 0.38794977 0.24079641
3.53242783 2.19254141 0.22838973 0.14175914 2.09329056 1.2992838
-1.93551304 -1.20135292 -0.12514093 -0.07767368 -1.14697069 -0.71191284
-0.95848674 -0.59492281 -0.06197113 -0.03846484 -0.56799214 -0.35254685
-0.71533556 -0.44400139 -0.04625014 -0.02870699 -0.42390256 -0.26311193
-0.60912918 -0.37808018 -0.03938335 -0.02444484 -0.36096544 -0.22404751
-0.55175389 -0.34246793 -0.03567374 -0.02214232 -0.32696527 -0.20294396
-0.51704528 -0.32092465 -0.03342965 -0.02074944 -0.3063972 -0.19017757
-0.49451577 -0.30694083 -0.031973 -0.01984531 -0.29304638 -0.18189086
 Chart Title

5.0000

4.0000

3.0000
Axis Title
 5.0000

4.0000

3.0000

Axis Title
2.0000

1.0000

77 78 79 80 0.0000
90 91 92 93 94 95 96

Axis Title

HR 60% HR 50% HR 100% HR 90% HR 80% HR 70% H

HR 0% HR 40% HR 30% HR 20% HR 10% H
Chart Title
 94 95 96 97 98 99 100

Axis Title

% HR 80% HR 70% HR 60% HR 50%

% HR 20% HR 10% HR 0%
 K convertir a bar m3/kmol
ij Tc Pc Vc ij Zcij
Agua 11 647.3 220.9 0.0568 0.233
Pentano 22 469.7 33.69 0.304 0.262
Mezcla 12 551.395 76.907 0.1475 0.2475
Temperatura en K 373

R 8.314E-05
11 Vci^1/3 0.38439946855
12 Vci^1/3 0.67239508136 NO MOVER
vc 12 0.00014753046
B* -0.3392

K convertir a bar m3/kmol

ij Tc Pc Vc ij Zcij
Pentano 22 469.7 33.69 0.304 0.262
Etano 33 305.4 48.8 0.1479 0.284
MEZCLA 23 378.743 39.676 0.2167 0.273
Temperatura en K 373

R 8.314E-05
11 Vci^1/3 0.67239508136
12 Vci^1/3 0.52883808591 NO MOVER
vc 12 0.00021666659
B* -0.3392

K convertir a bar m3/kmol

ij Tc Pc Vc ij Zcij
Agua 11 647.3 220.9 0.0568 0.233
Etano 33 305.4 48.8 0.1479 0.284
MEZCLA 13 444.618 100.368 0.0952 0.2585
Temperatura en K 373

R 8.314E-05
11 Vci^1/3 0.38439946855
12 Vci^1/3 0.52883808591 NO MOVER
vc 12 9.52053382E-05
B* -0.3392
Bkk(P-Pksat) y2y3(2delta21..)
P (kPa) 209.698 phi 1 -0.00036507 -2.061218E-05
Y1 0.45 0.00451 phi 2 0.002564723 -1.652667E-05
phi 1 1 phi 3 -0.01604096 -1.025725E-12
 gamma 1 1
p1 sat 99.86
Y2 0.3 0.00024 X1 0.9334
phi 2 1 X2 0.055406501
gamma 2 2.0661 X3 0.0024
p2 sat 596.86 0.9912
Y3 0.25 0.00002
phi 3 1
gamma 3 1
p3 sat 13035.4877

A B C B/T+C T Presion kPa

16.5362 3985.44 -38.9974 11.9270058051 373.15 100.4032
13.9778 2554.6 -36.2529 7.58273075072 373.15 598.8848
13.8797 1582.18 -13.7622 4.40243102298 373.15 13059.4720

CALCULO DE GAMMA
 w Tr ij b* B' Bij B sombrero
0.3442 0.5762 -0.8194 -1.60278643 -0.00033403 -1.37106914
0.2486 0.7941 -0.4905 -0.31389519 -0.000659 -0.56852937
0.2964 0.6765 -0.6340 -0.74917042 -0.00051026 -0.85601526

NOTA
para el calculo de pc, los valores que están en la tabla convertirlos a bar para que se ajuste a las ecuaciones

w Tr ij b* B' Bij B sombrero

0.2486 0.7941 -0.4905 -0.31389519 -0.000659 -0.56852937
0.0989 1.2213 -0.2463 0.064732075 -0.00012483 -0.23992508
0.17375 0.9848 -0.3476 -0.04440007 -0.00028199 -0.35530941
-0.003446
-0.00432
NOTA -0.004223
para el calculo de pc, los valores que están en la tabla convertirlos a bar para que se ajuste a las ecuaciones

w Tr ij b* B' Bij B sombrero

0.3442 0.5762 -0.8194 -1.60278643 -0.00033403 -1.37106914
0.0989 1.2213 -0.2463 0.064732075 -0.00012483 -0.23992508
0.22155 0.8389 -0.4493 -0.22066493 -0.00018347 -0.49815211
-0.003446
-0.00432
NOTA -0.004223
para el calculo de pc, los valores que están en la tabla convertirlos a bar para que se ajuste a las ecuaciones

y1y3(-delta13) y3y2(2delta31..) SUMA RT DIVISION PHI

-1.03412E-05 -2.700269E-06 -0.0003819 0.03101122 -0.01231487 0.9878
-1.648853E-05 2.6082935E-05 0.002561257 0.03101122 0.082591312 1.086
2.853016E-05 6.3070005E-05 -0.01599516 0.03101122 -0.51578624 0.597
X normalizado
x1 0.9417
x2 0.0559
x3 0.0024
1.0000

AGUA
PENTANO
ETANO

·
 B11 -0.000334025
B22 -0.000658996
B12 -0.000510256

DELTA 12 -2.749098E-05
RO 12

a las ecuaciones

B11 -0.000658996
B22 -0.000124835
B12 -0.000281991

DELTA 23 0.0002198471

a las ecuaciones

B11 -0.000334025
B22 -0.000124835
B12 -0.000183469

DELTA 13 9.192177E-05

a las ecuaciones