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P-V Diagram CO2 PR
P-V Diagram CO2 PR
at selected temperatures:
V /cm3 mol−1
600
600
600
600
600
600
Note: use Solver to make f(Z) zero by varying Vc
Pressure-Volume Diagram for CO2 (Peng-Robinson)
15 T = 255.2 K T = 265.1 K T = 274.4 K
T = 284.0 K T = 294.4 K Tc = 304.1 K
T = 314.1 K T = 324.1 K T = 334.1 K
T = 344.1 K T = 354.1 K P⁰ at 255.2 K
P⁰ at 265.1 K P⁰ at 274.4 K P⁰ at 284.0 K
P⁰ at 294.4 K P⁰c at 304.1 K Critical Point (calc)
Critical Point (lit) Bubble Point (lit) Dew Point (lit)
10 Bubble Point (calc) Dew Point (calc)
Pressure, P /Mpa
0
0 100 200 300 400 500 600
Temp /K Pressure /MPaMolar Volume /m3 mol−1 (liq)Molar Volume /m3 mol−1 (gas)
Molar Volume /cm3 mol−1 (liq)
253.65 2.0 0.000043 0.000838 42.8
255.25 2.1 0.000043 0.000795 43.1
256.79 2.2 0.000043 0.000757 43.4
258.29 2.3 0.000044 0.000722 43.7
259.73 2.4 0.000044 0.000689 44.0
261.14 2.5 0.000044 0.000659 44.3
262.50 2.6 0.000045 0.000631 44.6
263.83 2.7 0.000045 0.000605 44.9
265.12 2.8 0.000045 0.000581 45.2
266.37 2.9 0.000046 0.000558 45.6
267.60 3.0 0.000046 0.000537 45.9
268.79 3.1 0.000046 0.000517 46.2
269.96 3.2 0.000047 0.000499 46.5
271.10 3.3 0.000047 0.000481 46.8
272.22 3.4 0.000047 0.000464 47.2
273.31 3.5 0.000048 0.000448 47.5
274.38 3.6 0.000048 0.000433 47.8
275.43 3.7 0.000048 0.000419 48.2
276.45 3.8 0.000049 0.000406 48.5
277.46 3.9 0.000049 0.000393 48.9
278.45 4.0 0.000049 0.000380 49.2
279.42 4.1 0.000050 0.000368 49.6
280.37 4.2 0.000050 0.000357 50.0
281.31 4.3 0.000050 0.000346 50.3
282.23 4.4 0.000051 0.000336 50.7
283.13 4.5 0.000051 0.000326 51.1
284.02 4.6 0.000051 0.000316 51.5
284.89 4.7 0.000052 0.000307 51.9
285.75 4.8 0.000052 0.000298 52.3
286.60 4.9 0.000053 0.000289 52.8
287.43 5.0 0.000053 0.000281 53.2
288.26 5.1 0.000054 0.000273 53.7
289.06 5.2 0.000054 0.000265 54.1
289.86 5.3 0.000055 0.000257 54.6
290.65 5.4 0.000055 0.000250 55.1
291.42 5.5 0.000056 0.000243 55.6
292.18 5.6 0.000056 0.000236 56.2
292.93 5.7 0.000057 0.000229 56.7
293.68 5.8 0.000057 0.000222 57.3
294.41 5.9 0.000058 0.000215 57.9
295.13 6.0 0.000059 0.000209 58.6
295.84 6.1 0.000059 0.000202 59.3
296.54 6.2 0.000060 0.000196 60.0
297.23 6.3 0.000061 0.000190 60.8
297.92 6.4 0.000062 0.000183 61.6
298.59 6.5 0.000063 0.000177 62.5
299.26 6.6 0.000064 0.000171 63.5
299.92 6.7 0.000065 0.000165 64.6
300.56 6.8 0.000066 0.000158 65.9
301.20 6.9 0.000067 0.000152 67.3
301.83 7.0 0.000069 0.000145 68.9
302.45 7.1 0.000071 0.000137 71.0
303.07 7.2 0.000074 0.000129 73.7
303.67 7.3 0.000078 0.000118 78.1
304.13 7.4 0.000094 0.000094 94.1
Molar Volume /cm3 mol−1 (gas)
837.6
795.4
756.9
721.6
689.0
659.0
631.1
605.2
581.0
558.4
537.2
517.3
498.6
480.9
464.2
448.4
433.4
419.1
405.6
392.6
380.2
368.4
357.1
346.3
335.8
325.8
316.2
306.9
297.9
289.3
280.9
272.8
264.9
257.3
249.8
242.6
235.5
228.6
221.8
215.2
208.7
202.3
195.9
189.7
183.4
177.2
171.0
164.7
158.3
151.7
144.8
137.3
128.8
118.0
94.1
R744 - Carbon Dioxide Saturation Properties (Pressure Table)
Pressure /MPaTemp /°CSpecific Volume /m3 kg−1 (liq)Specific Volume /m3 kg−1 (gas)
2.0 -19.50 0.000971 0.019033
2.1 -17.90 0.000979 0.018074
2.2 -16.36 0.000986 0.017199
2.3 -14.86 0.000993 0.016396
2.4 -13.42 0.001000 0.015656
2.5 -12.01 0.001007 0.014973
2.6 -10.65 0.001014 0.014340
2.7 -9.32 0.001021 0.013751
2.8 -8.03 0.001028 0.013202
2.9 -6.78 0.001035 0.012688
3.0 -5.55 0.001043 0.012207
3.1 -4.36 0.001050 0.011755
3.2 -3.19 0.001057 0.011329
3.3 -2.05 0.001064 0.010928
3.4 -0.93 0.001072 0.010548
3.5 0.16 0.001079 0.010189
3.6 1.23 0.001087 0.009848
3.7 2.28 0.001095 0.009524
3.8 3.30 0.001103 0.009215
3.9 4.31 0.001111 0.008921
4.0 5.30 0.001119 0.008640
4.1 6.27 0.001127 0.008372
4.2 7.22 0.001135 0.008114
4.3 8.16 0.001144 0.007868
4.4 9.08 0.001152 0.007631
4.5 9.98 0.001161 0.007404
4.6 10.87 0.001170 0.007185
4.7 11.74 0.001179 0.006974
4.8 12.60 0.001189 0.006770
4.9 13.45 0.001199 0.006573
5.0 14.28 0.001209 0.006383
5.1 15.11 0.001219 0.006198
5.2 15.91 0.001230 0.006019
5.3 16.71 0.001241 0.005846
5.4 17.50 0.001252 0.005677
5.5 18.27 0.001264 0.005512
5.6 19.03 0.001276 0.005351
5.7 19.78 0.001289 0.005194
5.8 20.53 0.001303 0.005041
5.9 21.26 0.001317 0.004890
6.0 21.98 0.001332 0.004742
6.1 22.69 0.001347 0.004596
6.2 23.39 0.001364 0.004452
6.3 24.08 0.001382 0.004310
6.4 24.77 0.001401 0.004168
6.5 25.44 0.001421 0.004027
6.6 26.11 0.001444 0.003885
6.7 26.77 0.001469 0.003742
6.8 27.41 0.001497 0.003597
6.9 28.05 0.001529 0.003446
7.0 28.68 0.001567 0.003289
7.1 29.30 0.001613 0.003120
7.2 29.92 0.001675 0.002927
7.3 30.52 0.001774 0.002680
7.377 30.98 0.002139 0.002139
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