Académique Documents
Professionnel Documents
Culture Documents
1000 M a 50
CURVA DE VALORACION
0.8000
0.7000
Eind (V)
0.6000
0.5000
0.4000
0.3000
0.2000
0.1000
0.0000
0 10 20 30 40 50 60 70 80
-0.1000
Volumen (ml) AgNO3
Vol (ml) AgNO3 Eind (V) dV dEin dEind/dV d2Eind/dV2
5 -0.0399
15 0.0837 10 0.1236 0.0124
25 0.1005 10 0.0168 0.0017 -0.0107
30 0.1126 5 0.0121 0.0024 0.0007
35 0.1320 5 0.0194 0.0039 0.0015
39 0.1745 4 0.0425 0.0106 0.0068
39.5 0.1924 0.5 0.0180 0.0359 0.0253
39.6 0.1982 0.1 0.0058 0.0576 0.0217
39.7 0.2056 0.1 0.0074 0.0742 0.0166
39.8 0.2161 0.1 0.0104 0.1045 0.0303
39.9 0.2339 0.1 0.0178 0.1784 0.0739
39.95 0.2517 0.05 0.0178 0.3565 0.1781
39.99 0.2931 0.04 0.0414 1.0341 0.6776
40 0.344 0.01 0.0511 5.1066 4.0725
40.01 0.6834 0.01 0.3392 33.9228 28.8163
40.05 0.6834 0.04 0.0000 -0.0003 -33.9231
40.1 0.6834 0.05 0.0000 -0.0003 0.0000
40.2 0.6833 0.1 0.0000 -0.0003 0.0000
40.3 0.6833 0.1 0.0000 -0.0003 0.0000
40.4 0.6833 0.1 0.0000 -0.0003 0.0000
40.5 0.6832 0.1 0.0000 -0.0003 0.0000
41 0.6831 0.5 -0.0001 -0.0003 0.0000
45 0.6820 4 -0.0011 -0.0003 0.0000
50 0.6807 5 -0.0013 -0.0003 0.0000
55 0.6794 5 -0.0013 -0.0003 0.0000
70 0.6760 15 -0.0034 -0.0002 0.0000
PRIMERA DERIVADA.
40
35
30
25
dEind/dV
20
15
10
5
0
0 10 20 30 40 50 60 70 80
-5
Volumen (ml) AgNO3
SEGUNDA DERIVADA
40
30
20
10
d2Eind/dV2
0
0 10 20 30 40 50 60 70 80
-10
-20
-30
-40
Volumen(ml) AgNO3
Titulación de HNO2 0.05000 M con Ce4+ 0.
SEMIRREACCIONES 〖𝐶𝑒〗 ^(4+)+ 𝑒^−
〖𝑁𝑂 3 〗 ^(− )+3𝐻^(+ )+ 〖 2𝑒 〗 ^
〖 2𝐶𝑒 〗 ^(4+)+ HN𝑂_2+ 𝐻_2 𝑂
〖𝑁𝑂 3 〗 ^(− )+3𝐻^+
[] Inicial HNO2, M 0.05 E° (II) 0.94
Volumen HNO2, mL 40.00 E° 'ce (IV) 1.44
[]Ce [IV], M 0.08 Vequi(ml) 50
Eind
0.93
0.94 CURVA DE TITULACIÓN
0.95 1.60
0.96 1.40
0.98 1.20
1.01
1.00
1.02
Eind(V)
0.80
1.02
0.60
1.02
1.03 0.40
1.04 0.20
1.05 0.00
0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00 90.00 100.00
1.07
Volumen(ml) Ce (IV)
1.11
1.22
1.26
1.28
1.30
1.31
1.32
1.32
1.34
1.40
1.42
1.43
Volumen de Ce(IV), mL Eind dV dEin dEind/dV d2Eind/dV2
5.00 0.93
10.00 0.94 5.00 0.01 0.0021
15.00 0.95 5.00 0.01 0.0014 -0.0007
25.00 0.96 10.00 0.01 0.0011 -0.0003
40.00 0.98 15.00 0.02 0.0012 0.0001
49.00 1.01 9.00 0.03 0.0036 0.0024
49.50 1.02 0.50 0.01 0.0181 0.0145
49.60 1.02 0.10 0.00 0.0289 0.0109
49.70 1.02 0.10 0.00 0.0372 0.0083
49.80 1.03 0.10 0.01 0.0523 0.0151
49.90 1.04 0.10 0.01 0.0893 0.0370
49.95 1.05 0.05 0.01 0.1783 0.0890
49.99 1.07 0.04 0.02 0.5171 0.3388
50.00 1.11 0.01 0.04 3.9445 3.4273
50.01 1.22 0.01 0.11 11.4502 7.5057
0.00 100.00
50.05 1.26 0.04 0.04 1.0338 -10.4165
50.10 1.28 0.05 0.02 0.3562 -0.6776
50.20 1.30 0.10 0.02 0.1781 -0.1781
50.30 1.31 0.10 0.01 0.1042 -0.0739
50.40 1.32 0.10 0.01 0.0739 -0.0303
50.50 1.32 0.10 0.01 0.0573 -0.0166
51.00 1.34 0.50 0.02 0.0356 -0.0217
60.00 1.40 9.00 0.06 0.0066 -0.0290
75.00 1.42 15.00 0.02 0.0016 -0.0050
90.00 1.43 15.00 0.01 0.0008 -0.0008
PRIMERA DERIVADA
14
12
10
8
dEind/dV
0
0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00 90.00 100.00
Volumen(ml) Ce(IV)
Segunda derivada
10
5
d2Eind/dV2
0
0.00 10.00 20.00 30.00 40.00 50.00 60.00 70.00 80.00 90.00 100.00
-5
-10
-15
Volumen (ml) Ce (IV)
0.00 100.00