23 to 34)
1 INTRODUCTION
The vehicles for modeling pastes are acrylic polymer emulsions. The
exact identification of the emulsions or dispersions in commercial fillers is
generally a trade secret and is only generically listed by the
manufacturers. The polymers are often combinations of methyl, ethyl,
butyl acrylates, and methacrylates. The bulking agents are frequently
forms of calcium carbonate, but calcium sulfate, barium sulfate, talc
(French chalk), kaolin, and other clays may be present. Additional
ingredients may be ammonia or ammoniated compounds, ethylene
glycols, pigments, and emulsifying or foaming agents. The ammonia or
ammoniated compounds present in most acrylic fillers may serve a role
as biocides. The ammonia or ammoniated compounds, which may cause
corrosion on some metals, are present in extremely small quantities. No
problems of corrosion related to the fillers have been located in
conservation publications.
A few commonly used modeling pastes available in the United States
are: Liquitex Modeling Paste, Golden Molding Pastes, and Utrecht
Modeling Paste. Introduced in 1958, Liquitex Modeling Paste probably
finds the most widespread use in objects conservation in the United
States. Modeling pastes have been extensively used for gap filling on
ceramics, especially low-fire earthenware, plaster sculpture or gesso,
and, to a lesser extent, on wood and metal artifacts. Flexibility of the
dried films varies considerably. The lesser flexibility of some, especially
Liquitex Modeling Paste, limits potential use on checks or cracks in wood
or on hygroscopic materials, such as ivory. Modeling pastes are intended
for indoor applications only.
The pastes are available in many grades, labeled light, heavy, or hard.
The manufacturers' instructions recommend building forms or creating
textures with the modeling pastes. Only Liquitex Modeling Paste is
recommend as carvable. Golden Light Molding Paste is intended to help
build depth without adding weight. Many of the modeling or molding
pastes form very flexible and soft films which may not be suitable for gap
filling on rigid materials, objects that will be handled or displayed in the
open.
The pastes are suitable for application with spatulas. Multiple thin
applications are preferred to avoid shrinkage or evaporation cracks.
Evaporation cracks are formed by the varying rate of escaping water
from the thick and thin areas of the fill. The cracks can be avoided by
applying thin layers and slow drying. The cracks can be filled with no
effect on the final strength and bond of the filler (Wall 1997). The
modeling pastes can be thinned with water to be made brushable or
modified with compatible media supplied by the manufacturers.
Extenders, retarders, gels, and acrylic paints are available. Tools can be
cleaned with water before drying. Once opened, the container should be
tightly closed to prevent drying out. The manufacturers recommend
working above 50° F. The products must be kept at temperatures above
freezing during shipment and storage.
When dry, the acrylic fills can be sanded or rubbed down with solvent.
Acetone (ketone) or toluene (aromatic hydrocarbon) are suitable solvents
for removing excess filler or smoothing the surface. Liquitex Modeling
Paste is the most easily sanded of the acrylic products mentioned. The
others feel more plastic, elastic, or “rubbery,” tend to grab abrasives, and
peel up. The fillers are thermoplastic and can be slightly modified using
heat. Acrylic emulsion paints, resin-based paints, watercolor, and
gouache are suitable for inpainting.
There are limited conservation references regarding acrylic fillers.
Reports of testing (Barov and Lambert 1984) indicate that the thermal
expansion of Liquitex Modeling Paste, and by inference the other acrylic
fillers, makes it compatible with ceramic objects under extreme thermal
fluctuations possibly experienced during transport. No major problems of
incompatibility, rapid deterioration, decrease in reversibility over time, or
other conservation problems regarding acrylic fillers are noted in the
literature. Recently, however, turbidity and the formation of crystals of
poly(ethylene glycol) compounds in Liquitex acrylic emulsion paint films
have been documented (Whitmore et al. 1996), but no extension of the
phenomena or problem has been made yet in regard to the modeling
paste.
4 VINYL-
VINYL-BASED COMMERCIAL FILLERS: GENERAL
DISCUSSION
Many vinyl-based fillers are available in the building supply and hardware
markets. Three commonly mentioned for use in objects conservation
include DAP Vinyl Spackling, Polyfix, and Polyfilla Fine Surface (from
England). Another, Perma-fill Ready Mixed Spackle, was unavailable at
the time of writing. In January 1997, CPC began to offer BEVA Gesso-P
and BEVA Gesso-V as part of its product line. BEVA Gessoes are the
first fillers designed specifically for conservation use. These gessoes,
which vary from the other vinyl commercial fillers, are based on resins
rather than emulsions or dispersions.
The vinyl emulsion fillers contain a polyvinylacetate dispersion or
emulsion as the vehicle or binder. The bulking agent is usually calcium
carbonate in the form of marble flour or ground limestone. Other
ingredients may include biocides and thickeners. Pigments are not added
to the vinyl-based fillers as frequently as in acrylic modeling pastes.
The vinyl emulsion fillers can be applied with a spatula as supplied. A
drop of water can be added to make the mix softer or creamier. They
cannot be easily or successfully thinned with water enough to be brushed
on. The addition of adequate water to permit brush application results in
a very weak and powdery layer. Tools and surfaces can be cleaned with
water. Unlike acrylic-based fillers, vinyl emulsion fillers remain readily
water-soluble after drying. The products contain sufficient filler or bulking
agents relative to the quantity of vehicle to make sanding or abrasion
easy. The resultant films or fills are less flexible and elastic than the
modeling pastes. The appearance of the fills is matte but gentle
burnishing can slightly increase the gloss and density of the surface.
The BEVA Gessoes are the first commercial vinyl resin fillers designed
solely for conservation use. The products have not been available long
enough for an adequate evaluation for use on objects, but they appear to
have great potential. The setting occurs by evaporation of organic
solvents from the bulked resin mixture rather than water from emulsions
or dispersions. While the use of resins makes the products toxic to
handle when wet, it also makes them indefinitely resoluble and
reworkable. The vehicle or binder is based on hydrogenated hydrocarbon
resins and ethylene-vinylacetate copolymer (EVA). Adhesive tests have
shown that BEVA 371, a comparable vinyl adhesive to those used in
BEVA Gesso, is stable (Down et al. 1996). The gesso shares solubility
characteristics with BEVA 371; it is soluble in petroleum distillates,
ketones, and aromatic hydrocarbons but insoluble in water.
R1, R2, and R3 are alkyl groups (of general formula Cn H2n+1
{univalent}) of which one or more is methyl… . Amongst its
notable properties are excellent adhesion and wetting, affording
the necessary high CPCV (critical pigment/volume
concentration).
5 CONCLUSIONS
While commercial fillers have been used successfully in gap filling in the
treatment of a variety of different media, little scientific analysis has been
published to assist the conservator in making informed choices.
Information is incomplete and generic. Additional testing and analysis are
needed, especially to reveal their composition.
Commercial fillers broaden treatment options for gap filling. Incomplete
knowledge of the contents and the possibility of changing formulations
present the greatest disadvantages in recommending their use. Several
of the products, especially DAP Spackling Compound, Liquitex Modeling
Paste, and Polyfilla, have been used for many years in ceramic and
sculpture treatment without reports of any resultant conservation
problems. The newer products require additional testing and observation
to determine safety and effectiveness in specific treatment situations.
ACKNOWLEDGEMENTS
REFERENCES
SOURCES OF MATERIALS
AUTHOR INFORMATION
Section Index
Copyright © 1998 American Institute for Conservation of Historic and Artistic Works
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Fecha de creación: 18/06/2008 10:02:00
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