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MCPL
15/11/98
MODHERA CHEMICALS PVT. LTD., offers “MODSCOUR-BL” as a product which is well tried and tested in hydrogen
peroxide bleaching. The most distinguished properties of this product lie in that it enables various functions to be
performed in one bath and also allow the fundamental needs of the consumers for more environmental compatibility. It is
bio-degradable to high degree. Besides preventing redeposition of impurities the product offers good stability against acids
(important for acid extraction) and alkalies, excellent wetting and re-wetting properties, inhibition of iron and stabilising
action for peroxide.
MODSCOUR-BL is suited for all types of machinery (continues and discontinuous) and guarantees minimal fibre damage,
while achieving a high degree of whiteness at the same time. The user will benefit in quality from the universal means of
applying this hitech MCPL product, and will also have savings in time, water and energy.
Advantages:
☛ Only one product now needed for peroxide bleaching
☛ Optimum degree of whiteness
☛ Reduced use of chemicals possible
☛ Excellent d.p. values
☛ Very good re-wetability
☛ Suitable for all types of machines and processes
☛ Stable to acids, alkali, electrolytes and temperatures upto 135ºC
☛ Energy saving due to shortened processes
☛ Complete dispensation of silicate
☛ Biodegradable
Scope of Applications:
Bleach bath stabilisation
Demineralisation bleaching by one bath / two step process
“Three in one” product
- Wetting / scouring
- Dispersing
- Stabilisation
Profile of MODSCOUR-BL
Good Biodegradibility
Stabilisation by complete
dispensation of silicate
MODSCOUR-BL : Manganese, Iron, Copper binding capacity at 98ºC.
400
mg metal ions / g
300
product
pH 7
200 pH 9
pH 11
100
0
manganese iron copper
Metal Ions
100
90
80
70
Residual H2O2, (%)
60 Mod scour- BL
50 Perostab -BLN
Silicate
40
30
20
10
90
80
Residual Peroxide
Final Stabilisation
70
60
in %
50
40
30
20
Modscour- BL
10
0 Waterglass
2ºdH
4ºdH
8ºdH
12ºdH
16ºdH
20ºdH
32ºdH
48ºdH
64ºdH
80ºdH
Addition of Magnesium Chloride
[ºdH]
BLEACHING OF TOWELLING
Machine : Thies Roto Stream
Material : 100% cotton
Liquor ratio : 1 : 10
Bleaching recipe:
1~1.5 g/l : MODSCOUR-BL
2 g/l : NaOH Flakes
5~5.5 m/l : H2O2 50%
Water hardness : 8º Gh = 10ºEh
(If only deionized water is available add 0.3 g/l MgCl2 . 6H2O)
2.5°C/min.
80°C
25°C
Drain
Production Steps
1. Demineralization / Bleaching (Semi White)
2. Vat Dyeing
3. Reactive dyeing
Problematic
Repeatly unlevelness on light Vat and Reactive shades occurred in the past in so far as the package inside was lighter than
outside. Analyses of the yarn led to the result that deposits of mineral hydroxides caused a blockage of the liquor flow.
40 min.
95°C 95°C
40°C Drain
2. Vat Dyeing
(on different machine, closed apparatus with alternating circulation)
2.1 Pigmentation
1 g/l MODQUEST-FSN
1 g/l MODLEVELLER-VL
0.25% Pigment (Fine dispersion)
0.061% Pigment (Colloidal)
5 m/l NaOH
-10 min. at 80°C
2.2 Vatting
3~3.5 g/l Sodium hydrosulphite
- 20 min. at 80°C
- 30 min. at 60°C
2.4 Soaping
1~1.5 g/l MODLEVELLER-VL
1~1.5 g/l MODQUEST-WS
- 15 min. at 96°C
2.5 Acidification
0.5 ml/l Acetic acid 60%
- 10 min. at 40°C
2.7 Softening
3. Reactive Dyeing
3.1 Pre-Bleach, same as for Vats
3.2 Dye Process
% shade required Reactive dye
1~1.5 g/l MODQUEST-FSN
50 g/l Glauber’s salt
20 g/l Soda ash
25°C 25°C
Soda ash Drain
MODQUEST-FSN
Dyestuff
Salt
3.2 Rinsing
- 5 min. at 25°C
- 5 min. at 25°C
- 5 min. at 25°C, addition of 0.4 ml/l Acetic acid 60%
3.4 Washing-off
- 10 min. at 98°C
addition of 1~2 g/l MODQUEST-FSN
3.5 Rinsing
- 5 min. at 40°C
3.6 After treatment
0.5 ml/l Acetic acid 60%
2% ECOFIX-2F
- 10 min. at 40°C
BLEACHING:
Starting recipe - MODSCOUR-BL 1 g/l
- NaOH 50% 1 g/l
- H2O2 50% 4 g/l
If only soft water is available add 0.6 g/l MgCl2, otherwise add only 0.2 g/l MgCl2.
500 ltr.
B) 20 g/lNaOH 50% } Stock solutions
3 g/l MODSCOUR-BL } ⇓
Dosage: 80 ltr./hr.
C) 40 g/lH2O2 50% }
4 g/l MODSCOUR-BL }
3 g/l MgCl2 }
Classical Procedure Indicative formulation with MODSCOUR-BL
COLD PAD-BATCH
LABORATORY TESTS
------>
1 2 3 4 5 6
7 8 9
Information about the process run
3. Process
1st Step: Combined alkali + oxidative treatment, dwelling process
2nd Step: a) Washing-off solubilized impurities and decomposed
starch
b) Peroxide-Pad steam
3.1 Advantages of the oxidative desizing in the alkali step
- Maximum swelling of cellulose, breaking up of husks, saponification of waxes and grease.
- Persulphate decomposes starch as well as polyvinyl alcohol
- Alkali solubilizes polyacrylate
- Shorter dwell time (4 hours) as compared to enzymatic desizing
Remarks : Padding at 90ºC, covering of batching roller with foil
Temperature is kept due to exothermic reactions:
Starch + Persulphate exothermic >
Polyvinylalcohol + Persulphate exothermic >
90 = 90 = factor 3
F2 – F1 90-60
4. Results
Degree of Damage factor Degree of Whiteness
Polymerization by Eisenhut Elrepho Filter
Grey fabric 1820 48.9%
Treated fabric (without
Mercerization) 1550 0.29 70%
No optical brightening
Process-steps
Recipe 1
Addition into compartment No. 3, with overflow in compartment No. 2 and No.1
Recipe 2
Starting concentration:
4 g/l Na-persulfate
0.5~1 g/l ALTRANOL-CD / MODSCOUR-LF
25 g/l NaOH flakes
Concentration of feed liquor: 4 times
C: Steaming
2 times 15 min/102ºC
U-Box-Steamer
D: Recipe 3
3 Compartments at 80-95ºC overflow rinse
1 Compartment cold overflow rinse
E: Peroxide bleaching
Recipe 4
Starting concentration
8 g/l MODSCOUR-BL
20 g/l NaOH flakes
40 g/l H2O2 50%
0.3 g/l MgCl2.6H2O
(necessary if water hardness is below 8ºGh or 10ºEh)
Concentration of feed liquor : 4 times
F: Steaming
15 min/102ºC
U-Box-steamer
G: Recipe 5
4 Compartments hot rinse
overflow (counter current if possible)
H: Cylinder-dryer
Fabric
① ② Na2S2O8
NaOH
Modscour-BL
fabric ③ ④ H2O2 fabric
NaOH
Impregnation bath,
4 x wash-off 4 times conc. of U-Box-Steamer
50-60 sec. total feed liquor 15 min/102ºC
fabric ⑤
4 x wash-off
50-60 sec. total cylinder
dryer See recipe 1-5
Continuous-pretreatment- plant
BLEACHING BY PAD-STEAM METHOD
METHOD : ❍ Singeing
❍ Desizing (Enzymatic)
❍ Hydrogen Peroxide treatment(Pad steam)
RECIPE :
❍ DESIZING : Enzyme As per recommendation
Allendet-NI/Altranol-OL 2 g/l
pH As per recommendation
Retention time As per recommendation
❍ WASHING : 90ºC, 95ºC, 95 (3 Compartments)
❍ BLEACHING : - Pick-up 100%
- Water hardness 15º (french hardness)
(=8º German hardness)
That means magnesium chloride is not
necessary.
- Steaming time 25 min. at 102ºC
Recipes
COMPETITORS
❍ 30 ml/l NaOH 36 Bè
❍ 70 ml/l H2O2 35% (= 46 ml/l H2O2 50%)
❍ 8 g/l Stabilizer
❍ 6 g/l Wetting agent
❍ 4 g/l Sequestering agent
❍ 1 g/l Defoamer
MODHERA CHEMICALS PVT. LTD.
RESULTS
DP S Degree of Water
(STN whiteness absorbency
2.075/84)
Grey Fabric 1883 35 /
S= Damage factor
Bleaching by pad steam method
Result
- Desizing = very good
(assessment by TEGEWA Violet = standard: note 9)
- Water absorbency = Penetration 3 sec.
Spreading: Warp 35 mm
Weft 31 mm
- Whiteness = good
- Seed removal = complete
- DP decrease = 6%
- Damage factor = very good, undamaged (Damage factor Eisenhut: 0.04)
Degree of polymerisation:
In continental Europe fluidity is not normally used as an expression of chemical damage but a measure of the degree of
polymerization (DP). It is obtained from the viscosity using a modified Staudinger equation. The development of these
equations and their use is given by O. Deschler (textile-Praxis 1958, 13, p 927)
Damage factor:
The damage factor (S), suggested by O. Eisenhut (Melliand Textilber. 1941,22, p 424) relates damage to the change in DP
and so takes into account high initial DPs.
S=log10 (2000 _ 2000 + 1) log102
Ptx Ptx
Pt = DP before chemical treatment Ptx = DP after chemical treatment 2000 = reference value
The damage factor has been categorized to indicate the degree of damage.
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8 factor comment
----------------------------------------------------------------------------------------------------------
0.01 – 0.2 very good – undamaged
0.21 – 0.3 good – very carefully bleached
0.31 – 0.5 satisfactory
0.5 – 0.75 slightly damaged
0.75 badly damaged
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PEROXIDE BLEACHING - DISCONTINUOUS
Package Yarn (Hanks) Jigger Jet Winch
Liquor ratio 1:8 - 1:10 1:15 1:3 – 1:6 1:8 - 1:10 1:20
Temperature 98 98 98 98
Duration (min) 30-45 60 60 30-45 30-45
Magnesium chloride (g/l) ⇒ water 0.2-0.3 0.2-0.3 0.2-0.3 0.2-0.3 0.2-0.3
hardness 8-12° dH
MODSCOUR-BL (g/l) 0.8-1.5 0.8-1.2 3-5 1.2-1.5 0.4-0.8
ALTRANOL-CD 0.5 ---- ---- ---- ----
Caustic soda flakes (g/l) 1.5-3 1.5-2 4-5 1.5-3 1-1.5
Hydrogen peroxide 35 weight-% (ml/l) 4-8 4-6 10-15 6-8 2-4
The above technical presentation proves MODSCOUR-BL as ECONOMICALLY & ECOLOGICALLY improved
peroxide bleach