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History
Carbon black is one of the oldest manufactured materials. Early uses
can be traced back to ancient China, the early Egyptians and the
production of Indian Inks. Early demand for carbon black was
driven by the invention of movable type used in fifteenth century
printing. The discovery that carbon black reinforces natural rubber
and thereby greatly increasing the longevity of tires in the early
nineteenth century thrust the material into the modern age.
Today carbon black is found in all aspects of modern life. It is used in inkjet printer ink,
as reinforcements for natural and synthetic rubber, it is the active agent in electrically
conductive plastics and is used as a pigment and tinting-aid in paints, coatings, news
paper inks and cosmetics to name a few. Carbon black is ubiquitous.
Production
There are three significant processes for the manufacture of carbon black: the furnace
process, the channel process and the acetylene process. The furnace process is the most
prevalent by far accounting for over 80% of capacity. The products made by each process
have unique characteristics. For example, the acetylene process produces a carbon black
with very low structure (particle complexity) and the particles have higher graphitic
content than those produced by the furnace process. The remainder of this overview will
concentrate on carbon blacks manufactured by the furnace process.
Although there are differences among the processes they all involve combusting a fuel in
a controlled atmosphere environment. In the furnace process “resid” or “decant” oils, low
cut fractions from the oil refining process, are combusted in a controlled atmosphere at
high temperatures. Typical processing temperatures are in the order of 800C to 1200C.
The best way to envision a carbon black reactor is to imagine a very large blow torch in a
ceramic tube with insufficient oxygen to cause combustion. If too much oxygen is present
soot formation takes place.
In the furnace process, fuel is atomized and sent to the reaction chamber where
carbonization starts. Oxygen levels are maintained below the level where soot formation
takes place. The atomized fuel undergoes reaction to eliminate non-carbonaceous
materials and the carbon atoms begin to bond to nearby neighbors within the droplet
starting the solidification process. It is this carbonized droplet that forms the most
fundamental carbon black particle, called the “primary particle.” As the carbonizing fuel
droplet leaves the reaction chamber and progresses down the path of the furnace it may
come in contact with other carbonizing droplets and under the appropriate conditions they
bond to one another to form a carbon black “aggregate.” The carbon black primary
particles fuse to form a coalesced mass. One can view a carbon black aggregate particle
as a “bunch” of grapes. Each individual grape is a primary particle and the “bunch” is the
aggregate particle.
The aggregates travel down the flight of the reactor. During this flight the reaction can be
quenched by water addition or temperature control. Both are used to selectively modify
the surface chemistry, size and complexity of the aggregate particle. After quenching the
particles travel the flight of the reactor where they are captured in bag filters or cyclones
separators. The particles at this stage are referred to as “fluffy” and have very low bulk
density.
Some degree of densification is required to convert the fluffy to a more useable form.
Densification can be achieved though pelletization processes, where the fluffy is mixed
with binders or water under low sheer conditions. Various densification processes are
used in the manufacturing of carbon black pellets and include vacuum rollers, pin
pelletizers and stirred tanks.
Fundamental Properties
The utility and ultimate economic value of carbon black is determined through a complex
mix of carbon chemistry, surface energy and particle physics. The most important
properties include the surface area, primary particle size,
structure (complexity of composition), surface chemistry and
binder chemistries used in the pelletization process. Frequently, tradeoffs and
compromises are made between desired end-use performance and the ability to disperse
carbon black.
Primary Particles: The smallest unit of a carbon black particle, the primary
particle, has dimensions of size, graphitic content, shape and crytallinity.
Although the majority of processes manufacture near-spherical shaped primary
particles some processes produce primary particles having aspect ratios higher
than those of true spheres. The higher aspect ratio leads to higher surface area per
unit volume and provides more wetable surface area improving ease of dispersion
and increasing electrical conductivity. Primary particle attributes influence color,
electrical conductivity and UV blocking performance of the carbon black.
The ability to break up the agglomerates into the constituent aggregates and
achieve adequate dispersion is critical to achieving desirable end-use performance
in many applications. A significant body of literature has been developed on the
science surrounding dispersion of carbon black in various medium, however, for
industrial applications dispersion remains an art with experience practitioners
having the advantage of know how, technique and trade secrets.
Color Properties
Owing to the variety of shape and size, carbon black can exhibit a range of color
properties. Important color properties include jetness, mass tone and tinting strength. The
delicate interaction between primary particle size, surface area and aggregate size
determines the ultimate color, whereas, structure influences the dispersability of carbon
black and thus determines the level of color achievable in the
host matrix. Carbon black is added to plastics not only to
make plastics black but also to change the tint characteristics of other colors.
Color properties of carbon black are measured using colorimeters and have values of L,
a*, b*. Typically, carbon black is compounded into the host plastic matrix at
concentrations near 1-2% and the color values measured on a molded plack specimen.
The L value (white = 100, black = 0) measures color density, the b* value is indicative of
the yellow/blue balance (positive values indicate yellow and negative values indicate
blue) and the a* value is reflective of the red/green balance (positive values indicating red
and negative values indicating green.)
The “L” value can be correlated to the ratio of particle size to surface area and is a useful
tool for comparing competitive grades of carbon black. The b* is indicative of jetness and
correlated to the L value.
Masstone. When compounded into plastics carbon black can impart colors
ranging from a bluish black to a brown/black undertone. This color range is
referred to as the masstone of the black and is strongly correlated to particle size
and the scattering of light in the host plastic matrix. Owing to differences in
refractive index and light scattering for different plastics two different plastics
containing well-dispersed carbon black can have the same jetness but differ
greatly in masstone.
Tinting Strength. An important property of carbon black is
its ability to modify the visual appearance of other colors. The tinting strength is a
measure of the effectiveness of the carbon black. There are a variety of methods
used in measuring tinting strength but the most prevalent is ASTM D 3265. In this
method, carbon black is added to a mixture of zinc oxide in dispersion medium
(soy oil for example) and the reflectance values are measured relative to the zinc
oxide standard. Tinting strength increases with decreasing primary particle size
and decreases with aggregate structure complexity. Tinting strength reaches a
maximum for primary particle sizes of less than 20nm.
Characterization Methods
Carbon black manufactured by commercial processes is a complex mixture of particles.
Industrial grades of carbon black exhibit a distribution of aggregate sizes and shapes,
each aggregate comprised of a distribution of different size and shaped primary particles.
Consequently, property measurements of carbon black are a statistical average around a
mean value of the bulk sample.
Surface area and structure are the key properties that influence the utility and value of
carbon black in many applications. For example, surface area influences the ability of
carbon black to absorb UV radiation. Structure influences the ease or difficulty of
dispersion and electrical conductivity properties. It is the balance of surface area and
structure that determines the utility of the particular grade of carbon black.
Iodine Number. In the manufacturing environment, where the target carbon black
grade properties are known, the Iodine method (ASTM D 1510) is used to
measure surface area. The method is useful for quality control but is influenced by
active surface chemistry, unreacted feedstock, oils and binders. The reported
iodine number should not be used as a guide for grade selection when developing
a plastic compound or end use article.
DBP Method. The most frequently used method of characterizing the structure of
carbon black is the adsorption of dibutylpthlate, DBP (ASTM 2414-90.) The
method is based on measuring the torque of carbon black powder as DBP is
added. At the point of full absorption, correlating to full surface area coverage, the
mixture reaches a plasticization state and the torque rises quickly at this point the
level of DBP added is recorded. Higher levels of DBP addition correlate to higher
structure.
The method (ASTM D 3493) involves subjecting the carbon black to several
cycles of high pressure, typically 165MPa, before conducting the DBP
measurement. The high pressure serves to break agglomerates and separate the
particles captured in the occluded volumes of larger aggregates.